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At least 199 records · Page 11

Sulfate reduction accelerates groundwater arsenic contamination even in aquifers with abundant iron oxides

Groundwater contamination by geogenic arsenic is a global problem affecting nearly 200 million people. In South and Southeast Asia, a cost-effective mitigation strategy is to use oxidized low-arsenic aquifers rather than reduced high-arsenic aquifers. Aquifers with abundant oxidized iron minerals are presumably safeguarded against immediate arsenic contamination, due to strong sorption of arsenic onto iron minerals. However, preferential pumping of low-arsenic aquifers can destabilize the boundaries between these aquifers, pulling high-arsenic water into low-arsenic aquifers. We investigate this scenario in a hybrid field-column experiment in Bangladesh where naturally high-arsenic groundwater is pumped through sediment cores from a low-arsenic aquifer, and detailed aqueous and solid-phase measurements are used to constrain reactive transport modelling. Here we show that elevated groundwater arsenic concentrations are induced by sulfate reduction and the predicted formation of highly mobile, poorly sorbing thioarsenic species. Furthermore, this process suggests that contamination of currently pristine aquifers with arsenic can occur up to over 1.5 times faster than previously thought, leading to a deterioration of urgently needed water resources.

54 ENVIRONMENTAL SCIENCES↗

Fitness factors impacting survival of a subsurface bacterium in contaminated groundwater

Many factors contribute to the ability of a microbial species to persist when encountering complexly contaminated environments, including time of exposure, the nature and concentration of contaminants, availability of nutritional resources, and possession of a combination of appropriate molecular mechanisms needed for survival. Herein we sought to identify genes that are most important for survival of Gram-negative Enterobacteriaceae in contaminated groundwater environments containing high concentrations of nitrate and metals using the metal-tolerant Oak Ridge Reservation isolate, Pantoea sp. MT58 (MT58). Survival fitness experiments in which a randomly barcoded transposon insertion (RB-TnSeq) library of MT58 was exposed directly to contaminated Oak Ridge Reservation groundwater samples from across a nitrate and mixed metal contamination plume were used to identify genes important for survival with increasing exposure times and concentrations of contaminants, and availability of a carbon source. Genes involved in controlling and using carbon, encoding transcriptional regulators, and related to Gram-negative outer membrane processes were among those found to be important for survival in contaminated Oak Ridge Reservation groundwater. A comparative genomics analysis of 75 Pantoea genus strains allowed us to further separate the survival determinants into core and non-core genes in the Pantoea pangenome, revealing insights into the survival of subsurface microorganisms during contaminant plume intrusion.

59 BASIC BIOLOGICAL SCIENCES↗

Optimized Machine Learning Model for Predicting Groundwater Contamination

The use of physical models to predict groundwater contaminant movement remains technically challenging due to the complexity of the phenomena, the heterogeneity of key parameters in nature, and the presence of poorly defined interactive and feedback processes. New approaches to address these challenges are needed. In this study, we evaluate various Artificial Intelligence (AI)-based approaches to understand a hexavalent chromium (Cr(VI)) plumes located on the U.S. Department of Energy’s (DOE) Hanford Site in Richland, WA. The groundwater monitoring dataset used in this study included data from the 100 Area along the Columbia River and included data collected between 2010 to 2019. This study investigates the most prominent contaminant, Cr(VI), with the Extreme Gradient Boosting (XGBoost) machine learning model. The XGBoost models were compared with optimized versions using an Empirical Bayes Search Cross-Validation technique for better prediction. The optimized XGBoost model yielded an R^2 value of 0.99 on the training set and 0.85 on the testing set, whereas XGBoost without optimization yielded a value of 0.83 on the training set and 0.85 on the testing set. This paper provides an overview of a computational method for groundwater contamination modeling that shows promise for improving current remediation efforts.

Mazumdar, Hirak↗

Hydrologic windows into the crystalline basement and their controls on groundwater flow patterns across the Paradox Basin, western USA

Conceptual models of sedimentary basin groundwater flow systems typically assume that the crystalline basement acts as an impermeable boundary and can be neglected. In this study, we use hydrologic models constrained by isotopic and geochemical datasets to argue that the La Sal Mountains, Utah, USA, act as a hydrologic window into the Paradox Basin’s lower aquifer system and underlying crystalline basement. We conducted a sensitivity study in which we varied crystalline basement/laccolith permeability as well as fault zone connectivity along a cross-sectional transect from the La Sal Mountains to Lisbon Valley. When the crystalline basement/laccolith units are set at relatively permeable levels (10–14 m 2 ), simulated tracers that include total dissolved solids, oxygen isotopic composition of pore fluids (δ 18 O), and groundwater residence times are in closest agreement with field measurements. Model results indicate that pore fluids in the basal aquifer system underlying the Paradox Formation confining unit are a mixture of relatively young meteoric fluids and older Paradox Formation brines. The presence of faults did not significantly modify fluid exchange between the upper and lower aquifer systems. This was due, in part, to underpressuring within the Paradox Formation. Our study concludes that the Paradox Basin represents a regional recharge area for the Colorado Plateau, with groundwater discharge occurring along the Colorado River within the Grand Canyon some 375 km away to the southwest. This is only possible with a permeable crystalline basement. Our findings help explain the genesis of Mississippi Valley-type ore deposits of the US Midcontinent, where the presence of a permeable basement may be useful in addressing issues related to solute mass and energy balance.

54 ENVIRONMENTAL SCIENCES↗

Impact of Lateral Groundwater Flow and Subsurface Lower Boundary Conditions on Atmospheric Boundary Layer Development over Complex Terrain

Credible soil moisture redistribution schemes are essential to meteorological models, as lower boundary moisture influences the balance of surface turbulent fluxes and atmospheric boundary layer (ABL) development. While land surface models (LSMs) have vastly improved in their hydrologic representation, several commonly held assumptions, such as free-draining lower boundary, one-dimensional moisture flux, and lack of groundwater representation, can bias the terrestrial water balance. This study explores the impact of LSM hydrology representation on ABL development in the Weather Research and Forecasting (WRF) meteorological model. The results of summertime WRF simulations with Noah LSM, characterized by 2-m-thick soil and one-dimensional flow, are shown for a domain in the Colorado Rocky Mountain headwaters region. A reference WRF simulation is compared to 1) the same model with soil moisture initialized by the hydrologic model ParFlow; 2) a deep, free-draining simulation; and 3) WRF coupled to ParFlow, a three-dimensional, integrated groundwater-surface water model. Results show that both lateral transport of groundwater and the rate of drainage from the lower soil layer can weaken or reverse the coupling strength between evaporative fraction and ABL over a 5-month summer period. The resulting shifts in low-level moist convection in river valleys and thermally driven airflows yield strengthened anabatic upslope winds and perturbations to regional precipitation.

Forrester, Mary M.↗

Hyporheic zone, river, and groundwater metagenome resolved genomes and rpS3 genes in East River Watershed, Colorado USA Summer 2020, 2021

Here we present metagenome assembled genomes (MAGs) for the bacterial and archaeal communities from water filter collected across 8 locations along the East River Watershed, CO, and 1 nearby groundwater well. The purpose was to look for connectivity and similarities across the network and to see the impact of the groundwater. As a part of Lawrence Berkeley National Laboratory (LBNL) Watershed Science Focus Area (SFA), we assessed community composition and strain similarities between the sites and we also compared it to previous metagenomic studies within the watershed looking at floodplain (Matheus Carnevali et al. 2021) and hillslope (Lavy et al. 2019) microbiomes. Here we present metagenome assembled genomes (MAGs) for the bacterial and archaeal communities from filters across 8 locations during August 2020 and July 2021. This resulted in 32 samples. The groundwater sample was sequenced at UC Berkley's QB3. The other 31 samples were sequenced at University of Maryland. Metagenomes were assembled using four autobinners and the best bins were selected using dasTool. The genomes were dereplicated at 95% with dRep and the subset of winning genomes were manually curated based on visual inspection of taxonomic profile, GC content, coverage, and a set of 51 bacterial single copy genes (BSCG), and 38 archaeal signal copy genes (ASCG). The dataset includes a zip file of 311 genomes (HZ_River_SW_MAGS_Dereplicated_95.zip). The dataset additionally includes a zipped file of ribosomal protein small subunit 3 (rpS3) proteins from the hyporheic zone and river data (rpS3_Proteins_HZ_River.zip), a metadata file used to register associated samples with IGSNs (International Generic Sample Numbers) (samples.csv), a location metadata file (locations.csv). This work was supported by the Watershed Function Science Focus Area at Lawrence Berkeley National Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-05CH11231.

DNA↗

Evaluation of Dose- and Risk-Based Groundwater Cleanup Levels for Low Energy Beta Radioisotopes

Low-energy beta-emitting radionuclides that were released historically during reactor operations and plutonium separations activities at some U.S. Department of Energy sites have migrated into the groundwater, forming contaminant plumes that are subject to federally regulated remediation actions. At the Hanford Site, the low-energy beta-emitting radionuclides include iodine-129, technetium-99, chlorine-36, carbon-14, and tritium (H-3). All are highly mobile in the subsurface, and except for tritium, and have very long half-lives—thousands to millions of years. The geochemistry and transport behavior of these contaminants in the subsurface present significant challenges for remediation of groundwater to federal drinking water standards (DWS)—the appropriate or relevant and applicable requirements (ARARs) for cleanup. For some of the low-energy beta-emitter contaminants, particularly iodine-129, cleanup and restoration of groundwater to DWS may not be attainable within a reasonable timeframe using currently available treatment technologies.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Y-12 Groundwater Protection Program Data Management Plan

This Data Management Plan (DMP) describes the processes in place to ensure the integrity of groundwater monitoring information collected by the U.S. Department of Energy (DOE), National Nuclear Security Administration (NNSA), Y-12 National Security Complex (Y-12), Groundwater Protection Program (GWPP). This information includes program plans, reports, and computer systems used to capture monitoring station information and analytical data. The primary computer system used by the GWPP is the Groundwater Information Management System (GIMS). Procedures used to ensure the integrity of the data are included in this document by reference.

54 ENVIRONMENTAL SCIENCES↗

Adaptive Site Management Strategies for the Hanford Central Plateau Groundwater

Adaptive site management (ASM) is a systematic and iterative management approach that can be used to expedite the remediation of large and/or complex sites. ASM is defined as a formal and systematic project or site management approach centered on rigorous site planning and a firm understanding of site conditions and uncertainties, using science and technology to routinely re-evaluate and prioritize site remedial actions and characterization activities. The goal of the approach is to create a framework of structured and continuous planning, implementation, and assessment processes that accommodates new information and changing site conditions to develop effective and efficient cleanup approaches that achieves the required outcome(s) while optimizing costs, cleanup timeframe, and performance. Central to ASM is an evolving conceptual site model (CSM). Over time, incremental reductions in uncertainty associated with the CSM will occur, while supporting continued progress toward site cleanup and closure through remedy optimization and evaluation. ASM has the potential to expedite cleanup for the Central Plateau area at Hanford through a planned and systematic approach for reducing uncertainty with targeted characterization activities, while continuing remediation activities that advance cleanup for key risk-driving contaminants. A core component of cleanup within the Central Plateau is the 200 West Pump-and-Treat (P&T) system. Even with an active P&T remedy, uncertainty exists with respect to plume distributions, total mass in the aquifer, and currently known continuing sources. Additional uncertainty is associated with multiple contaminant source locations in the vadose zone, which have the potential to create new groundwater plumes in the absence of any source control measures, although not all contaminant fluxes to groundwater will result in contaminant concentrations above cleanup levels. Collectively, these uncertainties need to be addressed in the CSM to support effective and efficient site progress toward cleanup goal(s). Other nontechnical factors that may warrant an ASM approach at the Hanford Central Plateau are associated with the formation of operable units (OUs) used to manage cleanup. With the exception of the 200-ZP-1 OU, the three remaining groundwater OUs only have interim action records of decision. Nine vadose zone source area OUs are also in the early stages of the remedial investigation and feasibility study process, with pending characterization and technology identification activities. A set of proposed site objectives for the Central Plateau are provided in this document as an initial consideration/example and basis for discussion for ASM implementation. These example site objectives were selected with the goal of maintaining protectiveness at the Columbia River through confinement of contaminant plumes within an administratively controlled area below existing surface waste sites and waste disposal facilities. Although site decision makers and regulators need to provide concurrence, these site objectives are used in this document to describe the elements of an ASM approach, including selection of interim objectives and a long-term adaptive management plan. Interim objectives are also defined to yield measurable incremental progress toward the overall site goals. This document identifies initial technical considerations for developing an ASM framework for the Central Plateau cleanup decisions. These considerations are intended to facilitate more specific decisions, such as objectives, near- and long-term actions, and performance metrics, to develop an overall approach that maintains protectiveness but recognizes the uncertainty, long timeframe, and technical challenges that need to be considered in selecting, implementing, and managing remediation at the Hanford Central Plateau.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Hydrologic Data for the Groundwater Flow and Contaminant Transport Model of Corrective Action Units 101 and 102: Central and Western Pahute Mesa, Nye County, Nevada, Revision 1

This hydrologic data document (HDD) has been prepared for Corrective Action Units (CAUs) 101 and 102, Central and Western Pahute Mesa, in order to support the development of a groundwater flow and contaminant transport model. Central and Western Pahute Mesa are two of the five CAUs on the Nevada National Security Site (NNSS) (formerly the Nevada Test Site [NTS]) used for underground nuclear testing (Figure 1-1). The nuclear tests resulted in groundwater contamination in the vicinity of the underground test areas. As a result, the U.S. Department of Energy (DOE), Environmental Management (EM) Nevada Program is currently conducting a corrective action investigation (CAI) of the Pahute Mesa underground test areas. This work is a part of the Underground Test Area (UGTA) Activity in accordance with the Federal Facility Agreement and Consent Order (FFACO) (1996, as amended). The CAU groundwater flow and transport model is composed of two pieces, a flow model and a transport model, that together provide the contaminant boundary forecasts required by the FFACO. The hydrologic data necessary for the flow model portion of the CAU model are presented in this report. The transport data necessary for the transport model portion of the CAU model will be provided in a separate report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

NAWI Research Spotlight: Technoeconomic Assessment of Brine Valorization from Brackish Groundwater

This NAWI Research Spotlight Webinar was presented to the NAWI Alliance on June 27, 2024. The presentation describes project progress to date on a technoeconomic assessment of brine valorization from brackish groundwater. Desalination at inland brackish groundwater treatment plants is currently limited by high costs of concentrate management and disposal. With current methods, 5-25% of the feed is disposed of as concentrate, with 98% of disposal using conventional methods (i.e. no byproduct recovery). This project aims to assess the technical and economic feasibility of industrial ecosystems to desalinate brackish groundwater and supply existing and potential markets for clean concentrate or other bulk constituents from the brine.

Fritz, Alison↗

Building 100 Groundwater Bioremediation at the Former DOE Pinellas Plant, Florida: Review of Progress and Opportunities

Weapons research, development, and production operations at the former Pinellas Plant, which includes the Building 100 area, released chlorinated organic solvents into the subsurface, contaminating the underlying soil and groundwater. The site was sold to Pinellas County and is now home to a thriving industrial park known as the Young - Rainey Science, Technology, and Research (STAR) Center. The US Department of Energy (DOE) has applied bioremediation at the Building 100 Area as a key technology to clean up the chlorinated volatile organic compound (cVOC) contamination in soil and groundwater. The monitoring data indicate significant progress toward remedial objectives over the past two decades. Starting conditions in the 1980s-1990s included areas containing residual undissolved dense nonaqueous phase liquids (DNAPLs) and the associated presence of an extensive high concentration plume in the groundwater. The original parent cVOCs were primarily tetrachloroethene (PCE) and trichloroethene (TCE). After several informative pilot studies, bioremediation was implemented at the Building 100 Area of the site and relies on reductive biological pathways and the sequential removal of chlorine from the parent cVOCs forming dichloroethane (DCE) and chloroethene (vinyl chloride, VC). As bioremediation sites evolve toward cleanup, the trends in VC concentrations often serve as a critical indicator for progress and remediation timeframe because VC typically has a lower concentration target remedial objective (nominally 1 to 2 μg/L) compared to PCE and TCE (nominally 3 to 5 μg/L).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Groundwater sapping valleys: Experimental studies, geological controls and implications to the interpretation of valley networks on Mars

An integrated approach using experimental laboratory models, field studies of terrestrial analogs, and remote studies of terrestrial field sites were applied to the goals of understanding the nature and morphology of valley networks formed by groundwater sapping. In spite of problems with scaling, the experimental studies provide valuable insights into concepts relating to the initiation, development, and evolution of valleys by groundwater sapping. These investigations are also aimed at developing geomorphic criteria for distinguishing valleys formed by surface runoff from those formed by groundwater sapping processes. Channels that were field classified as sapping vs. runoff were successfully distinguished using statistical analysis of their respective morphologies; therefore, it may be possible to use similar techniques to interpret channel genesis on Mars. The terrestrial and flume studies provide the ground truth dataset which can be used (and will be during the present year) to help interpret the genesis of valley networks on Mars.

Kochel, R. Craig↗

Role of artesian groundwater in forming Martian permafrost features

Various landforms possibly related to formation (growth), movement, or decay of ground ice have been identified on Mars, including fretted terrain (ft) and associated lobate debris aprons (lda), the chaotic terrain, concentric crater fills (ccf), polygonal ground, softened terrain, small domes that are possibly pingos, and curvilinear (fingerprint) features (cuf). Glaciers may also have been present. Some of these may involve ice derived from artesian groundwater. Topical areas of discussion are: Mars groundwater and the location of permafrost features; the ft, lda, ccf, and cuf; role of artesian groundwater in formation of fretted terrain, lobate debris blankets, and concentric crater fills; sources of glacial ice; and pingos and other pseudovolcanic structures.

Howard, Alan D.↗

Karst Groundwater Hydrologic Analyses Based on Aerial Thermography

On February 23, 1999, thermal imagery of Marshall Space Flight Center, Alabama was collected using an airborne thermal camera. Ground resolution was I in. Approximately 40 km 2 of thermal imagery in and around Marshall Space Flight Center (MSFC) was analyzed to determine the location of springs for groundwater monitoring. Subsequently, forty-five springs were located ranging in flow from a few ml/sec to approximately 280 liter/sec. Groundwater temperatures are usually near the mean annual surface air temperature. On thermography collected during the winter, springs show up as very warm spots. Many of the new springs were submerged in lakes, streams, or swamps; consequently, flow measurements were difficult. Without estimates of discharge, the impacts of contaminated discharge on surface streams would be difficult to evaluate. An approach to obtaining an estimate was developed using the Environmental Protection Agency (EPA) Cornell Mixing Zone Expert System (CORMIX). The thermography was queried to obtain a temperature profile down the center of the surface plume. The spring discharge was modeled with CORMIX, and the flow adjusted until the surface temperature profile was matched. The presence of volatile compounds in some of the new springs also allowed MSFC to unravel the natural system of solution cavities of the karst aquifer. Sampling results also showed that two springs on either side of a large creek had the same water source so that groundwater was able to pass beneath the creek.

Campbell, C. Warren↗

Soil, Groundwater, Surface Water, and Sediments of Kennedy Space Center, Florida: Background Chemical and Physical Characteristics

This study documented background chemical composition of soils, groundwater, surface; water, and sediments of Kennedy Space Center. Two hundred soil samples were collected, 20 each in 10 soil classes. Fifty-one groundwater wells were installed in 4 subaquifers of the Surficial Aquifer and sampled; there were 24 shallow, 16 intermediate, and 11 deep wells. Forty surface water and sediment samples were collected in major watershed basins. All samples were away from sites of known contamination. Samples were analyzed for organochlorine pesticides, aroclors, chlorinated herbicides, polycyclic aromatic hydrocarbons (PAH), total metals, and other parameters. All aroclors (6) were below detection in all media. Some organochlorine pesticides were detected at very low frequencies in soil, sediment, and surface water. Chlorinated herbicides were detected at very low frequencies in soil and sediments. PAH occurred in low frequencies in soiL, shallow groundwater, surface water, and sediments. Concentrations of some metals differed among soil classes, with subaquifers and depths, and among watershed basins for surface water but not sediments. Most of the variation in metal concentrations was natural, but agriculture had increased Cr, Cu, Mn, and Zn.

Shmalzer, Paul A.↗

Groundwater and Terrestrial Water Storage

Groundwater is a vital resource and also a dynamic component of the water cycle. Unconfined aquifer storage is less responsive to short term weather conditions than the near surface terrestrial water storage (TWS) components (soil moisture, surface water, and snow). However, save for the permanently frozen regions, it typically exhibits a larger range of variability over multi-annual periods than the other components. Groundwater is poorly monitored at the global scale, but terrestrial water storage (TWS) change data from the Gravity Recovery and Climate Experiment (GRACE) satellite mission are a reasonable proxy for unconfined groundwater at climatic scales.

Rodell, Matthew↗

Groundwater and Terrestrial Water Storage

Groundwater, soil moisture, surface water, snow, and ice are the components of terrestrial water storage (TWS). On multi-annual timescales groundwater typically controls TWS variability, except in permanently frozen regions (Li et al. 2015). Even on an annual basis TWS changes are a reasonable proxy for groundwater storage changes, the latter being insufficiently observed in most of the world. From 2002 to 2017 the Gravity Recovery and Climate Experiment (GRACE; Tapley et al. 2004) and since 2018 the GRACE Follow On (GRACE-FO) satellite missions have enabled estimation of TWS anomalies (departures from the long-term mean) based on precise observations of variations in Earth’s gravity field. To bridge the 11-month gap between GRACE and GRACE-FO we make use of output from a land surface model that assimilates data from both missions (Li et al. 2019)

Matthew Rodell↗