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At least 199 records · Page 11

Processing Science and Technology

The heat capacity at constant pressure,Cp, of poly-p-xylylene (PPX) was measured from 220 to 625 degrees K using differential scanning calorimetry. The heat capacities at constant volume, Cv, of both PPX and its isomer polystyrene (PS were interpreted using literature data on full normal mode calculations for PS and estimates from low molecular weight analogues for PPX for the 39 group vibrations. Nine skeletal vibrations were used with theta sub 1 and theta sub 3 temperatures of 534.5 degrees K and 43.1 degrees K for PS. It was also possible to calculate a heat capacity contribution of a phenylene group within a polymer chain. Single 48-vibration theta sub 1 temperatures of 3230 degrees K for PS and 2960 degrees K for PPX are sufficient to describe Cv above 220 degrees K. Below 140 deg K, PS heat capacity shows deviations from the Tarasov treatment.

Source record↗

High temperature polymers - A review of novel thermally stable hexafluoroisopropylidene-containing polymers

The synthesis and properties to date of several novel HFIP-containing polymers and copolymers are presented. Thermal analyses of polyether ketones (PEK), aromatic polyesters, and polymers from a novel 18F-diacid were performed on a thermal analyzer. All three polymer types exhibited enhanced solubility, thermal stability, and low dielectric constants that are predicted for polymers containing the HFIP moiety. The moderate thermal stability observed in the polymers derived from the 18F-diacid is attributed to the oxidatively weak methylene linkage between the HFIP groups and the phenyl rings. PEKs and polyarylates show potential as high emissivity coatings under conditions where atomic oxygen is present.

Kane, K. M.↗

Tests of a simple data merging algorithm for the GONG project

The GONG (Global Oscillation Network Group) project proposes to reduce the impact of diurnal variations on helioseismic measurements by making long-term observations of solar images from six sites placed around the globe. The sun will be observed nearly constantly for three years, resulting in the acquisition of l+ terabyte of image data. To use the solar network to maximum advantage, the images from the sites must be combined into a single time series to determine mode frequencies, amplitudes, and line widths. Initial versions of combined, i.e., merged, time series were made using a simple weighted average of data from different sites taken simultaneously. In order to accurately assess the impact of the data merge on the helioseismic measurements, a set of artificial solar disk images was made using a standard solar model and containing a well known set of oscillation modes and frequencies. This undegraded data set and data products computed from it were used to judge the relative merits of various data merging schemes. The artificial solar disk images were subjected to various instrumental and atmospheric degradations, dependent on site and time, in order to create a set of images simulating those likely to be taken at the site. The degraded artificial solar disk images for the six observing sites were combined in various ways to form merged time series of images and mode coefficients. Various forms of a weighted average were used, including an equally-weighted average, an average with weights dependent upon air mass and averages with weights dependent on various quality assurance parameters. Both the undegraded solar disk image time series and several time series made up of various combinations of the degraded solar disk images from the six sites were subjected to standard helioseismic measurement processing. This processing consisted of coordinate remapping, detrending, spherical harmonic transformation, computation of power series for the oscillation mode coefficients, and mode frequency identification. Visual and statistical evaluation of the merged data sets themselves and differences between the merged and undegraded data set shows good agreement between the two data sets. Some slight differences in image scale and registration appear between the undegraded data set and the various merged data sets. In the set of power series made from the mode coefficients of the merged data sets, some power leakage is observed into the background and into slightly lower l-value modes, especially at higher l-value mode frequencies. The results of the comparison of time series and mode oscillation frequencies of the undegraded data with those of the data merged using weighted averages indicate that, at least for p-mode solar oscillations, a weighted average of either the detrended remapped images or the mode coefficients gives good determination of the mode frequencies and adequate-to-good determination of the amplitudes and widths of the mode frequency lines. This conclusion is most advantageous to the analysis of the massive amounts of data to be received by the GONG network.

Williams, W. E.↗

New Cepheid distances to nearby galaxies based on BVRI CCD photometry. II - The local group galaxy M33

A true distance modulus to the nearby spiral galaxy M33 has been determined based on CCD photometry obtained at BVRI wavelengths. M33 is presently one of five nearby galaxies used in the calibration of the IR Tully-Fisher relation, and thereby in the determination of the Hubble constant. Using period-luminosity relations at several wavelengths offers the advantage that the distance moduli derived can be corrected for the effects of interstellar extinction. These data indicate that there is internal reddening affecting the Cepheid photometry in M33 which must be accounted for if a true distance modulus is to be obtained for this galaxy. Adopting a true distance modulus to the LMC of 18.5 mag, the new CCD data yield a true distance to M33 of 24.64 + or - 0.09 mag, corresponding to a linear distance of 840 kpc. A mean value of the total color excess (foreground and internal) for the Cepheids in M33 is estimated to be E(B - V) = 0.10 + or - 0.09 mag, assuming a value for the total mean LMC Cepheid color excess of 0.10 mag.

Freedman, Wendy L.↗

Large steric effect in the substitution reaction of amines with phosphoimidazolide-activated nucleosides

Aliphatic amines react with phosphoimidazolide-activated derivatives of guanosine and cytidine (ImpN) by replacing the imidazole group. The kinetics of reaction of guanosine 5'-phospho-2-methylimidazolide (2-MeImpG) with glycine ethyl ester, glycinamide, 2-methoxyethylamine, n-butylamine, morpholine, dimethylamine (Me2NH), ethylmethylamine (EtNHMe), diethylamine (Et2NH), pyrrolidine, and piperidine were determined in water at 37 degrees C. With primary amines, a plot of the logarithm of the rate constant for attack by the amine on the protonated substrate, log kSH(A), versus the pKa of the amine exhibits a good linear correlation with a Bronsted slope, beta nuc = 0.48. Most of the secondary amines tested react with slightly higher reactivity than primary amines of similar pKa. Interestingly, some secondary amines show substantially lower reactivity than might be expected: EtNHMe reacts about eight times, and Et2NH at least 100 times, more slowly than Me2NH although all three amines are of similar basicity. For comparison, the kinetics of reaction of guanosine 5'-phosphoimidazolide (ImpG) and cytidine 5'-phosphoimidazolide (ImpC) were determined with Me2NH, EtNHMe, and Et2NH, and similar results were obtained. These results establish that the increased steric hindrance observed with the successive addition of ethyl groups are not due to any special steric requirements imposed by the guanosine or the methyl on the 2-methylimidazole leaving group of 2-MeImpG. It is concluded that addition of ethyl and, perhaps, groups larger than ethyl dramatically increases the kinetic barrier for addition of aliphatic secondary amines to the P-N bond of ImpN. This study supports the observation that the primary amino groups on the natural polyamines are at least 2 orders of magnitude more reactive than the secondary amino groups in the reaction with ImpN.

Non-NASA Center↗

Regular and Chaotic Quantum Dynamics of Two-Level Atoms in a Selfconsistent Radiation Field

Dynamics of two-level atoms interacting with their own radiation field in a single-mode high-quality resonator is considered. The dynamical system consists of two second-order differential equations, one for the atomic SU(2) dynamical-group parameter and another for the field strength. With the help of the maximal Lyapunov exponent for this set, we numerically investigate transitions from regularity to deterministic quantum chaos in such a simple model. Increasing the collective coupling constant b is identical with 8(pi)N(sub 0)(d(exp 2))/hw, we observed for initially unexcited atoms a usual sharp transition to chaos at b(sub c) approx. equal to 1. If we take the dimensionless individual Rabi frequency a = Omega/2w as a control parameter, then a sequence of order-to-chaos transitions has been observed starting with the critical value a(sub c) approx. equal to 0.25 at the same initial conditions.

Konkov, L. E.↗

MISTE flight experiment status

The MISTE flight experiment has made significant scientific and technical progress in preparing for a future microgravity flight. We are collaborating with several theoretical modeling groups that have developed crossover (equation-of-state) models for predicting thermodynamic behavior near the liquid-gas critical point. Several of these models have already been used to test experimental measurements of the heat capacity at constant volume, isothermal susceptibility, and coexistence curve in the crossover region near the 3He liquid-gas critical point. A brief description of these models and a representative fit to experimental data will be presented. In collaboration with Mission Research Corporation, MISTE has been testing a new small pneumatic valve for use at low temperatures. The results of recent successful low temperature actuation tests will also be discussed.

critical phenomena liquid-gas critical point↗

Resistance exercise countermeasures for space flight: implications of training specificity

While resistance exercise should be a logical choice for prevention of strength loss during unloading, the principle of training specificity cannot be overlooked. Our purpose was to explore training specificity in describing the effect of our constant load exercise countermeasure on isokinetic strength performance. Twelve healthy men (mean +/- SD: 28.0 +/- 5.2 years, 179.4 +/- 3.9 cm, 77.5 +/- 13.6 kg) were randomly assigned to no exercise or resistance exercise (REX) during 14 days of bed rest. REX performed five sets of leg press exercise to volitional fatigue (6-10 repetitions) every other day. Unilateral isokinetic concentric-eccentric knee extension testing performed before and on day 15 prior to reambulation included torque-velocity and power-velocity relationships at four velocities (0.52, 1.75, 2.97, and 4.19 rad s-1), torque-position relationship, and contractile work capacity (10 repetitions at 1.05 rad s-1). Two (group) x 2 (time) ANOVA revealed no group x time interactions; thus, groups were combined. Across velocities, angle-specific torque fell 18% and average power fell 20% (p < 0.05). No velocity x time or mode (concentric/eccentric) x time interactions were noted. Torque x position decreased on average 24% (p < 0.05). Total contractile work dropped 27% (p < 0.05). Results indicate bed rest induces rapid and marked reductions in strength and our constant load resistance training protocol did not prevent isokinetic strength losses. Differences between closed-chain training and open-chain testing may explain the lack of protection.

Randomized Controlled Trial↗

Two-electron bond-orbital model. I

The one-electron bond-orbital model of Harrison (1973) for tetrahedrally coordinated solids is modified to a two-electron model using a generalization of Falicov and Harris' (1969) method for treating the hydrogen molecule. Expressions for nuclear-exchange and pseudodipolar interactions are obtained in terms of bond-orbital model parameters. The eigenfunctions and eigenvalues of the Hamiltonian are employed along with standard perturbation theory to calculate the energy shifts resulting from the application of an external electric field and induced by the magnetic interaction between the nuclear spins and the bond-electron spins. The quantitative predictions of the derived formulas are examined for real semiconductors involving elements and compounds from periodic groups III, IV, and V. It is concluded that the present two-electron model makes it possible to assess the quantitative effects of electron correlation in the anion-cation bond for both nonmagnetic properties (electric susceptibility, dielectric constant) and magnetic properties (nuclear-exchange and pseudodipolar interactions) of various materials.

Huang, C.↗

Fatigue Life Methodology for Tapered Composite Flexbeam Laminates

The viability of a method for determining the fatigue life of composite rotor hub flexbeam laminates using delamination fatigue characterization data and a geometric non-linear finite element (FE) analysis was studied. Combined tension and bending loading was applied to non-linear tapered flexbeam laminates with internal ply drops. These laminates, consisting of coupon specimens cut from a full-size S2/E7T1 glass-epoxy flexbeam were tested in a hydraulic load frame under combined axial-tension and transverse cyclic bending. The magnitude of the axial load remained constant and the direction of the load rotated with the specimen as the cyclic bending load was applied. The first delamination damage observed in the specimens occurred at the area around the tip of the outermost ply-drop group. Subsequently, unstable delamination occurred by complete delamination along the length of the specimen. Continued cycling resulted in multiple delaminations. A 2D finite element model of the flexbeam was developed and a geometrically non-linear analysis was performed. The global responses of the model and test specimens agreed very well in terms of the transverse displacement. The FE model was used to calculate strain energy release rates (G) for delaminations initiating at the tip of the outer ply-drop area and growing toward the thick or thin regions of the flexbeam, as was observed in the specimens. The delamination growth toward the thick region was primarily mode 2, whereas delamination growth toward the thin region was almost completely mode 1. Material characterization data from cyclic double-cantilevered beam tests was used with the peak calculated G values to generate a curve predicting fatigue failure by unstable delamination as a function of the number of loading cycles. The calculated fatigue lives compared well with the test data.

Murri, Gretchen B.↗

Fatigue Life Methodology for Tapered Composite Flexbeam Laminates

The viability of a method for determining the fatigue life of composite rotor hub flexbeam laminates using delamination fatigue characterization data and a geometric non-linear finite element (FE) analysis was studied. Combined tension and bending loading was applied to nonlinear tapered flexbeam laminates with internal ply drops. These laminates, consisting of coupon specimens cut from a full-size S2/E7T1 glass-epoxy flexbeam were tested in a hydraulic load frame under combined axial-tension and transverse cyclic bending loads. The magnitude of the axial load remained constant and the direction of the load rotated with the specimen as the cyclic bending load was applied. The first delamination damage observed in the specimens occurred at the area around the tip of the outermost ply-drop group. Subsequently, unstable delamination occurred by complete delamination along the length of the specimen. Continued cycling resulted in multiple delaminations. A 2D finite element model of the flexbeam was developed and a geometrically non-linear analysis was performed. The global responses of the model and test specimens agreed very well in terms of the transverse flexbeam tip-displacement and flapping angle. The FE model was used to calculate strain energy release rates (G) for delaminations initiating at the tip of the outer ply-drop area and growing toward the thick or thin regions of the flexbeam, as was observed in the specimens. The delamination growth toward the thick region was primarily mode 2, whereas delamination growth toward the thin region was almost completely mode 1. Material characterization data from cyclic double-cantilevered beam tests was used with the peak calculated G values to generate a curve predicting fatigue failure by unstable delamination as a function of the number of loading cycles. The calculated fatigue lives compared well with the test data.

Murri, Gretchen B.↗

The infall velocity toward Virgo, the Hubble constant, and a search for motion toward the microwave background

The perturbation of the local velocity field due to the overdensity of the Virgo complex (VC) is investigated theoretically, using an idealized spherically symmetric Virgocentric flow model and testing for a correlation between cos theta (where theta is the angle from the VC direction to eight groups and clusters with velocity 800-2500 km/s) and the relevant velocity residuals. The data and results are presented in extensive tables, graphs, and a map in extragalactic coordinates. The infall of the Local Group (LG) toward the VC is estimated as 200 + or - 50 km/s, corresponding to a mean mass/light ratio M/L(B) = about 70 for a sphere centered at the VC core and extending to the LG. The rate of free expansion within the VC is estimated as 52 + or 2 km/s Mpc for a VC distance of 21.6 Mpc. It is pointed out that the LG infall toward the VC cannot account for observations of an apparent 630-km/s motion of the LG toward the microwave background.

Tammann, G. A.↗

Mass spectrometric studies of trimethylindium pyrolysis

The kinetics of the pyrolysis of trimethylindium (TMIn) in He, D2, and H2 carriers was investigated using the atmospheric pressure flow-tube apparatus described by Larsen et al. (1987) and a time-of-flight mass spectrometer. The rate constant for the pyrolysis of TMIn in He was found to be comparable to that found by Jacko and Price (1964) for TMIn in toluene carrier (a radical scavenger), indicating that TMIn decomposes in He not by radical attack of methyl groups, but by homolytic fission. The decomposition of TMIn is enhanced in D2 and H2 carriers, where the principal products are CH3D and C2H6, and CH4 and C2H6, respectively, indicating that the reaction pathway in these carriers is different from those in He and toluene. The pyrolysis in H2 and D2 is attributed to a radical attack by H or D on TMIn. A reaction mechanism involving a short-lived hypervalent DTMIn species was proposed and was tested using numerical modeling techniques.

Buchan, N. I.↗

Fault Injection Campaign for a Fault Tolerant Duplex Framework

Fault tolerance is an efficient approach adopted to avoid or reduce the damage of a system failure. In this work we present the results of a fault injection campaign we conducted on the Duplex Framework (DF). The DF is a software developed by the UCLA group [1, 2] that uses a fault tolerant approach and allows to run two replicas of the same process on two different nodes of a commercial off-the-shelf (COTS) computer cluster. A third process running on a different node, constantly monitors the results computed by the two replicas, and eventually restarts the two replica processes if an inconsistency in their computation is detected. This approach is very cost efficient and can be adopted to control processes on spacecrafts where the fault rate produced by cosmic rays is not very high.

fault injector↗

Task switching in a hierarchical task structure: evidence for the fragility of the task repetition benefit

This study examined how task switching is affected by hierarchical task organization. Traditional task-switching studies, which use a constant temporal and spatial distance between each task element (defined as a stimulus requiring a response), promote a flat task structure. Using this approach, Experiment 1 revealed a large switch cost of 238 ms. In Experiments 2-5, adjacent task elements were grouped temporally and/or spatially (forming an ensemble) to create a hierarchical task organization. Results indicate that the effect of switching at the ensemble level dominated the effect of switching at the element level. Experiments 6 and 7, using an ensemble of 3 task elements, revealed that the element-level switch cost was virtually absent between ensembles but was large within an ensemble. The authors conclude that the element-level task repetition benefit is fragile and can be eliminated in a hierarchical task organization.

Reaction Time↗

SOFIA'S Challenge: Scheduling Airborne Astronomy Observations

The Stratospheric Observatory for Infrared Astronomy (SOFIA) is NASA's next generation airborne astronomical observatory, and will commence operations in 2005. The facility consists of a 747-SP modified to accommodate a 2.5 meter telescope. SOFIA is expected to fly an average of 140 science flights per year over its 20 year lifetime. Depending on the nature of the instrument used during flight, 5-15 observations per flight are expected. The SOFIA telescope is mounted aft of the wings on the port side of the aircraft and is articulated through a range of 20deg to 60deg of elevation. The telescope has minimal lateral flexibility; thus, the aircraft must turn constantly to maintain the telescope's focus on an object during observations. A significant problem in future SOFIA operations is that of scheduling flights in support of observations. Investigators are expected to propose small numbers of observations, and many observations must be grouped together to make up single flights. Flight planning for the previous generation airborne observatory, the Kuiper Airborne Observatory (KAO), was done by hand; planners had to choose takeoff time, observations to perform, and decide on setup-actions (called "dead-legs") to position the aircraft prior to observing. This task frequently required between 6-8 hours to plan one flight The scope of the flight planning problem for supporting GI observations with the anticipated flight rate for SOFIA makes the manual approach for flight planning daunting. In response, we have designed an Automated Flight Planner (AFP) that accepts as input a set of requested observations, designated flight days, weather predictions and fuel limitations, and searches automatically for high-quality flight plans that satisfy all relevant aircraft and astronomer specified constraints. The AFP can generate one candidate flight plan in 5-10 minutes, of computation time, a feat beyond the capabilities of human flight planners. The rate at which the AFP can generate flights enables humans to assess and analyze complex tradeoffs between fuel consumption, estimated science quality and the percentage of scheduled observations. Due to the changing nature of SOFIA scheduling problems, this functionality will play a crucial role in optimizing science and minimizing costs during operations. In the full paper, we will summarize the technical challenges that have been met in order to build this system. These include: design of the search algorithm, design of appropriate heuristics and approximations, and reduction in the size of the search space. We will also describe technical challenges that are currently being addressed, including the extension of the existing approach to handle new solution criteria. Finally, we will describe a variety of cultural challenges that the astronomical community must address in order to successfully use SOFIA, and describe how the AFT can be used to address some of these challenges. Specifically, many of the intended science users are accustomed to using ground-based or space-based observatories; we will identify some differences that arise due to the nature of airborne observatories, and how the AFT can be extended to provide useful services to ease these cultural differences.

Frank, Jeremy↗

Spatial Burnout in Water Reactors with Nonuniform Startup Distributions of Uranium and Boron

Spatial burnout calculations have been made of two types of water moderated cylindrical reactor using boron as a burnable poison to increase reactor life. Specific reactors studied were a version of the Submarine Advanced Reactor (sAR) and a supercritical water reactor (SCW) . Burnout characteristics such as reactivity excursion, neutron-flux and heat-generation distributions, and uranium and boron distributions have been determined for core lives corresponding to a burnup of approximately 7 kilograms of fully enriched uranium. All reactivity calculations have been based on the actual nonuniform distribution of absorbers existing during intervals of core life. Spatial burnout of uranium and boron and spatial build-up of fission products and equilibrium xenon have been- considered. Calculations were performed on the NACA nuclear reactor simulator using two-group diff'usion theory. The following reactor burnout characteristics have been demonstrated: 1. A significantly lower excursion in reactivity during core life may be obtained by nonuniform rather than uniform startup distribution of uranium. Results for SCW with uranium distributed to provide constant radial heat generation and a core life corresponding to a uranium burnup of 7 kilograms indicated a maximum excursion in reactivity of 2.5 percent. This compared to a maximum excursion of 4.2 percent obtained for the same core life when w'anium was uniformly distributed at startup. Boron was incorporated uniformly in these cores at startup. 2. It is possible to approach constant radial heat generation during the life of a cylindrical core by means of startup nonuniform radial and axial distributions of uranium and boron. Results for SCW with nonuniform radial distribution of uranium to provide constant radial heat generation at startup and with boron for longevity indicate relatively small departures from the initially constant radial heat generation distribution during core life. Results for SAR with a sinusoidal distribution rather than uniform axial distributions of boron indicate significant improvements in axial heat generation distribution during the greater part of core life. 3. Uranium investments for cylindrical reactors with nonuniform radial uranium distributions which provide constant radial heat generation per unit core volume are somewhat higher than for reactors with uniform uranium concentration at startup. On the other hand, uranium investments for reactors with axial boron distributions which approach constant axial heat generation are somewhat smaller than for reactors with uniform boron distributions at startup.

Fox, Thomas A.↗

Spatiotemporal processing of linear acceleration: primary afferent and central vestibular neuron responses

Spatiotemporal convergence and two-dimensional (2-D) neural tuning have been proposed as a major neural mechanism in the signal processing of linear acceleration. To examine this hypothesis, we studied the firing properties of primary otolith afferents and central otolith neurons that respond exclusively to horizontal linear accelerations of the head (0.16-10 Hz) in alert rhesus monkeys. Unlike primary afferents, the majority of central otolith neurons exhibited 2-D spatial tuning to linear acceleration. As a result, central otolith dynamics vary as a function of movement direction. During movement along the maximum sensitivity direction, the dynamics of all central otolith neurons differed significantly from those observed for the primary afferent population. Specifically at low frequencies (</=0.5 Hz), the firing rate of the majority of central otolith neurons peaked in phase with linear velocity, in contrast to primary afferents that peaked in phase with linear acceleration. At least three different groups of central response dynamics were described according to the properties observed for motion along the maximum sensitivity direction. "High-pass" neurons exhibited increasing gains and phase values as a function of frequency. "Flat" neurons were characterized by relatively flat gains and constant phase lags (approximately 20-55 degrees ). A few neurons ("low-pass") were characterized by decreasing gain and phase as a function of frequency. The response dynamics of central otolith neurons suggest that the approximately 90 degrees phase lags observed at low frequencies are not the result of a neural integration but rather the effect of nonminimum phase behavior, which could arise at least partly through spatiotemporal convergence. Neither afferent nor central otolith neurons discriminated between gravitational and inertial components of linear acceleration. Thus response sensitivity was indistinguishable during 0.5-Hz pitch oscillations and fore-aft movements. The fact that otolith-only central neurons with "high-pass" filter properties exhibit semicircular canal-like dynamics during head tilts might have important consequences for the conclusions of previous studies of sensory convergence and sensorimotor transformations in central vestibular neurons.

NASA Discipline Neuroscience↗