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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Irradiation and measurements of fluorinated ethylene-propylene-A on silicon solar cells in vacuum

Silicon monoxide (SiO) coated silicon solar cells covered with fluorinated ethylene-propylene-A (FEP-A) were irradiated by 1-MeV electrons in vacuum. The effect of irradiation on the light transmittance of FEP-A was checked by measuring the short-circuit current of the cells while in vacuum after each dose increment, immediately after the irradiation, and again after a minimum elapsed time of 16 hr. The results indicated no apparent loss in transmission due to irradiation of FEP-A and no delamination from the SiO surface while the cells were in vacuum, but embrittlement of FEP-A occurred at the accumulated dose.

Marsik, S. J.↗
NASA NTRS1975

Kinetics of the fluorination of zinc

The reaction between zinc metal and fluorine gas can be described by a parabolic rate law. This reaction is both temperature and pressure dependent. Simple kinetics are complicated by the considerable vaporization rate for zinc at temperatures above 300 C (573 K).

Odonnell, P. M.↗
NASA NTRS1975

Effect of viscosity on rolling-element fatigue life at cryogenic temperature with fluorinated ether lubricants

Rolling-element fatigue tests were conducted with 12.7-mm-(1/2-in.-) diameter AISI 52100 steel balls in the NASA five-ball fatigue tester, with a maximum hertz stress of 5500 mN/m2 (800 000 psi), a shaft speed of 4750 rpm, lubricant temperature of 200 K (360 R), a contact angle of 20 deg, using four fluorinated ether lubricants of varying viscosities. No statistically significant differences in rolling-element fatigue life occurred using the four viscosity levels. Elastohydrodynamic calculations indicate that values of the lubricant film parameter were approximately 2 or greater.

Dietrich, M. W.↗
NASA NTRS1975

Microwave spectra of some chlorine and fluorine compounds

A computer-controlled microwave spectrometer was used to catalog reference spectra for chemical analysis. Tables of absorption frequencies, peak absorption intensities, and integrated intensities are shown for 21 organic compounds which contain chlorine, fluorine, or both.

White, W. F.↗
NASA NTRS1975

Study of safety implications for shuttle launched spacecraft using fluorinated oxidizers. Volume 1: Complete text

The safety implications of space shuttle launched spacecraft using liquid flourine as the oxidizer for spacecraft propulsion were investigated. Feasibility of safe operation was investigated and the equipment and procedures necessary to maximize the chance of success determined. Hazards to the shuttle were found to be similar in kind if not degree to those encountered in use of nitrogen tetroxide (also toxic oxidizer). It was concluded that residual risks from spacecraft using fluorine and nitrogen tetroxide during ground and flight handling may be reduced by isolation of the oxidizer to only its tank. Operation of planetary spacecraft propulsion in the vicinity of the shuttle in earth orbit is not required. The primary hazard to personnel was identified as propellant loading operations, which should be accomplished in an area reasonably remote from personnel and facilities concentrations. Clearing the pad during spacecraft mating with the shuttle orbiter is recommended.

Source record↗
NASA NTRS1976

Comparison of type A and C Fluorinated Ethylene Propylene (FEP) as cover materials for silicon solar cells

Fluorinated ethylene propylene film (FEP, 0.0127 cm thick) was heat and pressure laminated to silicon solar cells as a low cost substitute for quartz covers. The FEP-C, treated on one side for bonding, was compared to FEP-A, an untreated FEP. With FEP-A, a silane adhesion promoter was applied to the cells. The FEP-C covers delaminated during accelerated temperature-humidity testing and Earth environmental exposure testing; FEP-A covers were unchanged. No differences were observed in peel tests, but FEP-A is superior in its resistance to tearing and in retention of transmission properties after exposure to ultraviolet radiation.

Broder, J. D.↗
NASA NTRS1976

Advanced helium regulator for a fluorine propellant system

The space storable propulsion module is an advanced high performance (375 seconds Isp minimum) planetary spacecraft propulsion system with a mission life of 5-10 years. The propellants used are liquid fluorine and amine fuel. This application requires high pressure regulator accuracy to optimize propellant depletion characteristics. An advanced regulator concept was prepared which is compatible with both fuel and oxidizer and which features design concepts such as redundant bellows, all-metallic/ceramic construction, friction-free guidance of moving parts and gas damping. Computer simulation of the propulsion module performance over two mission profiles indicated satisfactory minimization of those propellant residual requirements imposed by regulator performance variables.

Wichmann, H.↗
NASA NTRS1976

Fluorine as a constituent in lunar magmatic gases

Fluorine surface deposits on Apollo 15 green glass, Apollo 17 orange glass, and on vesicle linings from Apollo 15 basalts were studied by a resonant nuclear reaction technique. Surface layers of about 10 to the 15th F atoms/sq cm were observed on unbroken spheroidal glass surfaces, whereas thinner (about 10 to the 14th atoms/sq cm) deposits were found on the vesicle linings.

Goldberg, R. H.↗
NASA NTRS1968

Fluorine-containing polyformals

A fluorine-containing polymeric polyformals is described which has the repeating unit O CH2 O CH2 (CF2) sub n CH2 wherein n is an integer of from about 3 to about 6 prepared by reacting trioxane with a diol having the formula HO CH2 (CF2) sub n CH2 OH. These polymeric polyformals are useful directly for impervious coatings on metals and the like.

Trischler, F. D.↗
NASA NTRS1979

Technology status of a fluorine-hydrazine propulsion system for planetary spacecraft

The basic technology exists and a system integration program is well underway to allow incorporation of a fluorine-hydrazine propulsion system into future spacecraft required for unmanned planetary missions. These spacecraft would be inserted in earth orbit using the Space Transportation System Shuttle and given its initial sendoff by the Inertial Upper Stage (IUS). The design of a typical propulsion system, assessment of thermal and structural impacts on a selected spacecraft and comparative studies with conventional propulsion systems have been completed. A major part of the current JPL Program involves assembly of a 3650 N thrust demonstration system using titanium tanks, flight weight components and structure. This system will be used to demonstrate the state-of-the-art throughout a representative flight system's qualification.

Bond, D. L.↗
NASA NTRS1979

Argon/UF6 plasma exhaust gas reconstitution experiments using preheated fluorine and on-line diagnostics

The feasibility of employing a flowing, high-temperature, pure fluorine/UF6 regeneration system to efficiently convert a large fraction of the effluent plasma exhaust back to pure UF6 was demonstrated. The custom built T.O.F. mass spectrometer sampling system permitted on-line measurements of the UF6 concentration at different locations in the exhaust system. Negligible amounts ( 100 ppm) of UF6 were detected in the axial bypass exhaust duct and the exhaust ducts downstream of the cryogenic trap system used to collect the UF6, thus verifying the overall system efficiency over a range of operating conditions. Use of a porous Monel duct as part of the exhaust duct system, including provision for injection of pure fluorine, provided a viable technique to eliminate uranium compound residue on the inside surface of the exhaust ducts. Typical uranium compound mass deposition per unit area of duct was 2 micron g/sq cm. This porous duct technique is directly applicable to future uranium compound transfer exhaust systems. Throughout these experiments, additional basic data on the corrosion aspects of hot, pressurized UF6/fluorine were also accumulated.

Roman, W. C.↗
NASA NTRS1979

Electron energy-loss spectra in molecular fluorine

Electron energy-loss spectra in molecular fluorine, for energy losses from 0 to 17.0 eV, have been taken at incident electron energies of 30, 50, and 90 eV and scattering angles from 5 to 140 deg. Features in the spectra above 11.5 eV energy loss agree well with the assignments recently made from optical spectroscopy. Excitations of many of the eleven repulsive valence excited electronic states are observed and their location correlates reasonably well with recent theoretical results. Several of these excitations have been observed for the first time and four features, for which there are no identifications, appear in the spectra.

Nishimura, H.↗
NASA NTRS1980

Technology status of a liquid fluorine-hydrazine rocket engine for a planetary spacecraft propulsion system

This paper discusses the current status of a fluorine-hydrazine rocket engine development program. Incorporation of a thin rhenium inner liner successfully eliminated corrosion of the carbon/carbon composite thrust chamber wall experienced during a previous test program. The results of hot-fire tests utilizing reworked and new injectors which provide increased fuel film cooling showed that thrust chamber head-end temperatures could be maintained at an acceptable level. As expected, the accompanying specific impulse performance loss requires optimizing the amount of film cooling to minimize the loss. The efforts to refine the rhenium liner vapor deposition process culminated in a carbon/carbon composite thrust chamber total test duration of 1008 seconds. Tasks presently in process include: (1) fabrication of two carbon/carbon composite thrust chambers incorporating 60:1 expansion ratio nozzles; (2) injector tests to optimize performance and cooling; (3) additional refinements to the rhenium lining process; and (4) fabrication and test of a freestanding rhenium thrust chamber.

Appel, M. A.↗
NASA NTRS1984

Fluorine Mixer/Vaporizer for Chemical Lasers

A mixer/vaporized chamber gasifies liquid fluorine before it is injected into lasing cavity of hydrogen fluoride/deuterium fluoride laser. Flourine vaporized by flow of helium.

Giandomenico, A.↗
NASA NTRS1984

Development of partially fluorinated resin apex seals

Partially fluorinated polyimides were prepared and molded in the form of discs and pins for test as potential apex seal materials for advanced rotary combustion engines. The polyimides were formulated from the diamine 2,2-bis 4-(4-aminophenoxy)phenyl hexafluoropropane (4-BDAF) and the dianhydrides of pyromellitic acid (PMDA) and benzophenonetetracarboxylic acid (BTDA). Tribological testing was performed at sliding speeds of 0.31 to 11.6 m/s and at temperatures of from 298K to 573K. It is shown that the carbon fiber filled polyimides, particularly the 80/20 compositions, have an excellent balance of wear/friction at 573K. The unfilled, 80/20 and 60/40 compositions indicate an unusual combination of high friction and low wear which may be advantageous in such applications as brakes and traction drives.

Green, H. E.↗
NASA NTRS1985

Tribological properties of graphite-fiber-reinforced, partially fluorinated polyimide composites

Graphite-fiber-reinforced polyimide (GFRPI) composites were formulated from three new partially fluorinated polyimides and three types of graphite fiber. Nine composites were molded into pins and evaluated in a pin-on-disk tribometer. Friction coefficients, wear rates, pin wear surface morphology, and transfer film formation were assessed at 25 and 300 C. Also assessed was the effect of sliding speed on friction. Wear was up to two orders of magnitude lower at 25 C and up to one order of magnitude lower at 300 C than with previously formulated NASA GFRPI composites.

Fusaro, R. L.↗
NASA NTRS1983

Fluorine disposal

A preliminary design of an F2 dispoal system for HELSTF is presented along with recommendations on operational policy and identification of potential operational problems. The analysis is based on sizing a system to handle two different modes of the HELSTF Fluorine Flow System (one operational and one catastrophic). This information should serve both as a guide to a final detailed design for HELSTF as well as a reference for subsequent monitoring and/or modification of the system which consists of a charcoal reactor followed by a dry soda lime scrubber.

Rakow, A.↗