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At least 199 records · Page 11

Properties of solid polymer electrolyte fluorocarbon film

The ionic fluorocarbon film used as the solid polymer electrolyte in hydrogen/oxygen fuel cells was found to exhibit delamination failures. Polarized light microscopy of as-received film showed a lined region at the center of the film thickness. It is shown that these lines were not caused by incomplete saponification but probably resulted from the film extrusion process. The film lines could be removed by an annealing process. Chemical, physical, and tensile tests showed that annealing improved or sustained the water contents, spectral properties, thermo-oxidative stability, and tensile properties of the film. The resistivity of the film was significantly decreased by the annealing process.

Alston, W. B.↗

Flame resistant fibrous materials

Four chlorofluoropolymer systems were developed that satisfactorily met the criteria for classification as self-extinguishing. Three of these systems consisted of Halar (a copolymer of chlorotrifluoroethylene and ethylene) and tin-based flame retardants. The fourth system was a copolymer of chlorotrifluoroethylene and tetrafluoroethylene with no flame retardants added. Production of fibers from all four candidates, by melt extrusion, was demonstrated. Fibers produced from the chlorotrifluoroethylene tetrafluoroethylene copolymer showed the most promise.

Source record↗

Mare ridges and lava lakes

The autointrusive hypothesis of the origin of several vagaries of prominent mare ridges is explained. Data are based on a comparison between the structure of a Hawaiian lava lake and the mare ridges. Resulting data suggest that these ridges may have formed as squeeze-ups and autointrusives in tension fractures over buried topography in the crust of luna lava lakes. Data also suggest that mare ridges may result from: (1) pressure ridges in flows, (2) compressional features resulting from subsidence of mare lava, (3) volcanic ring structures and extrusives, or loccoliths fed by lunar grid controlled dikes, (4) draped topography and fissure eruptives, (5) drag folds or tension-gash dikes caused by wrench faulting at depth, and (6) postmare thrust faults.

Hodges, C. A.↗

Small structures of the Taurus-Littrow region

Apollo 17 photographs of small structures expressed as scarps, ledges, flow fronts, and mare type ridges are compared in an effort to determine the origin of such structures. The resulting data revealed that these structures were probably developed as lava extrusions from fractures and fissures along with associated faulting and folding.

Scott, D. H.↗

Volcanic features of far side Crater Aitken

Volcanic features of the far side Aitken Crater including post-impact volcanism and volcanic events extending beyond the period of mare type crater flooding are discussed. The features attributed to extrusions of viscous lava are also discussed.

Bryan, W. B.↗

Dissimilar metals joint evaluation

Dissimilar metals tubular joints between 2219-T851 aluminum alloy and 304L stainless steel were fabricated and tested to evaluate bonding processes. Joints were fabricated by four processes: (1) inertia (friction) weldings, where the metals are spun and forced together to create the weld; (2) explosive welding, where the metals are impacted together at high velocity; (3) co-extrusion, where the metals are extruded in contact at high temperature to promote diffusion; and (4) swaging, where residual stresses in the metals after a stretching operation maintain forced contact in mutual shear areas. Fifteen joints of each type were prepared and evaluated in a 6.35 cm (2.50 in.) O.D. size, with 0.32 cm (0.13 in.) wall thickness, and 7.6 cm (3.0 in) total length. The joints were tested to evaluate their ability to withstand pressure cycle, thermal cycle, galvanic corrosion and burst tests. Leakage tests and other non-destructive test techniques were used to evaluate the behavior of the joints, and the microstructure of the bond areas was analyzed.

Wakefield, M. E.↗

Design and fabrication of a boron reinforced intertank skirt

Analytical and experimental studies were performed to evaluate the structural efficiency of a boron reinforced shell, where the medium of reinforcement consists of hollow aluminum extrusions infiltrated with boron epoxy. Studies were completed for the design of a one-half scale minimum weight shell using boron reinforced stringers and boron reinforced rings. Parametric and iterative studies were completed for the design of minimum weight stringers, rings, shells without rings and shells with rings. Computer studies were completed for the final evaluation of a minimum weight shell using highly buckled minimum gage skin. The detail design is described of a practical minimum weight test shell which demonstrates a weight savings of 30% as compared to an all aluminum longitudinal stiffened shell. Sub-element tests were conducted on representative segments of the compression surface at maximum stress and also on segments of the load transfer joint. A 10 foot long, 77 inch diameter shell was fabricated from the design and delivered for further testing.

Henshaw, J.↗

TDNiCr (ni-20Cr-2ThO2) forging studies

Elevated temperature tensile and stress rupture properties were evaluated for forged TDNiCr (Ni-20Cr-2ThO2) and related to thermomechanical history and microstructure. Forging temperature and final annealed condition had pronounced influences on grain size which, in turn, was related to high temperature strength. Tensile strength improved by a factor of 8 as grain size changed from 1 to 150 microns. Stress-rupture strength was improved by a factor of 3 to 5 by a grain size increase from 10 to 1000 microns. Some contributions to the elevated temperature strength of very large grain material may also occur from the development of a strong texture and a preponderance of small twins. Other conditions promoting the improvement of high temperature strength were: an increase of total reduction, forging which continued the metal deformation inherent in the starting material, a low forging speed, and prior deformation by extrusion. The mechanical properties of optimally forged TDNiCr compared favorably to those of high strength sheet developed for space shuttle application.

Filippi, A. M.↗

Shuttle active thermal control system development testing. Volume 8: Tube anomaly investigation

A modular radiator system projected for use on the space shuttle has been tested. During thermal vacuum testing of the radiator panels leaks developed in the coolant fluid tubes containing the Freon 21 refrigerant. An analysis of thermal vacuum test conditions revealed that the test anomaly consisted of trapped Freon 21 fluid between frozen tube corners colder than the remainder of the panel. The trapped fluid expanded on further warming, causing high pressures to develop in the tubes. The pressure was sufficient to induce tube ruptures. Metallurgical analysis showed that concentric extrusion holes and heat treatment of the aluminum alloy to the -T6 condition would have prevented the ruptures. Thermal analysis indicates that attaching the tube corners to the radiator fin could eliminate the fluid trapping.

Reed, M. W.↗

Lava flows in Mare Imbrium - Geologic evaluation from Apollo orbital photography

A study of Apollo photographs indicates that all Eratosthenian age mare deposits in the Imbrium basin consist of extensive lava flows from a single eruptive source region bounded by 18 to 23 N and 28 to 32 W in the south-southwest corner of the basin. It is suggested that three major eruptive periods occurred between 3.0 plus or minus 0.4 and 2.5 plus or minus 0.3 b.y. Lavas assigned to these three phases extended for 1200, 600, and 400 km, respectively, over slopes approaching 1:1000. These materials cover an area of 200,000 sq km and have a volume of perhaps 40,000 cu km. The vent source of the youngest lava phase appears to be a 20 km long, structurally controlled fissure at 22 deg 50 min N and 31 deg 20 min W. The flow heights and lengths are consistent with the lunar gravity and imply extremely high rates of lava extrusion with low viscosity of the basalt melt playing a secondary role. The location of the volcanic source region on the intersection of major ring faults from two large basins suggests a basin structural control.

Schaber, G. G.↗

The Old Imbrium Hypothesis

It is proposed that the order of lunar events was such that the Imbrium event predates the formation of the lunar rock type called KREEP. This hypothesis is used to explain the distribution of KREEP in the regions of Imbrium ejecta and the location of KREEP within the Imbrium and Procellarum mare regions. Model ages of KREEP materials have been previously interpreted to mean that their 'formation' age (time of initial extrusion) is about 4.3 to 4.4 AE. Consequently it is suggested that the Imbrium impact was before 4.3 to 4.4 AE rather than at about 3.9 AE, as is currently believed. This Old Imbrium Hypothesis is not yet proven, but seems to be consistent with a large variety of basic lunar observations.

Schonfeld, E.↗

Ruemker Hills - A lunar volcanic dome complex

The Ruemker Hills, a volcanic dome-flow complex in the northern Oceanus Procellarum, is characterized by overlapping plains-forming units with lobate scarps, volcanic domes, a 60-km ring, and a scarp which separates the plateau from surrounding mare materials. Plains-forming units are interpreted as fluid volcanic flows, and domes as viscous extrusions. One dome may be a stratovolcano. The ring system is discordant with regional structural trends and probably has a local origin. The Ruemker Hills is the closest lunar analog to the large Martian shield structures revealed on the Mariner 9 photographs of Mars.

Smith, E. I.↗

Liquid-metal atomization for hot working preforms

Rapid quenching of a liquid metal by atomization or splat cooling overcomes the major limitation of most solidification processes, namely, the segregation of alloying elements, impurities, and constituent phases. The cooling rates of different atomizing processes are related to the dendrite arm spacings and to the microstructure of the atomized powders. The increased solubility limits and the formation of metastable compounds in splat-cooled alloys are discussed. Consolidation of the powders by hot isostatic compaction, hot extrusion, or hot forging and rolling processes yields billets with properties equivalent to or better than those of the wrought alloys. The application of this powder processing technology to high-performance alloys is reviewed.

Grant, N. J.↗

Development of advanced high strength tantalum base alloys. Part 2: Scale-up investigation

Three experimental tantalum alloy compositions containing 14-16% W, 1% Re, 0.7% Hf, 0.025% C or 0.015% C and 0.015% N were prepared as two inch diameter ingots by consumable electrode vacuum arc melting. The as-cast ingots were processed by extrusion and swaging to one inch and 0.4 inch diameter rod and evaluated. Excellent high temperature forging behavior was exhibited by all three compositions. Creep strength at 2000 F to 2400 F was enhanced by higher tungsten additions as well as substitution of nitrogen for carbon. Weldability of all three compositions was determined to be adequate. Room temperature ductility was retained in the advanced tantalum alloy compositions as well as a notched/unnotched strength ratio of 1.4 for a notched bar having a K sub t = 2.9.

Ammon, R. L.↗

A study of the oxide dispersion and recrystallization in NiCrAl prepared from preoxidized powder

The sintered aluminum powder (SAP) technique of dispersion strengthening (formation of an oxide dispersion by preoxidation of metal powders) was applied to atomized powder of a nickel alloy containing, by weight, 17% Cr, 5% Al, and 0.2% Y. The SAP-NiCrAl alloy (without the ytterbium removed by oxdation) was worked by extrusion and rod rolling at 1205 C and by swaging at 760 C. Annealing treatments were applied after working to determine the recrystallization response. The NiCrAlY alloy, similarly prepared from atomized powder, but without a preoxidation treatment, was examined for comparison. The SAP-NiCrAl alloy exhibited oxide particle size and spacing much larger than that usually observed in oxide dispersion strengthened alloys; nonetheless, it was possible to achieve abnormal (secondary) recrystallization in the SAP-NiCrAl alloy as has been reported for other oxide dispersion strengthened alloys. In contrast, the unoxidized NiCrAlY alloy exhibited only primary recrystallization.

Glasgow, T. K.↗

An interpretation of volcanic and structural features of crater Aitken

Detailed observations from the study of Apollo 17 panoramic photography of the Aitken crater are reported which suggest that there has been significant late-stage compressional deformation of the crater and its adjacent highlands. A speculative interpretation of eruptive activity and drain-back events within Aitken is presented, which leads to the conclusion that hummocky topography within certain cones represents collapsed lava rather than extrusive domes. That is, eruptive activity within Aitken probably commenced with an explosive cone-building stage, followed by lava eruptions from cones and fissures, and ended with drain-back restricted to the relatively deep lava ponded in the vents.

Bryan, W. B.↗

Use of ERTS imagery for natural resources research and development in Lesotho

The author has identified the following significant results. As far as the geological aspects of the project were concerned, the project was a success. It was concluded that: (1) It is possible to trace the lithological boundaries between sedimentary rocks and basaltic rocks, both extrusive and intrusive. (2) It was possible to localize sponges in the mountain areas, some of which may conceal undiscovered diamond pipes. (3) Possible main structural axes were localized within the framework of lineaments. Due to drought which occured at the time the images were gathered by ERTS-1, the usefulness of the data was limited for agricultural purposes.

Nixon, P. H.↗

An oxide dispersion strengthened Ni-W-Al alloy with superior high temperature strength

An experimental oxide dispersion strengthened (ODS) alloy, WAZ-D, derived from the WAZ-20 composition was produced by the mechanical alloying process. Cast WAZ-20 is strengthened by both a high refractory metal content, and 70 volume percent of gamma prime. The ODS alloy WAZ-D was responsive to variables of alloy content, of attritor processing, of consolidation by extrusion, and of heat treatment. The best material produced had large highly elongated grains. It exhibited tensile strengths generally superior to a comparable cast alloy. The ODS alloy exhibited high temperature stress rupture life considerably superior to any known cast superalloy. Tensile and rupture ductility were low, as was intermediate temperature rupture life. Very low creep rates were noted and some specimens failed with essentially no third stage creep. Also the benefit derived from the oxide dispersion, far out-weighed that from the elongated microstructure alone.

Glasgow, T. K.↗