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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Drop Breakup in Fixed Bed Flows as Model Stochastic Flow Fields

We examine drop breakup in a class of stochastic flow fields as a model for the flow through fixed fiber beds and to elucidate the general mechanisms whereby drops breakup in disordered, Lagrangian unsteady flows. Our study consists of two parallel streams of investigation. First, large scale numerical simulations of drop breakup in a class of anisotropic Gaussian fields will be presented. These fields are generated spectrally and have been shown in a previous publication to be exact representations of the flow in a dilute disordered bed of fibers if close interactions between the fibers and the drops are dynamically unimportant. In these simulations the drop shape is represented by second and third order small deformation theories which have been shown to be excellent for the prediction of drop breakup in steady strong flows. We show via these simulations that the mechanisms of drop breakup in these flows are quite different than in steady flows. The predominant mechanism of breakup appears to be very short lived twist breakups. Moreover, the occurrence of breakup events is poorly predicted by either the strength of the local flow in which the drop finds itself at breakup, or the degree of deformation that the drop achieves prior to breakup. It is suggested that a correlation function of both is necessary to be predictive of breakup events. In the second part of our research experiments are presented where the drop deformation and breakup in PDMS/polyisobutylene emulsions is considered. We consider very dilute emulsions such that coalescence is unimportant. The flows considered are simple shear and the flow through fixed fiber beds. Turbidity, small angle light scattering, dichroism and microscopy are used to interrogate the drop deformation process in both flows. It is demonstrated that breakup at very low capillary numbers occurs in both flows but larger drop deformation occurs in the fixed bed flow. Moreover, it is witnessed that breakup in the bed occurs continuously during flow and apparently with uniform probability through the bed length. The drop deformations witnessed in our experiments are larger than those predicted by the numerical simulations, and future plans to investigate these differences are discussed.

Shaqfeh, Eric S. G.↗
NASA NTRS2000

Cosmic Ray Astronomy

The cosmic ray division participation in the cooperative agreement was activated in the second year. The scientific goals will be analysis of cosmic ray data from the Japanese-American Cooperative Emulsion Experiments (JACEE). Measurements of primary cosmic rays in the JACEE emulsion chambers will be made to derive for each detected particle the deposited energy in the chamber and the primary charge (atomic number). The data will be corrected to the primary flux above the atmosphere, and the composition and energy spectra will be derived. The spectra of the individual elements will be interpreted in context with the supernova shock and other models of cosmic ray acceleration. Additional information is contained in the original extended abstract.

Wu, S. T.↗
NASA NTRS1960

An Investigation of a Photographic Technique of Measuring High Surface Temperatures

A photographic method of temperature determination has been developed to measure elevated temperatures of surfaces. The technique presented herein minimizes calibration procedures and permits wide variation in emulsion developing techniques. The present work indicates that the lower limit of applicability is approximately 1,400 F when conventional cameras, emulsions, and moderate exposures are used. The upper limit is determined by the calibration technique and the accuracy required.

Siviter, James H., Jr.↗
NASA NTRS1994

Multiplicities of secondaries in nuclear interactions, induced by 20Ne, 40Ar and 56Fe nuclei at 0.1-0.5 GeV/nucleon

Multiplicities of various species of charged secondaries produced in inelastic interactions of 20Ne, 40Ar and 56Fe nuclei with emulsion nuclei at 0.1-0.5 GeV/nucleon have been measured. The data obtained are compared with the results for interactions of higher energy nuclei with emulsion nuclei. The dependences of the nucleus-nucleus interaction parameters on masses and energies of colliding nuclei are examined.

NASA Discipline Radiation Health↗
NASA NTRS2003

Learning New Techniques for Remediation of Contaminated Sites

The project emphasizes NASA's Missions of understanding and protecting our home planet as well as of inspiring the next generation of explorers. The project fellow worked as part of a team on the development of new emulsion-based technologies for the removal of Contaminants from soil, sediment, and groundwater media with the scientists in charge of the emulsion-based technologies. Hands-on chemistry formulation and analyses using a GCM, as well as field sampling was done. The fellow was tidy immersed in lab and fieldwork, as well as, training sessions to qualify her to do the required work. The principal outcome of the project is the motivation to create collaboration links between major research university (UCF) and an emerging research university (UT).

Lipsett-Ruiz, Teresa↗
NASA NTRS2003

Treatment to Destroy Chlorohydrocarbon Liquids in the Ground

A relatively simple chemical treatment that involves the use of emulsified iron has been found to be effective in remediating groundwater contaminated with trichloroethylene and other dense chlorohydrocarbon liquids. These liquids are members of the class of dense, nonaqueous phase liquids (DNAPLs), which are commonly recognized to be particularly troublesome as environmental contaminants. The treatment converts these liquids into less-harmful products. As a means of remediation of contaminated groundwater, this treatment takes less time and costs less than do traditional pump-and-treat processes. At some sites, long-term leakage and/or dissolution of chlorohydrocarbon liquids from pools and/or sorbed concentrations in rock and soil gives rise to a need to continue pumpand- treat processes for times as long as decades in order to maintain protection of human health and the environment. In contrast, the effects of the emulsified-iron treatment are more lasting, decreasing the need for long-term treatment and monitoring of contaminated areas. The material used in this treatment consists of iron particles with sizes of the order of nanometers to micrometers contained within the micelles of a surfactant-stabilized, biodegradable, oil-in-water emulsion. The emulsion is simple to prepare and consists of relatively inexpensive and environmentally acceptable ingredients: One typical formulation consists of 1.3 weight percent of a food-grade surfactant, 17.5 weight percent of iron particles, 23.2 weight percent of vegetable oil, and 58.0 weight percent of water.

Quinn, Jacqueline↗
NASA NTRS2006

Evaluating Trichloroethylene Degradation Using Differing Nano- and Micro-Scale Iron Particles

Trichioroethylene, or TCE, is a central nervous system depressant and possible carcinogen, as well as a persistent groundwater pollutant. TCE exists in the aquifer either as free product in the form of a dense non-aqueous phase liquid (DNAPL) or as a dissolved-phase constituent. It is only slightly soluble in water, so dissolution of the contaminant is a long-term process and in-situ remediation is difficult. To remedy this, NASA and the University of Central Florida developed Emulsified Zero-Valent Iron, or EZVI. The emulsion droplet contains ZVI particles and water encapsulated by an oil/surfactant membrane, and effectively penetrates to degrade DNAPL-phase TCE. To maximize the efficiency of this process, several commercially available ZVIs of radically different particle sizes and morphologies both in emulsion and as neat (unemulsified) metal were evaluated for relative effectiveness at TCE degradation.

Berger, Cristina M.↗
NASA NTRS2006

pH Sensitive Microcapsules for Delivery of Corrosion Inhibitors

A considerable number of corrosion problems can be solved by coatings. However, even the best protective coatings can fail by allowing the slow diffusion of oxygen and moisture to the metal surface. Corrosion accelerates when a coating delaminates. Often, the problems start when microscopic nicks or pits on the surface develop during manufacturing or through wear and tear. This problem can be solved by the incorporation of a self-healing function into the coating. Several new concepts are currently under development to incorporate this function into a coating. Conductive polymers, nanoparticles, and microcapsules are used to release corrosion-inhibiting ions at a defect site. The objective of this investigation is to develop a smart coating for the early detection and inhibition of corrosion. The dual function of this new smart coating system is performed by pH-triggered release microcapsules. The microcapsules can be used to deliver healing agents to terminate the corrosion process at its early stage or as corrosion indicators by releasing dyes at the localized corrosion sites. The dyes can be color dyes or fluorescent dyes, with or without pH sensitivity. Microcapsules were formed through the interfacial polymerization process. The average size of the microcapsules can be adjusted from 1 to 100 micron by adjusting the emulsion formula and the microcapsule forming conditions. A typical microcapsule size is around 10 microns with a narrow size distribution. The pH sensitivity of the microcapsule can also be controlled by adjusting the emulsion formula and the polymerization reaction time. Both corrosion indicator (pH indicator) and corrosion inhibitor containing microcapsules were formed and incorporated into paint systems. Test panels of selected steels and aluminum alloys were painted using these paints. Testing of compatibility between the microcapsule system and different paint systems are in progress. Initial experiments with the microcapsule containing paint show visible color changes at induced corrosion sites and improvement of corrosion protection. Further investigation of the performance of the coating using electrochemical techniques and long term exposure are currently underway.

Li, Wenyan↗
NASA NTRS2015

Elongated Microcapsules and Their Formation

Elongated microcapsules, such as elongated hydrophobic-core and hydrophilic-core microcapsules, may be formed by pulse stirring an emulsion or shearing an emulsion between two surfaces moving at different velocities. The elongated microcapsules may be dispersed in a coating formulation, such as paint.

Calle, Luz M.↗
NASA NTRS2017

The Early Planetary Research of Tobias C. Owen

Tobias Chant Owen (Toby) was a graduate student of G. P. Kuiper, receiving his Ph.D. in the Dept. of Astronomy, University of Arizona, in 1965. His thesis was broadly titled "Studies of Planetary Spectra in the Photographic Infrared", and primarily presented a study of the composition and other properties of Jupiter, as well as the abundance and surface pressure of CO2 on Mars. The surface pressure on Mars was a topic of debate at that time, with a wide range of diverse observational results from several investigators. The Jupiter work in particular consisted of the analysis of Kuiper's unpublished spectra that were made with photographic plates pushed to the longest wavelength possible, about 1120 nm, with ammonia-hypersensitized Kodak Z emulsions. Toby used the long-pathlength absorption cells at the Lunar and Planetary Lab to study the spectra of CH4 and NH3 at pressures and temperatures relevant to Jupiter (and Saturn), as well as to search for spectral signatures of potential minor components of their atmospheres. Toby also obtained new spectra of Io, Ganymede, and Saturn and its rings, extended to the long-wavelength limit of photographic emulsions. No new molecular absorptions were found, although Owen basically confirmed Kuiper's earlier result that Saturn's rings are covered (or composed of) with H2O ice or frost. As he pursued a broad range of problems of planetary atmospheres, Toby used existing and newly acquired spectra of the planets in the photographic and near-infrared wavelength regions, together with data he obtained in the laboratory with long-pathlength absorption cells, to resolve some outstanding issues of unidentified spectral features and to clarify issues of the compositions, temperatures, and atmospheric pressures of several bodies. This work laid the foundation for his later decades of studies of planetary atmospheres and comets with spacecraft as an active participant in many US and European missions. He was very influential in shaping the science goals of several missions, and in the interpretation of the results.

Mars↗
NASA NTRS2000

Evaluation of carrier agents for hyperpolarized xenon MRI

Several biocompatible carrier agents, in which xenon is highly soluble and has a long T(1), were tested, and injected in living rats. These included saline, Intralipid suspension, perfluorocarbon emulsion and (129)Xe gas-filled liposomes. The T(1) of (129)Xe in these compounds ranged from 47 to 116 s. Vascular injection of these carrier agents was tolerated well, encouraging their use for further experiments in live animals. In vivo spectra, obtained from gas-filled liposomes and perfluorocarbon solutions, suggest that these carrier agents have potential for use in angiography and perfusion imaging. Copyright 2000 John Wiley & Sons, Ltd.

Non-NASA Center↗