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At least 199 records · Page 11

Isothermal evaporation of a-pinene ozonolysis SOA: volatility, phase state, and oligomeric composition

We present measurements of the isothermal evaporation of a-pinene ozonolysis secondary organic aerosol (SOA). Using a novel, filter-based method, we replicate previous findings of the volume fraction remaining, presented here as carbon number weighted signal fraction remaining (SFR), as a function of evaporation time. We apply two detailed physical models to interpret the evaporative behavior of both the bulk SOA and individual components. Both models find that a combination of effectively non-volatile products, together with reversible oligomers (or otherwise reactive monomers) having a decomposition lifetime of 9 to 28 hours, best explains the evolution of composition and volatility as particles age in the absence of both organic vapors and oxidants, even under an assumption of relatively viscous (soft wax-like) particles. We find that the residence time in the SOA formation chamber, and time spent undergoing isothermal evaporation, both indicative of the physical age of the aerosol, are the most important experimental parameter determining the evaporation rate. The evolution of volatility observed in these experiments is compared to field measurements in a boreal forest site. The ambient monoterpene-dominated SOA volatility is only reproduced in the laboratory after 24 hours of extended aging in a dilute, dark, oxidant-free environment.

D'Ambro, Emma↗

Understanding Atom Probe Tomography of Oxide-Supported Metal Nanoparticles by Correlation with Atomic Resolution Electron Microscopy and Field Evaporation Simulation

Metal-dielectric composite materials, specifically metal nanoparticles supported on or embedded in metal oxides, are widely used in catalysis. The accurate optimization of such nanostructures warrants the need for detailed three-dimensional characterization. Atom probe tomography is uniquely capable of generating sub-nanometer structural and compositional data with part-per-million mass sensitivity, but there are reconstruction artifacts for composites containing materials with strongly differing fields of evaporation, as for oxide-supported metal nanoparticles. By correlating atom probe tomography with scanning transmission electron microscopy for Au nanoparticles embedded in an MgO support, deviations from an ideal topography during evaporation are demonstrated directly, and correlated with compositional errors in the reconstructed data. Finite element simulations of the field evaporation process confirm that protruding Au nanoparticles will evolve on the tip surface, and that evaporation field variations lead to an inaccurate assessment of the local composition, effectively lowering the spatial resolution of the final reconstructed dataset. Cross-correlating the experimental data with simulations results in a more detailed understanding of local evaporation aberrations during APT analysis of metal-oxide composites, paving the way towards a more accurate three-dimensional characterization of this technologically important class of materials.

Environmental Molecular Sciences Laboratory↗

Strong Local Evaporative Cooling Over Land Due to Atmospheric Aerosols

Abstract Aerosols can enhance terrestrial productivity through increased absorption of solar radiation by the shaded portion of the plant canopy—the diffuse radiation fertilization effect. Although this process can, in principle, alter surface evaporation due to the coupling between plant water loss and carbon uptake, with the potential to change the surface temperature, aerosol‐climate interactions have been traditionally viewed in light of the radiative effects within the atmosphere. Here, we develop a modeling framework that combines global atmosphere and land model simulations with a conceptual diagnostic tool to investigate these interactions from a surface energy budget perspective. Aerosols increase the terrestrial evaporative fraction, or the portion of net incoming energy consumed by evaporation, by over 4% globally and as much as ∼40% regionally. The main mechanism for this is the increase in energy allocation from sensible to latent heat due to global dimming (reduction in global shortwave radiation) and slightly augmented by diffuse radiation fertilization. In regions with moderately dense vegetation (leaf area index >2), the local surface cooling response to aerosols is dominated by this evaporative pathway, not the reduction in incident radiation. Diffuse radiation fertilization alone has a stronger impact on gross primary productivity (+2.18 Pg C y −1 or +1.8%) than on land evaporation (+0.18 W m −2 or +0.48%) and surface temperature (−0.01 K). Our results suggest that it is important for land surface models to distinguish between quantity (change in total magnitude) and quality (change in diffuse fraction) of radiative forcing for properly simulating surface climate.

Chakraborty, TC↗

Spatial pattern of lake evaporation increases under global warming linked to regional hydroclimate change

Abstract Lakes are critical natural resources that are vulnerable to climate change. In a warmer climate, lake evaporation is projected to increase globally, but with substantial variation between regions. Here, based on ensemble projections of climate and lake models and an attribution method, we show that future lake evaporation increase is strongly modulated by regional hydroclimate change. Specifically, a drying hydroclimate will amplify evaporation increase by enlarging surface vapor pressure deficit and reducing cloud shortwave reflection. Future lake evaporation increase is amplified in tropical America, the Mediterranean and Southeast China with drier future hydroclimates, and dampened in high latitudes and the Tibetan Plateau with wetter future hydroclimates. Such spatially coupled changes in lake evaporation and hydroclimate have important implications on regional lake water balance and volume change, which can aggravate water scarcity and flood risks.

54 ENVIRONMENTAL SCIENCES↗

A purely kinetic description of the evaporation of water droplets

The process of water evaporation, although deeply studied, does not enjoy a kinetic description that captures known physics and can be integrated with other detailed processes such as drying of catalytic membranes embedded in vapor-fed devices and chemical reactions in aerosol whose volumes are changing dynamically. In this work, we present a simple, three-step kinetic model for water evaporation that is based on theory and validated by using well-established thermodynamic models of droplet size as a function of time, temperature, and relative humidity as well as data from time-resolved measurements of evaporating droplet size. Additionally, the kinetic mechanism for evaporation is a combination of two limiting processes occurring in the highly dynamic liquid-vapor interfacial region: direct first order desorption of a single water molecule and desorption resulting from a local fluctuation, described using third order kinetics. The model reproduces data over a range of relative humidities and temperatures only if the interface that separates bulk water from gas phase water has a finite width, consistent with previous experimental and theoretical studies. The influence of droplet cooling during rapid evaporation on the kinetics is discussed; discrepancies between the various models point to the need for additional experimental data to identify their origin.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Direct numerical simulation of turbulent dispersion of evaporative aerosol clouds produced by an intense expiratory event

Airborne particles are a major route for transmission of COVID-19 and many other infectious diseases. When a person talks, sings, coughs, or sneezes, nasal and throat secretions are spewed into the air. After a short initial fragmentation stage, the expelled material is mostly composed of spherical particles of different sizes. While the dynamics of the largest droplets are dominated by gravitational effects, the smaller aerosol particles, mostly transported by means of hydrodynamic drag, form clouds that can remain afloat for long times. In subsaturated air environments, the dependence of pathogen-laden particle dispersion on their size is complicated due to evaporation of the aqueous fraction. Particle dynamics can significantly change when ambient conditions favor rapid evaporation rates that result in a transition from buoyancyto-drag dominated dispersion regimes. To investigate the effect of particle size and evaporation on pathogen-laden cloud evolution, a direct numerical simulation of a mild cough was coupled with an evaporative Lagrangian particle advection model. The results suggest that while the dispersion of cough particles in the tails of the size distribution are unlikely to be disrupted by evaporative effects, preferential aerosol diameters (30-40 μm) may exhibit significant increases in the residence time and horizontal range under typical ambient conditions. Using estimations of the viral concentration in the spewed fluid and the number of ejected particles in a typical respiratory event, we obtained a map of viral load per volume of air at the end of the cough and the number of virus copies per inhalation in the emitter vicinity.

60 APPLIED LIFE SCIENCES↗

Volatile propellant droplet evaporation measurements in metered dose inhaler sprays

Many aerosol products rely on the rapid vaporization of volatile propellants to produce a fine spray. In the simplest case, these are binary mixtures of propellant and a delivered product which undergo a flash-evaporation process leaving only the less volatile product in the resultant droplet. In more complex applications, such as pressurized metered-dose inhalers, the non-propellant component may contain dissolved or suspended drug which precipitates or dries to form a matured particle. The size and morphology of the particles depend strongly on the time-history of the droplet as the propellant evaporates. However, measuring the dynamic evaporation processes that occur in dense sprays containing millions of droplets is challenging. In this paper, we demonstrate a novel application of Ultra Small Angle X-ray Scattering to measure the bulk composition of volatile HFC134a–ethanol sprays and compare the obtained results with simple evaporation models in a dry nitrogen environment. The data reveal that diffusion-limiting processes inside the droplet are equally important as external convection and mixing-limited factors in determining evaporative timescales.

42 ENGINEERING↗

Efficiency Limits of Evaporative Fabric Drying Methods

Cloth drying is a major consumer of energy, and most drying is conducted by evaporative methods. The evaporative drying energy efficiency limit is commonly assumed to be 100%: one unit of latent heat removed per unit of energy expended. However, this ignores the “free drying” available from unsaturated ambient air and the possible role of heat pumping. We demonstrate that efficiency limits for evaporative drying are fundamentally related to both drying rate and ambient psychrometric conditions. A relationship among efficiency, drying rate, and ambient conditions is quantified for several evaporative drying technologies, and a comparison among evaporative technologies is provided. In addition, a comparison is provided between efficiency limits and state of the art device performance. This research will help guide future research in the most promising directions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

How important are electron beams in driving chromospheric evaporation in the 2014 March 29 flare?

We present high spatial resolution observations of chromospheric evaporation in the flare SOL2014-03-29T17:48. Interface Region Imaging Spectrograph observations of the Fe xxi λ1354.1 line indicate evaporating plasma at a temperature of 10 MK along the flare ribbon during the flare peak and several minutes into the decay phase with upflow velocities between 30 and 200 km s{sup −1}. Hard X-ray (HXR) footpoints were observed by the Ramaty High Energy Solar Spectroscopic Imager for two minutes during the peak of the flare. Their locations coincided with the locations of the upflows in parts of the southern flare ribbon but the HXR footpoint source preceded the observation of upflows in Fe xxi by 30–75 s. However, in other parts of the southern ribbon and in the northern ribbon, the observed upflows were not coincident with an HXR source in time or space, most prominently during the decay phase. In this case evaporation is likely caused by energy input via a conductive flux that is established between the hot (25 MK) coronal source, which is present during the whole observed time-interval, and the chromosphere. The presented observations suggest that conduction may drive evaporation not only during the decay phase but also during the flare peak. Electron beam heating may only play a role in driving evaporation during the initial phases of the flare.

79 ASTRONOMY AND ASTROPHYSICS↗

Factors influencing quantum evaporation of helium from polar semiconductors from first principles

While there is much indirect evidence for the existence of dark matter (DM), to date it has evaded detection. Current efforts focus on DM masses over ~GeV—to push the sensitivity of DM searches to lower masses, new DM targets and detection schemes are needed. In this work, we focus on the latter—a novel detection scheme recently proposed to detect 10–100 meV phonons in polar target materials. Previous work showed that well-motivated models of DM can interact with polar semiconductors to produce an athermal population of phonons. This new sensing scheme proposes that these phonons then facilitate quantum evaporation of 3 He from a van der Waals film deposited on the target material. However, a fundamental understanding of the underlying process is still unclear, with several uncertainties related to the precise rate of evaporation and how it can be controlled. In this work, we use ab initio density functional theory calculations to compare the adsorption energies of helium atoms on a polar target material, sodium iodide, to understand the underlying evaporation physics. We explore the role of surface termination, monolayer coverage, and elemental species on the rate of He evaporation from the target material. Using this, we discuss the optimal target features for He-evaporation experiments and their range of tunability through chemical and physical modifications such as applied field and surface termination.

36 MATERIALS SCIENCE↗

AP-105 Melter Offgas Condensate and EMF Evaporator Concentrate Raman and LIBS Qualitative Evaluation for the use of In-Line Monitoring (Rev. 0)

The Pacific Northwest National Laboratory (PNNL) was tasked to perform Raman spectroscopy and laser induced breakdown spectroscopy (LIBS) testing on the melter off-gas condensate generated during low-activity waste process testing of a sample from Hanford Site tank AP-105 and/or evaporate from evaporation of the condensate. This was a proof-of-principle demonstration that Raman spectroscopy and LIBS have the potential to be used as analytical tools for in-line process analysis of key aqueous phase analytes in radioactive process streams associated with the Hanford Waste Treatment and Immobilization Plant. The work completed under this project complements work completed for WRPS with the development of in-line monitoring systems to characterize and quantify constituents of tank waste following Cs removal and filtration. The WRPS work is currently limited to Raman sensors and utilizes chemometric models for quantification of several anionic species in the sample system. It should be noted that while this approach can be applied to off-gas condensate streams, new chemometric models are needed to accurately quantify analytes under off-gas condensate conditions. The work completed under this project makes timely use of available samples and equipment at PNNL. The project utilized the opportunity to collect off-gas samples from planned AP-105 processing work and included the direct condensate and the evaporate from the DFLAW Radioactive Waste Test Platform. Samples were characterized by instruments already in place at PNNL including a Raman spectrometer optimized for in-line monitoring of flowing and stationary samples as well as a LIBS instrument, which was optimized for static liquid droplet analysis. The ultimate objective was to determine if these techniques could be used to qualitatively characterize analytes present within the off-gas samples. The testing confirmed the use of the Raman as an in-line monitoring system was able to qualitatively observe NO 3 - , NO 2 - , aluminum (as aluminate, Al(OH) 4 - ), SO 4 2- , CrO 4 2- , CO 3 2- , and PO 4 3- in the AP-105 melter feed evaporator condensate samples. The testing also confirmed LIBS as a potential useful technique for in-line monitoring, able to qualitatively detect Na, N, Al, and tentatively Cr and Cl in a simulant stock evaporate solution.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Psychrometric Analysis for New NuMI Evaporator Weather Station

Tritium (H-3) is a weakly radioactive isotope of hydrogen and is a byproduct of accelerator operations at Fermi National Accelerator Laboratory (Fermilab). The Neutrinos at the Main Injector (NuMI) target produced tritiated condensate exhausted via the MI-65 building evaporators. Re-condensation of tritium evaporate was observed on the MI-65 rooftop, on nearby buildings, and on the surrounding grounds due to inefficiency of the existing evaporator system. A new evaporator system is being designed to eliminate re-condensation, and psychrometric data (temperature, humidity and dew point) plays a vital role in determining the location of a weather station to control the new evaporator system.

Alvarado-Anderson, Chase↗

Review of Dew Point Evaporative Cooling Technology for Air Conditioning Applications

Indirect evaporative cooling has the potential to significantly improve the natural environment. It follows from a significant reduction in electricity consumption in the hot period, and hence lower operating costs for cooling systems. This paper presents the current state of knowledge and research directions on dew point indirect evaporative cooling. It was found that researchers focus on the development of dew point indirect evaporative coolers (DPIEC) by improving its design, geometry, water distribution, and new porous materials implementation. To evaluate the performance of new types of DPIEC, different methods are used by the scientists. Finally, optimized devices are studied in terms of their performance in different systems, like hybrid and desiccant systems, considering different climate conditions. Potential directions of development of evaporative technologies were indicated, such as increasing the coefficient of performance of solid desiccant evaporative cooling systems, developing novel geometry, and efficient water distribution, including development of porous materials.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

The Evaporation and Survival of Cluster Galaxies’ Coronae. II. The Effectiveness of Anisotropic Thermal Conduction and Survival of Stripped Galactic Tails

We simulate anisotropic thermal conduction between the intracluster medium (ICM) and the hot coronal interstellar medium (ISM) gas in cluster galaxies. In Paper I, we simulated the evaporation of the hot ISM due to isotropic (possibly saturated) conduction between the ISM and ICM. We found that hot coronae evaporate on ∼10{sup 2} Myr timescales, significantly shorter than the ∼10{sup 3} Myr gas loss times due to ram pressure stripping. No tails of stripped gas are formed. This is in tension with the observed ubiquity and implied longevity of compact X-ray coronae and stripped ISM tails, and requires the suppression of evaporation, possibly due to magnetic fields and anisotropic conduction. We perform a series of wind tunnel simulations similar to that in Paper I, now including ISM and ICM magnetic fields. We simulate the effect of anisotropic conduction for a range of extreme magnetic field configurations: parallel and perpendicular to the ICM wind, and continuous and completely disjointed between the ISM and ICM. We find that when conduction is anisotropic, gas loss due to evaporation is severely reduced; the overall gas loss rates with and without anisotropic conduction do not differ by more than 10%–20%. Magnetic fields also prevent stripped tails from evaporating in the ICM by shielding, and providing few pathways for heat transport between the ICM and ISM. The morphology of stripped tails and magnetic fields in the tails and wakes of galaxies are sensitive to the initial magnetic field configuration.

79 ASTRONOMY AND ASTROPHYSICS↗

Real-World Evaluation of National Energy Efficiency Potential of Cold Storage Evaporator Technology in the Context of Engine Start-Stop Systems

National concerns over energy consumption and emissions from the transportation sector have prompted regulatory agencies to implement aggressive fuel economy targets for light-duty vehicles through the U.S. National Highway Traffic Safety Administration/Environmental Protection Agency (EPA) Corporate Average Fuel Economy (CAFE) program. Automotive manufacturers have responded by bringing competitive technologies to market that maximize efficiency while meeting or exceeding consumer performance and comfort expectations. In a collaborative effort among Toyota Motor Corporation, Argonne National Laboratory (ANL), and the National Renewable Energy Laboratory (NREL), the real-world savings of one such technology is evaluated. A commercially available Toyota Highlander equipped with two-phase cold storage technology was tested at ANL’s chassis dynamometer testing facility. The cold storage technology maintains the thermal state of air-conditioning evaporators to enable longer and more frequent engine-off operation in vehicles equipped with start-stop functionality. Test results were analyzed and provided to NREL where a novel simulation framework was developed and calibrated to the test data. The vehicle model was then exercised over a large set of real-world drive cycle and ambient condition data to estimate national-level fuel economy benefits. Results indicate that the cold storage evaporator provided national fuel consumption reductions of 0.113% relative to a conventional evaporator in the same vehicle. In addition, when the cold storage evaporator engine stop/start was enabled for any temperature and the baseline was limited to the EPA menu, Start and Stop credit assumption of 27°C, a national fuel savings of 0.497% was found. Fuel savings resulted from a combination of extended engine-off duration during idle events and increased frequency of deceleration fuel cutoff, both enabled by the ability of the cold storage evaporator to maintain thermal state in situations where air conditioning is active.

DIRECT ENERGY CONVERSION↗

The GEWEX LandFlux project: Evaluation of model evaporation using tower-based and globally gridded forcing data

Determining the spatial distribution and temporal development of evaporation at regional and global scales is required to improve our understanding of the coupled water and energy cycles and to better monitor any changes in observed trends and variability of linked hydrological processes. With recent international efforts guiding the development of long-term and globally distributed flux estimates, continued product assessments are required to inform upon the selection of suitable model structures and also to establish the appropriateness of these multi-model simulations for global application. In support of the objectives of the Global Energy and Water Cycle Exchanges (GEWEX) LandFlux project, four commonly used evaporation models are evaluated against data from tower-based eddy-covariance observations, distributed across a range of biomes and climate zones. The selected schemes include the Surface Energy Balance System (SEBS) approach, the Priestley–Taylor Jet Propulsion Laboratory (PT-JPL) model, the Penman–Monteith-based Mu model (PM-Mu) and the Global Land Evaporation Amsterdam Model (GLEAM). Here we seek to examine the fidelity of global evaporation simulations by examining the multi-model response to varying sources of forcing data. To do this, we perform parallel and collocated model simulations using tower-based data together with a global-scale grid-based forcing product. Through quantifying the multi-model response to high-quality tower data, a better understanding of the subsequent model response to the coarse-scale globally gridded data that underlies the LandFlux product can be obtained, while also providing a relative evaluation and assessment of model performance. Using surface flux observations from 45 globally distributed eddy-covariance stations as independent metrics of performance, the tower-based analysis indicated that PT-JPL provided the highest overall statistical performance (0.72; 61 W m –2 ; 0.65), followed closely by GLEAM (0.68; 64 W m –2 ; 0.62), with values in parentheses representing the R 2 , RMSD and Nash–Sutcliffe efficiency (NSE), respectively. PM-Mu (0.51; 78 W m –2 ; 0.45) tended to underestimate fluxes, while SEBS (0.72; 101 W m –2 ; 0.24) overestimated values relative to observations. A focused analysis across specific biome types and climate zones showed considerable variability in the performance of all models, with no single model consistently able to outperform any other. Results also indicated that the global gridded data tended to reduce the performance for all of the studied models when compared to the tower data, likely a response to scale mismatch and issues related to forcing quality. Rather than relying on any single model simulation, the spatial and temporal variability at both the tower- and grid-scale highlighted the potential benefits of developing an ensemble or blended evaporation product for global-scale LandFlux applications. Hence, challenges related to the robust assessment of the LandFlux product are also discussed.

58 GEOSCIENCES↗

Evaporation in space manufacturing

'Normal evaporation' equations for predicting the compositional changes with time and temperature have been developed and correlated with actual experimental data. An evaporative congruent temperature is defined and used to explain, predict, or plan space experiments on anomalous constitutional melting (on cooling) or solidification (on heating). Uneven evaporation causes reactive jetting forces capable of initiating new convection currents, nongravitational accelerations, surface vibrations, or other disturbances. Applications of evaporation to space manufacturing are described concerning evaporative purification, surface cooling, specimen selection, particles splitting, freezing data interpretation, material loss and dimensional control, and surface contamination or compositional changes.

Li, C. H.↗

Evaporative winds in X-ray binaries

Evaporation of gas from the surface of HZ Her by Her X-1 and its implications regarding the mass transfer process are examined further. The powerful soft X-ray flux results in an evaporation rate greater than previous estimates. The evaporative flow is shown to be subsonic at first, with the result that the capture of evaporated gas by Her X-1 may be efficient, and the self-excited wind mechanism is possible. A criterion for stabilization of mass transfer by stellar wind mass loss is derived. Possible mechanisms for the long-period variability of HZ Her are discussed. Evaporative winds are also estimated for Sco X-1 and Cyg X-2 spectra.

Basko, M. M.↗