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At least 199 records · Page 11

Correlation of Dimer-Linker-Induced Conformational Lock with Nonradiative Energy Loss in Organic Solar Cells

The efficiencies of dimer-based devices still lag those of their small molecule-based counterparts. This is primarily due to the considerable dihedrals in the dimer skeleton, which compromises the molecular packing, thus influencing the charge generation and nonradiative voltage loss (ΔV oc,nr ). Herein, we developed two dimeric acceptors with varied π-linkers to investigate the influence of linker-induced conformational lock on ΔV oc,nr . We find that the helically lapped O-shaped dimer delivers better intermolecular packing than the planar S-shaped one that incorporates a bulkier π-linker. However, its planar skeleton is instead more favorable for forming a compact and ordered stacking with the host acceptor in ternary blend. This possibly promotes exciton dissociation, thus reducing the nonradiative decay of excited states. Moreover, its longer exciton lifetime could offer additional charge-transfer channels. Finally, these contributions effectively minimize ΔV oc,nr to 0.195 eV, while delivering a high efficiency approaching 20% in the derived ternary device.

36 MATERIALS SCIENCE↗

Energy loss of a relativistic ion in a plasma.

The stopping power of a plasma for a relativistic heavy ion is calculated in a simplified derivation. The total contribution results from (1) individual electron scattering in the Coulomb field of the ion wherein large momentum transfers are involved and (2) small momentum transfers in which quantized plasma oscillations are excited. The resulting general formula for the stopping power is in agreement with a specialization of the results of a more elaborate treatment by Tsytovich. The nonrelativistic limit of the general formula agrees with an expression given earlier by Larkin from field-theory techniques and by the author in a Born-approximation approach. However, the general formula differs slightly in its details from that given by Hayakawa and Kitao.

Gould, R. J.↗