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At least 199 records · Page 11

Valley development on Hawaiian volcanoes

Work in progress on Hawaiian drainage evolution indicates an important potential for understanding drainage development on Mars. Similar to Mars, the Hawaiian valleys were initiated by surface runoff, subsequently enlarged by groundwater sapping, and eventually stabilized as aquifers were depleted. Quantitative geomorphic measurements were used to evaluate the following factors in Hawaiian drainage evolution: climate, stream processes, and time. In comparing regions of similar climate, drainage density shows a general increase with the age of the volcani island. With age and climate held constant, sapping dominated valleys, in contrast to runoff-dominated valleys, display the following: lower drainage densities, higher ratios of valley floor width to valley height, and more positive profile concavities. Studies of stream junction angles indicate increasing junction angles with time on the drier leeward sides of the major islands. The quantitative geomorphic studies and earlier field work yielded important insights for Martian geomorphology. The importance of ash mantling in controlling infiltration on Hawaii also seems to apply to Mars. The Hawaiian valley also have implications for the valley networks of Martian heavily cratered terrains.

Baker, Victor R.↗

Gale Crater: An Amazonian Impact Crater Lake at the Plateau/Plain Boundary

Gale is a 140-km diameter impact crater located at the plateau/plain boundary in the Aeolis Northeast subquadrangle of Mars (5S/223W). The crater is bordered in the northward direction by the Elysium Basin, and in eastward direction by Hesperian channels and the Aeolis Mensae 2. The crater displays a rim with two distinct erosion stages: (a) though eroded, the south rim of Gale has an apparent crest line visible from the north to the southwest (b) the west and northwest rims are characterized by a strong erosion that, in some places, partially destroyed the rampart, leaving remnant pits embayed in smooth-like deposits. The same type of deposits is observed north, outside Gale, it also borders the Aeolis Mensae, covers the bottom of the plateau scarp, and the crater floor. The central part of Gale shows a 6400 km2 subround and asymmetrical deposit: (a) the south part is composed of smooth material, (b) the north part shows spectacular terraces, streamlines, and channels. The transition between the two parts of the deposit is characterized by a scarp ranging from 200 to 2000 in high. The highest point of the scarp is at the center of the crater, and probably corresponds to a central peak. Gale crater does not show a major channel directly inflowing. However, several large fluvi systems are bordering the crater, and could be at the origin of the flooding of the crater, or have contributed to. One fluvial system is entering the crater by the southwest rim but cannot be accounted alone for the volume of sediment deposited in the crater. This channel erodes the crater floor deposit, and ends in a irregular-shaped and dark albedo feature. Gale crater shows the morphology of a crater filled during sedimentation episodes, and then eroded Part of the lower sediment deposition contained in Gale might be ancient and not only aqueous in origin. According to the regional geologic history, the sedimentary deposit could be a mixture of aeolian and pyroclastic material, and aqueous sedimentary material that can originate both from drainage of the regional subsurface aquifer, and/or from surface flood. The central deposit shows three main levels: (a) the current crater floor (north of Gale), (b) an ancient level about 200 rn higher (south of Gale), and (c) the massive terraced deposits. A crater statistics on the 15,400 kM2 area of the crater floor and deposit [3,41 gave: 259+/-112.4 craters, most of them partly embayed in the sedimentary deposit, and all inferior to 5-km diameter. For superimposed crater population only, the result is 194+/-112. The deduced relative ages ranges from Early to Middle Amazonian. The population of craters are comparable for the three levels, implying that the last sedimentation/erosion episode on Gale was recent and affected the whole crater. The streamlined morphology of the border of the deposit, the layering, the channels, and the terraces are compatible with a significant fluvio-lacustrine history of the site. Multiple levels may suggest different episodes, but the common statistical age of the three levels shows that the last episode involved the whole crater. The origin of the lake water in Gale may have varied in time. Three major contributions have been proposed: (a) the drainage of the regional underground aquifer by Gale crater over an area of 110-km radius around the crater which would have provided approximately 1,600 cubic km of water, (b), surface drainage entering Gale by the south and north rims. In the south, a 250-km long system originates in the cratered uplands in a Noachian crater material plain (Nc), and crosses Hesperian and Amazonian crater material plains (AHc) northward [1]. Several fluvial systems originate in the Aeolis Mensae, east of Gale. They may had two functions in time: to recharge, the underground aquifer in the region of Gale, and to supply surface water in the crater by overspilling the northern rim, and (c) surface floods that originated from the rising of the water level in the Elysium Basin. According to the Amazonian age of Gale's floor, and the erosion direction in the crater, a flood from Elysium Basin is the most likely event to explain the material observed in Gale, and the formation of the last lake. This last flood may have been important enough to flood the central deposit up to about 1400 m above the crater floor, leaving two islands (non stream lined features) at the center of the deposit. Terrace spacing suggests a regular drop of the lake level in time. Fractures in terraces perpendicular to the shoreline can be interpreted either as: (a) the result of the drainage systems during the waning of the lake, or (b) traces of the pressure of an ice-covered sheet associated with subglacial drainage. The presence of a lake of such volume during the Amazonian period is one more evidence that water was still active on Mars relatively recently. Gale crater offers the rare opportunity to unveil a key-period of the martian history. The Amazonian might proved not as cold and dry as previously thought. The presence of large lakes and basins (Elysium Basin is large as the Mediterranean Sea), reinforces the model of an extensive water activity during the Amazonian that has still to be understood in the context of an assumed cooling and drying planet. The sediments and rocks that were left of this period in Gale keep the record of the climatic conditions of the Amazonian and the clues that are missing to understand the climatic evolution of Mars. In addition, Gale crater presents the advantage to be located at the plateau/plain boundary, which has never been studied and contains information about the two main martian geological units. As a conclusion, we propose a table that summarizes the worthiness of a mission in Gale crater, and the expected science return relative to the objectives to be met by the Surveyor Program. Additional information contained in the original.

Cabrol, N. A.↗

Analysis of Ancient Fluvial Patterns on the Surface of Mars

This project involves the study of ancient fluvial patterns on the surface of Mars, including raised curvilinear features (RCFs) and negative relief channels. It requires the use of geological images provided by the Mars Reconnaissance Orbiter to determine how water shaped the surface of Mars in the form of rivers, lakes and/or oceans approximately 3.5 billion years ago, during the Noachian period. The role of the intern is to examine the images and record the corresponding measurements of ancient river systems in an Excel spreadsheet to assist in determining the Noachian water cycle on Mars. Resources used to make these measurements include the Arena software, hand-drawn sketch maps, Microsoft Word, Microsoft Excel and the images provided by the Mars Reconnaissance Orbiter. The Context Imager (CTX) returns black and white images at a resolution of six meters per pixel. The camera can take images with a width of 30 km and a length of 160 km. Seventeen images were observed in total. Images are analyzed and notes are taken concerning their terminal deposits, stream ordering and drainage pattern. The Arena software is utilized to make the images more visible by allowing control of contrast and magnification. Once the image is adjusted, measurements: length, average width, drainage basin area, sinuous ridge area are recorded, at a magnification of one, through using the line segment and polygon tools. After an image has been analyzed and measured, a sketch map is drawn in order to clearly identify the various segments, basins and terminal deposits the intern observed. Observations are used to further classify the fluvial patterns; their drainage pattern is defined as dendritic, parallel, trellis, rectangular, radial, centripetal, deranged or discordant. Once observational notes are completed, mathematical relations are used to determine drainage density, stream frequency, theoretic basin area and sinuosity index. These data will be added to a larger data set that will yield a comprehensive view of early Mars drainage systems. The data obtained from the work conducted will be used to characterize the nature and behavior of water on the surface of Mars. Thorough understanding of the Martian water cycle will serve as biologically significant information. Through working on this project, I acquired insight into the study of planet Mars, and skills in the Arena software as well as the organization of a vast amount of data.

Jethani, Henna↗

Compound flood simulations indicate rising public exposure to sewage-contaminated waters in Waikīkī, Hawai‘i

Waikīkī, Hawai‘i serves as a valuable case study for flood vulnerability due to its low elevation, present-day exposure to multiple flood sources, and role as the state’s economic engine. This study applies the high-resolution, open-source WRF-Hydro-CUFA (Coastal Urban Flood Application) model to simulate compound flood interactions among pluvial, fluvial, coastal, storm drain-driven, and subsurface processes, and to evaluate how flood characteristics in Waikīkī evolve under projected sea-level rise (SLR). Simulated water levels in an estuarine drainage canal, serving as the primary outlet for gravity-flow drainage from Waikīkī, show strong agreement with observations (r ≥ 0.935, R 2 ≥ 0.874), accurately reproducing flooding observed during recent 5-year and 50-year storm events. Simulations incorporating SLR demonstrate a shift in dominant flood drivers as sea levels rise. In addition, results identify critical thresholds at which elevated estuarine tailwater conditions cause widespread drainage backflow, eventually occurring in the absence of rainfall. These findings suggest that tidally driven flooding will progressively dominate over rainfall-driven events, increasing public exposure to highly contaminated canal and groundwater sources. The results underscore the urgent need to integrate water quality issues and drainage failure into coastal flood management strategies for low-lying urban environments, particularly those reliant on polluted estuarine waterways for stormwater management.

Compound flooding↗

Global River Topology (GRIT): A Bifurcating River Hydrography

Existing global river networks underpin a wide range of hydrological applications but do not represent channels with divergent river flows (bifurcations, multi‐threaded channels, canals), as these features defy the convergent flow assumption that elevation‐derived networks (e.g., HydroSHEDS, MERIT Hydro) are based on. Yet, bifurcations are important features of the global river drainage system, especially on large floodplains and river deltas, and are also often found in densely populated regions. Here we developed the first raster and vector‐based Global RIver Topology that not only represents the tributaries of the global drainage network but also the distributaries, including multi‐threaded rivers, canals and deltas. We achieve this by merging a 30 m Landsat‐based river mask with elevation‐generated streams to ensure a homogeneous drainage density outside of the river mask for rivers narrower than approximately 30 m. Crucially, we employ the new 30 m digital terrain model, FABDEM, based on TanDEM‐X, which shows greater accuracy over the traditionally used SRTM derivatives. After vectorization and pruning, directionality is assigned by a series of elevation, flow angle and continuity approaches. The new global network and its attributes are validated using gauging stations, comparison with existing networks, and randomized manual checks. The new network represents 19.6 million km of streams and rivers with drainage areas greater than 50 km 2 and includes 67,495 bifurcations. With the advent of hyper‐resolution modeling and artificial intelligence, GRIT is expected to greatly improve the accuracy of many river‐based applications such as flood forecasting, water availability and quality simulations, or riverine habitat mapping.

54 ENVIRONMENTAL SCIENCES↗

Dynamic soil columns simulate Arctic redox biogeochemistry and carbon release during changes in water saturation

Thawing Arctic permafrost can induce hydrologic change and alter redox conditions, shifting the balance of soil organic matter (SOM) decomposition. There remains uncertainty about how soil saturation and redox transitions impact dissolved and gas phase carbon fluxes, and efforts to link hydrobiogeochemical processes to ecosystem-scale models are limited. This study evaluates SOM decomposition of Arctic tundra soils using column experiments, water chemistry measurements, microbial community analysis, and a PFLOTRAN reactive transport model. Soil columns from a thermokarst channel (TC) and an upland tundra (UC) were exposed to cycles of saturation and drainage, which controlled carbon emissions. During saturation, an outflow of dissolved organic carbon from the UC soil correlated with elevated reduced iron and decreased pH; during drainage, UC carbon dioxide fluxes were 70% higher than TC fluxes. Intermittent methane release was observed for TC, consistent with higher methanogen abundance. Slower drainage in the TC soil correlated with more subtle biogeochemical changes. PFLOTRAN simulations captured experimental trends in soil carbon fluxes, oxygen concentrations, and water contents. The model was then used to evaluate additional soil water drainage rates. This study emphasizes the importance of considering hydrologic change when evaluating and simulating SOM decomposition in dynamic Arctic tundra environments.

54 ENVIRONMENTAL SCIENCES↗

Hydrologic response of artificially drained agricultural watersheds: insights from high-resolution integrated surface/subsurface simulations

Artificial drainage systems comprising subsurface networks of perforated pipes (tile drains) and engineered surface ditches are widely used to remove excess water from poorly drained agricultural regions. Artificial drainage lowers the water table by design but also has inadvertent effects on the watershed-scale hydrologic response with important implications for flood risk and nutrient exports. We investigated the effects of tile drains on watershed-scale hydrologic response in the Portage River, OH, Watershed using a high-resolution physically based integrated surface/subsurface hydrology model with recently developed capabilities to represent artificial drainage. Tile drains were found to enhance streamflow during times of low flow, generally consistent with previous studies. Streamflow flashiness was found to have a non-monotonic dependence on tile spacing with a minimum at intermediate spacings (∼50 m). Flashiness and the event hydrographs for small tile spacing were similar to the situation with no tiles, but flow paths from farm to stream were very different for those two end member cases, emphasizing the limitations of the stream hydrograph in characterizing hydrologic response. For typical tile spacings, peak flow can either be enhanced or attenuated by the presence of tiles, depending on the size of the event and the antecedent meteorological conditions. Tiles enhance peak flow when the event is below a threshold of ∼25 mm or when events arrive in dry conditions. Peak flow is reduced by tiles when events are large and arrive in conditions that are not overly dry. The dependence on event size and antecedent conditions is explained by differences in available storage and flow paths to the streams. These results provide additional insights into how tile drainage modulates event-scale hydrologic response, an important control on flood generation mechanisms and nutrient exports.

agricultural watershed↗

Physics of Channelization: Theory and Observation (Final Report)

This project investigated how the growth of erosive channels and resulting drainage networks can be influenced by the seepage of water out of the subsurface. The most significant results showed how channelization by seepage results in characteristic geometric signatures at the scale of the drainage network. These results were verified by comparing theoretical predictions to observations at a field site on the Florida Panhandle. The project's analyses of drainage networks throughout the contiguous United States suggested that seepage plays a significant role in shaping drainage systems in humid climates. Additional results concerned the shape of valley heads and the longitudinal profile of streams. Theoretical work suggested that the direction and rate of growth of streams can be predicted from symmetry arguments.

54 ENVIRONMENTAL SCIENCES↗

Non-linear hydrologic organization

We revisit three variants of the well-known Stommel diagrams that have been used to summarize knowledge of characteristic scales in time and space of some important hydrologic phenomena and modified these diagrams focusing on spatiotemporal scaling analyses of the underlying hydrologic processes. In the present paper we focus on soil formation, vegetation growth, and drainage network organization. We use existing scaling relationships for vegetation growth and soil formation, both of which refer to the same fundamental length and timescales defining flow rates at the pore scale but different powers of the power law relating time and space. The principle of a hierarchical organization of optimal subsurface flow paths could underlie both root lateral spread (RLS) of vegetation and drainage basin organization. To assess the applicability of scaling, and to extend the Stommel diagrams, data for soil depth, vegetation root lateral spread, and drainage basin length have been accessed. The new data considered here include timescales out to 150 Myr that correspond to depths of up to 240 m and horizontal length scales up to 6400 km and probe the limits of drainage basin development in time, depth, and horizontal extent.

58 GEOSCIENCES↗

Application of remote sensing technology to the solution of problems in the management of resources in Indiana

The author has identified the following significant results. Twenty-eight quarter sections were mapped, representing a total area of 4480 acres or approximately 1.25% of the county. Soil series were not consistently separated on a countywide basis. When internal drainage and parent materials were ascertained, a soil series could be predicted. Each soil spectral class represented one predominant drainage class with minor inclusions of other drainage classes. The same is true with conventional field mapping units that also contain minor inclusions of other drainage classes. Most wetlands could be identified in the LANDSAT classification. There appeared to be some confusion in distinguishing between different wetland types and between some wetland and upland cover types.

Weismiller, R. A.↗

Development of an information data base for watershed monitoring

Landsat multispectral scanner data, Defense Mapping Agency digital terrain data, conventional maps, and ground data were integrated to create a comprehensive information data base (the Image Based Information System), to monitor the water quality of the Lake Tahoe Basin. Landsat imagery was used as the planimetric base to which all other data were registered. A georeference image plane, which provided an interface between all data planes for the Lake Tahoe Basin data base, was created from the drainage basin map. The data base was used to extract each drainage basin for separate display. The Defense Mapping Agency-created elevation image was processed with VICAR software to produce a component representing slope magnitude, which was cross-tabulated with the drainage basin georeference table. Future applications of the data base include the development of precipitation modeling, surface runoff models, and classification of drainage basin cover types.

Smith, A. Y.↗

Erosion of Terrestrial Rift Flank Topography: A Quantitative Study

Many rifted or passive continental margins feature a seaward-facing erosional escarpment which abruptly demarcates deeply weathered, low relief, interior uplands from a deeply incised, high relief coastal zone. It is generally accepted that these escarpments originate at the time of continental rifting and propagate inland through the elevated rift flank topography at rates on the order of 1 km/Myr over the course of a margin's history. Considering the length of passive margins worldwide and an average rift flank plateau height of several hundred meters, it is clear that sediment eroded from passive margins is an important component of the mass flux from continents to oceans through geologic time. The overall goal of the research reported here is to develop a quantitative understanding of the kinematics of escarpment propagation across passive margins and the underlying geological processes responsible for this behavior. Plateau-bounding escarpments in general exhibit two basic forms depending on the direction of surface water drainage on the plateau interior relative to the escarpment. Where surface water flows away from the escarpment, the escarpment takes the form of subdued embayments and promontories, such that its overall trend remains fairly straight as it evolves with time. Where upland streams flow across the escarpment, it takes the form of dramatic, narrow gorges whose heads appear to propagate up the plateau drainage systems as large-scale knickpoints. From work on the Colorado Plateau, Schmidt (1987) noted that the Colorado River is located much closer to the Grand Canyon's south rim, a drainage divide escarpment, than to the north rim, which is a gorge-like escarpment. The main implication is that the gorge-like form might be associated with higher long-term average erosion rates compared to the drainage divide escarpment type.

Weissel, Jeffrey K.↗

A Computational Fluid Dynamics Study of Swirling Flow Reduction by using Anti-vortex Baffle

An anti-vortex baffle is a liquid propellant management device placed adjacent to an outlet of the propellant tank. Its purpose is to substantially reduce or eliminate the formation of free surface dip and vortex, as well as prevent vapor ingestion into the outlet, as the liquid drains out through the flight. To design an effective anti-vortex baffle, Computational Fluid Dynamic (CFD) simulations were undertaken for the NASA Ares I vehicle LOX tank subjected to the simulated flight loads with and without the anti-vortex baffle. The Six Degree-Of-Freedom (6- DOF) dynamics experienced by the Crew Launch Vehicle (CLV) during ascent were modeled by modifying the momentum equations in a CFD code to accommodate the extra body forces from the maneuvering in a non-inertial frame. The present analysis found that due to large moments, the CLV maneuvering has significant impact on the vortical flow generation inside the tank. Roll maneuvering and side loading due to pitch and yaw are shown to induce swirling flow. The vortical flow due to roll is symmetrical with respect to the tank centerline, while those induced by pitch and yaw maneuverings showed two vortices side by side. The study found that without the anti-vortex baffle, the swirling flow caused surface dip during the late stage of drainage and hence early vapor ingestion. The flow can also be non-uniform in the drainage pipe as the secondary swirling flow velocity component can be as high as 10% of the draining velocity. An analysis of the vortex dynamics shows that the swirling flow in the drainage pipe during the Upper Stage burn is mainly the result of residual vortices inside the tank due to conservation of angular momentum. The study demonstrated that the swirling flow in the drainage pipe can be effectively suppressed by employing the anti-vortex baffle.

Yang, H. Q.↗

A Computational Fluid Dynamics Study of Swirling Flow Reduction by Using Anti-Vortex Baffle

An anti-vortex baffle is a liquid propellant management device placed adjacent to an outlet of the propellant tank. Its purpose is to substantially reduce or eliminate the formation of free surface dip and vortex, as well as prevent vapor ingestion into the outlet, as the liquid drains out through the flight. To design an effective anti-vortex baffle, Computational Fluid Dynamic (CFD) simulations were undertaken for the NASA Ares I vehicle LOX tank subjected to the simulated flight loads with and without the anti-vortex baffle. The Six Degree-Of-Freedom (6-DOF) dynamics experienced by the Crew Launch Vehicle (CLV) during ascent were modeled by modifying the momentum equations in a CFD code to accommodate the extra body forces from the maneuvering in a non-inertial frame. The present analysis found that due to large moments, the CLV maneuvering has a significant impact on the vortical flow generation inside the tank. Roll maneuvering and side loading due to pitch and yaw are shown to induce swirling flow. The vortical flow due to roll is symmetrical with respect to the tank centerline, while those induced by pitch and yaw maneuverings showed two vortices side by side. The study found that without the anti-vortex baffle, the swirling flow caused surface dip during the late stage of drainage and hence early vapor ingestion. The flow can also be non-uniform in the drainage pipe as the secondary swirling flow velocity component can be as high as 10% of the draining velocity. An analysis of the vortex dynamics shows that the swirling flow in the drainage pipe during the Upper Stage burn is mainly the result of residual vortices inside the tank due to the conservation of angular momentum. The study demonstrated that the swirling flow in the drainage pipe can be effectively suppressed by employing the anti-vortex baffle.

Yang, H. Q.↗

A Computational Fluid Dynamics Study of Swirling Flow Reduction by Using Anti-Vortex Baffle

An anti-vortex baffle is a liquid propellant management device placed adjacent to an outlet of the propellant tank. Its purpose is to substantially reduce or eliminate the formation of free surface dip and vortex, as well as prevent vapor ingestion into the outlet, as the liquid drains out through the flight. To design an effective anti-vortex baffle, Computational Fluid Dynamic (CFD) simulations were undertaken for the NASA Ares I vehicle LOX tank subjected to the simulated flight loads with and without the anti-vortex baffle. The Six Degree-Of-Freedom (6-DOF) dynamics experienced by the Crew Launch Vehicle (CLV) during ascent were modeled by modifying the momentum equations in a CFD code to accommodate the extra body forces from the maneuvering in a non-inertial frame. The present analysis found that due to large moments, the CLV maneuvering has a significant impact on the vortical flow generation inside the tank. Roll maneuvering and side loading due to pitch and yaw are shown to induce swirling flow. The vortical flow due to roll is symmetrical with respect to the tank centerline, while those induced by pitch and yaw maneuverings showed two vortices side by side. The study found that without the anti-vortex baffle, the swirling flow caused surface dip during the late stage of drainage and hence early vapor ingestion. The flow can also be non-uniform in the drainage pipe as the secondary swirling flow velocity component can be as high as 10% of the draining velocity. An analysis of the vortex dynamics shows that the swirling flow in the drainage pipe during the Upper Stage burn is mainly the result of residual vortices inside the tank due to the conservation of angular momentum. The study demonstrated that the swirling flow in the drainage pipe can be effectively suppressed by employing the anti-vortex baffle.

Yang, H. Q.↗

Field-Scale Lysimeter Studies of Glass and Cementitious Waste Forms at the Hanford Site - 20392

The Hanford site Integrated Disposal Facility (IDF) will receive waste forms from vitrification activities at the Hanford Waste Treatment and Immobilization Plant (WTP). The waste form inventory to be disposed of at the IDF will consist of vitrified low-activity waste (LAW) in glass forms and solidified (or encapsulated) secondary wastes in cementitious forms. The IDF is a near-surface burial facility located near Hanford's Waste Treatment and Immobilization Plant in the 200 East Area of the site's Central Plateau. An extensive set of laboratory experimental data has been collected to support IDF performance assessment calculations of the eventual degradation of waste forms and mobility of contaminants. This paper describes the start of a field experiment to generate waste-form performance data on a larger scale (tens of centimeters), over a longer duration (five years or more), and under field conditions representative of the IDF. Results from this study are expected to improve model descriptions of contaminant mobility, reduce uncertainties about the representativeness of laboratory results in the IDF performance assessment, improve stakeholder confidence in the safe disposal of treated waste at the IDF, and facilitate the adoption of informed facility designs with the potential to reduce operational costs. A lysimeter test facility near Hanford's 200 West Area has been repurposed to carry out long-term assessments of waste forms buried in sediments excavated from the IDF. The waste forms are buried in large drainage lysimeters, open caissons that are two meters in diameter and three meters deep. Waste forms are buried in up to six locations in each lysimeter. Samplers collect pore water and drainage water beneath the waste forms and air from the pore space adjacent to waste forms. Sensors measure temperature, soil water content, soil water tension, and drainage flux. One lysimeter containing cementitious waste forms and one containing glass waste forms have been completed, along with a control lysimeter (without waste forms). The cementitious waste forms are Cast Stone grout formulations using a liquid secondary waste simulant and a generic Hanford high-salt simulant, as well as a hydrated lime-based grout formulation using a liquid secondary waste simulant. Technetium-99 and iodine-127 were added as tracers to monitor contaminant mobility. Glass waste forms were fabricated in two formulations (LAWA44 and ORLEC28), with rhenium and molybdenum tracers to monitor waste form degradation. The predicted performance of the waste forms in the lysimeters was modeled prior to installation to determine waste form size, tracer concentration/activity, and locations of sensors and samplers. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Revisiting the definition of field capacity as a functional parameter in a layered agronomic soil profile beneath irrigated maize

The soil water content at the condition of field capacity (θ FC ) is a key parameter in irrigation scheduling and has been suggested to be determined by running a synthetic drainage experiment until the flux rate (q) at the bottom of the soil profile achieves a predefined negligible value (q FC ). We question the impact of q FC on the assessment of field capacity. Moreover, calculating θ FC as the integral mean of the water content profile when q is equal to q FC is strictly valid only for uniform soil profiles. By contrast, this practice is ambiguous and biased for stratified soil profiles due to the soil water content discontinuity at the layer interfaces. In this study, the concept of field capacity was revisited and adapted to practical agronomic heuristics. By resorting to the assessment of root-zone water storage capacity (W), we envision field capacity as a functional hydraulic parameter derived from synthetic irrigation scheduling scenarios to minimize drought stress, drainage, and nitrate leachate below the root zone. A functional analysis was carried out on a 135-cm-thick layered soil profile beneath maize in eastern Nebraska. On-farm irrigation scheduling applications and agricultural practices were recorded for 20 years (2001–2020) at a daily time step. Hydrus-1D was calibrated and validated with direct measurements of the soil water retention curve and soil water content data, respectively, in each soil layer. A set of functional field capacity values was derived from 24 irrigation scheduling scenarios, and the optimal water storage capacity at field capacity (W FC ) was approximately 50 cm (corresponding to about 80% saturation in the soil profile). An average irrigation amount of 217.5 mm distributed over 21 events was obtained by using optimal irrigation scheduling, which was initiated when the matric pressure head took on a value of –700 cm and the irrigation rate was set at 1.0 cm d –1 . This irrigation practice ensured water storage at approximately the same level (ideally at W FC ) by sustaining only evapotranspiration fluxes in the uppermost portion of the root zone and by limiting excessive drainage. This protocol can be transferred to other agricultural fields.

54 ENVIRONMENTAL SCIENCES↗

The effect of original and initial saturation on residual nonwetting phase capillary trapping efficiency

Injection of supercritical carbon dioxide (CO 2 ) into geological formations is a strategy for both atmospheric greenhouse gas reduction (climate change mitigation) and enhanced oil recovery. To understand CO 2 trapping efficiency, the capillary trapping behaviors that immobilize subsurface fluids were analyzed at the pore-scale using pairs of proxy fluids representing the range of in situ nonwetting and wetting fluid properties encountered in geologic storage reservoirs. The pairs of fluids were cycled through imbibition and drainage processes using a flow cell apparatus containing a sintered glass bead column. Computed x-ray microtomography (microCT) was used to identify immobilized nonwetting fluid after imbibition and drainage events. From microCT images, the trapped residual (post-secondary imbibition) nonwetting phase was spatially correlated to both the original (post-primary imbibition) and the initial (post-primary drainage) nonwetting phase; this relationship is referred to here as the original saturation dependence (SO-dependence) and initial saturation dependence (SI-dependence), respectively. Significant trends of decreasing SO- and SI-dependence with increasing wetting and nonwetting fluid phase viscosities were observed. This finding implies that the amount of CO 2 injected and ultimately trapped is dependent on the nonwetting phase (e.g. oil or gas) already present in the formation, as well as on the manner in which supercritical CO 2 is initially injected, which are factors not considered in current trapping models. To explore the potential effect that varying viscosity and interfacial tension (IFT) might have on this process, we report on a variety of fluid pairs with different viscosities and IFT.

42 ENGINEERING↗