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At least 199 records · Page 11

Implementation and evaluation of multi-dual mode counter-current chromatography in the CUP Modeler software

Counter-current chromatography (CCC) is a separation technique that utilizes immiscible solvent pairs as stationary and mobile phases, which imparts numerous benefits compared to solid-liquid chromatography including the ability to treat either the more-dense or less-dense solvent layer as the mobile phase. Multi-dual mode (MDM) is a CCC elution mode capable of improving the separation of closely eluting compounds by alternating upper- and lower-layer solvent flows in opposing directions within the same separation. While some effort has been made to model MDM, implementation of these models in experimental design has yet to be widely adopted. Accordingly, we further developed our previously published cell utilized partitioning (CUP) model to include MDM predictions with CCC and packaged the full suite of CUP modeling capabilities into a user-friendly, open-source tool called the CUP Modeler. The mathematical model for MDM CCC was derived and validated with experimental separation of ethyl guaiacol (EG) and ethyl phenol (EP), two compounds that co-elute in our previously demonstrated reductive catalytic fractionation (RCF) lignin monomer isolation method. The developed MDM model provided insights into the effect of multiple operating parameters - including stationary phase retention, flow rate, column efficiency, feed concentration ratio, selectivity factor, and solute distribution ratios - on the separation yields, productivity, and purities. Our model agreed with prevailing understanding of MDM but also revealed new insights including that the ideal distribution ratios for co-eluting solutes to be separated by MDM is between 1.1 and 1.5, with the lower value ideally close to 1.25. Overall, this work provides fundamental insights for MDM process design and enables broader adoption of general liquid-liquid chromatography with a new, open-source user-friendly interface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Parametric fit to electron transport properties

Experimental data acquired over the past few years were gathered, and parametric fits made to these data. The following properties of electron transport were represented by simple functions of atomic number and energy: transmitted electron number, transmitted electron spectra, range, backscatter coefficient, angular distribution, energy deposition, bremsstrahlung intensity and energy spectra, and bremsstrahlung angular distribution and photon attenuation. The formulas cover the energy ranges of interest in space shielding problems (0.1 to 10.0 MeV). Procedures for using these formulas in practical situations are suggested.

Lonergan, J. A.↗

Analysis of the effect of engine characteristics on the external aerodynamics of STOL wing propulsion systems

The effects of engine presssure ratio, engine size, and engine location on the pressure distribution, lift coefficient, and flow field of a STOL wing propulsion system are presented. The flow variables of the engines are included in the two-dimensional potential flow analysis by considering the effects of mass flow coefficient at the engine inlet and thrust coefficient at the engine exit. A functional relation between these coefficients and engine pressure ratio is given. The results of this study indicate that the effect of engine pressure ratio on the external aerodynamics is a function of engine location. For engines located on the bottom of the wing, the highest pressure ratio engine resulted in the highest lift coefficient. For engines located on the top of the wing, the lowest pressure ratio engine resulted in the highest lift coefficient.

Albers, J. A.↗

Electron transport and space shielding handbook

The transport of electrons through material is discussed with emphasis on space radiation problems. Brief reviews of the electron radiation environment and electron transport properties are presented. Parametric representations of the electron transmitted fraction, energy spectrum, angular distribution, backscatter coefficient, and energy deposition are given as functions of electron energy and target material. Parametric equations for thick target bremsstrahlung are presented. Calculations of the transport of isotropically incident electrons relevant to space applications are shown. Comparisons of parametric representation with data, photon attenuation coefficients, electron energy deposition data, flux-to-dose conversion relations, and formalism applicable to space shielding problems are presented.

Shreve, D. C.↗

Normal loads program for aerodynamic lifting surface theory

A description of and users manual are presented for a U.S.A. FORTRAN 4 computer program which evaluates spanwise and chordwise loading distributions, lift coefficient, pitching moment coefficient, and other stability derivatives for thin wings in linearized, steady, subsonic flow. The program is based on a kernel function method lifting surface theory and is applicable to a large class of planforms including asymmetrical ones and ones with mixed straight and curved edges.

Medan, R. T.↗

Plasma kinetic processes in a strong d.c. magnetic field

Recent results in the kinetic theory of a strongly magnetized plasma are surveyed. Emphasis is on the electrostatic guiding-center plasma in two dimensions, in both the fluid and 'charged rod' descriptions. The basic kinetic description of the plasma is in terms of the statistically-distributed Fourier coefficients associated with the velocity and 'enstrophy' (charge density) fields. It is a universal tendency in such media for enstrophy to flow to shorter wavelengths but for energy to flow to longer wavelengths. A consequence of the energy flow to longer wavelengths is the generation of long-range order in the form of macroscopic vortices. These kinds of structure have been called 'convection cells' and can be extraordinarily efficient in transporting particles transverse to a magnetic field. The tendency to vortex formation can be disrupted by collisions between particles. Modifications of the Fokker-Planck equation for a plasma produced by a strong dc magnetic field are considered in both two and three dimensions.

Montgomery, D.↗

Three dimensional steady and unsteady asymmetric flow past wings of arbitrary planforms

The nonlinear discrete vortex method was extended to treat the problem of asymmetric flows past a wing with leading-edge separation, including steady and unsteady flows. The problem was formulated in terms of a body-fixed frame of reference, and the nonlinear discrete vortex method was modified accordingly. Only examples of flows past delta wings are presented. Comparison of these results with experimental results for a delta wing undergoing a steady rolling motion at zero angle of attack demonstrates the superiority of the present method in obtaining highly accurate loads. Numerical results for yawed wings at large angles of attack are also presented. In all cases, total load coefficients, pressure distributions and shapes of the free-vortex sheets are shown.

Kandil, O. A.↗

Plasma kinetic processes in a strong d.c. magnetic field

The electrostatic guiding center approximation is used to describe the kinetic processes of a strongly magnetized tenuous plasma in two dimensions, in both the fluid and charged rod descriptions. The basic kinetic description of the plasma is in terms of the statistically-distributed Fourier coefficients associated with the velocity and enstrophy (charge density) fields. It is shown that the system exhibits a tendency to long range order characterized by macroscopic vorticity concentrations comparable in size to that of the system. These types of structure have historically been called convection cells and can be quite efficient at transporting particles transverse to a magnetic field.

Montgomery, D.↗

Three dimensional steady and unsteady asymmetric flow past wings of arbitrary planforms

The nonlinear discrete vortex method is extended to treat the problem of asymmetric flows past a wing with leading edge separation, including steady and unsteady flows. The problem is formulated in terms of a body fixed frame of reference and the nonlinear-discrete vortex method is modified accordingly. Although the method is general, only examples of flows past delta wings are presented due to the availability of experimental data as well as approximate theories. Comparison of results with experimental results for a delta wing undergoing a steady rolling motion at zero angle of attack demonstrate the superiority of the present method over existing approximate theories in obtaining highly accurate loads. Numerical results for yawed wings at large angles of attack are also presented. In all cases, total load coefficients, pressure distributions, and shapes of the free vortex sheets are shown.

Kandil, O. A.↗

Exact results on the temperature dependence of the specific equilibrium recombination rate coefficient

Two theorems based on Laplace transforms are used to relate threshold and high energy behavior to a temperature dependent variable. A recombination reaction involving electrically neutral species is presented to illustrate the dynamics of the activation energy and the associated rate coefficient. The distribution functions are shown to correspond with those predicted by Boltzmann's equations.

Mickens, R. E.↗

Computations for the 16-foot transonic tunnel, NASA, Langley Research Center, revision 1

The equations used by the 16 foot transonic tunnel in the data reduction programs are presented in eight modules. Each module consists of equations necessary to achieve a specific purpose. These modules are categorized in the following groups: tunnel parameters; jet exhaust measurements; skin friction drag; balance loads and model attitudes calculations; internal drag (or exit-flow distributions); pressure coefficients and integrated forces; thrust removal options; and turboprop options. This document is a companion document to NASA TM-83186, A User's Guide to the Langley 16 Foot Transonic Tunnel, August 1981.

Mercer, Charles E.↗

Parameterization of near infrared absorption by atmospheric gases

An absorption coefficient (k) distribution model is presented for fast calculation of atmospheric transmittances based solely on essential data from line-by-line (LBL) calculations. The absorption at any site is summed over the spectra obtained by LBL calculations. Application of the scaling model is illustrated with sample calculations for 0.72 micron emissions and the 1.36 micron water vapor band. LBL absorption spectra are calculated for the pressure levels 260 mb, 400 mb and 1000 mb.

Ridgway, W. L.↗

Prediction of internal performance for two-dimensional convergent-divergent nozzles

A three-dimensional code (PAB3D) has been under development to simulate underexpanded and overexpanded supersonic jet exhaust effects on a nonaxisymmetric nozzle/afterbody. The code is a multiblock/multizone technique solving the simplified Navier-Stokes equations. This method was applied to the solution of two nozzle configurations to verify the recent implementation of a nozzle performance calculation package. Static pressure distributions, discharge coefficient and thrust ratio quantities were calculated for on-design and off-design operating conditions for rectangular convergent-divergent nozzles with different throat designs. Approaches involved in computing the flows for these nozzles are presented. Computation of performance parameters were typically within 1 percent of experimental on-design and off-design data.

Carlson, John R.↗

Prediction of static performance for single expansion ramp nozzles

A multiblock three-dimensional Navier-Stokes method was utilized in a two-dimensional fully implicit mode to calculate the flowfield of a single expansion ramp nozzle configuration. The code has been shown previously to be fairly accurate in predicting three-dimensional nozzle flowfields and internal performance for several axisymmetric and nonaxisymmetric geometries. A two-dimensional implementation of the method was used to reduce the resources required to obtain preliminary performance parameters of nozzle concepts. A two-dimensional description of a single-expansion ramp nozzle configuration was analyzed to verify the applicability of the Navier-Stokes code and nozzle performance package to this class of nozzles. Internal static pressure distributions, discharge coefficient and thrust ratio quantities were calculated for a range of operating conditions. Comparisons of predicted performance parameters with experimental data were within 0.5 percent for mass flow, and typically within l.5 percent for thrust ratio.

Carlson, John R.↗