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At least 199 records · Page 11

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NASA NTRS1997

The Effect of Micro-Gravity on in vitro Calcification

The experiment focuses on mineral deposition or calcification of cartilage. The experiments were used to compare the mineral formed in the microgravity of space with that formed on earth. Results of these experiments were anticipated to provide direct insight into how calcification in cartridge and bone may be controlled in space. In the C-2 experiment (STS 66), we found that mineralization started later in the cartridges (both on the ground and in hypo-gravity) than in plastic, and that mineralization appeared to be retarded in hypo-gravity. The flight experiments also showed that the cells differentiated normally, but more slowly than the ground controls, and that the matrix produced was not different from that made on the ground. The purpose of the C-5 experiment was to confirm these findings. The C-5 experiment was flown on STS-72. Because of a computer problem, cells received no gases and no nutrition. The C-7 was flown on STS-77. Ground controls were repeated a week later, however, because there was a problem with the temperature control during the flight, the concurrent ground controls were performed at a different temperature. Despite these problems, the results of the C-2 experiment were confirmed. The cells in the flight cultures did not mature, formed few cartilage nodules, and showed no evidence of mineral deposition up to a culture age of 28 days. Ground controls showed the presence of mineral (based on chemical, spectroscopic, and histochemical analyses) by 21 days. The mineral in these cultures was analogous to that found in calcifying cartilage of young chicks.

Boskey↗

NASA NTRS1978

Model potentials for electron scattering - Converged close coupling calculations for the differential cross section for e/-/N2 at 30-50 eV

A calculation has been made of the elastic scattering and rotational excitation cross sections for e(-)-N2 scattering at 30 and 50 eV using quantum chemical techniques specially designed to be applicable to elastic and inelastic electron scattering by general polyatomic molecules. The angle dependence of the sum of the elastic and rotational excitation differential cross sections is in good agreement with experiment at all scattering angles at both energies, but at 50 eV the difference from experiment exceeds the experimental uncertainty at small scattering angles and near the minimum of the differential cross section. At large scattering angles the rotational excitation cross sections are predicted to exceed the elastic scattering cross sections. The absolute cross sections agree with experiment at some angles but at other angles are as much as 51% (30 eV) or 90% (50 eV) higher; this may be due at least in part to the difficulty of putting the experimental results on an absolute scale.

Onda, K.↗

NASA NTRS1992

Investigation of the effects of Extra Vehicular Activity (EVA) and Launch and Entry (LES) gloves on performance

Human capabilities such as dexterity, manipulability, and tactile perception are unique and render the hand as a very versatile, effective and a multipurpose tool. This is especially true for unknown environments such as the EVA environment. In the microgravity environment interfaces, procedures, and activities are too complex, diverse, and defy advance definition. Under these conditions the hand becomes the primary means of locomotion, restraint, and material handling. Facilitation of these activities, with simultaneous protection from the cruel EVA environment are the two, often conflicting, objectives of glove design. The objectives of this study was (1) to assess the effects of EVA gloves at different pressures on human hand capabilities, (2) to devise a protocol for evaluating EVA gloves, (3) to develop force time relations for a number of EVA glove pressure combinations, and (4) to evaluate two types of launch and entry suit gloves. The objectives were achieved through three experiments. The experiments for achieving objectives 1, 2, and 3 were performed in the glove box in building 34. In experiment 1 three types of EVA gloves were tested at five pressure differentials. A number of performance measures were recorded. In experiment 2 the same gloves as in experiment 1 were evaluated in a reduced number of pressure conditions. The performance measure was endurance time. Six subjects participated in both the experiments. In experiment 3 two types of launch and entry suit gloves were evaluated using a paradigm similar to experiment 1. Currently the data is being analyzed. However for this report some summary analyses have been performed. The results indicate that a) With EVA gloves strength is reduced by nearly 50 percent, b) performance decrements increase with increasing pressure differential, c) TMG effects are not consistent across the three gloves tested, d) some interesting gender glove interactions were observed, some of which may have been due to the extent (or lack of) fit of the glove to the hand, and e) differences in performance exist between partial pressure suit glove and full pressure suit glove, especially in the unpressurized condition.

Bishu, Ram R.↗

DOE OSTI2020

Experimental investigation and thermodynamic modeling of the binary Pt–Sn system

Here, the thermodynamics of the Pt–Sn system is revisited with attention to phase equilibria involving PtSn 4 , a topological quantum material with interesting physical properties. The phase relationship in the Sn-rich region of the Pt–Sn binary system was investigated by a combination of differential scanning calorimetry and equilibration experiments. Based on the present experiments and a critical evaluation of the available thermodynamic and phase diagram data reported in the literature, thermodynamic assessments of the entire Pt–Sn system were performed using the CALPHAD approach. Two sets of thermodynamic parameters were optimized, where the liquid phase was described using the Bragg-Williams random mixing model and the associate solution model, respectively. The modeling results are compared with the reliable experimental data and are shown to provide good representations of the phase equilibria and thermodynamic properties in this system.

36 MATERIALS SCIENCE↗

DOE OSTI2020

Measurement of groomed jet substructure observables in p+p collisions at $\sqrt{s} =$ 200 GeV with STAR

In this letter, measurements of the shared momentum fraction ( z g ) and the groomed jet radius ( R g ), as defined in the SoftDrop algorithm, are reported in p+p collisions at s = 200 GeV collected by the STAR experiment. These substructure observables are differentially measured for jets of varying resolution parameters from R = 0.2 – 0.6 in the transverse momentum range 15 < p T , jet < 60 GeV/ c . These studies show that, in the p T , jet range accessible at s = 200 GeV and with increasing jet resolution parameter and jet transverse momentum, the z g distribution asymptotically converges to the DGLAP splitting kernel for a quark radiating a gluon. The groomed jet radius measurements reflect a momentum-dependent narrowing of the jet structure for jets of a given resolution parameter, i.e., the larger the p T , jet , the narrower the first splitting. For the first time, these fully corrected measurements are compared to Monte Carlo generators with leading order QCD matrix elements and leading log in the parton shower, and to state-of-the-art theoretical calculations at next-to-leading-log accuracy. We observe that PYTHIA 6 with parameters tuned to reproduce RHIC measurements is able to quantitatively describe data, whereas PYTHIA 8 and HERWIG 7, tuned to reproduce LHC data, are unable to provide a simultaneous description of both z g and R g , resulting in opportunities for fine parameter tuning of these models for p+p collisions at RHIC energies. We also find that the theoretical calculations without non-perturbative corrections are able to qualitatively describe the trend in data for jets of large resolution parameters at high p T , jet , but fail at small jet resolution parameters and low jet transverse momenta.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

DOE OSTI2021

Pulse Radiolysis Investigation of Radicals Derived from Water-Soluble Cyanine Dyes: Implications for Super-resolution Microscopy

Light-induced blinking, an inherent feature of many forms of super-resolution microscopy, has been linked to transient reduction of the fluorescent cyanine dye used as an imaging agent. There is, however, only scant literature information related to one-electron reduced cyanine dyes, especially in an aqueous environment. Here, we examine a small series of cyanine dyes, possessing disparate π-conjugation lengths, under selective reducing or oxidizing conditions. The experiment allows recording of both differential absorption spectra and decay kinetics of the resultant one-electron reduced or oxidized transient species in water. Relative to the ground state, absorption transitions for the various radicals are weak and somewhat broadened but do allow correlation with the π-conjugation length. In all cases, absorption maxima lie to the blue of the main ground-state transition. Under anaerobic conditions, the transient species decay on the microsecond to millisecond time scale, with the mean lifetime depending on molecular structure, radiation dose, and dye concentration. The experimental absorption spectra recorded for the one-electron reduced radicals and the presumed dimer cation radical compare well to spectra obtained from time-dependent density functional theory calculations. Furthermore, the results allow conclusions to be drawn regarding the plausibility of the reduced species being responsible for light-induced blinking in direct stochastic optical reconstruction microscopy.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

Unravel unusual hardening behavior of a Pd–Ni–P metallic glass in its supercooled liquid region

Monolithic metallic glasses often exhibit work softening induced by high atom mobility in the supercooled liquid region in tension. In this work, we report an unusual viscous flow of the Pd 42.5 Ni 42.5 P 15 metallic glass in its supercooled liquid region, which is characterized by a remarkable hardening behavior with decent plasticity during tension. To unravel the causes of this unusual hardening, we conducted structural and thermodynamic analyses by employing several experiments, including dynamic mechanical analysis, differential scanning calorimetry, high-resolution transmission electron microscopy, and in situ heating synchrotron high-energy x-ray diffraction. It was found that the unusual hardening behavior was attributed to structural ordering during deformation, rather than nanocrystallization or structural relaxation observed, sometimes, in metallic glasses deformed in supercooled liquid region. We also incorporated an additional work hardening region in the modified deformation map for metallic glasses.

36 MATERIALS SCIENCE↗

DOE OSTI2026

Observable CMB B -modes from cosmological phase transitions

A B -mode polarization signal in the cosmic microwave background (CMB) is widely regarded as smoking gun evidence for gravitational waves produced during inflation. Here, we demonstrate that tensor perturbations sourced during noninflationary epochs can yield non-negligible B -mode signals, which can in principle complicate the interpretation of future observational data. As a case study, we consider tensor perturbations sourced in the bubble collision stage of a first-order cosmological phase transition occurring in a secluded dark sector. Although phase transitions arise from causal subhorizon physics, they nevertheless exhibit a white noise power spectrum on superhorizon scales. Power is suppressed on the large scales relevant for CMB B -mode polarization, but it is not necessarily negligible. We show that for appropriately chosen phase transition parameters, the maximal B -mode amplitude can compete with inflationary predictions that can be tested with current and future experiments. These scenarios can be differentiated by performing measurements on multiple angular scales, since the phase transition signal predicts peak power on smaller scales.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2023

Advanced Fuel Cycle Cost Basis Report: Supporting Documents 2 Production Based Costing

The purpose of this section is to outline a method of cost analysis whereby a significantly better representation of “should achieve” costs may be attained for NOAK systems. Based on economists’ notions of producer theory, and grounded in the cost analysts’ and project managers’ tool called the Work Breakdown Structure (WBS), this section describes best practices in cost estimation. It then illustrates how the Code of Accounts (COA) structure, developed by the Economic Modeling Working Group (EMWG) of the Generation IV International Forum in “Cost Estimating Guidelines for Generation IV Nuclear Energy Systems [EMWG 2007] (hereafter “Gen IV Guidelines Document”), can be used to differentiate “should achieve” versus “did experience” costs.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2024

Measurement report: The Fifth International Workshop on Ice Nucleation phase 1 (FIN-01): intercomparison of single-particle mass spectrometers

Knowledge of the chemical composition and mixing state of aerosols at a single-particle level is critical for gaining insights into atmospheric processes. One common tool to make these measurements is single-particle mass spectrometry. There remains a need to compare the performance of different single-particle mass spectrometers (SPMSs). An intercomparison of SPMSs was conducted at the Aerosol Interaction and Dynamics in the Atmosphere (AIDA) chamber at the Karlsruhe Institute of Technology (KIT) in November 2014, as part of the first phase of the Fifth International Workshop on Ice Nucleation (FIN-01). In this paper we compare size distributions and mass spectra of atmospherically relevant particle types measured by five SPMSs. These include different minerals, desert and soil dusts, soot, bioaerosol (Snomax; protein granule), secondary organic aerosol (SOA), and SOA-coated mineral particles. Most SPMSs reported similar vacuum aerodynamic diameter (d va ) within typical instrumental ranges from ~100–200 nm (lower limit) to ~2–3 µm (upper limit). In general, all SPMSs exhibited a wide dynamic range (up to ~10 3 ) and high signal-to-noise ratio (up to ~10 4 ) in mass spectra. Common spectral features with small diversities in mass spectra were found with high average Pearson's correlation coefficients, i.e., for average positive spectra r avg-pos =0.74 ± 0.12 and average negative spectra r avg-neg =0.67 ± 0.22. We found that instrument-specific detection efficiency (DE) was more dependent on particle size than particle type, and particle identification favored the use of bipolar, rather than monopolar, instruments. Particle classification from “blind experiments” showed that all instruments differentiated SOA, soot, and soil dust and detected subtle changes in the particle internal mixing but had difficulties differentiating among specific mineral types and dusts. This study helps to further understand the capabilities and limitations of the single-particle mass spectrometry technique in general and the specific performance of the instrument in characterizing atmospheric aerosol particles.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1980

Zonal and meridional circulation of the lower atmosphere of Venus determined by radio interferometry

The results of the Pioneer Venus differential long-baseline interferometry experiment are presented. The velocity component of the Pioneer probes as they fell to the surface of Venus was calculated from the Doppler shift of the received signal, and the other two orthogonal components were determined by long-baseline interferometry. The ambient wind velocity was about 1 m/s or less near the surface of the planet and about 100 m/s at an altitude of about 65 km at all four probe locations. Strata of high wind shear were found at altitudes of 15, 45, and 60 km. The wind velocity was always directed within a few degrees of due west except at a few km above the surface. The dominant motion of the lower atmosphere seems to be a retrograde zonal rotation, and eddies appear to account for most of the instantaneous meridional velocity. The data suggest that, within the clouds, a thermally driven mean meridional circulation is superimposed upon the much more rapid zonal rotation.

Counselman, C. C., III↗

NASA NTRS1981

Cosmic ray detector for high energy iron nuclei

An experiment to directly measure the differential energy spectra of nuclei with charge between 15-28 inclusive with a balloon borne instrument is presented. A High Energy Gas Cerenkov Spectrometer (HEGCS) is described, and consists of a 3 m diam drum 4.5 m tall containing three light diffusion chambers. A hodoscopic array of scintillators emit light into the top and bottom light chambers which serve for track recordings of the trajectory and charge of incident cosmic rays. A center chamber pressure vessel, the HEGCS, has a 4.0 m sr and a threshold of 50 GeV/amu. The hexagonal array scintillators have 24 elements/array feeding photomultiplier tubes at the vertices between the scintillators, with other PMTs located around the top and bottom chambers to capture escaped scintillator light. The HEGCS is filled with freon-12, with reflective paint on the inner surface to convert UV Cerenkov photons into visible photons near 425 nm.

Streitmatter, R. E.↗

NASA NTRS1983

Investigation of superelastic electron scattering by laser-excited Ba - Experimental procedures and results

Differential (in angle) electron scattering experiments on laser-excited Ba-138 1P were carried out at 30- and 100-eV impact energies. The laser light was linearly polarized and located in the scattering plane. The superelastic scattering signal was measured as a function of polarization direction of the laser light with respect to the scattering plane. It was found at low electron scattering angles that the superelastic scattering signal was asymmetric to reflection of the polarization vector with respect to the scattering plane. This is in contradiction with theoretical predictions. An attempt was made to pinpoint the reason for this observation, and a detailed investigation of the influence of experimental conditions on the superelastic scattering was undertaken. No explanation for the asymmetry has as yet been found.

NASA NTRS1986

Linewidth characteristics of Raman-shifted dye laser output at 720 and 940 nm

A compact and simple simultaneous multi-wavelength dye laser cavity was developed for a differential absorption technique. Dielectric multilayer interference filters were inserted inside the cavities as tuning elements, and two types of a DIAL system were constucted by using the dye laser tuned with dielectric multilayer filters to measure NO2 concentration. The usefulness of this dye laser was clarified for the differential absoroption technique in outdoor experiments. Some basic designs of the laser cavity with these filters to get simultaneously multi-wavelength output are summarized.

Grossmann, B. E.↗

NASA NTRS1987

Airborne intercomparisons of carbon monoxide measurement techniques

Results from an airborne intercomparison of techniques to measure tropospheric levels of carbon monoxide (CO) are discussed. The intercomparison was conducted as part of the National Aeronautics and Space Administration's Global Tropospheric Experiment and included a laser differential absorption method and two grab sample/gas chromatograph methods. Measurements were obtained during approximately 90 flight hours, during which the CO mixing ratios ranged from about 60 to 140 ppbv. The level of agreement observed for the ensemble of measurements was well within the overall accuracy stated for each instrument. The correlation observed between the measurements from the respective pairs of instruments ranged from 0.85 to 0.98, with no evidence for the presence of either a constant or proportional bias between any of the instruments.

Hoell, James M., Jr.↗

NASA NTRS1991

Characterizing water/rock interaction in simulated comet nuclei via calorimetry: Tool for in-situ science, laboratory analysis, and sample preservation

Although results from the Giotto and Vega spacecraft flybys of comet P/Halley indicate a complex chemistry for both the ices and dust in the nucleus, carbonaceous chondrite meteorites are still regarded as useful analogs for the rocky components. Carbonaceous chondrites mixed with water enable simulation of water/rock interactions which may occur in cometary nuclei. Three general types of interactions can be expected between water and minerals at sub-freezing temperatures: heterogeneous nucleation of ice by insoluble minerals; adsorption of water vapor by hygroscopic phases; and freezing and melting point depression of liquid water sustained by soluble minerals. Two series of experiments were performed in a differential scanning calorimeter (DSC) with homogenized powders of the following whole-rock meteorites and comparison samples: Allende (CV3), Murchison (CM2), Orgueil (CI), Holbrook (L6), and Pasamonte (eucrite) meteorites as well as on peridotite (PCC-1, USGS), saponite (Sap-Ca-1, CMS), montmorillonite (STx-1, CMS), and serpentine (Franciscan Formation, California). Results are briefly discussed.

Allton, Judith H.↗

NASA NTRS1992

High-pressure melting of carbonaceous chondrite

Phase equilibria experiments investigating the melting and differentiation of the primordial Earth require a realistic 'initial' chemical composition. Carbonaceous chondrites are good analogues for the initial bulk chemical composition of an accreting early Earth because they contain approximately solar abundances of the non-volatile elements and are the most primitive objects yet sampled in the solar system.

Agee, Carl B.↗

NASA NTRS1998

Remote Sensing Measurements of Vertical and Horizontal Moisture Variations from Aircraft Instruments

The research in this paper focuses on describing vertical and horizontal of water vapor variability using two remote sensing aircraft instruments. To achieve this goal we will compare precipitable water and upper level humidity estimates derived from the each of the instruments. The Multispectral Atmospheric Mapping Sensor (MAMS) is a visible and infrared radiometer with similar channels to that of the GOES imager. MAMS has flown aboard the NASA ER-2 numerous times. It has been used to validate features observed with the previous series of GOES satellites. MAMS data has been used to study precipitable water and upper level water vapor as well as other geophysical parameters. MAMS provides the opportunity to obtain water vapor Imagery at 6.7 mm. Upper tropospheric humidity can be computed using this channel in a similar fashion to that of Soden and Bretherton. In addition to the water vapor channel, MAMS records data In 3 other Infrared channels and 8 visible and near Infrared bands at high spatial resolution (I 00 Abstract: m). The 1 1 and 12 mm infrared channels allow for the application of a split technique to derive total precipitable water. The Udar Atmospheric Sensing Experiment (LASE) which uses the Differential Absorption Udar (DIAL) technique for obtaining simultaneous water vapor and aerosol profiles through the entire troposphere. LASE operates In the 81 5 nm wavelength region and uses a double pulsed Ti:sapphire laser that is locked onto a water vapor line. LASE has good horizontal (IO km) and excellent vertical (300 m) resolution. MAMS and LASE collected data simultaneously on several ER-2 flights in September 1995. LASE mixing ratio profiles will be Integrated for comparison with MAMS precipitable water estimates and the upper tropospheric humidity will be computed for the layer observed by the MAMS 6.7 mm channel for comparison for this time period. Results show a significant correlation between the measurements of the two Instruments. Regions of high/low upper tropospheric humidity are apparent In measurements from both instruments. Also changes in boundary layer moisture depicted by LASE are reflected in the total precipitable water measured by MAMS.

Atkinson, R. J.↗