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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

TESS in the Extended Mission: A Powerful Tool for Time-Domain Exoplanet Science

Since its launch in 2018, the Transiting Exoplanet Survey Satellite (TESS) has embarked on an ambitious mission to image almost the entire sky in search of nearby transiting exoplanet systems. Upon completion of its Primary Mission in July 2020, TESS transitioned to its first Extended Mission, during which it has returned to both the southern and northern ecliptic hemispheres and revisited most of the targets it observed during the first two years of operation. With future Extended Missions likely, the end-to-end time baseline provided by TESS will significantly exceed that of Kepler, enabling a plethora of scientific investigations into time-domain exoplanet science. TESS has already established itself as an extremely productive tool for studying visible-wavelength exoplanet phase curves. During the Primary Mission, we carried out a systematic phase-curve analysis of more than 30 transiting exoplanet systems. These datasets constrained the dayside hemisphere brightness temperatures, day-night brightness contrasts, and optical geometric albedos of a wide range of gas giant planets, revealing some tantalizing trends that warrant further study. In particular, we uncovered a tentative positive correlation between geometric albedo and equilibrium temperature for gas giants with 1500 < Teq < 3000 K. The new light curves from the Extended Mission have refined the measured astrophysical parameters of the previously studied systems and yielded statistically significant secondary eclipse and phase-curve detections for dozens of more systems. By comparing the phase-curve properties obtained from TESS observations separated by months or years, we have also probed for possible atmospheric variability, as well as transit-timing variations due to orbital decay or additional companions. In this presentation, I will provide an overview of the main results from our ongoing multiyear study of TESS light curves and discuss potentially fruitful avenues for further research as TESS continues its all-sky survey into the future.

Ian Wong↗

Mixing Cell Model: A One-Dimensional Numerical Model for Assessment of Water Flow and Contaminant Transport in the Unsaturated Zone

This report describes the Mixing Cell Model code, a one dimensional model for water flow and solute transport in the unsaturated zone under steady state or transient flow conditions. The model is based on the principles and assumptions underlying mixing-cell model formulations. The unsaturated zone is discretized into a series of independent mixing cells. Each cell may have unique hydrologic, lithologic, and sorptive properties. Ordinary differential equations describe the material (water and solute) balance within each cell. Water-flow equations are derived from the continuity equation, assuming that unit gradient conditions exist at all times in each cell. Pressure gradients are considered implicitly through model discretization. Unsaturated hydraulic conductivity and moisture contents are determined by the material specific moisture-characteristic curves. Solute-transport processes include explicit treatment of advective processes, first order chain decay, and linear sorption reactions. Dispersion is addressed through implicit and explicit dispersion. Implicit dispersion is an inherent feature of all mixing-cell models and originates from the formulation of the problem in terms of mass balance around fully mixed volume elements. Expressions are provided that relate implicit dispersion to the physical dispersion of the system. Two FORTRAN codes were developed to solve the water flow and solute-transport equations: (1) the Mixing Cell Model for Flow (MCMF) solves transient water-flow problems and (2) the Mixing Cell Model for Transport (MCMT) solves the solute-transport problem. The transient water-flow problem is typically solved first by estimating the water flux through each cell in the model domain as a function of time using the MCMF code. These data are stored in either ASCII or binary files that are later read by the solute transport code (MCMT). Code output includes solute pore water concentrations, water and solute inventories in each cell and at each specified output time, and water and solute fluxes through each cell and specified output time. Computer run times for coupled transient water flow and solute transport were typically several seconds on a 2 GHz Intel Pentium IV desktop computer. The model was benchmarked against analytical solutions and finite element approximations to the partial differential equations (PDE) describing unsaturated flow and transport. Differences between the maximum solute flux estimated by the mixing cell model and the PDE models were typically less than two percent. This revision includes an option for a fixed concentration lower boundary condition for diffusive fluxes for versions 020321 and later.

54 ENVIRONMENTAL SCIENCES↗

Abundances and Transients from Neutron Star–White Dwarf Mergers

Abstract We systematically investigate the mergers of neutron star–white dwarf binaries from beginning to end, with a focus on the properties of the inflows and outflows in accretion disks and their electromagnetic emissions. Using population synthesis models, we determine a subset of these binaries in which the white dwarf companion undergoes unstable mass transfer and complete tidal disruption, forming a large accretion disk around the neutron star. The material evolves according to a one-dimensional advection-dominated accretion-disk model with nuclear burning, neutrino emissions, and disk-surface wind ejection. The extreme dynamics of the entire process have proven difficult to analyze, and thus currently, the properties are poorly understood. The outflows from the mergers are iron- and nickel-rich, giving rise to optical and infrared emissions powered by the decay of the radioactive iron-type isotopes, calculated via the SuperNu light-curve code. We find these systems capable of powering bright, yet short-lived, optical transients with the potential to power gamma-ray bursts.

79 ASTRONOMY AND ASTROPHYSICS↗

Actinide signatures in low electron fraction kilonova ejecta

ABSTRACT Neutron star (NS) mergers are known to produce heavy elements through rapid neutron capture (r-process) nucleosynthesis. Actinides are expected to be created solely by the r-process in the most neutron-rich environments. Confirming if NS mergers provide the requisite conditions for actinide creation is therefore central to determining their origin in the Universe. Actinide signatures in kilonova (KN) spectra may yield an answer, provided adequate models are available in order to interpret observational data. In this study, we investigate actinide signatures in neutron-rich merger ejecta. We use three ejecta models with different compositions and radioactive power, generated by nucleosynthesis calculations using the same initial electron fraction ($Y_e = 0.15$) but with different nuclear physics inputs and thermodynamic expansion history. These are evolved from 10 to 100 d after merger using the sumo non-local thermodynamic equilibrium (NLTE) radiative transfer code. We highlight how uncertainties in nuclear properties, as well as choices in thermodynamic trajectory, may yield entirely different outputs for equal values of $Y_e$. We consider an actinide-free model and two actinide-rich models, and find that the emergent spectra and light-curve evolution are significantly different depending on the amount of actinides present, and the overall decay properties of the models. We also present potential key actinide spectral signatures, of which doubly ionized $_{89}$Ac and $_{90}$Th may be particularly interesting as spectral indicators of actinide presence in KN ejecta.

Pognan, Quentin (ORCID:0000000152550782)↗

Understanding capacity fade in organic redox-flow batteries by combining spectroscopy with statistical inference techniques

Organic redox-active molecules are attractive as redox-flow battery (RFB) reactants because of their low anticipated costs and widely tunable properties. Unfortunately, many lab-scale flow cells experience rapid material degradation (from chemical and electrochemical decay mechanisms) and capacity fade during cycling (>0.1%/day) hindering their commercial deployment. In this work, we combine ultraviolet-visible spectrophotometry and statistical inference techniques to elucidate the Michael attack decay mechanism for 4,5-dihydroxy-1,3-benzenedisulfonic acid (BQDS), a once-promising positive electrolyte reactant for aqueous organic redox-flow batteries. We use Bayesian inference and multivariate curve resolution on the spectroscopic data to derive uncertainty-quantified reaction orders and rates for Michael attack, estimate the spectra of intermediate species and establish a quantitative connection between molecular decay and capacity fade. Our work illustrates the promise of using statistical inference to elucidate chemical and electrochemical mechanisms of capacity fade in organic redox-flow battery together with uncertainty quantification, in flow cell-based electrochemical systems.

25 ENERGY STORAGE↗

Multi-Wavelength Observations of the Type IIb Supernova 2009mg

We present Swift UVOT and XRT observations, and visual wavelength spectroscopy of the Type IIb supernova (SN) 2009mg, discovered in the Sb galaxy ESO 121-G26. The observational properties of SN 2009mg are compared to the prototype Type IIb SNe 1993J and 2008ax, with which we find many similarities. However,minor differences are discernible including SN 2009mg not exhibiting an initial fast decline or micro-band upturn as observed in the comparison objects, and its rise to maximum is somewhat slower leading to slightly broader light curves. The late-time temporal index of SN 2009mg, determined from 40 days post-explosion, is consistent with the decay rate of SN 1993J, but inconsistent with the decay of Co-56. This suggests leakage of gamma-rays out of the ejecta and a stellar mass on the small side of the mass distribution. Our XRT nondetection provides an upper limit on the mass-loss rate of the progenitor of M less than 1.5 x 10(exp -5) solar mass yr(exp -1). Modelling of the SN light curve indicates a kinetic energy of 0.15 sup +0.02 sub -0.13 x 10(exp 51) erg, an ejecta mass of 0.56 sup+0.10 sub -.26 solar mass and a Ni-56 mass of 0.10 plus or minus 0.01 solar mass.

Oates, S. R.↗

Simulating Discharge Curves of an All-Aqueous TRAB to Identify Pathways for Improving System Performance

Thermally regenerative ammonia batteries (TRABs) are an emerging technology that use low temperature heat (T < 150 °C) to recharge a flow battery that produces electrical power on demand. The all-aqueous copper TRAB can provide high power densities and thermal energy efficiencies relative to other devices that harvest energy from waste heat, but its performance is adversely impacted by the crossover of undesired species through the membrane and lower cell voltages compared to conventional batteries. In this work, we developed a numerical model to simulate discharge curves while accounting for crossover inefficiencies without tracking all electrolyte species through the membrane. The model was able to successfully reproduce discharge curves across a diverse range of battery conditions using a single fitting parameter to account for decay of electrode standard potential due to species crossover with minimal error (< 5%). The model was then used to simulate different design scenarios to estimate changes in energy output from alterations to the aspects of the battery electrolyte chemistry. Results from this study are used to identify pathways for improving future TRAB designs with respect to energy capacity and cost-effectiveness of the technology.

25 ENERGY STORAGE↗

The MXB1916-053/4U1915-05: Burst properties and constraints on a 50 minute binary secondary

Results are presented from OSO-8 and HEAO-1 A2 observations of 34 bursts from the X-ray burster MXB1916-053/4U1915-05 recently discovered to show a 50 minute binary period. While 11 burst previously reported all had similar light curves, 22 observed two years later show a factor of 3 range of peak fluxes and decay times between 3 and 20 s. Recurrence times between successive bursts vary between 3 and 6 hours. A ratio of steady flux to average burst flux of equiv 120 is developed. A burst observed with the HEAO-1 A2 experiment showed an initial temperature rise to a peak black body temperature of equiv 3 keV followed by the cooling typical of type I bursts. The burst was unusual in that the apparent projected size of a blackbody source increased by a factor of 3 during the cooling phase.

Swank, J. H.↗

MXB 1916-053/4U 1915-05 - Burst properties and constraints on a 50 minute binary secondary

Results are presented from OSO-8 and HEAO-1 A2 observations of 34 bursts from the X-ray burster MXB 1916-053/4U 1915-05 recently discovered to show a 50 minute binary period. While 11 burst previously reported all had similar light curves, 22 observed two years later show a factor of 3 range of peak fluxes and decay times between 3 and 20 s. Recurrence times betweeen successive bursts vary between 3 and 6 hours. A ratio of steady flux to average burst flux of equiv 120 is developed. A burst observed with the HEAO-1 A2 experiment showed an initial temperature rise to a peak black body temperature of equiv 3 keV followed by the cooling typical of type I bursts. The burst was unusual in that the apparent projected size of a blackbody source increased by a factor of 3 during the cooling phase. Previously announced in STAR as N83-34872

Swank, J. H.↗

The numerical design of a spherical baroclinic experiment for Spacelab flights

The near-zero G environment of Spacelab is the basis of a true spherical experimental model of synoptic scale baroclinic atmospheric processes, using a radial dielectric body force analogous to gravity over a volume of liquid within two concentric spheres. The baroclinic motions are generated by corotating the spheres and imposing thermal boundary conditions, such that the liquid is subjected to a stable radial gradient and a latitudinal gradient. Owing to mathematical difficulties associated with the spherical geometry, quantitative design criteria can be acquired only by means of numerical models. The procedure adopted required the development of two computer codes based on the Navier-Stokes equations. The codes, of which the first calculates axisymmetric steady flow solutions and the second determines the growth or decay rates of linear wave perturbations with different wave numbers, are combined to generate marginal stability curves.

Fowlis, W. W.↗

Pre-mixed flame simulations for non-unity Lewis numbers

A principal effect of turbulence on premixed flames in the flamelet region is to wrinkle the flame fronts. For non-unity Lewis numbers (Le), the local flame structure is altered in curved regions. This effect is examined using direct numerical simulations of the three dimensional, constant density, decaying isotropic turbulence with a single step, finite rate chemical reaction. Simulations of Lewis numbers 0.8, 1.0, and 1.2 are compared. The turbulent flame speed, S(sub T), increases as Le decreases. The correlation between S(sub T) and u prime found in previous Le = 1 simulations has a strong Lewis number dependency. The variance of the pdf of the flame curvature increases as Le decreases, indicating that the flames become more wrinkled. A strong correlation between local flame speed and curvature was found. For Le greater than 1, the flame speed increases in regions concave towards the products and decreases in convex regions. The opposite correlation was found for Le less than 1. The mean temperature of the products was also found to vary with Lewis number. For Le = 0.8, it is less than the adiabatic flame temperature and for Le = 1.2 it is greater.

Rutland, C. J.↗

P/Halley - Effects of time-dependent production rates on spatial emission profiles

Spatial profiles of C2, CN, NH2, and O(D-1) in Comet P/Halley taken on 1986 March 1.54 and 2.55 and April 14.32 and 15.30 clearly show the effect of the 7 day periodic variation seen in photometric observations. With a time-dependent model based upon the light curve and employing standard scale lengths for each species reduced to the appropriate heliocentric distance, we are able to reproduce the highly variable profiles for all species. We computed the phase lag and amplitude correction between the actual gas production at the nucleus and the temporal/spatial filter imposed by the finite aperture photometry. For early March we find a phase lag and amplitude correction of 12 hr and -9 percent, respectively, whereas in mid-April the values are 6 hr and -27 percent. The same phase lag and amplitude correction work equally well for all four species despite their wide variation in photochemical lifetimes for production and decay. The same model integrated over circular apertures is able to reproduce the entire published March and April photometric light curves for C2. Our results require the use of the 7.60 day period for the March data as opposed to the 7.37 day period that is relevant for the April data, in agreement with the published analysis of the photometric data. Our results will help to reconcile the placement of active areas on the surface of Halley's comet with various remote observations and spacecraft images of the nucleus.

Combi, Michael R.↗

Comprehensive Insights into Nucleation, Autocatalytic Growth, and Stripping Efficiency for Lithium Plating in Full Cells

Synchrotron high-energy X-ray diffraction is used to enable nondestructive detection and quantification of heterogeneous lithium plating in working batteries. In this study a LiNi 0.5 Mn 0.3 Co 0.2 O 2 /graphite pouch cell was operated under 6C fast-charge rate for greater than 1200 cycles. The magnitude and spatial distribution of lithium plating, lithium stripping, and the effect of metallic lithium deposition on lithium intercalation into graphite were quantified. Fully intercalated graphite (LiC 6 ) was detected after discharge with a lateral distribution closely correlated with lithium plating, which can be used as a higher-sensitivity indicator for lithium plating. Over an extended cycle life, the overall metallic lithium concentration followed a sigmoidal curve indicating two-stage continuous nucleation and autocatalytic growth. The lithium stripping efficiency underwent an exponential decay as a function of cycle life as the buildup of metallic lithium hindered the efficient dissolution back into the electrolyte. The findings provide direct insights into the characteristics of lithium plating and stripping under realistic fast-charge conditions.

25 ENERGY STORAGE↗

Temperature dependence of the time decay of the magnetization in particulate media

The time decay of magnetization in commercial CrO2, gamma-Fe2O3, and Co-doped gamma-Fe2O3 tapes is investigated experimentally at temperatures 6, 50, 100, 200, 250, and 300 K. The decay is found to be linearly dependent on temperature in all four tapes tested, but when the curves are extrapolated to 0 K, there is a large finite intercept - in contrast to similar measurements on ferromagnetic materials and rocks.

Oseroff, S. B.↗

Photometric and spectroscopic observations of SN 1990E in NGC 1035 - Observational constraints for models of type II supernovae

We present 126 photometric and 30 spectral observations of SN 1990E spanning from 12 days before B maximum to 600 days past discovery. These observations show that SN 1990E was of type II-P, displaying hydrogen in its spectrum, and the characteristic plateau in its light curve. SN 1990E is one of the few SNe II which has been well observed before maximum light, and we present evidence that this SN was discovered very soon after its explosion. In the earliest spectra we identify, for the first time, several N II lines. We present a new technique for measuring extinction to SNe II based on the evolution of absorption lines, and use this method to estimate the extinction to SN 1990E, A(V) = 1.5 +/- 0.3 mag. From our photometric data we have constructed a bolometric light curve for SN 1990E and show that, even at the earliest times, the bolometric luminosity was failing rapidly. We use the late-time bolometric light curve to show that SN 1990E trapped a majority of the gamma rays produced by the radioactive decay of Co-56, and estimate that SN 1990E ejected an amount of Ni-56 virtually identical to that of SN 1987A.

Schmidt, Brian P.↗

The Central Engine of GRB 130831A and the Energy Breakdown of a Relativistic Explosion

Gamma-ray bursts (GRBs) are the most luminous explosions in the Universe, yet the nature and physical properties of their energy sources are far from understood. Very important clues, however, can be inferred by studying the afterglows of these events. We present optical and X-ray observations of GRB 130831A obtained by Swift, Chandra, Skynet, Reionization And Transients Infra-Red camera, Maidanak, International Scientific Optical-Observation Network, Nordic Optical Telescope, Liverpool Telescope and Gran Telescopio Canarias. This burst shows a steep drop in the X-ray light curve at asymptotically equal to 10(exp 5) s after the trigger, with a power-law decay index of alpha that is approximately 6. Such a rare behaviour cannot be explained by the standard forward shock (FS) model and indicates that the emission, up to the fast decay at 10(exp 5) s, must be of internal origin, produced by a dissipation process within an ultrarelativistic outflow. We propose that the source of such an outflow, which must produce the X-ray flux for an asymptotically equal to 1 d in the cosmological rest frame, is a newly born magnetar or black hole. After the drop, the faint X-ray afterglow continues with a much shallower decay. The optical emission, on the other hand, shows no break across the X-ray steep decrease, and the late-time decays of both the X-ray and optical are consistent. Using both the X-ray and optical data, we show that the emission after an asymptotically equal to 10(exp 5) scan be explained well by the FS model. We model our data to derive the kinetic energy of the ejecta and thus measure the efficiency of the central engine of a GRB with emission of internal origin visible for a long time. Furthermore, we break down the energy budget of this GRB into the prompt emission, the late internal dissipation, the kinetic energy of the relativistic ejecta,and compare it with the energy of the associated supernova, SN 2013 fu.

radiation mechanisms: non-thermal – shock waves ↗

Repeatable, multiple-peaked structure in Type I X-ray bursts

A distinct, identifiable, multiple-peaked structure has been observed in Type I X-ray bursts from three sources. At energies below 6 keV, the light curves look like typical Type I bursts. At higher energies, the burst is double-peaked, with both the depth of the dip and the separation between the peaks increasing with energy. A light curve of the energy-integrated intensity shows no distinct double peak, suggesting that only a single energy release occurs. Blackbody fits to the evolving burst spectra yield changing radii and temperatures, inversely correlated, during the early part of the burst. The physical interpretation of these changes is uncertain. Burst decay spectra yield relatively constant radii with decreasing temperatures. It is proposed that Compton scattering may be responsible for the dips in the higher-energy light curves by shifting photons to lower energies.

Hoffman, J. A.↗