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At least 199 records · Page 11

Electrode-molecule energy level offsets in a gold-benzene diamine-gold single molecule tunnel junction

One means for describing electron transport across single molecule tunnel junctions (MTJs) is to use density functional theory (DFT) in conjunction with a nonequilibrium Green’s function formalism. This description relies on interpreting solutions to the Kohn–Sham (KS) equations used to solve the DFT problem as quasiparticle (QP) states. Many practical DFT implementations suffer from electron self-interaction errors and an inability to treat charge image potentials for molecules near metal surfaces. For MTJs, the overall effect of these errors is typically manifested as an overestimation of electronic currents. Correcting KS energies for self-interaction and image potential errors results in MTJ current–voltage characteristics in close agreement with measured currents. An alternative transport approach foregoes a QP picture and solves for a many-electron wavefunction on the MTJ subject to open system boundary conditions. It is demonstrated that this many-electron method provides similar results to the corrected QP picture for electronic current. The analysis of these two distinct approaches is related through corrections to a junction’s electronic structure beyond the KS energies for the case of a benzene diamine molecule bonded between two gold electrodes.

Szepieniec, Mark S.↗

Dynamic Density: An Air Traffic Management Metric

The definition of a metric of air traffic controller workload based on air traffic characteristics is essential to the development of both air traffic management automation and air traffic procedures. Dynamic density is a proposed concept for a metric that includes both traffic density (a count of aircraft in a volume of airspace) and traffic complexity (a measure of the complexity of the air traffic in a volume of airspace). It was hypothesized that a metric that includes terms that capture air traffic complexity will be a better measure of air traffic controller workload than current measures based only on traffic density. A weighted linear dynamic density function was developed and validated operationally. The proposed dynamic density function includes a traffic density term and eight traffic complexity terms. A unit-weighted dynamic density function was able to account for an average of 22% of the variance in observed controller activity not accounted for by traffic density alone. A comparative analysis of unit weights, subjective weights, and regression weights for the terms in the dynamic density equation was conducted. The best predictor of controller activity was the dynamic density equation with regression-weighted complexity terms.

Laudeman, I. V.↗

The Imaging X-Ray Polarimetry Explorer (IXPE)

The Imaging X-ray Polarimetry Explorer (IXPE) is an exciting international collaboration for a scientific mission that dramatically brings together the unique talents of the partners to expand observation space by simultaneously adding polarization measurements to the array of source properties currently measured (energy, time, and location). IXPE uniquely brings to the table polarimetric imaging. IXPE will thus open new dimensions for understanding how X-ray emission is produced in astrophysical objects, especially systems under extreme physical conditions-such as neutron stars and black holes. Polarization singularly probes physical anisotropies-ordered magnetic fields, aspheric matter distributions, or general relativistic coupling to black-hole spin-that are not otherwise measurable. Hence, IXPE complements all other investigations in high-energy astrophysics by adding important and relatively unexplored information to the parameter space for studying cosmic X-ray sources and processes, as well as for using extreme astrophysical environments as laboratories for fundamental physics.

X-ray astronomy x-ray polarimetry↗

Reconfigurable Drive Current System

A reconfigurable drive current system includes drive stages, each of which includes a high-side transistor and a low-side transistor in a totem pole configuration. A current monitor is coupled to an output of each drive stage. Input channels are provided to receive input signals. A processor is coupled to the input channels and to each current monitor for generating at least one drive signal using at least one of the input signals and current measured by at least one of the current monitors. A pulse width modulation generator is coupled to the processor and each drive stage for varying the drive signals as a function of time prior to being supplied to at least one of the drive stages.

Alhorn, Dean C.↗

ARTSN: An Automated Real-Time Spacecraft Navigation System

As part of the Deep Space Network (DSN) advanced technology program an effort is underway to design a filter to automate the deep space navigation process.The automated real-time spacecraft navigation (ARTSN) filter task is based on a prototype consisting of a FORTRAN77 package operating on an HP-9000/700 workstation running HP-UX 9.05. This will be converted to C, and maintained as the operational version. The processing tasks required are: (1) read a measurement, (2) integrate the spacecraft state to the current measurement time, (3) compute the observable based on the integrated state, and (4) incorporate the measurement information into the state using an extended Kalman filter. This filter processes radiometric data collected by the DSN. The dynamic (force) models currently include point mass gravitational terms for all planets, the Sun and Moon, solar radiation pressure, finite maneuvers, and attitude maintenance activity modeled quadratically. In addition, observable errors due to troposphere are included. Further data types, force and observable models will be ncluded to enhance the accuracy of the models and the capability of the package. The heart of the ARSTSN is a currently available continuous-discrete extended Kalman filter. Simulated data used to test the implementation at various stages of development and the results from processing actual mission data are presented.

Burkhart, P. Daniel↗

ORNL Contributions to the ENDF/B-VIII.1 Library [Slides]

For uranium and plutonium isotopes, evaluation work is converging to a stable configuration with an overall satisfactory benchmark performance (more information on the validation tests after CSEWG). Strontium evaluation was included in the repository library and successfully tested by processing codes relative to an alternative quantification of the external function. Cerium covariance matrices were updated to address review comments on the magnitude of the uncertainty. For future uncertainty quantification, theoretical observables should be properly decoupled from current measured guidelines. Tests to correctly include LP (from resonance parameters) fitted to measured energy-averaged data are in progress. Current ENDF files contains experimental LP data.

07 ISOTOPE AND RADIATION SOURCES↗

Middle-atmosphere positive ion measurements during solar eclipses

Solar effects on middle-atmosphere electrical parameters, as demonstrated by eclipse-associated responses of conductivity, ion mobility, and charge density, are considered for the total solar eclipses at Red Lake, Ontario, Canada on February 26, 1979 and at San Marco range, Kenya, on February 16, 1980. Negative-conductivity measurements for the Canadian eclipse and probe-current measurements for the Kenyan eclipse demonstrate a rapid loss of free electrons below 80 km at totality. During the Kenyan eclipse, positive-ion responses were different for each of two distinct ion mobility groups. Between 45 and 60 km, eclipse-related positive-ion responses are associated with the low-mobility ions. It is shown that these ions are lost at totality and that an excess buildup occurs following totality. Above 70 km, positive-ion loss at totality is associated with the more mobile ions and only low-mobility positive ions are measured in this region. The buildup in total ion density following totality is thought to result from a reduction in ion loss associated with weak-electron recovery in the region.

Mitchell, J. D.↗

Spacelab 1 experiments on interactions of an energetic electron beam with neutral gas

An unusual signature of return current and spacecraft charging potential was observed during the Spacelab 1 mission launched on November 28, 1983. The phenomenon occurred during neutral gas releases from the SEPAC (Space Experiments with Particle Accelerators) magnetoplasma-dynamic arcjet (MPD) concurrent with firings of the PICPAB (Phenomena Induced by Charged Particle Beams) electron gun and was recorded by the instruments of the SEPAC diagnostic package (DGP). Data from the langmuir probe, floating probes, neutral gas pressure gauge, and the plasma wave probes are reported. As the dense neutral gas was released, the return current measured by the langmuir probe changed from positive to negative and a positive potential relative to the spacecraft was measured by the floating probe. The anomalous return current is believed to be attributable to secondary electron fluxes escaping from the spacecraft, and the unusual charging situation is attributed to the formation of a double-layer structure between a hot plasma cloud localized to the MPD and the spacecraft. The charging scenario is supported by a computer simulation.

Marshall, J. A.↗

Lighting application efficacy: A framework for holistically measuring lighting use in buildings

Lighting consumes significant energy in buildings, but current measurements of lighting efficiency are inadequate in capturing the spatial and temporal effectiveness of light. The most widely used lighting energy efficiency measure, luminous efficacy, quantifies the amount of light generated by individual light sources. While luminous efficacy provides manufacturers and designers with a useful metric for quantifying the energy efficiency of individual lighting devices, it does not fully address the use of lighting in architectural spaces. Instead, application efficacy, the relationship between the electrical power consumed by lighting hardware and the amount of light that contributes to the visual perception of building occupants, must be measured. Here, we propose a framework for calculating lighting application efficacy (LAE) based on the primary pathway of light in architectural settings: the generation and emission of light from a luminaire, the travel of the light throughout the space and into occupants’ eyes, and the process of visual perception. The LAE framework will include the development of computational methods for estimating the proportion of emitted light that is directed to task areas and areas corresponding to occupants’ visual fields using ray-tracing lighting design software. Future modeling and validation work will quantify energy efficiency of buildings.

Durmus, Dorukalp↗

Method and apparatus for Delta Kappa synthetic aperture radar measurement of ocean current

A synthetic aperture radar (SAR) employed for delta k measurement of ocean current from a spacecraft without the need for a narrow beam and long observation times. The SAR signal is compressed to provide image data for different sections of the chirp band width, equivalent to frequencies and a common area for the separate image fields is selected. The image for the selected area at each frequency is deconvolved to obtain the image signals for the different frequencies and the same area. A product of pairs of signals is formed, Fourier transformed and squared. The spectrum thus obtained from different areas for the same pair of frequencies are added to provide an improved signal to noise ratio. The shift of the peak from the center of the spectrum is measured and compared to the expected shift due to the phase velocity of the Bragg scattering wave. Any difference is a measure of current velocity v sub o (delta k).

Jain, A.↗

Proposed Trace Gas Measurements Over the Western United States for TROPOMI Validation

The Alpha Jet Atmospheric eXperiment (AJAX), located in the Bay Area of California, is a joint effort between NASA Ames Research Center and H211, LCC. AJAX makes in-situ airborne measurements of trace gases 2-4 times per month, resulting in over 216 flights since 2011. Current measurements include ozone (O3), carbon dioxide (CO2), methane (CH4), water (H2O), formaldehyde (HCHO), and meteorological measurements (i.e., ambient pressure, temperature, and 3D winds). Currently, the AJAX team is working to incorporate nitrogen dioxide (NO2) measurements with a Cavity Attenuated Phase Shift Spectrometer (CAPS). Successful science flights coincident with satellite overpasses have been performed since 2011 by the Alpha Jet, with more than 40 flights under the Greenhouse Observing SATellite (GOSAT) and several flights under the Orbiting Carbon Observatory-2 (OCO-2). Results from these flights, which have covered a range of different surfaces and seasonal conditions, will be presented. In-situ vertical profiles of O3, CO2, CH4, H2O, HCHO, and NO2 from the surface to 28,000 feet made by AJAX will also be valuable for satellite validation of data products obtained from the TROPOspheric Montoring Instrument (TROPOMI). TROPOMI is on board the Copernicus Sentinel-5 precursor (S5p) satellite, with level 2 products including O3, CO, CH4, HCHO, NO2, and aerosols.

Parworth, Caroline L.↗

Exploitation of SAR data for measurement of ocean currents and wave velocities

Methods of extracting information on ocean currents and wave orbital velocities from SAR data by an analysis of the Doppler frequency content of the data are discussed. The theory and data analysis methods are discussed, and results are presented for both aircraft and satellite (SEASAT) data sets. A method of measuring the phase velocity of a gravity wave field is also described. This method uses the shift in position of the wave crests on two images generated from the same data set using two separate Doppler bands. Results of the current measurements are pesented for 11 aircraft data sets and 4 SEASAT data sets.

Shuchman, R. A.↗

Light-triggered electrochemical biosensor using singlet oxygen for self-powered operation and glucose detection

This study introduces a light-activated sensing strategy that integrates photosensitization with electrochemical detection. The sensor employs Eosin Y, a photosensitizer that generates singlet oxygen ( 1 O 2 ) via type II photosensitization. Immobilized within a thin polymer matrix on a carbon working electrode, Eosin Y produces 1 O 2 , under green light (520 nm) illumination, initiating a redox process that yields a measurable current. To incorporate biosensing capabilities and enable self-powered operation, this 1 O 2 – mediated process was coupled with glucose oxidase (GOx) to construct a fully operational glucose biosensor. The addition of glucose reverses the current flow by causing GOx to compete for electrons, with the resulting current magnitude correlating with glucose concentration providing a sensitive measure of glucose. The biosensor, as proof-of-principle, demonstrated excellent performance over a range of glucose concentrations (0–73 mM), achieving a detection limit (LOD) of 2.8 mM for steady state photocurrent under oxygen-saturated conditions. This platform leverages light and 1 O 2 as stimuli for tunable, on-demand signal control, offering a novel approach for adaptive, real-time biosensing technologies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Unattended Dual Current Monitor (UDCM)

Researchers at Los Alamos National Laboratory have developed the Unattended Dual Current Monitor (UDCM). The UDCM is an ideal solution for current measurement needs such as ion chamber gamma measurements. This data acquisition system simplifies hardware requirements for current applications, and provides added reliability, flexibility, and compatibility as compared with the legacy Miniature Gamma Ray and Neutron Detector (MiniGRAND) technology. It is lightweight, can be portable or mounted, is manufactured using COTS parts, and features a modern Internet-of-Things (IoT) enabled design.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Multi-Frequency Radiometer-Based Soil Moisture Retrieval and Algorithm Parameterization Using In Situ Sites

L-band brightness temperature (TB) has been shown to provide the best sensitivity to soil moisture (SM) although C- and X-band based products offer a longer time-series from satellite-based measurements. Currently, global coverage SM is routinely produced from spaceborne measurements using all three frequency bands, but despite continued validation efforts of the products, the relative characteristics and performance of these observations have not been fully established. Therefore, this study focused on the parametrization of SM retrieval algorithms at L-, C- and X-bands using TB observations from the L-band radiometer on NASA's SM Active Passive (SMAP) mission and the C- and X-band channels of JAXA's Advanced Microwave Scanning Radiometer 2 (AMSR2) onboard the GCOM-W satellite. These can be applied in global SM retrieval algorithms using either one of the frequencies or a combination of them. The reference in situ SM data was obtained from 12 core validation sites across various land cover types around the world. The investigation highlighted the known challenges of retrieving SM from C- and X-band data compared to the higher sensitivity of the L-band data. Even with a site-specific retrieval algorithm parameterization, the mean correlation of the C- and X-band retrievals for the core validation site SM measurement were much lower than that for L-band, being 0.52 (0.54) and 0.45 (0.47) for vertical (horizontal) polarization, respectively, while for the L-band retrieval the corresponding values were 0.81 (0.77). The parameterization exercise showed that matching the C- and X-band TB measurements with an emission model was not difficult; the problem was relating the observations to SM under the influence of large roughness and vegetation effects. As a result, parameter optimization produced values for some sites that were not realistic or did not allow any practical sensitivity to SM at C- and X-band. Considering the L-band observations, the parameter optimization resulted in superior bias performance as compared to the operational SMAP product parameterization, but the sensitivity to SM changes (R and unbiased root mean square difference) did not improve markedly, or in some cases degraded at the expense of a smaller bias.

passive microwave↗

Experimental measurement of the plasma conductivity of Z93 and Z93P thermal control paint

Two samples each of Z93 and Z93P thermal control paint were exposed to a simulated space environment in a plasma chamber. The samples were biased through a series of voltages ranging from -200 volts to +300 volts and electron and ion currents measured. By comparing the currents to those of pure metal samples of the same size and shape, the conductivity of the samples was calculated. Measured conductivity was dependent on the bias potential in all cases. For Z93P, conductivity was approximately constant over much of the bias range and we find a value of 0.5 micro-mhos per square meter for both electron and ion current. For Z93, the dependence on bias was much more pronounced but conductivity can be said to be approximately one order of magnitude larger. In addition to presenting these results, this report documents all of the experimental data as well as the statistical analyses performed.

Hillard, G. Barry↗