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The high resolution rotational band profiles were fitted with theoretical band profiles which are derived using a Boltzmann temperature of 70 K. A very rapid variation with heliocentric distance for the CS brightness was found. The implications of these results for models of the coma along with the origin of the CS species are discussed.
Results from ultraviolet spectrographic observations of Comet West (1975n) in the 1620-3960 A wavelength range are presented. Objective grating imagery of the comet reveals for the first time emission from sulfur atoms and CS molecules as well as previously observed lines or bands in carbon atoms and CO(+), CO2(+) and OH molecules. Some evidence exists for emission in the C2 Mulliken bands and in the CO Cameron bands. On the basis of the observations, production rates of C (ground state), C(1D), S, and CS are inferred to be 3.8 x 10 to the 29th per sec, 4.4 x 10 to the 29th per sec, 1.7 x 10 to the 28th per sec, and greater than approximately 3.1 x 10 to the 27th per sec, respectively.
The high resolution spectra of comets Giacobini-Zinner and Halley were measured in the region of the CS emission. Both spectra have essentially the same shape, but the Halley spectrum has a better signal to noise ratio. The rotational distribution of the radical in these comets was derived by using an inversion program and spectral simulation. Both procedures suggest that the rotational distribution is dominated by CS radical with J" is less than or = 5. Despite this it appears that another distribution with higher J''' is needed to explain the shape of the rotational distribution. It is suggested that this second distribution is due to a balance between collisions and radiation in the inner coma.
New vibrational bands of CS have been identified in several comets. The relative intensities of these bands are in agreement with a simple model, based upon most of the CS radicals being in the lowest vibrational level. The present observational accuracy is not sufficient to decide between this simple model and an earlier radiative equilibrium model. The observed intensity ratios appear to be similar in different comets, which means that they cannot depend strongly upon the total gas production rates.
The high resolution spectrum of comet P/Halley has been measured in the region of the CS emission. CS in comet Halley is produced by photodissociation of CS2 and subsequently reexcited by broad band solar radiation. An inversion procedure is introduced to extract the rotational population distribution from the dispersed fluorescence spectrum. Intensity anomalies in the wavelength region corresponding to P and Q branch emission are considered.
NASA’s Multi Purpose Transportation System (MPTS) is designed to transport the Space Launch System vehicle segments by waterway and roadway. It is tasked with transporting the vehicle from where it is manufactured to its intermediate test location and final launch destination. Its design incorporates mechanisms that release degrees of freedom to prevent excessive loading during transit and ensure a successful delivery of the vehicle to its intended destination. In addition to the CS (Core Stage) flight article, the system will also move three structural test articles and a simulated CS Pathfinder (weight, center of gravity, outer mold line dimensions, and overall length) over road terrain on four NASA centers and on the Pegasus barge. The MPTS independently supports the article at both ends while communicating as a combined unit through automated monitoring of its released degree of freedom and corrective responses. This allows the system to constrain its payload in a statically determinate manner while traversing across highly variable terrain. Multi-body simulation of the transportation route is useful to predict free-body motion within the specified travel ranges. The MPTS has completed its design and analysis developmental cycles. This unpublished paper will describe the design challenges encountered in developing this system of large scale structure which incorporates complex mechanisms. The unique techniques and methodologies developed for analytical assessment of the hardware will be also be discussed. Key results from analytical evaluations as well as ongoing performance testing will be presented.
NASA's Multi-Purpose Transportation System (MPTS) is designed to transport the Space Launch System (SLS) vehicle segments by waterway and roadway. It is tasked with transporting the vehicle from where it is manufactured to its intermediate test location and final launch destination. Its design incorporates mechanisms that release degrees of freedom to prevent excessive loading during transit and ensure a successful delivery of the vehicle to its intended destination. In addition to the Core Stage (CS) flight article, the system will also move three Structural Test Articles (STAs), the Dynamic Demonstration Unit (DDU), and a simulated CS Pathfinder (weight, center of gravity, outer mold line dimensions, and overall length) over road terrain at four NASA centers and on the Pegasus barge. The MPTS independently supports the article at both ends while operating as a combined unit through automated monitoring of its released degree of freedom and corrective responses. This allows the system to constrain its payload in a statically determinate manner while traversing highly variable terrain. Multi-body simulation of the transportation route is useful to predict free-body motion within its range of mobility. The MPTS has completed its design and analysis developmental cycles. This paper describes the design challenges encountered in developing this system of large-scale structure, which incorporates complex mechanisms. The unique techniques and methodologies developed for analytical assessment of the hardware are also discussed.
Tests were performed at SNS in collaboration with visiting colleagues from ISIS, UK to evaluate the uncesiated beam performance of the SNS RF H⁻ ion sources. Two spare experimental sources, one with internal antenna and one with external antenna were used for the tests. The beam currents achieved with Cs-free operations accounted for about 1/3 to 1/2 of the beam currents produced with cesiated operations. ~17 mA uncesiated H⁻ current was demonstrated within the tested RF power range up to 65 kW with the internal antenna source and ~15 mA with up to 40 kW RF with the external antenna source. In Cs-free operations, the power supply for the electron dumping electrode was loaded down below its set voltage but was not too drastic to tamper the operation.
CsFe2As2 crystallizes in the tetragonal I4/mmm space group. The structure is three-dimensional. Cs1+ is bonded in a distorted body-centered cubic geometry to eight equivalent As3- atoms. All Cs–As bond lengths are 3.66 Å. Fe+2.50+ is bonded to four equivalent As3- atoms to form a mixture of corner and edge-sharing FeAs4 tetrahedra. All Fe–As bond lengths are 2.34 Å. As3- is bonded in a 8-coordinate geometry to four equivalent Cs1+ and four equivalent Fe+2.50+ atoms.
CsOs2O6 crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Cs1+ is bonded to six equivalent O2- atoms to form CsO6 octahedra that share corners with twelve equivalent OsO6 octahedra. The corner-sharing octahedral tilt angles are 70°. All Cs–O bond lengths are 3.20 Å. Os+5.50+ is bonded to six equivalent O2- atoms to form OsO6 octahedra that share corners with six equivalent CsO6 octahedra and corners with six equivalent OsO6 octahedra. The corner-sharing octahedra tilt angles range from 40–70°. All Os–O bond lengths are 1.93 Å. O2- is bonded in a distorted bent 150 degrees geometry to one Cs1+ and two equivalent Os+5.50+ atoms.
Industrially, ammonia is produced by Haber-Bosch process under high temperatures and pressures, consuming more than >2% of the world's energy production. This paper presents microwave-assisted catalytic synthesis of ammonia operated at atmospheric pressure and temperatures from 260 to 360 °C. A Cs-promoted Ru catalyst supported on cerium oxide with different metal loading (4–24 wt% Ru) and support particle size (25nm, 50nm and 5μm) was investigated. The small size cerium oxide support resulted in the highest activity while the large cerium oxide support was less favorable, leading to lower activity associated to large Ru particle size and lower dispersion.
Microwave-initiated ammonia synthesis is a potential candidate to the current Haber-Bosch process that can operate from stranded renewable energy source. Our previous studies indicated Cs-Ru/CeO 2 is a promising catalyst for microwave-assisted ammonia synthesis and the morphology of CeO 2 significantly affects the catalytic performance. In this paper, CeO 2 support with distinct morphologies nanorod, nanoparticle, and microstructure, is studied comprehensively at ambient pressure and low temperature under microwave irradiation. Moreover, CeO 2 nanorods of various sizes were synthesized at different timing (24, 36, and 48 h). Nanorods synthesized at 36 h exhibited superior activity associated to high dispersion and small Ru particle size.
We report Doppler-only (cw) radar observations of 1991 CS obtained at Goldstone at a transmitter frequency of 8510 MHz (3.5 cm) on 1996 August 26, 27, 28, and 29.
Copper(I) halides are emerging as attractive alternatives to lead halide perovskites for optical and electronic applications. However, blue-emitting all-inorganic copper(I) halides suffer from poor stability and lack of tunability of their photoluminescence (PL) properties. In this work, the preparation of silver(I) halides A 2 AgX 3 (A = Rb, Cs; X = Cl, Br, I) through solid-state synthesis is reported. In contrast to the Cu(I) analogs, A 2 AgX 3 are broad-band emitters sensitive to A and X site substitutions. First-principle calculations show that defect-bound excitons are responsible for the observed main PL peaks in Rb 2 AgX 3 and that self-trapped excitons (STEs) contribute to a minor PL peak in Rb 2 AgBr 3 . This is in sharp contrast to Rb 2 CuX 3 , in which the PL is dominated by the emission by STEs. Moreover, the replacement of Cu(I) with Ag(I) in A 2 AgX 3 significantly improves photostability and stability in the air under ambient conditions, which enables their consideration for practical applications. Thus, luminescent inks based on A 2 AgX 3 are prepared and successfully used in anti-counterfeiting applications. The excellent light emission properties, significantly improved stability, simple preparation method, and tunable light emission properties demonstrated by A 2 AgX 3 suggest that silver(I) halides may be attractive alternatives to toxic lead halide perovskites and unstable copper(I) halides for optical applications.
Compositional tuning has been a major driving force behind the excellent optoelectronic properties observed in typical Pb-based perovskites. For lead-free perovskite derivatives, a challenge to understanding the connection between compositional tuning and intrinsic optoelectronic properties, hence a barrier towards boosting their performance, comes from the fact that multiple crystalline substructures can form based on composition, film processing, or both. Especially with lower dimensional (0D, 1D, 2D) substructures, the particular polymorph present in the film can be a greater determinant of optoelectronic properties than the composition itself. Herein, we report a simple method to alloy the halide site in all-inorganic lead-free Cs 3 Sb 2 I 9 films while maintaining a consistent 2D-layered substructure, as a means to independently study the photovoltaic implications of halide substitution. We use a broad suite of spectroscopy and device measurements to identify an optimal stoichiometric substitution of chloride for iodide (~ 8 mol%, measured) that balances both intrinsic and bulk optoelectronic properties to achieve a top power conversion efficiency of 2.2%. This work underscores the importance of controlling substructure while investigating the impacts of compositional tuning for the development of lead-free perovskites, and more broadly validates the approach towards realizing lead-free alternative perovskite solar technologies.
Cs 2 HfCl 6 (CHC) is a promising high density, high-Z, non-hygroscopic, and high energy resolution scintillator. In CHC, many crystals have CsCl inclusions that form during growth. In this paper, we investigate how material synthesis, growth rate, and thermal gradient affect the formation of CsCl inclusions and their effect on scintillation performance. First, precursor material was made through a methanol synthesis process both with and without hydrochlorination. Next, five crystals were grown using Bridgman method, at growth rates of 1 or 0.5 mm/h, and thermal gradients of 21 °C or 34 °C per millimeter. The best overall performance was observed in a 22 mm diameter crystal produced using hydrochlorination which was grown at 1 mm/h in a thermal gradient of 34 °C per millimeter. It had a light yield of 36,000 photons/MeV and an energy resolution of 4.0% at 662 keV. Finally, we have also shown that poorer scintillation performance in the lower quality crystals is most likely due to reduced light collection caused by a higher concentration of inclusions.
Here, we describe the crystal structure and basic magnetic properties of Cs 4 Ca 0.7 Mn 3.3 Cl 12 , a previously unreported twelve layer (12L-) hexagonal (R-3m) chloride perovskite. Its crystal structure features face sharing MnCl 6 octahedra that form Mn 3 Cl 12 trimers. The trimers, which form a triangular array, are separated by corner sharing to layers of disordered single Ca(Mn)Cl 6 octahedra. The decreased intratrimer Mn–Mn distance yields stronger magnetic coupling within trimers than between trimers. The dominant magnetic interactions are antiferromagnetic (θ CW = –105 K), the effective magnetic moment per Mn 2+ is 6.5 μ B , and potential signatures of magnetic frustration are observed. Behavior consistent with short- and long-range magnetic order is exhibited at approximately 37 and 0.7 K, respectively.
The toxicity and instability of lead-based metal halide perovskites are the two main obstacles that prevent perovskite materials from implementation in applications. Recently, layered double perovskites (LDPs) emerge as a new family of perovskite materials which provide a new route to solve these problems by lead-component replacement and reduction of crystal structure dimensionality. However, LDP nanocrystals (NCs) have been rarely studied, limiting the further property exploration and application realization. In this work, we report the colloidal synthesis of a series of Cs 4 Cd 1-x Cu x Sb 2 Cl 12 (0 ≤ x ≤ 1) LDP NCs by tuning the stoichiometry of metal precursors. The composition-structure-property relationships of the resulting LDP NCs are studied through materials characterizations, density functional theory calculations, and transient-absorption spectroscopy. In addition, we demonstrate that high-performance high-speed photodetectors can be fabricated using the colloidal LDP NCs through solution-processing. This work premises further expansion of such LDP-based materials for both fundamental studies and application integrations.