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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Managing photon flux in a miniaturized photoionization detector

Miniaturized photoionization detectors (PIDs) are used in conjunction with gas chromatography systems to detect volatile compounds in gases by collecting the current from the photoionized gas analytes. PIDs should be inexpensive and compatible with a wide range of analyte species. One such PID is based on the formation of a He plasma in a dielectric barrier discharge (DBD), which generates vacuum UV (VUV) photons from excited states of He to photoionize gas analytes. There are several design parameters that can be leveraged to increase the ionizing photon flux to gas analytes to increase the sensitivity of the PID. To that end, the methods to maximize the photon flux from a pulsed He plasma in a DBD-PID were investigated using a two-dimensional plasma hydrodynamics model. The ionizing photon flux originated from the resonance states of helium, He(3P) and He(2 1 P), and from the dimer excimer He 2 *. While the photon flux from the resonant states was modulated over the voltage pulse, the photon flux from He 2 * persisted long after the voltage pulse passed. Several geometrical optimizations were investigated, such as using an array of pointed electrodes. However, increasing the capacitance of the dielectric enclosing the plasma chamber had the largest effect on increasing the VUV photon fluence to gas analytes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Measurement of B$_\mathrm{c}$(2S)$^+$ and B$_\mathrm{c}^*$(2S)$^+$ cross section ratios in proton-proton collisions at $\sqrt{s} =$ 13 TeV

The ratios of the Bc(2S)+ to Bc+, Bc*(2S)+ to Bc+, and Bc*(2S)+ to Bc(2S)+ production cross sections are measured in proton-proton collisions at s=13 TeV, using a data sample collected by the CMS experiment at the LHC, corresponding to an integrated luminosity of 143 fb-1. The three measurements are made in the Bc+ meson phase space region defined by the transverse momentum pT>15 GeV and absolute rapidity |y|<2.4, with the excited Bc(*)(2S)+ states reconstructed through the Bc(*)+π+π−, followed by the Bc+→J/ψπ+ and J/ψ→μ+μ− decays. The Bc(2S)+ to Bc+, Bc*(2S)+ to Bc+, and Bc*(2S)+ to Bc(2S)+ cross section ratios, including the unknown Bc(*)(2S)+→Bc(*)+π+π− branching fractions, are (3.47±0.63(stat)±0.33(syst))%, (4.69±0.71(stat)±0.56(syst))%, and 1.35±0.32(stat)±0.09(syst), respectively. None of these ratios shows a significant dependence on the pT or |y| of the Bc+ meson. The normalized dipion invariant mass distributions from the decays Bc(*)(2S)+→Bc(*)+π+π− are also reported.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS2003

Foliar Reflectance and Fluorescence Responses for Plants Under Nitrogen Stress Determined with Active and Passive Systems

Vegetation productivity is driven by nitrogen (N) availability in soils. Both excessive and low soil N induce physiological changes in plant foliage. In 2001, we examined the use of spectral fluorescence and reflectance measurements to discriminate among plants provided different N fertilizer application rates: 20%, 50%, 100% and 150% of optimal N levels. A suite of optical, fluorescence, and biophysical measurements were collected on leaves from field grown corn (Zea mays L.) and soybean plants (Glycine max L.) grown in pots (greenhouse + ambient sunlight daily). Three types of steady state laser-induced fluorescence measurements were made on adaxial and abaxial surfaces: 1) fluorescence images in four 10 nm bands (blue, green, red, far-red) resulting from broad irradiance excitation; 2) emission spectra (5 nm resolution) produced by excitation at single wavelengths (280,380 or 360, and 532 nm); and 3) excitation spectra (2 nm resolution), with emission wavelengths fixed at wavelengths centered on selected solar Fraunhofer lines (532,607,677 and 745 nm). Two complementary sets of high resolution (less than 2 nm) optical spectra were acquired for both adaxial and abaxial leaf surfaces: 1) optical properties (350-2500 nm) for reflectance, transmittance, and absorptance; and 2) reflectance spectra (500-1000 nm) acquired with and without a short pass filter at 665 nm to determine the fluorescence contribution to apparent reflectance in the 650-750 spectrum, especially at the 685 and 740 nm chlorophyll fluorescence (ChIF) peaks. The strongest relationships between foliar chemistry and optical properties were demonstrated for C/N content and two optical parameters associated with the red edge inflection point. Select optical properties and ChIF parameters were highly correlated for both species. A significant contribution of ChIF to apparent reflectance was observed, averaging 10-25% at 685 nm and 2 - 6% at 740 nm over all N treatments. Discrimination of N treatment groups was possible with specific fluorescence band ratios (e.g., F740/F525 obtained with 380EX). From all measurements assessing fluorescence, higher ChIF and blue/green emissions were measured from the abaxial leaf surfaces; Abaxial surfaces also produced higher reflectances in the 400-800 nm spectrum. Fluorescence information collected in Fraunhofer regions located on the shoulders of ChIF features compared favorably with peak emissions. This supports the potential capability of a future space-born interferometer sensor to capture plant canopy fluorescence.

Middleton, E. M.↗
DOE OSTI2022

Machine-Learning for Excited-State Dynamics

The primary objective of this computational chemistry sciences team is to design a machine learning NAMD environment that will utilize current petascale and future exascale computational capabilities to advance understanding of charge and energy flow in materials. Our machine-learning NAMD environment will 1) integrate advanced NAMD capabilities directly into electronic structure software (e.g., ABINIT, Quantum Espresso, VASP, etc.); 2) merge the preparatory tools of Pychemia into PYXAID and Avogadro environments so that massive data collection from NAMD simulations.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Proton Transfer Dynamics in the Aprotic Proton Accepting Solvent 1-Methylimidazole

The dynamics of proton transfer to the aprotic solvent 1-methylimidazole (MeIm, proton acceptor) from the photoacid 8-hydroxypyrene-1,3,6-trisulfonic acid trisodium salt (HPTS) were investigated using fast fluorescence measurements. The closely related molecule, 8- methoxypyrene-1,3,6-trisulfonic acid trisodium salt (MPTS), which is not a photoacid, was also studied for comparison. Following optical excitation, the wavelength-dependent population dynamics of HPTS in MeIm resulting from the deprotonation process were collected over the entire fluorescence emission window. Analysis of the time-dependent fluorescence spectra revealed four distinct fluorescence bands that appear and decay on different time scales. We label these four states as: protonated (P), associated I (A I ), associated II (A II ), and deprotonated (D). We find that the simple kinetic scheme of P → A I → A II → D is not consistent with the data. Instead, the kinetic scheme that describes the data has P decaying into A I , which mainly goes on to deprotonation (D), but AI can also feed into A II . A II can return to A I or decay to the ground state, but does not deprotonate within experimental error. Finally, quantum chemistry and excitedstate QM/MM Born-Oppenheimer molecular dynamics simulations indicate that A I and A II are two H-bonding conformations of MeIm to the HPTS hydroxyl, axial and equatorial, respectively.

14 SOLAR ENERGY↗
NASA NTRS1974

Electron-impact excitation of the 3S0 and 5S0 states of atomic oxygen

The conditions of electron-impact excitation in flowing oxygen downstream from a discharge are reinterpreted. It is shown that total oxygen mass flow is not conserved as the discharge is turned on and off, even though the inlet flow rate remains constant. The total amount of gas is diminished when the discharge is turned on, apparently due to collection of atomic oxygen by the system walls. A revised total cross section is reported for the excitation of 1304-A radiation.

Stone, E. J.↗
DOE OSTI2025

Exciton dressing by extreme nonlinear magnons in a layered semiconductor

Collective excitations presenting nonlinear dynamics are fundamental phenomena with broad applications. A prime example is nonlinear optics, where diverse frequency mixing processes are central to communication, sensing, wavelength conversion, and attosecond physics. Leveraging recent progress in van der Waals magnetic semiconductors, we demonstrate nonlinear opto-magnonic coupling by presenting exciton states dressed by up to 20 harmonics of magnons, resulting from their nonlinearities, in the layered antiferromagnetic semiconductor CrSBr. We also create tunable optical side bands from sum- and difference-frequency generation between two optically bright magnon modes under symmetry breaking magnetic fields. Moreover, the observed difference-frequency generation mode can be continuously tuned into resonance with one of the fundamental magnons, resulting in parametric amplification of magnons. These findings realize the modulation of the optical frequency exciton with the extreme nonlinearity of magnons at microwave frequencies, which could find applications in magnonics and hybrid quantum systems, and provide new avenues for implementing opto-magnonic devices.

Diederich, Geoffrey M.↗
DOE OSTI2025

Chemical applications of variational quantum eigenvalue-based quantum algorithms: Perspective and survey

Exploring many-body chemical systems on classical computers often involves solving the Schrödinger equation. However, this approach is frequently limited by the exponential increase in the dimensionality of the Hamiltonian as the number of degrees of freedom increases. In contrast, quantum computing, specifically through the variational quantum eigensolver (VQE) framework, shows promise in overcoming this exponential cost. VQE can utilize the collective properties of quantum states to model the wavefunction in polynomial time. Despite the current limitations of quantum hardware, significant advances have been made in the development of VQE-based algorithms. Here, in this review, we provide an overview of emerging protocols, focusing on their applications in simulating the ground state, excited state, and vibrational properties of chemical systems. By examining notable algorithmic advancements and applications, this review aims to shed light on the challenges and potential of VQE-based algorithms in addressing relevant chemical problems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Time-domain study of coupled collective excitations in quantum materials

Quantum materials hold immense promises for future applications due to their intriguing electronic, magnetic, thermal, and mechanical properties that often arise from a complex interplay between microscopic degrees of freedom. Important insights of such interactions come from studying the collective excitations of electrons, spins, orbitals, and lattice, whose cooperative motions play a crucial role in determining the novel behavior of these systems and offer us a key tuning knob to modify material properties on-demand through external perturbations. In this regard, ultrafast light-matter interaction has shown great potential in controlling the couplings of collective excitations, and rapid progress in a plethora of time-resolved techniques down to the attosecond regime has significantly advanced our understanding of the coupling mechanisms and guided us in manipulating the dynamical properties of quantum materials. This review aims to highlight recent experiments on visualizing collective excitations in the time domain, focusing on the coupling mechanisms between different collective modes such as phonon-phonon, phonon-magnon, phonon-exciton, magnon-magnon, magnon-exciton, and various polaritons. We introduce how these collective modes are excited by an ultrashort laser pulse and probed by different ultrafast techniques, and we explain how the coupling between collective excitations governs the ensuing nonequilibrium dynamics. We also provide some perspectives on future studies that can lead to discoveries of the emergent properties of quantum materials both in and out of equilibrium.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Measurement of N* Cross-Sections from Single-Pion Electroproduction at low Q 2

Measurements of nucleon electroexcitation resonance cross-sections give unique insight into the dynamics of the strong interaction and our knowledge of Quantum Chromodynamics (QCD). The analysis of exclusive electroproduction data is an important tool in understanding the structure of the nucleon and its excited states. Exclusive channels give a clear way to extract the desired resonant contributions from non-resonant contributions. A gap in the helicity amplitudes extracted from single-pion cross-section data exists for virtual photon momentum transfers (Q 2 ) in the range of 1- 2 GeV 2 . Using data collected by the CEBAF Large Acceptance Spectrometer (CLAS) detector with a beam energy of 4.8 GeV, the reaction channel y*r &rarr; nπ + is used in this study to investigate the kinematic region covering W=[1.1,1.82)GeV and Q 2 = [1.1,3.5)GeV 2 . This work expands on the previous kinematic coverage for charged single-pion electroproduction and increases the angular coverage of previously extracted kinematic bins.

Tyler, Nicholas↗
DOE OSTI2023

High event rate analysis technique for the dual-axis duo-lateral position-sensitive silicon detectors of FAUST

The dual-axis duo-lateral (DADL) position-sensitive silicon detector was developed to obtain precise position and energy information for detected charged particles. The Forward Array Using Silicon Technology (FAUST) is currently equipped with 68 DADL detectors backed by CsI(Tl) scintillators for the study of charged particle correlations in heavy-ion collisions where precise position and energy information is essential. When conventional signal processing electronics were used for the DADL detectors, a position dependence of the measured energy as well as distortions in the calculated particle positions were observed. In previous work, waveforms from the detector after preamplification were studied to better understand the features that give rise to these distortions; therein, a waveform analysis technique was developed to improve the energy resolution and linearity in position reconstruction. However, the reading and writing of waveforms for an entire detector array limits data collection rates and adds significant burden in data storage and analysis speed. In this work, the integrators of a Struck SIS3316 ADC were utilized to process 228 Th source data to develop and optimize a new analysis method that captures the benefits of the waveform analysis technique while circumventing the waveform writing requirement. This integrator method – capable of 59 keV (FWHM) energy resolution – was used in the collection of 35 MeV/nucleon 28 Si + 12 C collision data using FAUST to investigate exotic decays of highly excited highly deformed nuclei. In this data, a position resolution of 0.4 mm (FWHM) was obtained for 25 MeV α-particles; for α-particles near this energy that originate from 8 Be ground state decays, a 8 Be ground state width of 30 keV (FWHM) was obtained. The impact of the energy-dependent DADL position resolution emergent from electronic noise on the quality of excited state measurement was modeled and compared to the experimental data.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Theoretical Advances in Polariton Chemistry and Molecular Cavity Quantum Electrodynamics

When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called polaritons, are formed due to quantum light–matter interactions. With the experimental demonstrations of modifying chemical reactivities by forming polaritons under strong light–matter interactions, theorists have been encouraged to develop new methods to simulate these systems and discover new strategies to tune and control reactions. This review summarizes some of these exciting theoretical advances in polariton chemistry, in methods ranging from the fundamental framework to computational techniques and applications spanning from photochemistry to vibrational strong coupling. Even though the theory of quantum light–matter interactions goes back to the midtwentieth century, the gaps in the knowledge of molecular quantum electrodynamics (QED) have only recently been filled. We review recent advances made in resolving gauge ambiguities, the correct form of different QED Hamiltonians under different gauges, and their connections to various quantum optics models. Then, we review recently developed ab initio QED approaches which can accurately describe polariton states in a realistic molecule–cavity hybrid system. We then discuss applications using these method advancements. We review advancements in polariton photochemistry where the cavity is made resonant to electronic transitions to control molecular nonadiabatic excited state dynamics and enable new photochemical reactivities. When the cavity resonance is tuned to the molecular vibrations instead, ground-state chemical reaction modifications have been demonstrated experimentally, though its mechanistic principle remains unclear. We present some recent theoretical progress in resolving this mystery. Finally, we review the recent advances in understanding the collective coupling regime between light and matter, where many molecules can collectively couple to a single cavity mode or many cavity modes. We also lay out the current challenges in theory to explain the observed experimental results. We hope that this review will serve as a useful document for anyone who wants to become familiar with the context of polariton chemistry and molecular cavity QED and thus significantly benefit the entire community.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

High-Pressure Effects on an Octa-Hydrated Curium Complex: An Experimental and Theoretical Investigation

An octa-hydrated curium compound [Cm(H 2 O) 8 ](Hdtp)(dtp)·H 2 O (Cm1,H 2 dtp = 2,3-di(tetrazol-5-yl)pyrazine) along with its lanthanide analogues [Ln(H 2 O) 8 ](Hdtp)-(dtp)·H 2 O (Ln1, Ln 3+ = La 3+ –Nd 3+ , Sm 3+ –Lu 3+ ) were synthesized and characterized using single crystal X-ray diffraction and spectroscopic methods. Bond length analysis of VIII Cm(III)–OH 2 (where VIII refers to the coordination number) was compared to VIII Ln(III)–OH 2 (Ln 3+ = Nd 3+ and Sm 3+ ), indicating similar VIII M(III)–OH 2 bond lengths owing to the similar eight-coordinate ionic radii of these VIII M(III) cations. Owing to the reduced coordination number, the VIII Cm(III)–OH 2 bond lengths were shorter than previously reported IX Cm(III)–OH 2 bonds in [Cm(H 2 O) 9 ](CF 3 SO 3 ) 3 . The octa-aquo complexes were also characterized by solid-state UV–vis–NIR spectroscopy in addition to variable-temperature and variable-pressure photoluminescence. Variable-pressure absorption spectra of Cm1 were compared with Ln1 and show that the Cm(III) f → f transitions have a stronger dependence on pressure than that observed in Ln1 (Ln 3+ = Nd 3+ and Sm 3+ ). The experimental and computational analyses reveal that the monotonic decrease in the computed energy difference between the ground state and the first excited state corresponds to the observed red shift of the photoluminescence peak. This is accompanied by a gradual reduction in the average Cm(III)–OH 2 bond length and a delocalization of spin densities, alongside an intensified interaction involving the 5f orbitals under increasing pressure. Furthermore, these changes accommodate the new geometry and collectively modify the energy landscape, resulting in peak broadening and quenching.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Observation of the Charged-Particle Multiplicity Dependence of 𝜎 𝜓⁡(2⁢𝑆 )/𝜎 𝐽/𝜓 in 𝑝-Pb Collisions at 8.16 TeV

Bound states of charm and anticharm quarks, known as charmonia, have a rich spectroscopic structure that can be used to probe the dynamics of hadron production in high-energy hadron collisions. Here, the cross section ratio of excited (𝜓⁡(2⁢𝑆)) and ground state (𝐽/𝜓) vector mesons is measured as a function of the charged-particle multiplicity in proton-lead (𝑝⁢Pb) collisions at a center-of-mass (CM) energy per nucleon pair of 8.16 TeV. The data corresponding to an integrated luminosity of 175 nb −1 were collected using the CMS detector. The ratio is measured separately for prompt and nonprompt charmonia in the transverse momentum range 6.5 < 𝑝 T < 30 GeV and in four rapidity ranges spanning −2.865 < 𝑦 CM < 1.935. For the first time, a statistically significant multiplicity dependence of the prompt cross section ratio is observed in proton-nucleus collisions. There is no clear rapidity dependence in the ratio. The prompt measurements are compared with a theoretical model which includes interactions with nearby particles during the evolution of the system. These results provide additional constraints on hadronization models of heavy quarks in nuclear collisions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Single-neutron adding on $^{34}$S

For this work, single-neutron adding data was collected in order to determine the distribution of the single-neutron strength of the 0ƒ 7/2 , 1p 3/2 , 1p 1/2 and 0ƒ 5/2 orbitals outside of Z = 16, N = 18, 34 S. The 34 S(d,p) 35 S reaction has been measured at 8 MeV/u to investigate cross sections to excited states in 35 S. Outgoing proton yields and momenta were analyzed by the Super-Enge Split-Pole Spectrograph in conjunction with the CeBrA demonstrator located at the John D. Fox Laboratory at Florida State University. Angular distributions were compared with Distorted Wave Born Approximation calculations in order to extract single-neutron spectroscopic overlaps. Spectroscopic overlaps and strengths were determined for states in S up through 6 MeV in excitation energy. Each orbital was observed to have fragmented strength where a single level carried the majority. The single-neutron centroids of the 0ƒ 7/2 , 1p 3/2 , 1p 1/2 and 0ƒ 5/2 orbitals were determined to be 2360$^{+90}_{-40}$ keV, 3280$^{+80}_{-50}$ keV, 4780$^{+60}_{-40}$ keV, and ≳7500 keV, respectively. A previous discrepancy in the literature with respect to the distribution of the neutron 1p 1/2 strength was resolved. The integration of the normalized spectroscopic strengths, up to 5.1 MeV in excitation energy, revealed fully-vacant occupancies for the 0ƒ 7/2 , 1p 3/2 , and 1p 1/2 orbitals, as expected. The spacing in the single-neutron energies highlighted a reduction in the traditional N = 28 shell-gap, relative to both the 1p spin-orbit energy difference (N = 32) and the lower limit on the N = 34 shell spacing.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2020

Synchrotron infrared nano-spectroscopy and -imaging

Infrared (IR) spectroscopy has evolved into a powerful analytical technique to probe molecular and lattice vibrations, low-energy electronic excitations and correlations, and related collective surface plasmon, phonon, or other polaritonic resonances. In combination with scanning probe microscopy, near-field infrared nano-spectroscopy and -imaging techniques have recently emerged as a frontier in imaging science, enabling the study of complex heterogeneous materials with simultaneous nanoscale spatial resolution and chemical and quantum state spectroscopic specificity. Here, we describe synchrotron infrared nano-spectroscopy (SINS), which takes advantage of the low-noise, broadband, high spectral irradiance, and coherence of synchrotron infrared radiation for near-field infrared measurements across the mid- to far-infrared with nanometer spatial resolution. This powerful combination provides a qualitatively new form of broadband spatio-spectral analysis of nanoscale, mesoscale, and surface phenomena that were previously difficult to study with IR techniques, or even any form of micro-spectroscopy in general. We review the development of SINS, describe its technical implementations, and highlight selected examples representative of the rapidly growing range of applications in physics, chemistry, biology, materials science, geology, and atmospheric and space sciences.

47 OTHER INSTRUMENTATION↗
DOE OSTI2023

Kondo Lattice Model of Magic-Angle Twisted-Bilayer Graphene: Hund’s Rule, Local-Moment Fluctuations, and Low-Energy Effective Theory

For this work, we apply a generalized Schrieffer-Wolff transformation to the extended Anderson-like topological heavy fermion (THF) model for the magic-angle (θ=1.05°) twisted bilayer graphene (MATBLG) [Phys. Rev. Lett. 129, 047601 (2022)], to obtain its Kondo lattice limit. In this limit localized $\mathcal{f}$ electrons on a triangular lattice interact with topological conduction $\mathcal{c}$ electrons. By solving the exact limit of the THF model, we show that the integer fillings ν=0, ±1, ±2 are controlled by the heavy $\mathcal{f}$ electrons, while ν=±3 is at the border of a phase transition between two $\mathcal{f}$-electron fillings. For ν=0, ±1, ±2, we then calculate the Ruderman-Kittel-Kasuya-Yosida (RKKY) interactions between the $\mathcal{f}$ moments in the full model and analytically prove the SU(4) Hund’s rule for the ground state which maintains that two $\mathcal{f}$ electrons fill the same valley-spin flavor. Our (ferromagnetic interactions in the) spin model dramatically differ from the usual Heisenberg antiferromagnetic interactions expected at strong coupling. We show the ground state in some limits can be found exactly by employing a positive semidefinite “bond-operators” method. We then compute the excitation spectrum of the $\mathcal{f}$ moments in the ordered ground state, prove the stability of the ground state favored by RKKY interactions, and discuss the properties of the Goldstone modes, the (reason for the accidental) degeneracy of (some of) the excitation modes, and the physics of their phase stiffness. We develop a low-energy effective theory for the $\mathcal{f}$ moments and obtain analytic expressions for the dispersion of the collective modes. We discuss the relevance of our results to the spin-entropy experiments in TBG.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Single-particle and collective excitations in Zn 66

Single-particle and collective excitations in 66 Zn have been investigated via the multinucleon transfer reaction, 26 Mg( 48 Ca, α4nγ) using the Gammasphere multidetector array and the Fragment Mass Analyzer. In addition to confirming and complementing the previously known low-spin structure, a new quasi-rotational band comprising several stretched E2 transitions has been established to high spins. However, due to fragmentary nature of its decay, it was not possible to link this sequence to the low-lying states and, thus, determine the absolute excitation energies, spins, and parities unambiguously. Large-scale shell-model calculations employing the JUN45 and jj44b effective interactions are able to successfully describe the low-spin structure and herewith confirm that it is dominated by single-particle excitations. Furthermore, the newly established rotational cascade is compared with known superdeformed bands in the A ≈ 60–70 mass region, and with results of calculations performed within the frameworks of the cranked shell model and the adiabatic and configuration-fixed constrained covariant density functional theory and the quantum particle-rotor model.

59 ≤ A ≤ 89↗