Process in the Search for Advanced Thermoelectric Materials for Terrestrial Applications at the Jet
The thermoelectric properties of several materials with the skutterudite structure have been.
Advanced Thermoelectric Materials↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Structural Framework for Flight I: NASA’s Role in Development of Advanced Composite Materials for Aircraft and Space Structures
This monograph is organized to look at: the successful application of composites on aircraft and space launch vehicles, the role of NASA in enabling these applications for each different class of flight vehicles, and a discussion of the major advancements made in discipline areas of research. In each section, key personnel and selected references are included. These references are intended to provide additional information for technical specialists and others who desire a more in-depth discussion of the contributions. Also in each section, lessons learned and future challenges are highlighted to help guide technical personnel either in the conduct or management of current and future research projects related to advanced composite materials.
Tenney, Darrel R.↗
Active Control Technology at NASA Langley Research Center
NASA Langley has a long history of attacking important technical Opportunities from a broad base of supporting disciplines. The research and development at Langley in this subject area range from the test tube to the test flight, The information covered here will range from the development of innovative new materials, sensors and actuators, to the incorporation of smart sensors and actuators in practical devices, to the optimization of the location of these devices, to, finally, a wide variety of applications of these devices utilizing Langley's facilities and expertise. Advanced materials are being developed for sensors and actuators, as well as polymers for integrating smart devices into composite structures. Contributions reside in three key areas: computational materials; advanced piezoelectric materials; and integrated composite structures.
Antcliff, Richard R.↗
Performance evaluation of ''Thermo-lag'' material for entry heat protection of advanced manned spacecraft Material development report, 1 Oct. 1962 - 1 Apr. 1963
Performance evaluation of Thermo-lag material for advanced manned spacecraft reentry heat protection
HIGH TEMPERATURE MATERIAL↗
Materials technology advancement program for expandable manned space structures Summary report
Composite materials testing for fire resistant wall structures for expandable manned space structures
Cordier, K. L.↗
Materials technology advancement program for expandable manned space structures Final report
Composite materials tests for expandable manned space structures including flammability, micrometeoroid impact, thermal shock, and tear, puncture, and fungus resistance
Cordier, K. L.↗
Space propulsion
Lewis Research Center is developing broad-based new technologies for space chemical engines to satisfy long-term needs of ETO launch vehicles and other vehicles operating in and beyond Earth orbit. Specific objectives are focused on high performance LO2/LH2 engines providing moderate thrusts of 7,5-200 klb. This effort encompasses research related to design analysis and manufacturing processes needed to apply advanced materials to subcomponents, components, and subsystems of space-based systems and related ground-support equipment. High-performance space-based chemical engines face a number of technical challenges. Liquid hydrogen turbopump impellers are often so large that they cannot be machined from a single piece, yet high stress at the vane/shroud interface makes bonding extremely difficult. Tolerances on fillets are critical on large impellers. Advanced materials and fabricating techniques are needed to address these and other issues of interest. Turbopump bearings are needed which can provide reliable, long life operation at high speed and high load with low friction losses. Hydrostatic bearings provide good performance, but transients during pump starts and stops may be an issue because no pressurized fluid is available unless a separate bearing pressurization system is included. Durable materials and/or coatings are needed that can demonstrate low wear in the harsh LO2/LH2 environment. Advanced materials are also needed to improve the lifetime, reliability and performance of other propulsion system elements such as seals and chambers.
Kazaroff, John M.↗
Neutron Characterization for Additive Manufacturing
Oak Ridge National Laboratory (ORNL) is leveraging decades of experience in neutron characterization of advanced materials together with resources such as the Spallation Neutron Source (SNS) and the High Flux Isotope Reactor (HFIR) shown in Fig. 1 to solve challenging problems in additive manufacturing (AM). Additive manufacturing, or three-dimensional (3-D) printing, is a rapidly maturing technology wherein components are built by selectively adding feedstock material at locations specified by a computer model. The majority of these technologies use thermally driven phase change mechanisms to convert the feedstock into functioning material. As the molten material cools and solidifies, the component is subjected to significant thermal gradients, generating significant internal stresses throughout the part (Fig. 2). As layers are added, inherent residual stresses cause warping and distortions that lead to geometrical differences between the final part and the original computer generated design. This effect also limits geometries that can be fabricated using AM, such as thin-walled, high-aspect- ratio, and overhanging structures. Distortion may be minimized by intelligent toolpath planning or strategic placement of support structures, but these approaches are not well understood and often "Edisonian" in nature. Residual stresses can also impact component performance during operation. For example, in a thermally cycled environment such as a high-pressure turbine engine, residual stresses can cause components to distort unpredictably. Different thermal treatments on as-fabricated AM components have been used to minimize residual stress, but components still retain a nonhomogeneous stress state and/or demonstrate a relaxation-derived geometric distortion. Industry, federal laboratory, and university collaboration is needed to address these challenges and enable the U.S. to compete in the global market. Work is currently being conducted on AM technologies at the ORNL Manufacturing Demonstration Facility (MDF) sponsored by the DOE's Advanced Manufacturing Office. The MDF is focusing on R&D of both metal and polymer AM pertaining to in-situ process monitoring and closed-loop controls; implementation of advanced materials in AM technologies; and demonstration, characterization, and optimization of next-generation technologies. ORNL is working directly with industry partners to leverage world-leading facilities in fields such as high performance computing, advanced materials characterization, and neutron sciences to solve fundamental challenges in advanced manufacturing. Specifically, MDF is leveraging two of the world's most advanced neutron facilities, the HFIR and SNS, to characterize additive manufactured components.
Watkins, Thomas↗
An early glimpse at long-term subsonic commercial turbofan technology requirements
This paper reports on the exploratory investigation and initial findings of the study of future turbofan concepts to conserve fuel. To date, these studies have indicated a potential reduction in cruise thrust specific fuel consumption in 1990 turbofans of approximately 15% relative to present day new engines through advances in internal aerodynamics, structure-mechanics, and materials. Advanced materials also offer the potential for fuel savings through engine weight reduction. Further studies are required to balance fuel consumption reduction with sound airlines operational economics.
Gray, D. E.↗
STOVL acoustic fatigue technologies
This paper assesses the state of the art in acoustic fatigue technologies as applied to an advanced supersonic short takeoff and vertical landing (STOVL) aircraft. The topics covered include advanced materials, fatigue, acoustic loads prediction, and stress response prediction. Advanced materials are compared from the standpoints of fatigue resistance and fatigue data availability. State of the art acoustic load prediction techniques are evaluated. Subsonic and supersonic jet noise generation mechanisms, axisymmetric and two-dimensional nozzles, and noise suppression methods are covered. Stress response prediction methods for acoustic, thermal, and maneuvering loads are addressed and the necessity of structural analysis with all three loading types applied simultaneously is assessed.
Groen, David S.↗
Evaluations of Candidate Materials for Advanced Space-Rated Vacuum Seals to Explore Space Environment Exposure Limits
For many materials used in space hardware, the environment in which they need to operate is harsher than the environment on earth. Exposure to vacuum conditions, atomic oxygen, and ultraviolet radiation can be detrimental, so testing of space hardware in simulated space environments is required. This is especially true for elastomeric components such as seals. NASA is developing advanced space-rated vacuum seals in support of future space exploration missions. These seals must exhibit extremely low leak rates to ensure that astronauts have sufficient breathable air during extended-duration missions. In some applications the seals are not mated during portions of the mission and are left uncovered and exposed to the conditions in space for prolonged periods of time prior to mating. Space-rated vacuum seals are often made of silicone because of the material's wide operating temperature range and ability to be molded or extruded into various shapes and cross sections. One approach being considered to achieve improved performance is to add titanium dioxide to the silicone material to make it more resistant to damage from ultraviolet radiation. In this study, seals made of the baseline material with and without 1.5 percent titanium dioxide additive (by weight) were exposed to atomic oxygen and increasing levels of ultraviolet radiation and then leak tested. Test results revealed that seals made of the new material could withstand longer exposures while still satisfying the leak rate requirement even under worst-case conditions of partial compression at the extremes of the anticipated operating temperature range.
Seals↗
Evaluations of Candidate Materials for Advanced Space-Rated Vacuum Seals to Explore Space Environment Exposure Limits
For many materials used in space hardware, the environment in which they need to operate is harsher than the environment on earth. Exposure to vacuum conditions, atomic oxygen, and ultraviolet radiation can be detrimental, so testing of space hardware in simulated space environments is required. This is especially true for elastomeric components such as seals. NASA is developing advanced space-rated vacuum seals in support of future space exploration missions. These seals must exhibit extremely low leak rates to ensure that astronauts have sufficient breathable air during extended-duration missions. In some applications the seals are not mated during portions of the mission and are left uncovered and exposed to the conditions in space for prolonged periods of time prior to mating. Space-rated vacuum seals are often made of silicone because of the material's wide operating temperature range and ability to be molded or extruded into various shapes and cross sections. One approach being considered to achieve improved performance is to add titanium dioxide to the silicone material to make it more resistant to damage from ultraviolet radiation. In this study, seals made of the baseline material with and without 1.5% titanium dioxide additive (by weight) were exposed to atomic oxygen and increasing levels of ultraviolet radiation and then leak tested. Test results revealed that seals made of the new material could withstand longer exposures while still satisfying the leak rate requirement even under worst-case conditions of partial compression at the extremes of the anticipated operating temperature range.
Ultraviolet radiation↗
C-130 Advanced Technology Center wing box conceptual design/cost study
A conceptual design was developed by Northrop/LTV for an advanced C-130 Center Wing Box (CWB) which could meet the severe mission requirements of the SOF C-130 aircraft. The goals for the advanced technology CWB relative to the current C-130H CWB were: (1) the same acquisition cost; (2) lower operating support costs; (3) equal or lower weight; (4) a 30,000 hour service life for the SOF mission; and (5) minimum impact on the current maintenance concept. Initially, the structural arrangement, weight, external and internal loads, fatigue spectrum, flutter envelope and design criteria for the SOF C-130 aircraft CWB were developed. An advanced materials assessment was then conducted to determine the suitability of advanced materials for a 1994 production availability and detailed trade studies were performed on candidate CWB conceptual designs. Finally, a life-cycle cost analysis was performed on the advanced CWB. The study results showed that a hybrid composite/metallic CWB could meet the severe SOF design requirements, reduce the CWB weight by 14 pct., and was cost effective relative to an all metal beefed up C-130H CWB.
Whitehead, R. S.↗
The effect of Low Earth Orbit space environment on polymeric spacecraft materials
The Advanced Composite Materials Exposure to Space Experiment flown on shuttle mission STS-41G was designed to investigate the effect of low Earth orbit space environment on polymeric spacecraft materials. The effect of the phenomenon attributed to atomic oxygen on Kapton and advanced composite materials of carbon-epoxy and kevlar epoxy is described. The results of true space exposure are compared to duplicate specimens subjected to a simulated environment in an Earth-based nozzle beam test facility utilizing microwave discharge to form atomic oxygen. Although the energy level for atomic oxygen in the beam facility did not achieve the orbital energy level of 5 eV, similar effects of surface erosion and degradation are observed after equivalent exposure times.
Zimcik, D. G.↗
Determination of Electromagnetic Properties of Mesh Material Using Advanced Radiometer Techniques
The need for a large diameter deployable antenna to map soil moisture with a 10 kilometer or better resolution using a microwave radiometer is discussed. A 6 meter deployable antenna is also needed to map sea surface temperature on the Navy Remote Ocean Sensor System (NROSS). Both of these deployable antennas require a mesh membrane material as the reflecting surface. The determination of the electromagnetic properties of mesh materials is a difficult problem. The Antenna and Microwave Research Branch (AMRB) of Langley Research Center was asked to measure the material to be used on MROSS by NRL. A cooperative program was initiated to measure this mesh material using two advanced radiometer techniques.
Arrington, R. F.↗
Fabrication of advanced electrochemical energy materials using sol-gel processing techniques
Advanced materials play an important role in electrochemical energy devices such as batteries, fuel cells, and electrochemical capacitors. They are being used as both electrodes and electrolytes. Sol-gel processing is a versatile solution technique used in fabrication of ceramic materials with tailored stoichiometry, microstructure, and properties. The application of sol-gel processing in the fabrication of advanced electrochemical energy materials will be presented. The potentials of sol-gel derived materials for electrochemical energy applications will be discussed along with some examples of successful applications. Sol-gel derived metal oxide electrode materials such as V2O5 cathodes have been demonstrated in solid-slate thin film batteries; solid electrolytes materials such as beta-alumina for advanced secondary batteries had been prepared by the sol-gel technique long time ago; and high surface area transition metal compounds for capacitive energy storage applications can also be synthesized with this method.
Chu, C. T.↗
Advanced Ceramic Materials for Future Aerospace Applications
With growing trend toward higher temperature capabilities, lightweight, and multifunctionality, significant advances in ceramic matrix composites (CMCs) will be required for future aerospace applications. The presentation will provide an overview of material requirements for future aerospace missions, and the role of ceramics and CMCs in meeting those requirements. Aerospace applications will include gas turbine engines, aircraft structure, hypersonic and access to space vehicles, space power and propulsion, and space communication.
durability↗
Development of thin film thermocouples on ceramic materials for advanced propulsion system applications
Thin film thermocouples were developed for use on metal parts in jet engines to 1000 C. However, advanced propulsion systems are being developed that will use ceramic materials and reach higher temperatures. The purpose is to develop thin film thermocouples for use on ceramic materials. The new thin film thermocouples are Pt13Rh/Pt fabricated by the sputtering process. Lead wires are attached using the parallel-gap welding process. The ceramic materials tested are silicon nitride, silicon carbide, aluminum oxide, and mullite. Both steady state and thermal cycling furnace tests were performed in the temperature range to 1500 C. High-heating-rate tests were performed in an arc lamp heat-flux-calibration facility. The fabrication of the thin film thermocouples is described. The thin film thermocouple output was compared to a reference wire thermocouple. Drift of the thin film thermocouples was determined, and causes of drift are discussed. The results of high heating rate tests up to 2500 C/sec are presented. The stability of the ceramic materials is examined. It is concluded that Pt13Rh/Pt thin film thermocouples are capable of meeting lifetime goals of 50 hr or more up to temperatures of 1500 C depending on the stability of the particular ceramic substrate.
Holanda, Raymond↗