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At least 199 records · Page 11

Critical speeding up in pure fluids

The extreme compressibility of a pure fluid near its critical point significantly affects its bulk dynamic response to temperature changes through adiabatic processes. Equations that describe the dynamics in the absence of gravity are developed, and the magnitude of the effect is illustrated with numerical solutions in one dimension. The results are remarkable: 5 mm of critical xenon, quenched from 20 to 10 mK above its critical temperature, cools by over 99 percent in less than 5 s. Moreover, adiabatic cooling is faster when the fluid is closer to the critical point.

Boukari, Hacene↗

The cold solar wind

From 3 to 10 percent of the time, the solar wind has a radial proton temperature between 15,000 K and 3500 K (the lowest recorded temperature). This 'cold' component shows some very important features that make it worthy of special study. It shows a temperature dependence on helicentric distance that is nearly adiabatic. When extrapolated back to 3 R(s), assuming adiabatic cooling, the resulting temperature for this cold component is in good agreement with coronal temperatures near the sonic point. Most importantly, the proton velocities and densities associated with this cold component match those predicted by solar wind models that do not incorporate significant wave heating. It is concluded that this is one solar wind component that fits well with appropriate models.

Freeman, J. W.↗

The depth of mantle convection

A one-layer model of convection in the mantle is considered. The presence of both an upper and a lower thermal boundary layer is assumed. The temperature at the core-mantle boundary is estimated to be 4000 + or - 500 K. Temperature fields computed for the two boundary layers are combined with the core-mantle boundary temperature estimate and with the adiabat to yield a curve of temperature versus depth representative of the mantle in its regime of convection. A theoretical analysis of mantle convection, based on the work of Turcotte and Oxburgh (1967) and extended by Golitsyn's (1977) scaling procedure, is presented. It is shown possible to reconcile the global averages of heat flow, plate sizes, speeds, mantle viscosity, plus some seismic data with the most general features of whole-mantle convection as predicted by the simple theory.

Elsasser, W. M.↗

Heat transfer, velocity-temperature correlation, and turbulent shear stress from Navier-Stokes computations of shock wave/turbulent boundary layer interaction flows

The properties of 2-D shock wave/turbulent boundary layer interaction flows were calculated by using a compressible turbulent Navier-Stokes numerical computational code. Interaction flows caused by oblique shock wave impingement on the turbulent boundary layer flow were considered. The oblique shock waves were induced with shock generators at angles of attack less than 10 degs in supersonic flows. The surface temperatures were kept at near-adiabatic (ratio of wall static temperature to free stream total temperature) and cold wall (ratio of wall static temperature to free stream total temperature) conditions. The computational results were studied for the surface heat transfer, velocity temperature correlation, and turbulent shear stress in the interaction flow fields. Comparisons of the computational results with existing measurements indicated that (1) the surface heat transfer rates and surface pressures could be correlated with Holden's relationship, (2) the mean flow streamwise velocity components and static temperatures could be correlated with Crocco's relationship if flow separation did not occur, and (3) the Baldwin-Lomax turbulence model should be modified for turbulent shear stress computations in the interaction flows.

Wang, C. R.↗

Multiscale Reactive Model for 1,3,5-Triamino-2,4,6-trinitrobenzene Inferred by Reactive MD Simulations and Unsupervised Learning

When high-energy-density materials are subjected to thermal or mechanical insults at extreme conditions (shock loading), a coupled response between the thermo-mechanical and chemical behaviors is systematically induced. Herein we develop a reaction model for the fast chemistry of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) at the mesoscopic scale, where the chemical behavior is determined by underlying microscopic reactive simulations. The slow carbon cluster formation is not discussed in the present work. All-atom reactive molecular dynamics (MD) simulations are performed with the ReaxFF potential, and a reduced-order chemical kinetics model for TATB is fitted to isothermal and adiabatic simulations of single crystal chemical decomposition. Unsupervised machine learning techniques based on non-negative matrix factorization are applied to MD trajectories to model the decomposition kinetics of TATB in terms of a four-component model. The associated heats of reaction are fit to the temperature evolution from adiabatic decomposition trajectories. Using a chemical species analysis, we show that non-negative matrix factorization captures the main chemical decomposition steps of TATB and provides an accurate estimation of their evolution with temperature. The final analytical formulation, coupled to a diffusion term, is incorporated into a continuum formalism, and simulation results are compared one-to-one against MD simulations of 1D reaction propagation along different crystallographic directions and with different initial temperatures. A good agreement is found for both the temporal and spatial evolution of the temperature field.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Bubble Combustion

A method of energy production that is capable of low pollutant emissions is fundamental to one of the four pillars of NASA s Aeronautics Blueprint: Revolutionary Vehicles. Bubble combustion, a new engine technology currently being developed at Glenn Research Center promises to provide low emissions combustion in support of NASA s vision under the Emissions Element because it generates power, while minimizing the production of carbon dioxide (CO2) and nitrous oxides (NOx), both known to be Greenhouse gases. and allows the use of alternative fuels such as corn oil, low-grade fuels, and even used motor oil. Bubble combustion is analogous to the inverse of spray combustion: the difference between bubble and spray combustion is that spray combustion is spraying a liquid in to a gas to form droplets, whereas bubble combustion involves injecting a gas into a liquid to form gaseous bubbles. In bubble combustion, the process for the ignition of the bubbles takes place on a time scale of less than a nanosecond and begins with acoustic waves perturbing each bubble. This perturbation causes the local pressure to drop below the vapor pressure of the liquid thus producing cavitation in which the bubble diameter grows, and upon reversal of the oscillating pressure field, the bubble then collapses rapidly with the aid of the high surface tension forces acting on the wall of the bubble. The rapid and violent collapse causes the temperatures inside the bubbles to soar as a result of adiabatic heating. As the temperatures rise, the gaseous contents of the bubble ignite with the bubble itself serving as its own combustion chamber. After ignition, this is the time in the bubble s life cycle where power is generated, and CO2, and NOx among other species, are produced. However, the pollutants CO2 and NOx are absorbed into the surrounding liquid. The importance of bubble combustion is that it generates power using a simple and compact device. We conducted a parametric study using CAVCHEM, a computational model developed at Glenn, that simulates the cavitational collapse of a single bubble in a liquid (water) and the subsequent combustion of the gaseous contents inside the bubble. The model solves the time-dependent, compressible Navier-Stokes equations in one-dimension with finite-rate chemical kinetics using the CHEMKIN package. Specifically, parameters such as frequency, pressure, bubble radius, and the equivalence ratio were varied while examining their effect on the maximum temperature, radius, and chemical species. These studies indicate that the radius of the bubble is perhaps the most critical parameter governing bubble combustion dynamics and its efficiency. Based on the results of the parametric studies, we plan on conducting experiments to study the effect of ultrasonic perturbations on the bubble generation process with respect to the bubble radius and size distribution.

Corrigan, Jackie↗

An interoperable implementation of collective‐variable based enhanced sampling methods in extended phase space within the OpenMM package

Collective variable (CV)-based enhanced sampling techniques are widely used today for accelerating barrier-crossing events in molecular simulations. A class of these methods, which includes temperature accelerated molecular dynamics (TAMD)/driven-adiabatic free energy dynamics (d-AFED), unified free energy dynamics (UFED), and temperature accelerated sliced sampling (TASS), uses an extended variable formalism to achieve quick exploration of conformational space. These techniques are powerful, as they enhance the sampling of a large number of CVs simultaneously compared to other techniques. Extended variables are kept at a much higher temperature than the physical temperature by ensuring adiabatic separation between the extended and physical subsystems and employing rigorous thermostatting. Here, in this work, we present a computational platform to perform extended phase space enhanced sampling simulations using the open-source molecular dynamics engine OpenMM. The implementation allows users to have interoperability of sampling techniques, as well as employ state-of-the-art thermostats and multiple time-stepping. This work also presents protocols for determining the critical parameters and procedures for reconstructing high-dimensional free energy surfaces. As a demonstration, we present simulation results on the high dimensional conformational landscapes of the alanine tripeptide in vacuo, tetra-N-methylglycine (tetra-sarcosine) peptoid in implicit solvent, and the Trp-cage mini protein in explicit water.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A two-stage magnetic refrigerator for astronomical applications with reservoir temperatures above 4 K

We propose a novel adiabatic demagnetization refrigerator (ADR) to produce temperatures as low as 100 mK starting from a high temperature reservoir between 4 and 8 K. The high temperature reservoir for the ADR can be provided by a mechanical cooler or an unpumped liquid helium bath. This refrigerator can be used to cool bolometric infrared detectors for low background astronomy from mountain tops, balloons or satellites as well as to cool cryogenic x-ray detectors. The two-stage ADR consists of a single magnet with a paramagnetic chromic-cesium-alum (CCA) salt pill to produce the low temperature and paramagnetic gadolinium-gallium-garnet (GGG) as the first stage to intercept heat from the high temperature reservoir. Thermal contact between the paramagnets and the reservoir during magnetization is made with a mechanical heat switch. The ADR is suspended with Kevlar chords under tension for high mechanical stiffness and low parasitic heat leak. In a single cycle, the ADR maintains a temperature of 100 mK for 10 to 100 hours. This time depends strongly on the magnetic field and reservoir temperature but not on the volume of the paramagnetic material as long as the heat leak is dominated by the suspension.

Hagmann, C.↗

Hidden variable in the electrocaloric effect of ferroics

Caloric effects allow for temperature control through adiabatic application of external fields and are actively explored for solid-state refrigeration. The common wisdom is that the application of ultrahigh fields enhances the effects, thus providing a route to their practical applications. Here, using the ferroelectric relaxor (Ba, Ca)(Ti, Zr)O 3 , we demonstrate that in ferroics, which are the prime candidates for such application, this is not true in general and that caloric effects can be enhanced through the reduction of the applied field. The explanation of such a counterintuitive response is in the dependence of the electrocaloric effect on the effective poling field that can be regarded as a “hidden” variable of the caloric effects.

36 MATERIALS SCIENCE↗

Heat-transfer testing procedures in phase B shuttle studies with emphasis on phase change data improvement

The procedures used in the application of the phase change technique to the phase B shuttle configuration are discussed along with factors which may affect data accuracy. These factors include variation of thermal properties of phase change model material, sensitivity of measured heat transfer coefficients to the assumed value of the adiabatic to total temperature ratio, and wall temperature effects. These sensitivities are illustrated in sample calculations for a shuttle geometry. Factors which may affect the visual clarity and interpretation of phase change data are discussed, and a method of improving photographic data quality through the use of polarized light is presented.

Throckmorton, D. A.↗

Further investigations of Jupiter models

It is noted that previously calculated models of Jupiter, in which the H/He ratio is assumed to be solar, required the inclusion of considerable additional mass in the form of volatilized condensates in the atmosphere and excess mass in the central core. Several additional models are considered in this paper which take into account the stricter constraints imposed by Pioneer 10 measurements of Jupiter's gravitational moments. These measurements have indicated that the mass of the excess volatilized condensates (assumed to be water) relative to the core mass (assumed to be rock) exceeds the relevant solar ratio. The present models are tested for sensitivity to variations in the H/He ratio, in the softness of the equation of state for water, in the treatment of the internal adiabat, in departures from an internal adiabat, and in temperature at the one-bar level. The preliminary results indicate that the ratio of excess water to rock in Jupiter is considerably in excess of the solar value.

Podolak, M.↗

Interior structure of Saturn inferred from Pioneer 11 gravity data

The structure of Saturn is studied via a fourth-order theory for rotating planets and equations of state for the envelope which depend parametrically on the helium abundance, on the starting temperature for the adiabat, and on adopted forms of the pressure-density curve in the region of transition from molecular to metallic hydrogen. Models are constrained by the values of J2 and J4 obtained from the Pioneer-Saturn celestial mechanics experiment. Equations of state are tested by computing Jupiter models, which can now be subjected to a more stringent comparison with observed zonal harmonics. It is found that Saturn has a low-density hydrogen-helium envelope with no evidence for enhancement of H2O, CH4, or other abundant compounds. Such compounds are presumably located near the core. The helium mass abundance for Saturn's envelope appears to be in the range of approximately 0.12 to 0.19, but this result is very model-dependent. The helium abundance in the envelope of Jupiter is apparently very similar to that of Saturn.

Hubbard, W. B.↗

Climate sensitivity of a one-dimensional radiative-convective model with cloud feedback

The potential complexity of the feedback between global mean cloud amount and global mean surface temperature when variations of the vertical cloud distribution are included is illustrated. This is done by studying the behavior of a one-dimensional radiative-convective model with two types of cloud variation: (1) variable cloud cover with constant optical thickness and (2) variable optical thickness with constant cloud cover. The variable parameter is calculated on the assumption that a correlation exists between cloud amount and precipitation or the vertical flux convergence of latent heat. Since the vertical latent heat flux is taken to be a fraction of the total heat flux, modeled by convective adjustment, the sensitivity of the results to two different critical lapse rates is examined. These are a constant 6.5 K/km lapse rate and a temperature-dependent, moist adiabatic lapse rate. The effects of the vertical structure of climate perturbations on the nature of the cloud feedback are also examined. The model results reveal that changes in the vertical cloud distribution and mean cloud optical thickness can be as important to climate variations as are changes in the total cloud cover.

Wang, W.-C.↗

The Cygnus loop - A detailed comparison of X-ray and optical emission

A comparison at a resolution of 17 arcsec is presented between optical emission from forbidden O III and forbidden S II and the thermal X-ray emission for a field on the southeast edge of the Cygnus Loop SNR. The relationship between optical and X-ray emission in the field is described, generalizing to the Loop as a whole when possible. Several possible explanations for the presence of bright X-ray emission in the vicinity of optical emission are presented and evaluated based on the data. These mechanisms involve evaporation, gradual variations and gradients in the density of the preshock intercloud medium, and additional compression of material which has already been heated to X-ray temperatures by the adiabatic blast wave. The additional compression could result from rapid deceleration of the blast wave itself or from reshocking by reflected or bow shocks around dense clouds. Implications of the observations for models of SNR evolution and the interstellar medium are discussed.

Cox, D. P.↗

A near-wall four-equation turbulence model for compressible boundary layers

A near-wall four-equation turbulence model is developed for the calculation of high-speed compressible turbulent boundary layers. The four equations used are the k-epsilon equations and the theta(exp 2)-epsilon(sub theta) equations. These equations are used to define the turbulent diffusivities for momentum and heat fluxes, thus allowing the assumption of dynamic similarity between momentum and heat transport to be relaxed. The Favre-averaged equations of motion are solved in conjunction with the four transport equations. Calculations are compared with measurements and with another model's predictions where the assumption of the constant turbulent Prandtl number is invoked. Compressible flat plate turbulent boundary layers with both adiabatic and constant temperature wall boundary conditions are considered. Results for the range of low Mach numbers and temperature ratios investigated are essentially the same as those obtained using an identical near-wall k-epsilon model. In general, the numerical predictions are in very good agreement with measurements and there are significant improvements in the predictions of mean flow properties at high Mach numbers.

Sommer, T. P.↗

Near-wall variable-Prandtl-number turbulence model for compressible flows

A near-wall four-equation turbulence model is developed for the calculation of high-speed compressible turbulent boundary layers. The four equations used are the k-epsilon equations and the theta(exp 2)-epsilon (sub theta) equations. These equations are used to define the turbulent diffusivities for momentum and heat fluxes, thus allowing the assumption of dynamic similarity between momentum and heat transport to be relaxed. The Favre-averaged equations of motion are solved in conjunction with the four transport equations. Calculations are compared with measurements and with another model's predictions where the assumption of the constant turbulent Prandtl number is invoked. Compressible flat plate turbulent boundary layers with both adiabatic and constant temperature wall boundary conditions are considered. Results for the range of low Mach numbers and temperature ratios investigated are essentially the same as those obtained using an identical near-wall k-epsilon model. In general, there are significant improvements in the predictions of mean flow properties at high Mach numbers.

Sommer, T. P.↗

The problem of cooling an air-cooled cylinder on an aircraft engine

An analysis of the cooling problem has been to show by what means the cooling of an air-cooled aircraft engine may be improved. Each means of improving cooling is analyzed on the basis of effectiveness in cooling with respect to power for cooling. The altitude problem is analyzed for both supercharged and unsupercharged engines. The case of ground cooling is also discussed. The heat-transfer process from the hot gases to the cylinder wall is discussed on the basis of the fundamentals of heat transfer and thermodynamics. Adiabatic air-temperature rise at a stagnation point in compressible flow is shown to depend only on the velocity of flow.

Brevoort, M J↗

Skin Friction at Very High Reynolds Numbers in the National Transonic Facility

Skin friction coefficients were derived from measurements using standard measurement technologies on an axisymmetric cylinder in the NASA Langley National Transonic Facility (NTF) at Mach numbers from 0.2 to 0.85. The pressure gradient was nominally zero, the wall temperature was nominally adiabatic, and the ratio of boundary layer thickness to model diameter within the measurement region was 0.10 to 0.14, varying with distance along the model. Reynolds numbers based on momentum thicknesses ranged from 37,000 to 605,000. The measurements approximately doubled the range of available data for flat plate skin friction coefficients. Three different techniques were used to measure surface shear. The maximum error of Preston tube measurements was estimated to be 2.5 percent, while that of Clauser derived measurements was estimated to be approximately 5 percent. Direct measurements by skin friction balance proved to be subject to large errors and were not considered reliable.

Watson, Ralph D.↗