Study of the synthesis of block copolymers Final report, 18 Oct. 1966 - 18 Aug. 1970
Chemical and mechanical properties and synthesis of 4-vinylbiphenyl-isoprene ABA block copolymers for permeation and propellant binder studies
Heller, J.↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Arco Solar, Incorporated: The industrial point of view
The status of technological developments in silicon wafer production is summarized. Wafer growing and casting/sawing methods are considered. aba J.D.
Yerkes, J. W.↗
Development and test fuel cell powered on-site integrated total energy systems. Phase 3: Full-scale power plant development
The on-site system application analysis is summarized. Preparations were completed for the first test of a full-sized single cell. Emphasis of the methanol fuel processor development program shifted toward the use of commercial shell-and-tube heat exchangers. An improved method for predicting the carbon-monoxide tolerance of anode catalysts is described. Other stack support areas reported include improved ABA bipolar plate bonding technology, improved electrical measurement techniques for specification-testing of stack components, and anodic corrosion behavior of carbon materials.
Kaufman, A.↗
Develop and test fuel cell powered on-site integrated total energy system
Satisfactory performance is reported for the first 12-cell sub-stack of the 5 kW rebuild using improved ABA reactant distribution plates. Construction and test results are described for the first full-sized single-cell test (0.33 m x 0.56 m). Test duration was 450 hours. Plans are outlined for construction and testing of two methanol reformer units based on commercially-available shell-and-tube heat exchangers. A 5 kW-equivalent precursor and a 50 kW-equivalent prototype will be built. Supporting design and single-tube experimental data are presented. Stack support efforts are summarized on corrosion currents of graphite materials and acid-management of single-cell test facilities. Comparative properties are summarized for the two methanol/steam reforming catalysts evauated under Task V (now completed); T2107RS and C70-2RS.
Kaufman, A.↗
Results of the AFRSI detailed-environment test of the 0.035-scale SSV pressure-loads model 84-0 in the Ames 11x11 ft. TWT and the Lewis 8x6 ft. and 10x10 ft. SWT (OA-310A, B, C), volume 1
Detailed orbiter aerodynamic and aeroacoustic pressure data were obtained in a three-part experimental investigation (OA-310A, B and C). The tests were conducted in three NASA facilities: OA-310A in the Ames 11x11-foot Transonic Wind Tunnel; OA-310B in the Lewis 8x6-foot Supersonic Wind Tunnel; and OA-310C in the Lewis 10x10-foot Supersonic Wind Tunnel. Test data were obtained to support analysis of the Space Transportation System (STS)-6 advanced flexible reusable surface insulation (AFRSI) anomaly using the 0.035-scale space shuttle vehicle pressure-loads Model 84-0. Data were obtained in the areas of the orbiter where AFRSI is to be applied to OV-099 and OV-103. Emphasis was placed on acquiring detailed aeroacoustic data and time-averaged pressure distributions on five affected areas: (1) canopy; (2) side of fuselage; (3) upper surface of wing; (4) OMS pods; and (5) vertical tail. Data were obtained at nominal ascent and entry atmospheric flight trajectory conditions between M=0.6 through M-3.5. Sample plotted data are given. aba M.G.
Marshall, B. A.↗
Cyclogenesis
In order to extend the conventional baroclinic instability concept, one has to picture the growth process as resulting from the superposition of two neutrally stable baroclinic waves, an upper and a lower one, each wave propagating along a near-discontinuity in the potential vorticity (PV) field. The PV discontinuity for the lower wave is given by the non-uniformity of the thermal field at the ground, while the discontinuity for the upper wave is given by the contrast, in the 400 to 200 mb range, between the high-PV polar stratosphere and the low-PV subtropical troposphere. The horizontal PV radients mentioned are approximately opposed to each other, causing the wo waves to travel in the opposite direction. As Hoskins et al. (1985) show convincingly, a phase lock between the upper and lower wave may occur, coupled with a tendency toward mutual amplification. The conceptual model just outlined is particularly attractive to synoptic meteorologists because it does not require the two waves to be of initially small amplitude and thus does not fly in the face of observational evidence. This model, by allowing a finite perturbation velocity and a considerable range of relative phase speeds at the time when the upper and lower wave reach the proper phase lag for amplification, may lead to growth rates larger than those predicted by linear theory. aba R.J.F.
Bleck, R.↗
Amino Acid Chemistry as a Link Between Small Solar System Bodies and Carbonaceous Chondrites
Establishing chemical links between meteorites and small solar system bodies, such as comets and asteroids, provides a tool for investigating the processes that occurred during the formation of the solar system. Carbonaceous meteorites are of particular interest, since they may have seeded the early Earth with a variety of prebiotic organic compounds including amino acids, purines and pyrimidines, which are thought to be necessary for the origin of life. Here we report the results of high-performance liquid chromatography (HPLC) based amino acid analyses of the acid-hydrolyzed hot water extracts from pristine interior pieces of the CI carbonaceous chondrites Orgueil and Ivuna and the CM meteorites Murchison and Murray. We found that the CI meteorites Orgueil and Ivuna contained high abundances of beta-alanine and glycine, while only traces of other amino acids like alanine, alpha-amino-n-butryic acid (ABA) and alpha-aminoisobutyric acid (AIB) were detected in these meteorites. Carbon isotopic measurements of beta-alanine and glycine in Orgueil by gas chromatography combustion-isotope ratio mass spectrometry clearly indicate an extraterrestrial origin of these amino acids. The amino acid composition of Orgueil and Ivuna was strikingly different from the CM chondrites Murchison and Murray. The most notable difference was the high relative abundance of B-alanine in Orgueil and Ivuna compared to Murchison and Murray. Furthermore, AIB, which is one of the most abundant amino acids found in Murchison and Murray, was present in only trace amounts in Orgueil and Ivuna. Our amino acid data strongly suggest that the CI meteorites Orgueil and Ivuna came from a different type of parent body than the CM meteorites Murchison and Murray, possibly from an extinct comet. It is generally thought that carbonaceous meteorites are fragments of larger asteroidal bodies delivered via near Earth objects (NEO). Orbital and dynamic studies suggest that both fragments of main belt asteroids and comets replenish the NEO population, therefore extinct comets may contribute up to half of all NEO's. A comparison of an amino acid analysis of a returned NEO sample to CI and CM carbonaceous chondrites would help establish a link between small solar system bodies and meteorites. Based on our amino acid measurements of CI and CM chondrites, amino acid chemistry can be included as an additional set of criteria to constrain the nature of meteorite parent bodies.
Glavin, Daniel P.↗
Amino acids in the Martian meteorite Nakhla
A suite of protein and nonprotein amino acids were detected with high-performance liquid chromatography in the water- and acid-soluble components of an interior fragment of the Martian meteorite Nakhla, which fell in Egypt in 1911. Aspartic and glutamic acids, glycine, alanine, beta-alanine, and gamma-amino-n-butyric acid (gamma-ABA) were the most abundant amino acids detected and were found primarily in the 6 M HCl-hydrolyzed, hot water extract. The concentrations ranged from 20 to 330 parts per billion of bulk meteorite. The amino acid distribution in Nakhla, including the D/L ratios (values range from <0.1 to 0.5), is similar to what is found in bacterially degraded organic matter. The amino acids in Nakhla appear to be derived from terrestrial organic matter that infiltrated the meteorite soon after its fall to Earth, although it is possible that some of the amino acids are endogenous to the meteorite. The rapid amino acid contamination of Martian meteorites after direct exposure to the terrestrial environment has important implications for Mars sample-return missions and the curation of the samples from the time of their delivery to Earth.
NASA Discipline Exobiology↗
Joining and Testing Composite Plates to Ti Tubes
The joining of metal tubes to composite plates is required for heat-rejection components in several space applications. Currently a number of different braze compositions are being evaluated as to their effectiveness. Such tube-plate configurations cannot be represented by traditional methods of testing, e.g., lap joints. The joined region is not between two flat surfaces, but rather between a flat surface and a curved surface. Therefore, several tests have been employed to ascertain the effectiveness of the different braze approaches in tension that are both simple and representative of the actual system and relatively straightforward in analysis. The results of these "tube-tests" will be discussed for the three different braze compositions, Cu-ABA, Ti-Cu-Sil, and Ti-Cu-Ni. In addition, fracture analysis of the failed joints was performed and offers insights into the cause of joint failure and the distinctions which need to be made between the "strength" of a joint versus the "load carrying ability" of a joint.
Morscher, Gregory N.↗
Active Metal Brazing of Carbon-Carbon Composites to Titanium
The Ti-metal/C-C composite joints were formed by reactive brazing with three commercial brazes, namely, Cu-ABA, TiCuNi, and TiCuSil. The joint microstructures were examined using optical microscopy, and scanning electron microscopy (SEM) coupled with energy dispersive spectrometry (EDS). The results of the microstructure analysis indicate solute redistribution across the joint which led to good wetting, spreading, and metallurgical bond formation via interdiffusion.
Singh, M.↗
Mechanical Characterization of Reactively Brazed Metal-Composite Joints for Heat Rejection Systems
The joining of metal tubes to composite plates is required for heat-rejection components in several space applications. Currently a number of different braze compositions are being evaluated as to their effectiveness. Such tube-plate configurations cannot be represented by traditional methods of testing, e.g., lap joints. The joined region is not between two flat surfaces, but rather between a flat surface and a curved surface. Therefore, several tests have been employed to ascertain the effectiveness of the different braze approaches in tension and in shear that are both simple and representative of the actual system and relatively straightforward in analysis. The results of these "tube tests" will be discussed for the three different braze compositions, Cu-ABA, Ti-Cu-Sil, and Ti-Cu-Ni. In addition, fracture analysis of the failed joints was performed and offers insights into the cause of joint failure and the distinctions which need to be made between the "strength" of a joint versus the "load carrying ability" of a joint.
Morscher, Gregory N.↗
Reactive Brazing of Carbon-Carbon Composites to Titanium
The Ti-metal/C-C composite joints were formed by reactive brazing with three commercial brazes, namely, Cu-ABA, TiCuNi, and TiCuSil. The joint microstructures were examined using optical microscopy, and scanning electron microscopy (SEM) coupled with energy dispersive spectrometry (EDS). The results of the microstructure analysis indicate solute redistribution across the joint and possible metallurgical bond formation via interdiffusion, which led to good wetting and spreading.
Shpargel, Tarah↗
Effects of Different Braze Materials and Composite Substrates on Composite/Ti Joints
An ever increasing number of applications require robust joining technologies of dissimilar materials. In this study, three types of ceramic composites (C-C, C-SiC, and SiC-SiC) were vacuum brazed to commercially pure Ti using the Cusil-ABA (63 Ag - 35.5 Cu - 1.75 Ti) active metal braze alloy. The study also compared composite specimens as-fabricated and after surface grinding/polishing. A butt-strap tensile shear strength test was used to evaluate the joined structures at room temperature, 270 and 500 C. The elevated temperatures represent possible use temperatures for some heat rejection type applications. Joint strength will be discussed in light of braze wetting and spreading properties, composite properties, and test temperature.
Morscher, Gregory N.↗
Effect of Composite Substrates on the Mechanical Behavior of Brazed Joints in Metal-Composite System
Advanced composite components are being considered for a wide variety of demanding applications in aerospace, space exploration, and ground based systems. A number of these applications require robust integration technologies to join dissimilar materials (metalcomposites) into complex structural components. In this study, three types of composites (C-C, C-SiC, and SiC-SiC) were vacuum brazed to commercially pure Ti using the active metal braze alloy Cusil-ABA (63Ag-35.3Cu-1.75Ti). Composite substrates with as fabricated and polished surfaces were used for brazing. The microstructure and composition of the joint, examined using scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDS), showed sound metallurgical bonding in all systems. The butt strap tensile (BST) test was performed on bonded specimens at room and elevated temperatures. Effect of substrate composition, interlaminar properties, and surface roughness on the mechanical properties and failure behavior of joints will be discussed.
Singh, M.↗
Joining of Zirconium Diboride-Based Ceramic Composites to Metallic Systems for High-Temperature Applications
Three types of hot-pressed zirconium diboride (ZrB2)-based ultra-high-temperature ceramic composites (UHTCC), ZrB2-SiC (ZS), ZrB2-SiC-C (ZSC), and ZrB2-SCS9-SiC (ZSS), were joined to Cu-clad-Mo using two Ag-Cu brazes (Cusil-ABA and Ticusil, T(sub L) approx.1073-1173 K) and two Pd-base brazes (Palco and Palni, T(sub L) approx.1493-1513 K). Scanning Electron Microscopy (SEM) coupled with energy-dispersive spectroscopy (EDS) revealed greater chemical interaction in joints made using Pd-base brazes than in joints made using Ag-Cu based active brazes. The degree of densification achieved in hot pressed composites influenced the Knoop hardness of the UHTCC and the hardness distribution across the braze interlayer. The braze region in Pd-base system displayed higher hardness in joints made using fully-dense ZS composites than in joints made using partially-dense ZSS composites and the carbon-containing ZSC composites. Calculations indicate a small negative elastic strain energy and an increase in the UHTCC's fracture stress up to a critical clad layer thickness . Above this critical thickness, strain energy in the UHTCC is positive, and it increases with increasing clad layer thickness. Empirical projections show a reduction in the effective thermal resistance of the joints and highlight the potential benefits of joining the UHTCC to Cu-clad-Mo.
Asthana, R.↗
Extraterrestrial Amino Acids in the Almahata Sitta Meteorite
Amino acid analysis of a meteorite fragment of asteroid 2008 TC(sub 3) called Almahata Sitta was carried out using reverse-phase high-perfo rmance liquid chromatography coupled with UV fluorescence detection a nd time-of-flight mass spectrometry (HPLC-FD/ToF-MS) as part of a sam ple analysis consortium. HPLC analyses of hot-water extracts from the meteorite revealed a complex distribution of two- to six-carbon aliph atic amino acids and one- to three carbon amines with abundances rang ing from 0.5 to 149 parts-per-billion (ppb). The enantiomeric ratios of the amino acids alanine, Beta-amino-n-butyric acid (Beta-ABA), 2-amino-2- methylbutanoic acid (isovaline), and 2-aminopentanoic acid (no rvaline) in the meteorite were racemic (D/L approximately 1), indicat ing that these amino acids are indigenous to the meteorite and not te rrestrial contaminants. Several other non-protein amino acids were also identified in the meteorite above background levels including alpha -aminoisobutyric acid (alpha-AIB), 4-amino-2- methybutanoic acid, 4-a mino-3-methylbutanoic acid, and 3-, 4-, and 5-aminopentanoic acid. Th e total abundances of isovaline and AlB in Almahata Sitta are approximately 1000 times lower than the abundances of these amino acids found in the CM carbonaceous meteorite Murchison. The extremely love abund ances and unusual distribution of five carbon amino acids in Almahata Sitta compared to Cl, CM, and CR carbonaceous meteorites and may be due to extensive thermal alteration of amino acids on the parent aster oid by partial melting during formation or impact shock heating.
Glavin, Daniel P.↗
Extraterrestrial Amino Acids in the Almahata Sitta Meteorite
Amino acid analysis of a meteorite fragment of asteroid 2008 TC3 called Almahata Sitta was carried out using reverse-phase liquid chromatography coupled with UV fluorescence detection and time-of-flight mass spectrometry (LC-FD/ToF-MS) as part of a sample analysis consortium. LC-FD/ToF-MS analyses of hot-water extracts from the meteorite revealed a complex distribution of two- to seven-carbon aliphatic amino acids and one- to three-carbon amines with abundances ranging from 0.5 to 149 parts-per-billion (ppb). The enantiomeric ratios of the amino acids alanine, R-amino-n-butyric acid (beta-ABA), 2-amino-2-methylbutanoic acid (isovaline), and 2-aminopentanoic acid (norvaline) in the meteorite were racemic (D/L approximately 1), indicating that these amino acids are indigenous to the meteorite and not terrestrial contaminants. Several other non-protein amino acids were also identified in the meteorite above background levels including alpha-aminoisobutyric acid (alpha-AIB), 4-amino-2- methylbutanoic acid, 4-amino-3-methylbutanoic acid, and 3-, 4-, and 5-aminopentanoic acid. The total abundances of isovaline and alpha-AIB in Almahata Sitta are 1000 times lower than the abundances of these amino acids found in the CM carbonaceous chondrite Murchison. The extremely low abundances and unusual distribution of five carbon amino acids in Almahata Sitta compared to Cl, CM, and CR carbonaceous chondrites may reflect extensive thermal alteration of amino acids on the parent asteroid by partial melting during formation or subsequent impact shock heating. It is also possible that amino acids were synthesized by catalytic reactions on the parent body after asteroid 2008 TC3 cooled to lower temperatures.
Glavin, Daniel P.↗
Microstructural and Mechanical Evaluation of a Cu-Based Active Braze Alloy to Join Silicon Nitride Ceramics
Self-joining of St. Gobain Si3N4 (NT-154) using a ductile Cu-Al-Si-Ti active braze (Cu-ABA) was demonstrated. A reaction zone approx.2.5-3.5 microns thick) developed at the interface after 30 min brazing at 1317 K. The interface was enriched in Ti and Si. The room temperature compressive shear strengths of Si3N4/Si3N4 and Inconel/Inconel joints (the latter created to access baseline data for use with the proposed Si3N4/Inconel joints) were 140+/-49MPa and 207+/-12MPa, respectively. High-temperature shear tests were performed at 1023K and 1073 K, and the strength of the Si3N4/Si3N4 and Inconel/Inconel joints were determined. The joints were metallurgically well-bonded for temperatures above 2/3 of the braze solidus. Scanning and transmission electron microscopy studies revealed a fine grain microstructure in the reaction layer, and large grains in the inner part of the joint with interfaces being crack-free. The observed formation of Ti5Si3 and AlN at the joint interface during brazing is discussed.
Singh, M.↗