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Ectomycorrhizal Community Structure and Soil Characteristics of Mature Lodgepole Pine (Pinus Contorta) and Adjacent Stands of Old Growth Mixed Conifer in Yellowstone National Park, Wyoming USA

Forest development patterns following disturbance are known to influence the physical and chemical attributes of soils at different points in time. Changes in soil resources are thought to have a corresponding effect on ectomycorrhizal (ECM) community structure. We used molecular methods to compare below-ground ECM species richness, composition, and abundance between adjacent stands of homogenous lodgepole pine and old growth mixed conifer in Yellowstone National Park (YNP). In each stand-type we collected soil cores to both identify mycorrhizae and assess soil chemistry. Although no statistical difference was observed in the mean number of ECM root tips per core between stand types, the total number of species identified (85 versus 35) and the mean number of species per core (8.8 +/- 0.6 versus 2.5 +/- 0.3) were significantly higher in lodgepole pine. Differences between the actual and estimated species richness levels indicated that these forest types support a high number of ECM species and that undersampling was severe. Species compositions were widely disparate between stands where only four species were shared out of a total of 116. Soil analysis also revealed that mixed conifer was significantly lower in pH, but higher in organic matter, potassium, phosphorus, and ammonium when compared to lodgepole pine stands. Species richness per core was correlated with these chemical data, however, analysis of covariance indicated that stand type was the only statistically significant factor in the observed difference in species richness. Our data suggest that ECM fungal richness increases as homogenous lodgepole pine stands grow and mature, but declines after Engelmann spruce and subalpine fir colonize. Despite difficulties linking species composition with soil chemistry, there are a variety of physical and chemical factors that could be influencing ECM community structure. Future field experiments are necessary to test some of the mechanisms potentially operating within this system.

Douglas, Robert B.↗

Mineralogical Characterization of Lunar Highland Soils

Ten pristine highland soils were selected for this study from Apollo 14 and 16 collections. These soils were chosen for their contrasting maturities, as reflected in their Is/FeO values [6]. For each soil, the 44- 20, 20-10, and < 10 m size fractions were obtained by wet sieving, with triply distilled water [7]. As outlined in Taylor et al. [2], each soil was split into appropriate sizes and distributed to LSCC members. The Tennessee team has characterized these soil size fractions both chemically and mineralogically, with detailed modal and phase compositional analyses, using techniques described previously by our group [8]. The results of the bulk chemistry of each size fraction of the highland soils was presented earlier.

Taylor, L. A.↗

Isolation and Identification of Microorganisms in JSC Mars-1 Simulant Soil

Microorganisms were isolated and identified in samples of JSC Mars-1, a Mars simulant soil. JSC Mars-1 is an altered volcanic ash from a cinder cone south of Mauna Kea, Hawaii. This material was chosen because of its similarity to the Martian soil in physical and chemical composition. The soil was obtained by excavating 40 cm deep in a vegetated area to prevent contamination. In previous studies, bacteria from this soil has been isolated by culturing on different types of media, including minimal media, and using biochemical techniques for identification. Isolation by culturing is successful only for a small percentage of the population. As a result, molecular techniques are being employed to identify microorganisms directly from the soil without culturing. In this study, bacteria were identified by purifying and sequencing the DNA encoding the 16s ribosomal RNA (16s rDNA). This gene is well conserved in species and demonstrates species specificity. In addition, biofilm formation, an indicator of microbial life, was studied with this soil. Biofilms are microbial communities consisting of microbes and exopolysaccharides secreted by them. This is a protective way of life for the microbes as they are more resistant to environmental pressures.

Mendez, Claudia↗

A Comparison of Land Surface Model Soil Hydraulic Properties Estimated by Inverse Modeling and Pedotransfer Functions

Soil hydraulic properties (SHPs) regulate the movement of water in the soil. This in turn plays an important role in the water and energy cycles at the land surface. At present, SHPS are commonly defined by a simple pedotransfer function from soil texture class, but SHPs vary more within a texture class than between classes. To examine the impact of using soil texture class to predict SHPS, we run the Noah land surface model for a wide variety of measured SHPs. We find that across a range of vegetation cover (5 - 80% cover) and climates (250 - 900 mm mean annual precipitation), soil texture class only explains 5% of the variance expected from the real distribution of SHPs. We then show that modifying SHPs can drastically improve model performance. We compare two methods of estimating SHPs: (1) inverse method, and (2) soil texture class. Compared to texture class, inverse modeling reduces errors between measured and modeled latent heat flux from 88 to 28 w/m(exp 2). Additionally we find that with increasing vegetation cover the importance of SHPs decreases and that the van Genuchten m parameter becomes less important, while the saturated conductivity becomes more important.

Gutmann, Ethan D.↗

Utilizing Calibrated GPS Reflected Signals to Estimate Soil Reflectivity and Dielectric Constant: Results from SMEX02

Extensive reflected GPS data was collected using a GPS reflectometer installed on an HC130 aircraft during the Soil Moisture Experiment 2002 (SMEX02) near Ames, Iowa. At the same time, widespread surface truth data was acquired in the form of point soil moisture profiles, areal sampling of near-surface soil moisture, total green biomass and precipitation history, among others. Previously, there have been no reported efforts to calibrate reflected GPS data sets acquired over land. This paper reports the results of two approaches to calibration of the data that yield consistent results. It is shown that estimating the strength of the reflected signals by either (1) assuming an approximately specular surface reflection or (2) inferring the surface slope probability density and associated normalization constants give essentially the same results for the conditions encountered in SMEX02. The corrected data is converted to surface reflectivity and then to dielectric constant as a test of the calibration approaches. Utilizing the extensive in-situ soil moisture related data this paper also presents the results of comparing the GPS-inferred relative dielectric constant with the Wang-Schmugge model frequently used to relate volume moisture content to dielectric constant. It is shown that the calibrated GPS reflectivity estimates follow the expected dependence of permittivity with volume moisture, but with the following qualification: The soil moisture value governing the reflectivity appears to come from only the top 1-2 centimeters of soil, a result consistent with results found for other microwave techniques operating at L-band. Nevertheless, the experimentally derived dielectric constant is generally lower than predicted. Possible explanations are presented to explain this result.

Katzberg, Stephen J.↗

Microwave Soil Moisture Retrieval Under Trees

Soil moisture is recognized as an important component of the water, energy, and carbon cycles at the interface between the Earth's surface and atmosphere. Current baseline soil moisture retrieval algorithms for microwave space missions have been developed and validated only over grasslands, agricultural crops, and generally light to moderate vegetation. Tree areas have commonly been excluded from operational soil moisture retrieval plans due to the large expected impact of trees on masking the microwave response to the underlying soil moisture. Our understanding of the microwave properties of trees of various sizes and their effect on soil moisture retrieval algorithms at L band is presently limited, although research efforts are ongoing in Europe, the United States, and elsewhere to remedy this situation. As part of this research, a coordinated sequence of field measurements involving the ComRAD (for Combined Radar/Radiometer) active/passive microwave truck instrument system has been undertaken. Jointly developed and operated by NASA Goddard Space Flight Center and George Washington University, ComRAD consists of dual-polarized 1.4 GHz total-power radiometers (LH, LV) and a quad-polarized 1.25 GHz L band radar sharing a single parabolic dish antenna with a novel broadband stacked patch dual-polarized feed, a quad-polarized 4.75 GHz C band radar, and a single channel 10 GHz XHH radar. The instruments are deployed on a mobile truck with an 19-m hydraulic boom and share common control software; real-time calibrated signals, and the capability for automated data collection for unattended operation. Most microwave soil moisture retrieval algorithms developed for use at L band frequencies are based on the tau-omega model, a simplified zero-order radiative transfer approach where scattering is largely ignored and vegetation canopies are generally treated as a bulk attenuating layer. In this approach, vegetation effects are parameterized by tau and omega, the microwave vegetation opacity and single scattering albedo. One goal of our current research is to determine whether the tau-omega model can work for tree canopies given the increased scatter from trees compared to grasses and crops, and. if so, what are effective values for tau and omega for trees.

O'Neill, P.↗

Satellite Mapping of Rain-Induced Nitric Oxide Emissions from Soils

We use space-based observations of NO2 columns from the Global Ozone Monitoring Experiment (GOME) to map the spatial and seasonal variations of NOx emissions over Africa during 2000. The GOME observations show not only enhanced tropospheric NO2 columns from biomass burning during the dry season but also comparable enhancements from soil emissions during the rainy season over the Sahel. These soil emissions occur in strong pulses lasting 1-3 weeks following the onset of rain, and affect 3 million sq km of semiarid sub-Saharan savanna. Surface observations of NO2 from the International Global Atmospheric Chemistry (IGAC)/Deposition of Biochemically Important Trace Species (DEBITS)/Africa (IDAF) network over West Africa provide further evidence for a strong role for microbial soil sources. By combining inverse modeling of GOME NO2 columns with space-based observations of fires, we estimate that soils contribute 3.3+/-1.8 TgN/year, similar to the biomass burning source (3.8+/-2.1 TgN/year), and thus account for 40% of surface NO(x) emissions over Africa. Extrapolating to all the tropics, we estimate a 7.3 TgN/year biogenic soil source, which is a factor of 2 larger compared to model-based inventories but agrees with observation-based inventories. These large soil NO(x) emissions are likely to significantly contribute to the ozone enhancement originating from tropical Africa.

Jaegle, L.↗

An Evaluation of Soil Moisture Retrievals Using Aircraft and Satellite Passive Microwave Observations during SMEX02

The Soil Moisture Experiments conducted in Iowa in the summer of 2002 (SMEX02) had many remote sensing instruments that were used to study the spatial and temporal variability of soil moisture. The sensors used in this paper (a subset of the suite of sensors) are the AQUA satellite-based AMSR-E (Advanced Microwave Scanning Radiometer- Earth Observing System) and the aircraft-based PSR (Polarimetric Scanning Radiometer). The SMEX02 design focused on the collection of near simultaneous brightness temperature observations from each of these instruments and in situ soil moisture measurements at field- and domain- scale. This methodology provided a basis for a quantitative analysis of the soil moisture remote sensing potential of each instrument using in situ comparisons and retrieved soil moisture estimates through the application of a radiative transfer model. To this end, the two sensors are compared with respect to their estimation of soil moisture.

Bolten, John D.↗

The Soil Moisture Active and Passive (SMAP) Mission

The Soil Moisture Active and Passive (SMAP) Mission is one of the first Earth observation satellites being developed by NASA in response to the National Research Council s Decadal Survey. SMAP will make global measurements of the moisture present at Earth's land surface and will distinguish frozen from thawed land surfaces. Direct observations of soil moisture and freeze/thaw state from space will allow significantly improved estimates of water, energy and carbon transfers between land and atmosphere. Soil moisture measurements are also of great importance in assessing flooding and monitoring drought. SMAP observations can help mitigate these natural hazards, resulting in potentially great economic and social benefits. SMAP soil moisture and freeze/thaw timing observations will also reduce a major uncertainty in quantifying the global carbon balance by helping to resolve an apparent missing carbon sink on land over the boreal latitudes. The SMAP mission concept would utilize an L-band radar and radiometer. These instruments will share a rotating 6-meter mesh reflector antenna to provide high-resolution and high-accuracy global maps of soil moisture and freeze/thaw state every two to three days. The SMAP instruments provide direct measurements of surface conditions. In addition, the SMAP project will use these observations with advanced modeling and data assimilation to provide deeper root-zone soil moisture and estimates of land surface-atmosphere exchanges of water, energy and carbon. SMAP is scheduled for a 2014 launch date

Entekhabi, Dara↗

Space Weathering Effects in Lunar Soils: The Roles of Surface Exposure Time and Bulk Chemical Composition

Space weathering effects on lunar soil grains result from both radiation-damaged and deposited layers on grain surfaces. Typically, solar wind irradiation forms an amorphous layer on regolith silicate grains, and induces the formation of surficial metallic Fe in Fe-bearing minerals [1,2]. Impacts into the lunar regolith generate high temperature melts and vapor. The vapor component is largely deposited on the surfaces of lunar soil grains [3] as is a fraction of the melt [4, this work]. Both the vapor-deposits and the deposited melt typically contain nanophase Fe metal particles (npFe0) as abundant inclusions. The development of these rims and the abundance of the npFe0 in lunar regolith, and thus the optical properties, vary with the soil mineralogy and the length of time the soil grains have been exposed to space weathering effects [5]. In this study, we used the density of solar flare particle tracks in soil grains to estimate exposure times for individual grains and then perform nanometer-scale characterization of the rims using transmission electron microscopy (TEM). The work involved study of lunar soil samples with different mineralogy (mare vs. highland) and different exposure times (mature vs. immature).

Zhang, Shouliang↗

On Simulating the Impacts of Open Water Bodies on the SMAP Passive Soil Moisture Data Product

The Soil Moisture Active and Passive (SMAP) mission is a NASA earth science mission aiming at improving our understanding of the dynamics of the cycles of energy, water, and carbon at global scales. The mission features two complementary sensors on the same low-Earth orbiting platform: an L-band synthetic aperture radar (SAR) operating at 1.26 GHz and an L-band radiometer operating at 1.41 GHz. Together these instruments will provide global mapping of soil moisture and freeze/thaw states in 2-3 days, with a tentative launch date in 2014. The work reported in this study focuses primarily on the development of the SMAP radiometer-only soil moisture data product. For passive soil moisture retrieval at satellite footprint scales, one way to improve retrieval accuracy is to correct for the microwave emission from open water bodies prior to retrieval. The accuracy of this correction will depend on not only the locations of these water bodies, but also the geolocation accuracy of the instrument. As perfect knowledge is never attainable in practice, it is important to assess the impacts of these uncertainties on the SMAP radiometer observations and hence the passive soil moisture retrieval accuracy. In this presentation, we present the results of our preliminary assessment on the impacts of these uncertainties. Our study consists of two parts: (1) a sensitivity analysis on the SMAP radiometer observations due to uncertainties in water-body classification, and (2) realistic global simulations that take into account of additional uncertainties (e.g., geolocation and ancillary data) and SMAP-specific instrument characteristics (e.g., orbit sampling and antenna pattern). The results will provide valuable prelaunch guidance to the SMAP team in identifying different error sources and their relative impacts on the passive soil moisture data product.

Chan, Steven↗

NASA's Soil Moisture Active and Passive (SMAP) Mission

The Soil Moisture Active-Passive (SMAP) Mission is one of the first Earth observation satellites being formulated by NASA in response to the 2007 National Research Council s Decadal Survey. SMAP will make global measurements of soil moisture at the Earth's land surface and its freeze-thaw state. These measurements will allow significantly improved estimates of water, energy and carbon transfers between the land and atmosphere. Soil moisture measurements are also of great importance in assessing flooding and monitoring drought. Knowledge gained from SMAP observations can help mitigate these natural hazards, resulting in potentially great economic and social benefits. SMAP observations of soil moisture and freeze/thaw timing over the boreal latitudes will also reduce a major uncertainty in quantifying the global carbon balance and help to resolve an apparent missing carbon sink over land. The SMAP mission concept will utilize an L-band radar and radiometer sharing a rotating 6-meter mesh reflector antenna flying in a 680 km polar orbit with an 8-day exact ground track repeat aboard a 3-axis stabilized spacecraft to provide high-resolution and high-accuracy global maps of soil moisture and freeze/thaw state every two to three days. In addition, the SMAP project will use these surface observations with advanced modeling and data assimilation to provide estimates of deeper root-zone soil moisture and net ecosystem exchange of carbon. SMAP recently completed its Phase A Mission Concept Study Phase for NASA and transitioned into Phase B (Formulation and Detailed Design). A number of significant accomplishments occurred during this initial phase of mission development. The SMAP project held several open meetings to solicit community feedback on possible science algorithms, prepared preliminary draft Algorithm Theoretical Basis Documents (ATBDs) for each mission science product, and established a prototype algorithm testbed to enable testing and evaluation of the performance of candidate algorithms. SMAP conducted an Applications Workshop in September 2009 to coordinate with potential application users interested in the mission data. A draft Applications Plan describing the Project s planned outreach to potential applications users has been prepared and will be updated during Phase B. SMAP made a significant evaluation of the potential terrestrial radio frequency interference (RFI) source environment and established radiometer and radar flight hardware and ground processing mitigation approaches. SMAP finalized its science orbit and orbit injection approach to optimize launch mass and prepared launch and commissioning scenarios and timeline. A science data communications approach was developed to maximize available science data volume to improve science margins while maintaining moderately short data product latencies to support many potential applications using existing ground assets and with minimum impact to the flight system. SMAP developed rigid multi-body and flexible body dynamics and control models and system designs for the 6-meter rotating instrument reflector-boom assembly (RBA) and flight system to confirm pointing and control performance, and devised strategies to efficiently implement on-orbit balancing if needed. Industry partners were selected for the spin mechanism assembly (SMA) and RBA. Preliminary designs for the radar and radiometer were initiated, including constructing breadboards of key assemblies.

Kellogg, Kent↗

Radio Heating of Lunar Soil to Release Gases

A report proposes the development of a system to collect volatile elements and compounds from Lunar soil for use in supporting habitation and processing into rocket fuel. Prior exploratory missions revealed that H2, He, and N2 are present in Lunar soil and there are some indications that water ice may also be present. The proposed system would include a shroud that would be placed on the Lunar surface. Inside the shroud would be a radio antenna aimed downward. The antenna would be excited at a suitably high power and at a frequency chosen to optimize the depth of penetration of radio waves into the soil. The radio waves would heat the soil, thereby releasing volatiles bound to soil particles. The escaping volatiles would be retained by the shroud and collected by condensation in a radiatively cooled vessel connected to the shroud. It has been estimated that through radio-frequency heating at a power of 10 kW for one day, it should be possible to increase the temperature of a soil volume of about 1 cubic m by about 200 C -- an amount that should suffice for harvesting a significant quantity of volatile material.

Chui, Talso↗

Electrokinetic In Situ Treatment of Metal-Contaminated Soil

An electrokinetic technique has been developed as a means of in situ remediation of soils, sludges, and sediments that are contaminated with heavy metals. Examples of common metal contaminants that can be removed by this technique include cadmium, chromium, zinc, lead, mercury, and radionuclides. Some organic contaminants can also be removed by this technique. In the electrokinetic technique, a low-intensity direct current is applied between electrodes that have been implanted in the ground on each side of a contaminated soil mass. The electric current causes electro-osmosis and migration of ions, thereby moving aqueous-phase subsurface contaminants from one electrode to the other. The half reaction at the anode yields H+, thereby generating an acid front that travels from the anode toward the cathode. As this acid front passes through a given location, the local increase in acidity increases the solubility of cations that were previously adsorbed on soil particles. Ions are transported towards one electrode or the other which one depending on their respective electric charges. Upon arrival at the electrodes, the ionic contaminants can be allowed to become deposited on the electrodes or can be extracted to a recovery system. Surfactants and other reagents can be introduced at the electrodes to enhance rates of removal of contaminants. Placements of electrodes and concentrations and rates of pumping of reagents can be adjusted to maximize efficiency. The basic concept of electrokinetic treatment of soil is not new. What is new here are some of the details of application and the utilization of this technique as an alternative to other techniques (e.g., flushing or bioremediation) that are not suitable for treating soils of low hydraulic conductivity. Another novel aspect is the use of this technique as a less expensive alternative to excavation: The cost advantage over excavation is especially large in settings in which contaminated soil lies near and/or under industrial buildings and therefore excavation would be made even more expensive by the need to prevent damage to numerous underground pipes and cables.

Quinn, Jacqueline↗

Low Biotoxicity of Mars Analog Soils Suggests that the Surface of Mars May be Habitable for Terrestrial Microorganisms

Recent studies on the interactive effects of hypobaria, low temperatures, and CO2-enriched anoxic atmospheres on the growth of 37 species of mesophilic bacteria identified 14 potential biocidal agents that might affect microbial survival and growth on the martian surface. Biocidal or inhibitory factors include (not in priority): (1) solar UV irradiation, (2) low pressure, (3) extreme desiccating conditions, (4) extreme diurnal temperature fluctuations, (5) solar particle events, (6) galactic cosmic rays, (7) UV-glow discharge from blowing dust, (8) solar UV-induced volatile oxidants [e.g., O2(-), O(-), H2O2, O3], (9) globally distributed oxidizing soils, (10) extremely high salts levels [e.g., MgCl2, NaCl, FeSO4, and MgSO4] in surficial soils at some sites on Mars, (11) high concentrations of heavy metals in martian soils, (12) likely acidic conditions in martian fines, (13) high CO2 concentrations in the global atmosphere, and (14) perchlorate-rich soils. Despite these extreme conditions several studies have demonstrated that dormant spores or vegetative cells of terrestrial microorganisms can survive simulated martian conditions as long as they are protected from UV irradiation. What has not been explored in depth are the effects of potential biotoxic geochemical components of the martian regolith on the survival and growth of microorganisms. The primary objectives of the research included: (1) prepare and characterize Mars analog soils amended with potential biotoxic levels of sulfates, salts, acidifying minerals, etc.; and (2) use the simulants to conduct biotoxicity assays to determine if terrestrial microorganisms from spacecraft can survive direct exposure to the analog soils.

Schuerger, A. C.↗

A Proposed Extension to the Soil Moisture and Ocean Salinity Level 2 Algorithm for Mixed Forest and Moderate Vegetation Pixels

The Soil Moisture and Ocean Salinity (SMOS)mission, launched in November 2009, provides global maps of soil moisture and ocean salinity by measuring the L-band (1.4 GHz) emission of the Earth's surface with a spatial resolution of 40-50 km.Uncertainty in the retrieval of soilmoisture over large heterogeneous areas such as SMOS pixels is expected, due to the non-linearity of the relationship between soil moisture and the microwave emission. The current baseline soilmoisture retrieval algorithm adopted by SMOS and implemented in the SMOS Level 2 (SMOS L2) processor partially accounts for the sub-pixel heterogeneity of the land surface, by modelling the individual contributions of different pixel fractions to the overall pixel emission. This retrieval approach is tested in this study using airborne L-band data over an area the size of a SMOS pixel characterised by a mix Eucalypt forest and moderate vegetation types (grassland and crops),with the objective of assessing its ability to correct for the soil moisture retrieval error induced by the land surface heterogeneity. A preliminary analysis using a traditional uniform pixel retrieval approach shows that the sub-pixel heterogeneity of land cover type causes significant errors in soil moisture retrieval (7.7%v/v RMSE, 2%v/v bias) in pixels characterised by a significant amount of forest (40-60%). Although the retrieval approach adopted by SMOS partially reduces this error, it is affected by errors beyond the SMOS target accuracy, presenting in particular a strong dry bias when a fraction of the pixel is occupied by forest (4.1%v/v RMSE,-3.1%v/v bias). An extension to the SMOS approach is proposed that accounts for the heterogeneity of vegetation optical depth within the SMOS pixel. The proposed approach is shown to significantly reduce the error in retrieved soil moisture (2.8%v/v RMSE, -0.3%v/v bias) in pixels characterised by a critical amount of forest (40-60%), at the limited cost of only a crude estimate of the optical depth of the forested area (better than 35% uncertainty). This study makes use of an unprecedented data set of airborne L-band observations and ground supporting data from the National Airborne Field Experiment 2005 (NAFE'05), which allowed accurate characterisation of the land surface heterogeneity over an area equivalent in size to a SMOS pixel.

Panciera, Rocco↗

Advances in Assimilation of Satellite-Based Passive Microwave Observations for Soil-Moisture Estimation

Satellite-based microwave measurements have long shown potential to provide global information about soil moisture. The European Space Agency (ESA) Soil Moisture and Ocean Salinity (SMOS, [1]) mission as well as the future National Aeronautics and Space Administration (NASA) Soil Moisture Active and Passive (SMAP, [2]) mission measure passive microwave emission at L-band frequencies, at a relatively coarse (40 km) spatial resolution. In addition, SMAP will measure active microwave signals at a higher spatial resolution (3 km). These new L-band missions have a greater sensing depth (of -5cm) compared with past and present C- and X-band microwave sensors. ESA currently also disseminates retrievals of SMOS surface soil moisture that are derived from SMOS brightness temperature observations and ancillary data. In this research, we address two major challenges with the assimilation of recent/future satellite-based microwave measurements: (i) assimilation of soil moisture retrievals versus brightness temperatures for surface and root-zone soil moisture estimation and (ii) scale-mismatches between satellite observations, models and in situ validation data.

De Lannoy, Gabrielle J. M.↗

Using Apollo Sites and Soils to Compositionally Ground Truth Diviner Lunar Radiometer Observations

Apollo landing sites and returned soils afford us a unique opportunity to "ground truth" Diviner Lunar Radiometer compositional observations, which are the first global, high resolution , thermal infrared measurements of an airless body. The Moon is the most accessible member of the most abundant class of solar system objects, which includes Mercury, asteroids, and icy satellites. And the Apollo samples returned from the Moon are the only extraterrestrial samples with known spatial context. Here we compare Diviner observations of Apollo landing sites and compositional and spectral laboratory measurements of returned Apollo soils. Diviner, onboard NASA's Lunar Reconnaissance Orbiter, has three spectral channels near 8 micron that were designed to characterize the mid-infrared emissivity maximum known as the Christiansen feature (CF), a well-studied indicator of silicate mineralogy. It has been observed that thermal infrared spectra measured in simulated lunar environment (SLE) are significantly altered from spectra measured under terrestrial or martian conditions, with enhanced CF contrast and shifted CF position relative to other spectral features. Therefore only thermal emission experiments conducted in SLE are directly comparable to Diviner data. With known compositions, Apollo landing sites and soils are important calibration points for the Diviner dataset, which includes all six Apollo sites at approximately 200 m spatial resolution. Differences in measured CFs caused by composition and space weathering are apparent in Diviner data. Analyses of Diviner observations and SLE measurements for a range of Apollo soils show good agreement, while comparisons to thermal reflectance measurements under ambient conditions do not agree well, which underscores the need for SLE measurements and validates our measurement technique. Diviner observations of Apollo landing sites are also correlated with geochemical measurements of Apollo soils from the Lunar Sample Compendium. In particular, the correlations between CF and FeO and AI203 are very strong, owing to the dependence on the feldspar-mafic ratio. Our analyses suggest that Diviner data may offer an independent measure of soil iron content from the existing optical and gamma-ray spectrometer datasets.

Greenhagen, Benjamin T.↗

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