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Analysis of CO Transport from Australia Fires and Its Impact to Ozone, Water Vapor and Clouds Using CrIS Single-Field-of-View Sounder Products and Other Remote Sensing and MERRA-2 Reanalysis Data

Australia’s unprecedented fire disasters at the end of 2019 to early 2020 emitted huge amounts of carbon monoxide (CO) and fire aerosol particles, and the long-range transport of the smoke plumes poses great impact to climate change, such as altering the Antarctic ozone (O3) hole. Spaceborne observations from satellites have been proven successful in monitoring CO from wildfires in the past decade and can be used to examine the associated CO transport. The primary remote sensing data used in this study is the Single Field of View (SFOV) Sounder Atmospheric Product (SiFSAP) derived from the Cross-track Infrared Sounder (CrIS) on SNPP, a new product that will be generated at NASA and released to the public in a few months. SiFSAP has a high spatial resolution of ~14 km and includes atmospheric profiles of temperature, water vapor, CO, O3, as well as cloud products, and as the SiFSAP algorithm performs both day- and night-time retrievals, it provides an additional observation for night-time in comparison to the day-time-only solar polar satellite instruments such as MOPPIT, OMPS, and TROPOMI. Most recent significant improvements in the quality of this product plus its good spatial resolution (better than most global weather and climate models) enable us to conduct process-oriented analysis of CO transport, and the variation of water vapor, O3 and clouds (optical depth, effective radius and cloud height) within and around the fire plumes. The wind fields from MERRA-2 reanalysis will be used to help characterize the transport. Other remote sensing data, such as CO from AIRS, MOPPIT and TROPOMI, O3 from OMPS and TROPOMI, as well as the UV aerosol index from OMI and OMPS, will be used and compared with SiFSAP sounder products. Cross-validation of CO and O3 from these different sensors with the corresponding MERRA-2 products will also be carried out. Along the plume transport path, some enhancement of O3 and correlation between fire aerosol, cloud optical depth and water vapor have been found but need further investigation. Using the transport of fire plumes over the Southern Pacific Ocean as a unique testbed, this study will demonstrate the trace species monitoring capability of current satellite observations, in particular, for CO and O3, and hopefully, it will provide some insight on the impacts on fire emissions on air quality and climate.

Xiaozhen (Shawn) Xiong↗

Evaluating SAR Radiometric Terrain Correction Solutions: Optimal products for applied users

Operational applications of Synthetic Aperture Radar (SAR) are under development around the world, driven by the regularly-acquired, free-and-open source C-band SAR observations provided by ESA’s Sentinel-1 sensor constellation since 2014. Groups like SERVIR, a joint NASA and USAID initiative, are at the forefront of remote sensing applications for societal benefit. A takeaway from SERVIR’s experience is the need for appropriately geocoded and fully calibrated SAR data that is ready to use for a range of ecosystems-related applications. Radiometric Terrain Corrected (RTC) data are key entry-level products for multiple applications that range from ecosystems to hazards. This work fills a gap in current research by evaluating several RTCs produced by open-source software solutions (SNAP-7 and ISCE-2), the gold standard commercial software (GAMMA), a Google Earth Engine (GEE) based workflow, and the uncorrected GRD products currently available in GEE. RTCs were analyzed for geolocation quality, absolute radiometric calibration, and fidelity of the radiometric terrain flattening over ten sites representing varied terrains. In addition, a time series analysis was conducted over two locations. Overall, no significant differences for radiometric calibration were found across RTC products. However, all RTCs performed better than uncorrected GRD products. The main differences between products were found in geolocation quality. These results not only demonstrate the need for the uptake and distribution of RTC products for ecosystems applications, but demonstrate the ability to do so with open source methods, adding value to developing affordable operational applications.

Helen Blue Parache↗

Continuity of A Global, Satellite-Based Terrestrial Primary Productivity Dataset in the VIIRS Era Achieved With Model-Data Fusion

The NASA Terra and Aqua satellites have been successfully operating for over two decades and have far exceeded their original 5‐year design life. However, the era of NASA’s Earth Observing System (EOS) may be coming to a close as early as 2023. We conducted a comprehensive calibration and validation of the MODIS MOD17 product [1,2] and the potential for continuity of multi‐decadal ecosystem gross primary productivity (GPP) and annual net primary productivity (NPP), using data from the Visible Infrared Imaging Radiometer Suite (VIIRS) sensors aboard Suomi NPP and NOAA‐20. We combined an 18‐year record of eddy covariance flux tower measurements with hundreds of field measurements of NPP from the Oak Ridge National Laboratories Multi‐Biome collection to benchmark MODIS MOD17 Collection 6.1 (C61) and to develop the first terrestrial productivity estimates from VIIRS. Plant traits from the literature and the global TRY database [3,4] provide strong priors for identifying model parameters in a Bayesian model‐data fusion. As MODIS‐like observations are still needed for global environmental applications, the new VIIRS VNP17 product has the potential to extend these continuous estimates of global, terrestrial primary productivity beyond 2030.

K. Arthur Endsley↗

Temporal and Spatial Dynamics of Nitric Oxide Production at High Latitudes During an ICME-driven Storm on Dec. 14, 2006

During geomagnetic storms driven by interplanetary coronal mass ejections (ICMEs), Earth’s upper atmosphere neutral mass density is directly driven by the geomagnetic storm cycle from intense driving and subsequent recovery. The neutral density heating and cooling times are shorter for stronger storms and longer for weaker storms. The influx of energy (Joule Heating and precipitation) into Earth’s upper atmosphere during the storm main phase allows for the enhanced production of nitric oxide (NO) at high latitudes, which in turn cools the thermosphere by radiating away excess energy. As a result, greater NO production results in quicker thermospheric cooling. Yet while the production of NO on a global scale has been examined in detail, the space and time evolution of NO is not well-known. In this study, we investigate the effects of a particular ICME-driven storm, which occurred on Dec. 14th, 2006, on the production of NO at high latitudes. We compare NO measurements from the Thermosphere, Ionosphere, Mesosphere Dynamics (TIMED) spacecraft to neutral mass density measurements from the Challenging Minisatellite Payload (CHAMP) spacecraft and find that the impact of the shock prior to the storm, not just the onset of the storm itself, is responsible for an increase in NO production. We also observe a dawn-dusk asymmetry in high-latitude NO production and discuss how the geometry of the solar wind driver may play a role in creating this asymmetry. Finally, we discuss how the improved hemispheric and local time coverage provided by the GDC and DYNAMIC missions will enable more robust studies of the spatiotemporal evolution of NO during storms. Since NO is an important factor in regulating the neutral density of the thermosphere, such studies will be relevant for more accurate orbital drag calculations.

Kevin Delano↗

Calipso Data Product Status

In this poster we review the recent data releases by the CALIPSO project since the last CALIPSO/CloudSat science team meeting and near-term data products scheduled to be publicly available in the coming months. The recent releases include a full suite of new V4.51 Lidar Level 2 data products (June 2023) and corresponding browse images, as well as V4.51 IIR Level 2 (October 2023) data products. Two new Lidar Level 0 data products and both an updated (V2-Antartica) and new (V1-Greenland) version of the Lidar Level 2 Blowing Snow products are scheduled in the fall. A new Lidar Level 2 Ocean product, which provides global observations of subsurface properties, is scheduled for release in the winter. In addition, with the end of the CALIPSO science operations that occurred on August 1, 2023, we will present the last planned efforts for the next two years and summarize the final planned data releases.

Brian Getzewich↗

Development of High-Resolution Soil Hydraulic Parameters with Use of Earth Observations for Enhancing Root Zone Soil Moisture Product

Regional quantification of energy and water balance fluxes depends inevitably on the estimation of surface and rootzone soil moisture. The simulation of soil moisture depends on the soil retention characteristics, which are difficult to estimate at a regional scale. Thus, the present study proposes a new method to estimate high-resolution Soil Hydraulic Parameters (SHPs) which in turn help to provide high-resolution (spatial and temporal) rootzone soil moisture (RZSM) products. The study is divided into three phases—(I) involves the estimation of finer surface soil moisture (1 km) from the coarse resolution satellite soil moisture. The algorithm utilizes MODIS 1 km Land Surface Temperature (LST) and 1 km Normalized difference vegetation Index (NDVI) for downscaling 25 km C-band derived soil moisture from AMSR-2 to 1 km surface soil moisture product. At one of the test sites, soil moisture is continuously monitored at 5, 20, and 50 cm depth, while at 44 test sites data were collected randomly for validation. The temporal and spatial correlation for the downscaled product was 70% and 83%, respectively. (II) In the second phase, downscaled soil moisture product is utilized to inversely estimate the SHPs for the van Genuchten model (1980) at 1 km resolution. The numerical experiments were conducted to understand the impact of homogeneous SHPs as compared to the three-layered parameterization of the soil profile. It was seen that the SHPs estimated using the downscaled soil moisture (I-d experiment) performed with similar efficiency as compared to SHPs estimated from the in-situ soil moisture data (I-b experiment) in simulating the soil moisture. The normalized root mean square error (nRMSE) for the two treatments was 0.37 and 0.34, respectively. It was also noted that nRMSE for the treatment with the utilization of default SHPs (I-a) and AMSR-2 soil moisture (I-c) were found to be 0.50 and 0.43, respectively. (III) Finally, the derived SHPs were used to simulate both surface soil moisture and RZSM. The final product, RZSM which is the daily 1 km product also showed a nearly 80% correlation at the test site. The estimated SHPs are seen to improve the mean NSE from 0.10 (I-a experiment) to 0.50 (I-d experiment) for the surface soil moisture simulation. The mean nRMSE for the same was found to improve from 0.50 to 0.31.

soil moisture downscaling↗

FLASHFlux Working Group Status: Assessing FF NOAA-20 Products and Future Upgrades

The CERES Fast Longwave and SHortwave radiative Flux working provides low latency data products from the CERES measurements within about 5-6 days of real time. This presentation reviews progress made toward evaluating the current data products and shows some examples of users daily averaged data products. Since the last CERES Science Team meeting the FLASHFlux group has updated it's production to use the GEOS-IT reanalysis from the GMAO. In this presentation the comparisons to surface surface measurements are made through December 2023 constrasting old and new versions for the SSF and TISA products. Also, we provide an update on activities to replace the footprint fluxes and also update our current gridded global products with GEO observations. Lastly, present update plans for the next 6-9 months.

radiation budget↗

Evaluating MODIS Snow Products Using an Extensive Wildlife Camera Network

Snow covers a maximum of 47 million km 2 of Earth's northern hemisphere each winter and is an important component of the planet's energy balance, hydrology cycles, and ecosystems. Monitoring regional and global snow cover has increased in urgency in recent years due to warming temperatures and declines in snow cover extent. Optical satellite instruments provide large-scale observations of snow cover, but cloud cover and dense forest canopy can reduce accuracy in mapping snow cover. Remote camera networks deployed for wildlife monitoring operate below cloud cover and in forests, representing a virtually untapped source of snow cover observations to supplement satellite observations. Using images from 1,181 wildlife cameras deployed by the Norwegian Institute for Nature Research (NINA), we compared snow cover extracted from camera images to Moderate Resolution Imaging Spectroradiometer (MODIS) snow cover products during winter months of 2018–2020. Ordinal snow classifications (scale = 0–4) from cameras were closely related to normalized difference snow index (NDSI) values from the MODIS Terra Snow Cover Daily L3 Global 500m (MOD10A1) Collection 6 product (R 2 = 0.70). Tree canopy cover, the normalized difference vegetation index (NDVI), and image color mode influenced agreement between camera images and MOD10A1 NDSI values. For MOD10A1F, MOD10A1's corresponding cloud-gap filled product, agreement with cloud-gap filled values decreased from 78.5% to 56.4% in the first three days of cloudy periods and stabilized thereafter. Using our camera data as validation, we derived a threshold to create daily binary maps of snow cover from the MOD10A1 product. The threshold corresponding to snow presence was an NDSI value of 40.50, which closely matched a previously defined global binary threshold of 40 using the MOD10A2 8-day product. These analyses demonstrate the utility of camera trap networks for validation of snow cover products from satellite remote sensing, as well as their potential to identify sources of inaccuracy.

Validation↗

Fuel preparation for use in the production of medical isotopes

The present invention relates generally to the field of medical isotope production by fission of uranium-235 and the fuel utilized therein (e.g., the production of suitable Low Enriched Uranium (LEU is uranium having 20 weight percent or less uranium-235) fuel for medical isotope production) and, in particular to a method for producing LEU fuel and a LEU fuel product that is suitable for use in the production of medical isotopes. In one embodiment, the LEU fuel of the present invention is designed to be utilized in an Aqueous Homogeneous Reactor (AHR) for the production of various medical isotopes including, but not limited to, molybdenum-99, cesium-137, iodine-131, strontium-89, xenon-133 and yttrium-90.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

An Assessment of Some Design Constraints on Heat Production of a 3D Conceptual EGS Model Using an Open-Source Geothermal Reservoir Simulation Code

Performance of heat production process over a 30-year period is assessed in a conceptual EGS model with a geothermal gradient of 65K per km depth in the reservoir. Water is circulated through a pair of parallel wells connected by a set of single large wing fractures. The results indicate that the desirable output electric power rate and lifespan could be obtained under suitable material properties and system parameters. A sensitivity analysis on some design constraints and operation parameters indicates that 1) the fracture horizontal spacing has profound effect on the long-term performance of heat production, 2) the downward deviation angle for the parallel doublet wells may help overcome the difficulty of vertical drilling to reach a favorable production temperature, and 3) the thermal energy production rate and lifespan has close dependence on water mass flow rate. The results also indicate that the heat production can be improved when the horizontal fracture spacing, well deviation angle, and production flow rate are under reasonable conditions. To conduct the reservoir modeling and simulations, an open-source, finite element based, fully implicit, fully coupled hydrothermal code, namely FALCON, has been developed and used in this work. Compared with most other existing codes that are either closed-source or commercially available in this area, this new open-source code has demonstrated a code development strategy that aims to provide an unparalleled easiness for user-customization and multi-physics coupling. Test results have shown that the FALCON code is able to complete the long-term tests efficiently and accurately, thanks to the state-of-the-art nonlinear and linear solver algorithms implemented in the code.

enhanced geothermal system↗

Metal ferrite oxygen carriers/catalyst for partial oxidation of methane for production of synthesis gas

Materials, methods to prepare, and methods of use for partial oxidation of methane. Embodiments include delivering a metal ferrite oxygen carrier to a fuel reactor, wherein the metal ferrite oxygen carrier comprises MFexOy where 1.ltoreq.x.ltoreq.3 and 3.ltoreq.y.ltoreq.5, and where M comprise a Group II alkali earth metals; and delivering a gaseous stream that contains methane to the metal ferrite oxygen carrier in the fuel reactor and maintaining the fuel reactor at a reducing temperature sufficient to reduce some portion of the metal ferrite oxygen carrier and oxidize some portion of the methane containing gas stream. Embodiments further include generating gaseous products containing H.sub.2 and CO gas in the fuel reactor; withdrawing a product stream from the fuel reactor, where the gaseous products comprise the product stream, and where at least >50 vol. % of the product stream includes CO and H.sub.2; oxidizing the reduced carrier in an oxidizing reactor by contacting the reduced carrier and an oxidizing gas at an oxidizing temperature, where the oxidizing gas is comprised of oxygen, and where the oxidizing temperature is sufficient to generate an oxidizing reaction, where the reactants of the oxidizing reaction comprise some portion of the oxygen, some portion of the M component, and some portion of the FecOd component, and further wherein the product of the oxidizing reaction is a re-oxidized carrier that comprises some portion of the MFexOy; and delivering heat generated in the oxidizing reactor to the fuel reactor for the reaction of metal ferrite with methane.

36 MATERIALS SCIENCE↗

Producing a titanium product

A method (400) for producing a titanium product is disclosed. The method (400) can include obtaining TiO.sub.2-slag (401), and producing a titanium product from the TiO.sub.2-slag using a metallic reducing agent (402) at a moderate temperature and a pressure to directly produce a titanium product chemically separated from metal impurities in the TiO.sub.2 slag (403). The titanium product can comprise TiH.sub.2 and optionally elemental titanium. Impurities in the titanium product can then removed (404) by leaching, purifying and separation to form a purified titanium product.

Fang, Zhigang Zak↗

A study of fission product migration paths in irradiated TRISO particle SiC

Tristructural isotropic (TRISO) coated fuel particles used in high-temperature gas-cooled nuclear reactors (HTGRs) provide key advantages in terms of passive safety and reactor energy efficiencies. TRISO fuel consists of a number of special coating layers surrounding the fissile material in the kernel as shown in Fig. 1. The coating layers consist of a carbon buffer layer, inner pyrolytic carbon (PyC) layer, a silicon carbide (SiC) layer as well as an outer pyrolytic carbon layer. Together the layers act as a pressure vessel and barrier to the release of radioactive fission products into the reactor environment. The cubic 3C-SiC layer of thickness approximately 35 µm, acts as the primary barrier to the migration of metallic fission products out of the particle. The finding, more than three decades years ago, that silver can be released by intact TRISO particles has led to significant research to determine possible transport mechanisms of certain fission products in SiC. Out-of-reactor experiments did not reveal any significant lattice diffusion of silver in SiC1. Many earlier findings alternatively proposed a dominating role of fast diffusion paths such as grain boundaries and dislocations in enhancing fission product migration in SiC. Recently the role of the fission product palladium in enhancing the transport rate of silver in SiC2 was confirmed by transmission electron microscopy (TEM) of neutron-irradiated SiC from a TRISO coated particle from Compact 4-1-1, which was irradiated to an average burnup of 19.38% fissions per initial metal atom (FIMA); a time-averaged, volume-averaged temperature of 1072 °C; a time-averaged peak temperature of 1182 °C; and an average fast fluence of 4.13 x 1021 n/cm2 as part of the US Department of Energy's Advanced Gas Reactor (AGR)-1 experiment3. Although other studies found that Ag was found separately (without Pd) in TRISO coated particles irradiated at 11.4 %, 16.7 and 18.6% FIMA, Pd could have been present at lower than measureable concentrations4. In this study, SiC focussed ion beam (FIB) sections obtained from Compact 4-1-1 from the AGR-1 experiment were analysed in a double Cs-corrected JEOL ARM 200F using atomically resolved scanning transmission electron microscopy (STEM). By using atom resolved STEM in combination with electron energy loss spectroscopy (EELS) and large angle energy dispersive spectroscopy (EDS) a much better understanding of the migration routes and mechanisms of fission products in irradiated polycrystalline 3C-SiC was achieved.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Enhancing Operational Performance and Productivity Benefits by Implementing Smart Manufacturing Technologies in Breweries

This paper uses case studies to demonstrate the potential of smart manufacturing (SM) and Internet of Things (IoT) technologies to enhance operational performance and productivity in the industry. The analysis highlights benefits like cost reduction, production flexibility, shorter product times-to-market, energy/water efficiency and environmental impact reduction, and increased productivity. To illustrate the effectiveness of SM and IoT approaches, the authors sought out manufacturers currently implementing or seeking to implement SM & IoT technologies. The authors identified beer brewing (NAICS Code —312120) as a rapidly expanding industry whose members appear eager to implement SM technologies to optimize production lines by revealing bottlenecks and identifying performance-reducing nodes. The paper presents two case studies based on SM and IoT technologies in breweries. It briefly describes a systematic framework introduced elsewhere by the authors and uses it to assess the energy productivity and competitiveness of SM applications in breweries. The paper addresses questions concerning the information and communications technology infrastructure needed to build smart breweries, and how corporations simplify the installation and deployment of SM and IoT components.

Nimbalkar, Sachin U.↗

Comparison of Fission Product Release Predictions using PARFUME with Results from the AGR-2 Irradiation Experiment

The PARFUME (PARticle FUel ModEl) code was used to predict fission product release from tristructural isotropic (TRISO) coated fuel particles and compacts during the second irradiation experiment (AGR-2) of the Advanced Gas Reactor Fuel Development and Qualification Program. The PARFUME model for the Advanced Gas reactor (AGR)GR-2 experiment used the fuel compact volume average temperature for each of the 560 days of irradiation to calculate the release of fission products of silver, cesium, and strontium from a representative particle for a select number of AGR -2 compacts. In addition, safety tests were performed on 15 compacts ranging from 1500 to 1800°C to determine fission product release at temperatures that bound reactor accident conditions. PARFUME was used to calculate the fission product release of silver, cesium, strontium, and krypton during these safety tests. Post-irradiation examination (PIE) measurements provided the data on release of fission products from the fuel compacts and fuel particles, and retention of fission products in the compacts outside the silicon carbide (SiC) layer. The predicted fraction release from PARFUME was then compared to PIE measurements.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Micro- and Nano-techniques for the Study of Fission Product Precipitation in SiC Layer

The complexity of fission product distribution and composition within the SiC layer of tristructural isotropic (TRISO) coated particles, irradiation effects on the SiC structure as well as the variable nature of metallic fission product release, has led to the exploration of multiple micro- and nano-characterization techniques. The fine scale of the fission product precipitates necessitates unique learnings and application of electron microscopic techniques with irradiated fuel during the Advanced Gas Reactor (AGR)-1 experiment analysis. A summarized discussion on the specific advanced techniques with associated method development for TRISO coated particles is provided followed by the down selected techniques currently considered to provide the highest impact. Techniques considered are electron probe micro-analyzer (EPMA), scanning transmission electron microscopy (STEM), and Precession electron diffraction (PED). SiC grain boundary characteristics are evaluated due to the mobility of specific fission products through grain boundaries. PED was performed for understanding the role of grain boundary character on fission product transport. One set of comparative analyses between AGR-1 and AGR-2 particles leads to a finding that the AGR-1, high-Ag-retention particle, had statistically more coincidence site lattice (CSL)-related grain boundaries (but fewer low-angle grain boundaries), compared to the AGR-2 particle. This implies that CSL-related grain boundaries may have a direct influence on Ag retention. However, precipitates were found on a relatively small fraction of CSL-related grain boundaries in both particles. In another set of comparison between AGR-1 and AGR-2 particles that were subjected to safety testing, there is significant differences in average SiC grain boundary distributions, but the fission product distributions on these grain boundaries are very similar.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Top-quark production measurements

Recent measurements of top-quark production at hadron colliders are reviewed. The inclusive top-quark pair production is determined at four centre-of-mass energies at Tevatron and LHC with experimental uncertainties that are close to the uncertainties in theoretical calculations at next-to-next-to-leading order in QCD. Several differential measurements are performed and compared to simulation. Production of single top quarks is studied in the three different production channels. Top-quark pair production with neutral and charged vector bosons has been observed by the LHC experiments. Finally, production of additional heavy flavour quark pairs ($b\bar{b}$, $t\bar{t}$) is studied or searched for.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Hierarchical printed product and composition and method for making the same

Disclosed herein are embodiments of a printable composition that can be used to make printed products of a chosen material chemistry that have different levels of porosity within the printed product's structure Also disclosed herein are embodiments of a printed product that has multiple levels of porosity throughout its structure, which can include a macroscale level of porosity, a microscale level of porosity, a nanoscale level of porosity and any combination thereof. These printed products can be made using a 3-D printer and can be made from a single printable composition without the need to add different structural components during the production process. Also disclosed herein are embodiments of a method for making and using a printed product.

Lee, Matthew N.↗

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