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At least 1,801 records · Page 100

Synergistic effects of nuclear and electronic energy loss in KTaO 3 under ion irradiation

In this paper, we use the inelastic thermal spike model for insulators and molecular dynamic simulations to investigate the effects of pre-existing damage on the energy dissipation and structural alterations in KTaO 3 under irradiation with 21 MeV Ni ions. Our results reveal a synergy between the pre-existing defects and the electronic energy loss, indicating that the defects play an important role on the energy deposition in the system. Our findings highlight the need for better understanding on the role of defects in electronic energy dissipation and the coupling of the electronic and atomic subsystems.

36 MATERIALS SCIENCE↗

Bandgap profiling in CIGS solar cells via valence electron energy-loss spectroscopy

A robust, reproducible method for the extraction of relative bandgap trends from scanning transmission electron microscopy (STEM) based electron energy-loss spectroscopy (EELS) is described. The effectiveness of the approach is demonstrated by profiling the bandgap through a CuIn 1-x Ga x Se 2 solar cell that possesses intentional Ga/(In + Ga) composition variation. The EELS-determined bandgap profile is compared to the nominal profile calculated from compositional data collected via STEM-based energy dispersive X-ray spectroscopy. The EELS based profile is found to closely track the calculated bandgap trends, with only a small, fixed offset difference. This approach, which is particularly advantageous for relatively narrow bandgap materials and/or STEM systems with modest resolution capabilities (i.e., >100 meV), compromises absolute accuracy to provide a straightforward route for the correlation of local electronic structure trends with nanoscale chemical and physical structure/microstructure within semiconductor materials and devices.

14 SOLAR ENERGY↗

Multiparticle losses in a linear quadrupole Paul trap

A linear quadrupole Paul trap is fabricated for capturing magnesium and aluminium ions. An experimental cycle performed has demonstrated ion capture and holding in a trap with an average ion lifetime of 1.7 s. Modelling of ion dynamics in the trap shows that the main mechanism responsible for losses of hot ions is multiparticle interaction, which results in that a kinetic energy of some ions increases and they leave the trapping zone. This mechanism is completely suppressed if ions are cooled. Another mechanism is the charge exchange; however, it is not substantial at a high average energy of ions produced in the result of an electron impact. Parameters of the trap allow one to perform precision spectroscopic measurements and to control ion quantum states. (laser cooling)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Loss-of-Coolant Accident Analysis of a High-Burnup Pressurized Water Reactor Core Design Using Gadolinia-Doped UO 2

High-burnup and extended enrichment fuels are of interest for extending the cycle lengths of pressurized water reactors from 18 to 24 months. Changes to the fuel design and core loading scheme have potentially significant safety implications due to power distribution effects, reduced thermal conductivity, and/or increased plenum pressures due to additional burnable poison loadings. Additionally, higher burnups result in increased material degradation and risk of fuel fragmentation, relocation, and dispersal (FFRD). A representative 24-month core design using gadolinia-doped UO 2 was analyzed for performance under large-break (LB) loss-of-coolant accident (LOCA) conditions using PARCS, RELAP5-3D, and BISON. Furthermore, all considered acceptance criteria were met, with no cases exceeding the 1477 K maximum cladding temperature or the post-quench ductility oxidation limit of 17% equivalent cladding reacted. Full-core FFRD susceptibility was estimated to be approximately 455 kg, though high uncertainties exist with current approaches for computing susceptibility. Undoped fuel rods are more likely to be limiting due to higher linear heat rates. Relatively high burnup and linear heat rate rods located in second batch assemblies are of greatest safety significance during LB LOCA for this high-burnup core design.

High burnup↗

Two-stage synergy of electronic energy loss with defects in LiTaO 3 under ion irradiation

Understanding energy dissipation in electronic and atomic subsystems and subsequent defect evolution is a scientific challenge. Separate and combined effects of electronic and nuclear energy deposition in z-cut LiTaO 3 have been investigated. Irradiation of pristine LiTaO 3 samples with 2 MeV Ta ions leads to amorphization due to atomic displacement damage, described by a disorder accumulation model. Here, while 21 MeV Si ions do not produce significant damage in pristine LiTaO 3 , introduction of pre-existing defects sensitizes LiTaO 3 to the formation of ion tracks from the electronic energy loss by 21 MeV Si ions that induce a synergistic two-stage phase transition process.

36 MATERIALS SCIENCE↗

Intermittent dust mass loss from activated asteroid P/2013 P5 (PANSTARRS)

We present observations and models of the dust environment of activated asteroid P/2013 P5 (PANSTARRS). The object displayed a complex morphology during the observations, with the presence of multiple tails. We combined our own observations, all made with instrumentation attached to the 10.4 m Gran Telescopio Canarias on La Palma, with previously published Hubble Space Telescope images to build a model aimed at fitting all the observations. Altogether, the data cover a full three month period of observations which can be explained by intermittent dust loss. The most plausible scenario is that of an asteroid rotating with the spinning axis oriented perpendicular to the orbit plane and losing mass from the equatorial region, consistent with rotational break-up. Assuming that the ejection velocity of the particles (v ∼ 0.02-0.05 m s{sup –1}) corresponds to the escape velocity, the object diameter is constrained to ∼30-130 m for bulk densities 3000-1000 kg m{sup –3}.

79 ASTRONOMY AND ASTROPHYSICS↗

Disk-loss and disk-renewal phases in classical Be stars. II. Contrasting with stable and variable disks

Recent observational and theoretical studies of classical Be stars have established the utility of polarization color diagrams (PCDs) in helping to constrain the time-dependent mass decretion rates of these systems. We expand on our pilot observational study of this phenomenon, and report the detailed analysis of a long-term (1989-2004) spectropolarimetric survey of nine additional classical Be stars, including systems exhibiting evidence of partial disk-loss/disk-growth episodes as well as systems exhibiting long-term stable disks. After carefully characterizing and removing the interstellar polarization along the line of sight to each of these targets, we analyze their intrinsic polarization behavior. We find that many steady-state Be disks pause at the top of the PCD, as predicted by theory. We also observe sharp declines in the Balmer jump polarization for later spectral type, near edge-on steady-state disks, again as recently predicted by theory, likely caused when the base density of the disk is very high, and the outer region of the edge-on disk starts to self absorb a significant number of Balmer jump photons. The intrinsic V-band polarization and polarization position angle of γ Cas exhibits variations that seem to phase with the orbital period of a known one-armed density structure in this disk, similar to the theoretical predictions of Halonen and Jones. We also observe stochastic jumps in the intrinsic polarization across the Balmer jump of several known Be+sdO systems, and speculate that the thermal inflation of part of the outer region of these disks could be responsible for producing this observational phenomenon. Finally, we estimate the base densities of this sample of stars to be between ≈8 × 10{sup –11} and ≈4 × 10{sup –12} g cm{sup –3} during quasi steady state periods given there maximum observed polarization.

79 ASTRONOMY AND ASTROPHYSICS↗

OH density, flux and loss probability measurements in a room temperature atmospheric pressure surface discharge by microscopic laser induced fluorescence

Many applications involving atmospheric pressure plasma-substrate interactions are enabled by the large fluxes of short-lived reactive species such as OH radicals to the substrate, nonetheless, the accurate measurement of radical densities and fluxes at substrates at atmospheric pressure has received little attention to date, particularly for surface ionization waves. We report the measurement of the OH density distribution in a surface discharge on a fused silica (quartz) substrate generated by an impinging atmospheric pressure plasma jet in dry and humid helium. The OH density is measured by microscopic laser induced fluorescence with a spatial resolution of 10 µm in the direction perpendicular to the quartz substrate. The measured OH diffusive flux varied for the investigated experimental conditions by almost three orders of magnitude and had a maximum value of 1.7 × 10 15 cm -2 s -1 . The corresponding surface loss probability of OH on the quartz surface was determined to be ~0.01. The high spatial resolution was required to accurately resolve the near surface gradient of OH radicals.

plasma-surface interactions↗

Ac losses in field-cooled type I superconducting cavities

As superconductors are cooled below their critical temperature, stray magnetic flux can become trapped in regions that remain normal. The presence of trapped flux facilitates dissipation of ac current in a superconductor, leading to losses in superconducting elements of microwave devices. In type II superconductors, dissipation is well-understood in terms of the dynamics of vortices hosting a single flux quantum. In contrast, the ac response of type I superconductors with trapped flux has not received much attention. Building on Andreev's early work (Andreev 1967 Sov. Phys. JETP 24 1019), here we show theoretically that the dominant dissipation mechanism is the absorption of the ac field at the exposed surfaces of the normal regions, while the deformation of the superconducting/normal interfaces is unimportant. We use the developed theory to estimate the degradation of the quality factors in field-cooled cavities, and we satisfactorily compare these theoretical estimates to the measured field dependence of the quality factors of two aluminum cavities. We also identify a regime in which the dissipated power depends weakly on the Ginzburg-Landau parameter; this makes it possible to apply our findings to cavities made of other materials, such as niobium.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Quantifying nitrogen loss hotspots and mitigation potential for individual fields in the US Corn Belt with a metamodeling approach

The high productivity in the US Corn Belt is largely enabled by the consumption of millions of tons of manufactured fertilizer. Excessive application of nitrogen (N) fertilizer has been pervasive in this region, and the unrecovered N eventually escaped from croplands in forms of nitrous oxide (N 2 O) emission and N leaching. Mitigating these negative impacts is hindered by a lack of practical information on where to focus and how much mitigation potential to expect. At a large scale, process-based crop models are the primary tools for predicting variables required by decision making, but their applications are prohibited by expensive computational and data storage costs. To overcome these challenges, we built a series of metamodels to learn the key mechanisms regarding the carbon (C) and N cycle from a well-validated process-based biogeochemical model, ecosys. The trained metamodel captures over 98% of the variability of the ecosys simulated outputs for 99 randomly selected counties in Iowa, Illinois, and Indiana. To identify hotspots with high mitigation potential, we introduce net societal benefit (NSB) as an indicator for synthesizing the loss in yield and social benefits through emissions and pollutants avoided. Our results show that reducing N fertilizer by 10% leads to 9.8% less N 2 O emissions and 9.6% less N leaching at the cost of 4.9% more SOC depletion and 0.6% yield reduction over the study region. The estimated total annual NSB is $\$395$ M (uncertainty ranges from $\$114$ M to $\$1271$ M), including $\$334$ from social benefits (uncertainty ranges from $\$46$ M to $\$1076$ M), $\$100$ M from saving fertilizer (uncertainty ranges from $\$13$ M to $\$455$ M), and –$\$40$ M due to yield changes (uncertainty ranges from –$\$261$ M to $\$69$ M). For the median scenario, we noted that 20% of the study area accounts for nearly 50% of the NSB, and thus represent hotspot locations for targeted mitigation. Although the uncertainty range suggests that developing such a high-resolution framework is not yet settled and the scenario based estimations are not appropriate to inform the management practices for individual farmers, our efforts shed light on the new generation of analytical tools for life cycle assessment.

54 ENVIRONMENTAL SCIENCES↗

DYNAMICS AND ENERGY LOSS IN SUPERBUBBLES

Interstellar bubbles appear to be smaller in observations than expected from calculations. Instabilities at the shell boundaries create three-dimensional (3D) effects and are probably responsible for part of this discrepancy. We investigate instabilities and dynamics in superbubbles using 3D hydrodynamics simulations with time-resolved energy input from massive stars, including supernova explosions. We find that the superbubble shells are accelerated by supernova explosions, coincident with substantial brightening in soft X-ray emission. In between the explosions, the superbubbles lose energy efficiently, approaching the momentum-conserving snowplow limit. This and enhanced radiative losses due to instabilities reduce the expansion compared to the corresponding radiative bubbles in pressure-driven snowplow models with constant energy input. We note generally good agreement with observations of superbubbles and some open issues. In particular, there are hints that the shell velocities in the X-ray-bright phases are underpredicted.

79 ASTRONOMY AND ASTROPHYSICS↗

Cryogenic growth of aluminum: Structural morphology, optical properties, superconductivity, and microwave dielectric loss

We explore the molecular beam epitaxy synthesis of superconducting aluminum thin films grown on c-plane sapphire substrates at cryogenic temperatures of 6 K and compare their behavior with films synthesized at room temperature. We demonstrate that cryogenic growth increases structural disorder, producing crystalline grains that modify the optical, electrical, and superconducting properties of aluminum. We observe that cryogenic deposition changes the color of aluminum from fully reflective to yellow and correlate the pseudodielectric function and reflectance with structural changes in the film. We find that smaller grain sizes enhance the superconductivity of aluminum, increasing its critical temperature and critical field. We then estimate the superconducting gap and coherence length of Cooper pairs in aluminum in the presence of disorder. In conclusion, we fabricate superconducting microwave resonators on these films and find that, independently of the growth temperature, the system is dominated by two-level system loss with similar quality factors in the high- and low-power regimes. We further measure a higher kinetic inductance in the cryogenically grown films.

36 MATERIALS SCIENCE↗

Polarization Selectivity of Aloof-Beam Electron Energy-Loss Spectroscopy in One-Dimensional ZnO Nanorods

Orientation-dependent electronic properties of wurtzite zinc oxide nanorods are characterized by aloof-beam electron energy-loss spectroscopy (EELS) carried out in a scanning transmission electron microscope (STEM). The two key crystal orientation differentiating transitions specific to the in-plane (13.0 eV) and out-of-plane (11.2 eV) directions with respect to the wurtzite structure are examined by first-principles density-functional theory calculations. We note some degree of orientation dependence at the onset of direct band gap transition near 3.4 eV. We demonstrate that good polarization selectivity can be achieved by placing the electron probe at different locations around the specimen with increasing impact parameter while keeping the beam-specimen orientation fixed. The observed results are qualitatively elucidated in terms of the perpendicular electric fields generated by the fast electron (60 kV) used in the microscope. The fact that good polarization selectivity can be achieved by aloof-beam EELS without the requirement of sample reorientation is an attractive aspect from the characterization method point of view in the STEM-EELS community.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Probing free carrier plasmons in doped semiconductors using spatially resolved electron energy loss spectroscopy

We report spatially resolved measurements of free carrier collective excitations in a doped semiconductor. Using ~10 meV resolution electron energy loss spectroscopy (EELS) in an electron microscope with Å spatial resolution, we identify both surface and bulk carrier plasmons at infrared energies in a freestanding film of indium tin oxide (ITO). The interference patterns of long wavelength propagating surface carrier plasmons are revealed using spatially resolved EELS, from which we extract a dispersion relation. We further show that the energies of these plasmons vary near the surfaces and grain boundaries of the film due to band bending. Modeling based on dielectric theory agrees very well with experimental results. Finally, carrier plasmons in amorphous and crystalline ITO films are compared. These results should also be helpful for understanding the free carrier plasmons in other doped semiconductors in nanoscale volumes.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Extracting correlation effects from momentum-resolved electron energy loss spectroscopy: Synergistic origin of the dispersion kink in Bi 2.1 Sr 1.9 CaCu 2 O 8 + x

We employ momentum-resolved electron energy loss spectroscopy (M-EELS) on Bi 2.1 Sr 1.9 CaCu 2 O 8 + x to resolve the issue of the kink feature in the electron dispersion widely observed in the cuprates. To this end, we utilize the GW approximation to relate the density response function measured in M-EELS to the self-energy, isolating contributions from phonons, electrons, and the momentum dependence of the effective interaction to the decay rates. The phononic contributions, present in the M-EELS spectra due to electron-phonon coupling, lead to kink features in the corresponding single-particle spectra at energies between 40 and 80 meV, independent of the doping level. We find that a repulsive interaction constant in momentum space is able to yield the kink attributed to phonons in ARPES. Hence, our analysis of the M-EELS spectra points to local repulsive interactions as a factor that enhances the spectroscopic signatures of electron-phonon coupling in cuprates. We conclude that the strength of the kink feature in cuprates is determined by the combined action of electron-phonon coupling and electron-electron interactions.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Consistency between reflection momentum-resolved electron energy loss spectroscopy and optical spectroscopy measurements of the long-wavelength density response of Bi 2 Sr 2 CaCu 2 O 8 + x

The density fluctuation spectrum captures many fundamental properties of strange metals. Using momentum-resolved electron energy-loss spectroscopy (M-EELS), we recently showed that the density response of the strange metal Bi 2 Sr 2 CaCu 2 O 8+x (Bi-2212) at large momentum, q, exhibits a constant-in-frequency continuum reminiscent of the marginal Fermi liquid (MFL) hypothesis of the late 1980s. However, reconciling this observation with infrared (IR) optics experiments, which show a well-defined plasmon excitation at q ~ 0, has been challenging. Here we report M-EELS measurements of Bi-2212 using 4× improved momentum resolution, allowing us to reach the optical limit. For momenta q < 0.04 r.l.u., the M-EELS data show a plasmon feature that is quantitatively consistent with IR optics. For q > 0.04 r.l.u., the spectra become incoherent with an MFL-like, constant-in-frequency form. Here we speculate that, at finite frequency, ω, and nonzero q, some attribute of this Planckian metal randomizes the probe electron, causing it to lose information about its own momentum.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Energy Loss at Propagating Jamming Fronts in Granular Gas Clusters

In this article we explore the initial moments of impact between two dense granular clusters in a two-dimensional geometry. The particles are composed of solid CO 2 and are levitated on a hot surface. Upon collision, the propagation of a dynamic ‘‘jamming front’’ produces a distinct regime for energy dissipation in a granular gas in which the translational kinetic energy decreases by over 90%. Experiments and associated simulations show that the initial loss of kinetic energy obeys a power law in time ΔE = Kt 3/2 that can be predicted from kinetic arguments.

36 MATERIALS SCIENCE↗

Latent diffusion can map beam loss to two-dimensional phase-space projections

Beam loss monitors (BLMs) and beam current monitors (BCMs) are ubiquitous at particle accelerators around the world. These simple devices provide noninvasive high-level beam measurements but give no insight into the detailed 6D (𝑥,𝑦,𝑧,𝑝 𝑥 ,𝑝 𝑦 ,𝑝 𝑧 ) beam phase-space distributions or dynamics. We show that generative conditional latent diffusion models can learn intricate patterns to solve the extreme inverse problem of mapping waveforms of tens of BLMs or BCMs along an accelerator to detailed 2D projections of a charged particle beam’s 6D phase-space density. This transformational method can be used at any particle accelerator to transform simple noninvasive devices into detailed beam phase-space diagnostics. We demonstrate this concept via multiparticle simulations of the high-intensity beam in the kilometer-long Los Alamos Neutron Science Center linear proton accelerator.

43 PARTICLE ACCELERATORS↗

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