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At least 181 records · Page 10

Wet and dry plastic deposition data for western US National Atmospheric Deposition Program sites (2017-2019)

Raw plastic counts and calculated plastic deposition rates for 11 National Atmospheric Deposition Program (NADP) sites in the western USA recorded from 2017-2019. Samples were collected to determine plastic deposition rates in remote locations and identify the potential sources of plastic to the atmosphere. Samples were collected using an Aerochem Metrics Wet and Dry sampler. Wet deposition refers to the material retained on a 0.45-micron filter. Dry deposition refers to the dry only deposition collected using a Dry Side Insert (DSI) (Brahney et al. 2020). Plastics are identified as either fibers or particles (includes small colored films). Wet deposition rates are recorded weekly and dry plastic deposition rates are based on monthly sampling intervals. Sites included are Grand Canyon National Park (AZ03), Joshua Tree National Park (CA67), Rocky Mountain National Park (CO98), Niwot Ridge (CO02), Ashley National Forest (UT95), East River SFA (CO10)), Craters of the Moon National Park (ID03), Great Basin National Park (NV05), Canyonlands National Park (UT09), Bryce Canyon Nationa Park (UT99), and Wind River Range (WY06). Data collection is being published in collaboration with the Department of Energy's research project, "Constraining physical understanding of aerosol loading, biogeochemistry, and snowmelt hydrology from hillslope to watershed scale in the East River Scientific Focus Areas.

54 ENVIRONMENTAL SCIENCES↗

Event-scale predictions of water and nitrogen exports in coastal watersheds

Focal Area(s): The purpose of this white paper is to call for the improvement of the predictability and explainability of the magnitude and timing of water and nutrient exports in coastal watersheds. In this regard, hybrid machine learning approaches and process-based numerical models provide new opportunities to maximize predictability, emulate process-based model components, and explicitly address model uncertainty associated with event-scale predictions in coastal watersheds.

54 ENVIRONMENTAL SCIENCES↗

Model Advancements to Enable Impact Analysis of Climate Change on Streamflow Temperature

With support from the Department of Energy’s Water Power Technologies Office, Pacific Northwest National Laboratory (PNNL) has developed new tools that incorporate cutting-edge climate and hydrological science capabilities to assess the potential long-term impacts of future climate conditions on unregulated streamflow and water temperature within watershed-river-reservoir systems. The objectives of this project were achieved by enhancing key hydrologic and hydrodynamic models and transferring them to a high-performance computing environment to provide a high-spatiotemporal resolution, multi-scale modeling framework. The new modeling framework has the potential to quantify risks related climate change impacts on runoff, unregulated streamflow, and water temperature. Initial development and demonstration of the modeling framework was conducted under historical and future climate conditions in the Columbia River Basin in the Pacific Northwest and the Connecticut River Basin in New England.

13 HYDRO ENERGY↗

Mapping snow depth and volume at the alpine watershed scale from aerial imagery using Structure from Motion

Time series mapping of snow volume in the mountains at global scales and at resolutions needed for water resource management is an unsolved challenge to date. Snow depth mapping by differencing surface elevations from airborne lidar is a mature measurement approach filling the observation gap operationally in a few regions, primarily in mountain headwaters in the Western United States. The same concept for snow depth retrieval from stereo- or multi-view photogrammetry has been demonstrated, but these previous studies had limited ability to determine the uncertainties of photogrammetric snow depth at the basin scale. For example, assessments used non-coincident or discrete points for reference, masked out vegetation, or compared a subset of the fully snow-covered study domain. Here, using a unique data set with simultaneously collected airborne data, we compare snow depth mapped from multi-view Structure from Motion photogrammetry to that mapped by lidar at multiple resolutions over an entire mountain basin (300 km 2 ). After excluding reconstruction errors (negative depths), SfM had lower snow-covered area (~27%) and snow volume (~16%) compared to lidar. The reconstruction errors were primarily in areas with vegetation, shallow snow (< 1 m), and steep slopes (> 60°C). Across the overlapping snow extent, snow depths compared well to lidar with similar mean values (< 0.03 m difference) and snow volume (± 5%) for output resolutions of 3 m and 50 m, and with a normalized median absolute deviation of 0.19 m. Our results indicate that photogrammetry from aerial images can be applied in the mountains but would perform best for deeper snowpacks above tree line.

54 ENVIRONMENTAL SCIENCES↗

2020 Multiscale Microbial Dynamics Modeling Course

The 2020 Multiscale Microbial Dynamics course is adapted from the virtual 2020 Mutliscale Microbial Dynamics Summer School that was hosted by Environmental Molecular Sciences Laboratory (EMSL), a U.S. Department of Energy (DOE) science user facility located on the Pacific Northwest National Laboratory (PNNL) campus, in collaboration with the Joint Genome Institute (JGI) and the DOE Systems Biology Knowledgebase (KBase). The course course covers how to incorporate microbial metagenomic and environmental metabolite data from watershed ecosystems into metabolic and community modeling using computational frameworks, such as KBase and PFLOTRAN. The curriculum includes lectures and software and data analysis tutorials. All materials are freely accessible to the community as part of the 2020 Microbial Dynamics Summer School Organization in KBase.

54 ENVIRONMENTAL SCIENCES↗

Relationship between isotope ratios in precipitation and stream water across watersheds of the National Ecological Observation Network

The timescales associated with precipitation moving through watersheds reveal processes that are critical to understanding many hydrologic systems. Measurements of environmental stable water isotope ratios (δ 2 H and δ 18 O) have been used as tracers to study hydrologic timescales by examining how long it takes for incoming precipitation tracers become stream discharge, yet limited measurements both spatially and temporally have bounded macroscale evaluations so far. Here in this observation driven study across North American biomes within the National Ecological Observation Network (NEON), we examined δ 18 O and δ 2 H stable water isotope in precipitation (δP) and stream water (δQ) at 26 co-located sites. With an average 54 precipitation samples and 139 stream water samples per site collected over 2014–2022, assessment of local meteoric water lines and local stream water lines showed geographic variation across North America. Taking the ratio of estimated seasonal amplitudes of δP and δQ to calculate young water fractions (F yw ), showed a Fyw range from 1% to 93% with most sites having F yw below 20%. Calculate d mean transit times (MTT) based on a gamma convolution model showed a MTT range from 0.10 to 13.2 years, with half of the sites having MTT estimates lower than 2 years. Significant correlations were found between the F yw and watershed area, longest flow length, and the longest flow length/slope. Significant correlations were found between MTT and site latitude, longitude, slope, clay fraction, temperature, precipitation magnitude, and precipitation frequency. The significant correlations between water timescale metrics and the environmental characteristics we report share some similarities with those reported in prior studies, demonstrating that these quantities are primarily driven by site or area specific factors. The analysis of isotope data presented here provides important constraints on isotope variation in North American biomes and the timescales of water movement through NEON study sites.

54 ENVIRONMENTAL SCIENCES↗

Water Level Data from Wells PLM1 and PLM6 for the East River Watershed, Colorado

This dataset (Williams et al., 2020) contains the original un-QA/QC-ed water level data for PLM1 and PLM6 and has been obsoleted. The data contained within this dataset is not to be used. Refer to Faybishenko et al., 2022 (DOI: 10.15485/1866836) for the latest QA/QC-ed data available via ESS-DIVE.This data set contains water level data for the PLM1 and PLM6 wells. PLM1 and PLM6 are location identifiers used by the Watershed Function SFA project for two groundwater monitoring wells along an elevation gradient located along the lower montane life zone of a hillslope near the Pumphouse location. These wells used to monitor subsurface water and carbon inventories and fluxes at the East River Watershed, Colorado, USA. Complete metadata information on the PLM1 and PLM6 wells are available in the related data package reference Varadharajan C, et al (2020). https://doi.org/10.15485/1660962.Data are reported in .csv files per well. The latitude and longitude of each location are given in a file called locations.csv. These data are used for determining the seasonally dependent flow of groundwater under the PLM hillslope. The downslope flow of groundwater in combination with data on groundwater chemistry can be used to estimate rates of solute export from the hillslope to the floodplain and river.These data products are part of the Watershed Function Scientific Focus Area collection effort to further scientific understanding of biogeochemical dynamics from genome to watershed scales.

54 ENVIRONMENTAL SCIENCES↗

Diminishing marginal effect in estimating the dissolved organic carbon export from a watershed

Dissolved organic carbon (DOC) can be initially moved from soils to inland waters with surface runoff, and then mineralized, buried, or eventually delivered to the coastal ocean. This land-to-ocean phase of the DOC flux must be accounted for to comprehensively understand the global carbon cycle. To estimate the terrestrial-aquatic DOC leaching, calculating the product of the riverine DOC concentration and the corresponding river discharge measured at the watershed outlet is a common method. However, it is challenging to frequently and exactly record riverine DOC concentrations, thus the relationship between DOC concentrations and discharges (C-Q relationship) are established and used to interpolate the time-series of DOC concentrations. We found that the widely used time-dependent and time-independent C-Q regression models are weak in representing their altered relationship when the discharge is extremely high, which was named as diminishing marginal effect. In this study, we evaluated the performance of two C-Q regression models and discussed possible reasons for the diminishing marginal effect. We suggest that repeated and long-term measurements of the DOC concentration are required to adequately analyze their relationships, especially during the early spring and seasons with heavy precipitations.

54 ENVIRONMENTAL SCIENCES↗

NASA 1990 Multisensor Airborne Campaigns (MACs) for ecosystem and watershed studies

The Multisensor Airborne Campaign (MAC) focus within NASA's former Land Processes research program was conceived to achieve the following objectives: to acquire relatively complete, multisensor data sets for well-studied field sites, to add a strong remote sensing science component to ecology-, hydrology-, and geology-oriented field projects, to create a research environment that promotes strong interactions among scientists within the program, and to more efficiently utilize and compete for the NASA fleet of remote sensing aircraft. Four new MAC's were conducted in 1990: the Oregon Transect Ecosystem Research (OTTER) project along an east-west transect through central Oregon, the Forest Ecosystem Dynamics (FED) project at the Northern Experimental Forest in Howland, Maine, the MACHYDRO project in the Mahantango Creek watershed in central Pennsylvania, and the Walnut Gulch project near Tombstone, Arizona. The OTTER project is testing a model that estimates the major fluxes of carbon, nitrogen, and water through temperate coniferous forest ecosystems. The focus in the project is on short time-scale (days-year) variations in ecosystem function. The FED project is concerned with modeling vegetation changes of forest ecosystems using remotely sensed observations to extract biophysical properties of forest canopies. The focus in this project is on long time-scale (decades to millenia) changes in ecosystem structure. The MACHYDRO project is studying the role of soil moisture and its regulating effects on hydrologic processes. The focus of the study is to delineate soil moisture differences within a basin and their changes with respect to evapotranspiration, rainfall, and streamflow. The Walnut Gulch project is focused on the effects of soil moisture in the energy and water balance of arid and semiarid ecosystems and their feedbacks to the atmosphere via thermal forcing.

Wickland, Diane E.↗

Elevation distributed micro-climatology data in a coastal glaciated watershed

Air temperature, ground temperature and relative humidity data were collected in a longitudinal transect of the Nooksack watershed at varying elevations from 500 to 1800 m above sea level. Data were collected by anchoring sensors from trees above winter snow levels and shaded from direct solar radiation. Paired sensors were also buried 3 cm under ground near each air temperature sensor to determine snow absence or presence. Select sites included relative humidity sensors to indicate whether precipitation was occurring. Data were collected every 3-4 h from December 2015 to Sept 2018 (with ongoing collection). Code for analysis of daily mean, minimum, maximum, and temperature change with elevation (lapse rates) are available on Github (https://doi.org/10.5281/zenodo.3239539). The sensor download and intermediate data products are available on HydroShare at (http://www.hydroshare.org/resource/222e832d3df24dea9bae9bbeb6f4219d) with publicly accessible visualization available from the Nooksack Observatory at data.cuahsi.org. Hydrologic models are generally structured with a single annual average lapse rate parameter which assumes a linear temperature gradient with elevation. The daily data (2016-2018) is used as part of ongoing studies on the non-linear dynamics and temporal variability of temperature with elevation to improve assessments of watershed function and salmon habitat.

54 ENVIRONMENTAL SCIENCES↗

Parsing Weather Variability and Wildfire Effects on the Post-Fire Changes in Daily Stream Flows: A Quantile-Based Statistical Approach and Its Application

Determining wildland fire impacts on streamflow can be problematic as the hydrology in burned watersheds is influenced by post-fire weather conditions. Here, this study presents a quantile-based analytical framework for assessing fire impacts on low and peak daily flow magnitudes, while accounting for post-fire weather influences. This framework entails (a) the bootstrap method to compute the relative change in the post-fire annual flow and weather statistics, (b) double mass analysis to detect if post-fire baseflow and quick-flow yield ratios are significantly altered, and (c) a quantile regression method to parse fire effects on flow at a specific quantile. We illustrate the applicability of this analytical framework using 44 western US streams with at least 5% of their watershed area burned. Results indicate that large, high-severity burns in upland watersheds can raise the streamflow magnitude at the 0. 05 th and 0. 95 th quantiles for at least the five post-fire years. Quantile regression results show that the median fire-related increase in flow for the five post-fire years can be up to 5,000% (Standard Error; S.E. < 2%) at the 0. 05 th E quantile and 161% (S.E. < 10%) at the 0. 95 th quantile. The fire-related increase in flow was often pronounced at the 0. 05 th quantile for streams in the Pacific Northwest and California regions. The difference in fire effects on flow (at both quantiles) across streams was related to post-fire weather, pyrology, physiography, and land cover. The proposed analytical framework can be useful for detecting and quantifying fire effects on the low and peak stream flows in burned watersheds without overlapping disturbances.

54 ENVIRONMENTAL SCIENCES↗

Surface Atmosphere Integrated Field Laboratory

To help improve understanding and modeling of processes connected to mountain hydrology, the Atmospheric Radiation Measurement (ARM) user facility will operate the Surface Atmosphere Integrated Field Laboratory (SAIL) field campaign in central Colorado. From September 2021 to June 2023, an ARM Mobile Facility will collect measurements with a focus on the 300-square-kilometer (116-square-mile) East River Watershed within the Upper Colorado River Basin. SAIL will combine atmospheric measurements from ARM, a U.S. Department of Energy (DOE) scientific user facility, with existing surface and subsurface data from partner research organizations. Researchers will develop detailed measurements of mountainous water-cycle processes as they pertain to the Colorado River, which supplies water for 40 million people in the American West. Through SAIL, researchers from DOE national laboratories, universities, and research centers and agencies will enable an atmosphere-through-bedrock understanding of mountainous water cycles. By observing what is happening above and below ground to influence hydrology at various scales across the East River Watershed, SAIL will provide insights into how Upper Colorado River watersheds interact with the atmosphere to produce water.

54 ENVIRONMENTAL SCIENCES↗

A deep learning hybrid predictive modeling (HPM) approach for estimating evapotranspiration and ecosystem respiration

Climate change is reshaping vulnerable ecosystems, leading to uncertain effects on ecosystem dynamics, including evapotranspiration (ET) and ecosystem respiration (R eco ). However, accurate estimation of ET and R eco still remains challenging at sparsely monitored watersheds, where data and field instrumentation are limited. In this study, we developed a hybrid predictive modeling approach (HPM) that integrates eddy covariance measurements, physically based model simulation results, meteorological forcings, and remote-sensing datasets to estimate ET and R eco in high space–time resolution. HPM relies on a deep learning algorithm and long short-term memory (LSTM) and requires only air temperature, precipitation, radiation, normalized difference vegetation index (NDVI), and soil temperature (when available) as input variables. We tested and validated HPM estimation results in different climate regions and developed four use cases to demonstrate the applicability and variability of HPM at various FLUXNET sites and Rocky Mountain SNOTEL sites in Western North America. To test the limitations and performance of the HPM approach in mountainous watersheds, an expanded use case focused on the East River Watershed, Colorado, USA. The results indicate HPM is capable of identifying complicated interactions among meteorological forcings, ET, and R eco variables, as well as providing reliable estimation of ET and R eco across relevant spatiotemporal scales, even in challenging mountainous systems. The study documents that HPM increases our capability to estimate ET and R eco and enhances process understanding at sparsely monitored watersheds.

54 ENVIRONMENTAL SCIENCES↗

WHONDRS-GUI: a web application for global survey of surface water metabolites

Background The Worldwide Hydrobiogeochemistry Observation Network for Dynamic River Systems (WHONDRS) is a consortium that aims to understand complex hydrologic, biogeochemical, and microbial connections within river corridors experiencing perturbations such as dam operations, floods, and droughts. For one ongoing WHONDRS sampling campaign, surface water metabolite and microbiome samples are collected through a global survey to generate knowledge across diverse river corridors. Metabolomics analysis and a suite of geochemical analyses have been performed for collected samples through the Environmental Molecular Sciences Laboratory (EMSL). The obtained knowledge and data package inform mechanistic and data-driven models to enhance predictions of outcomes of hydrologic perturbations and watershed function, one of the most critical components in model-data integration. To support efforts of the multi-domain integration and make the ever-growing data package more accessible for researchers across the world, a Shiny/R Graphical User Interface (GUI) called WHONDRS-GUI was created. Results The web application can be run on any modern web browser without any programming or operational system requirements, thus providing an open, well-structured, discoverable dataset for WHONDRS. Together with a context-aware dynamic user interface, the WHONDRS-GUI has functionality for searching, compiling, integrating, visualizing and exporting different data types that can easily be used by the community. The web application and data package are available at https://data.ess-dive.lbl.gov/view/doi:10.15485/1484811 , which enables users to simultaneously obtain access to the data and code and to subsequently run the web app locally. The WHONDRS-GUI is also available for online use at Shiny Server ( https://xmlin.shinyapps.io/whondrs/ ).

59 BASIC BIOLOGICAL SCIENCES↗

Hawaii Water Resources: Monitoring the Impact of Land-Based Sources of Pollution on Water Quality Along the Coast of West Maui, Hawai'i, to Assess Coral Reef Condition

West Maui is at risk of losing ecosystem services provided by coral reefs due to land-based sources of pollution (LBSP). In 2011, the US Coral Reef Task Force (USCRTF) identified the West Maui watershed as a priority watershed (along with its sub-watersheds of Wahikuli, Honokōwai, Kahana, Honokahua, and Honolua) after decades of coral decline, giving rise to the multi-agency West Maui Ridge to Reef (R2R) Initiative. The DEVELOP Hawai’i Water Resources team partnered with the R2R Initiative and the Hawai’i Department of Land and Natural Resources Division of Aquatic Resources (DLNR-DAR) to address the need for better watershed management practices. The team provided the partners with a Google Earth Engine tool that displays land use and land cover changes (LULCC) in the five watersheds and detects near-shore turbidity, chlorophyll-a (chl-a), and sea surface temperature using Landsat 4 Thematic Mapper (TM), Landsat 5 TM, Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Landsat 8 Operational Land Imager (OLI), Terra Moderate Resolution Imaging Spectroradiometer (MODIS), and Aqua MODIS. Team members used ancillary data provided by the R2R Initiative and the USGS Pacific Coastal and Marine Science Center (PCMSC) to validate satellite parameter values. The land cover analysis captured a general trend of increasing impervious cover and decreasing vegetated cover from 1989 to 2019; however, the extent of this change varied between each watershed. This analysis, coupled with the tool, can help project partners continually monitor terrestrial and marine patterns associated with coral decline.

Water Resources↗

Nitrate, ammonium, and DON mass time series output for East River stream, vadose zone and groundwater subwatersheds from HAN-SoMo model

There is a growing understanding of the role that bedrock weathering can play as a source of nitrogen (N) to soils, groundwater and river systems. The significance is particularly apparent in mountainous environments where weathering fluxes can be large. However, our understanding of the relative contributions of rock-derived, or geogenic, N to the total N supply of mountainous watersheds remains poorly understood. This dataset contains model output from the High-Altitude Nitrogen Suite of Models (HAN-SoMo), a watershed-scale ensemble of process-based models to quantify the relative sources, transformations, and sinks of geogenic and atmospheric N through a mountain watershed. Our study is based in the East River Watershed (ERW) in the Upper Colorado River Basin. The East River is a near-pristine headwater watershed underlain primarily by an N-rich Mancos Shale bedrock, enabling the timing and magnitude of geogenic and atmospheric contributions to watershed scale dissolved N-exports to be quantified. Six calibration scenarios were developed to explore equifinality using >1600 N concentration measurements from streams, groundwater, and vadose zone samples collected over the course of four years across the watershed, from 2014-2018. The files in this dataset are named according to which calibration scenario they represent (1, 2, 3, NM1, NM2, and NC), and include daily time series model output of nitrate, ammonium and dissolved organic nitrogen concentrations for all six calibration scenarios described in Maavara et al., 2021, "Modeling geogenic and atmospheric nitrogen through the East River Watershed, Colorado Rocky Mountains," PLOS One (in press), for the stream, vadose zone, and groundwater in the five discretized subwatersheds: Rustlers Gulch, Copper Creek, East above Quigley (EAQ), the Middle East River (ME), and Lower Triangle (LT) from Gothic to the Pumphouse. The READ_ME.txt file includes details on units and naming conventions in each of these files. Model files are in .mat format, to be opened in MATLAB.

54 ENVIRONMENTAL SCIENCES↗