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At least 181 records · Page 10

The contribution of electron collisions to rotational excitations of cometary water

The e-H2O collisional rate for exciting rotational transitions in cometary water is evaluated for conditions found in comet Halley during the Giotto spacecraft encounter. In the case of the O(sub 00) yields 1(sub 11) rotational transition, the e-H2O collisional rate exceeds that for excitation by neutral-neutral collisions at distances exceeding 3000 km from the cometary nucleus. Thus, the rotational temperature of the water molecule in the intermediate coma may be controlled by collisions with electrons rather than with neutral collisions, and the rotational temperature retrieved from high resolution infrared spectra of water in comet Halley may reflect electron temperatures rather than neutral gas temperature in the intermediate coma.

Xie, Xingfa↗

Testing of an AP-105 Precipitation Simulant

A tank AP-105 chemical simulant was developed and diluted with Washington River Protection Solutions (WRPS)-supplied raw water to evaluate the stability of AP Farm wastes with respect to precipitation under Direct Feed Low-Activity Waste (DFLAW)-typical waste feed staging operations. The current report provides a high-level summary of the basis for simulant selection, the recommended (and prepared) simulant chemistry, and observed stability with respect to solids formation upon simulant preparation and subsequent dilution with raw water.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Impact of climate change on adaptive management decisions in the face of water scarcity

Reoccurring drought through the early 2000s has caused a serious water scarcity issue in the Colorado River Basin. Previous modeling studies have focused on the impact of climate change without considering the adaptive behaviors of farmers and under-utilized Indian water rights. Here, we use a coupled agent-based water resource model (ABM) to investigate how the adaptive decisions of farmers can affect water resource management under both climate change impacts and fully utilized Indian water right conditions. We used five General Circulation Model projections with RCP8.5 scenarios for the study. The results of farm-level decision-making showed different responses in irrigated areas that were changing due to climate change impact. While winter precipitation changes might partially explain the behavior changes, no specific pattern could be concluded based on their location. Also, farmers’ responses about annual water diversion showed more significant inter-year variation compared to irrigated areas. Basin-level metrics showed that climate change impacts will generally worsen water scarcity issues as measured in Navajo Reservoir storage, flow to Lake Powell, and instream flow requirement. But these basin-level water scarcity metrics cannot reflect individual farm-level impacts under climate change, which is why modeling the bottom-up management actions is necessary. When the under-utilized Indian water rights are fully used, it is more likely to trigger the shortage sharing agreement due to the higher tribal water depletion. Evaluation of model uncertainty and a more realistic setup for adaptive actions under drought contingency plans are suggested for future research.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of long-term Northern Hemisphere snow water equivalent products

Nine gridded Northern Hemisphere snow water equivalent (SWE) products were evaluated as part of the European Space Agency (ESA) Satellite Snow Product Intercomparison and Evaluation Exercise (SnowPEx). Three categories of datasets were assessed: (1) those utilizing some form of reanalysis (the NASA Global Land Data Assimilation System version 2 – GLDAS-2; the European Centre for Medium-Range Weather Forecasts (ECMWF) interim land surface reanalysis – ERA-Interim/Land and ERA5; the NASA Modern-Era Retrospective Analysis for Research and Applications version 1 (MERRA) and version 2 (MERRA-2); the Crocus snow model driven by ERA-Interim meteorology – Crocus); (2) passive microwave remote sensing combined with daily surface snow depth observations (ESA GlobSnow v2.0); and (3) stand-alone passive microwave retrievals (NASA AMSR-E SWE versions 1.0 and 2.0) which do not utilize surface snow observations. Evaluation included validation against independent snow course measurements from Russia, Finland, and Canada and product intercomparison through the calculation of spatial and temporal correlations in SWE anomalies. The stand-alone passive microwave SWE products (AMSR-E v1.0 and v2.0 SWE) exhibit low spatial and temporal correlations to other products and RMSE nearly double the best performing product. Constraining passive microwave retrievals with surface observations (GlobSnow) provides performance comparable to the reanalysis-based products; RMSE over Finland and Russia for all but the AMSR-E products is ∼50 mm or less, with the exception of ERA-Interim/Land over Russia. Using a seven-dataset ensemble that excluded the stand-alone passive microwave products reduced the RMSE by 10 mm (20 %) and increased the correlation from 0.67 to 0.78 compared to any individual product. The overall performance of the best multiproduct combinations is still at the margins of acceptable uncertainty for scientific and operational requirements; only through combined and integrated improvements in remote sensing, modeling, and observations will real progress in SWE product development be achieved.

Northern Hemisphere snow water equivalent (SWE) pr↗

Validation and Simulation of Ares I Scale Model Acoustic Test - 3 - Modeling and Evaluating the Effect of Rainbird Water Deluge Inclusion

The Ares I Scale Model Acoustics Test (ASMAT) is a series of live-fire tests of scaled rocket motors meant to simulate the conditions of the Ares I launch configuration. These tests have provided a well documented set of high fidelity measurements useful for validation including data taken over a range of test conditions and containing phenomena like Ignition Over-Pressure and water suppression of acoustics. Building on dry simulations of the ASMAT tests with the vehicle at 5 ft. elevation (100 ft. real vehicle elevation), wet simulations of the ASMAT test setup have been performed using the Loci/CHEM computational fluid dynamics software to explore the effect of rainbird water suppression inclusion on the launch platform deck. Two-phase water simulation has been performed using an energy and mass coupled lagrangian particle system module where liquid phase emissions are segregated into clouds of virtual particles and gas phase mass transfer is accomplished through simple Weber number controlled breakup and boiling models. Comparisons have been performed to the dry 5 ft. elevation cases, using configurations with and without launch mounts. These cases have been used to explore the interaction between rainbird spray patterns and launch mount geometry and evaluate the acoustic sound pressure level knockdown achieved through above-deck rainbird deluge inclusion. This comparison has been anchored with validation from live-fire test data which showed a reduction in rainbird effectiveness with the presence of a launch mount.

Strutzenberg, Louise L.↗

Evapotranspiration partitioning estimates from 8 methods from 47 NEON sites, 2019-2021

This dataset provides daily estimates of evapotranspiration (ET) and the transpiration-to-evapotranspiration ratio (T/ET) across 47 terrestrial National Ecological Observatory Network (NEON) sites spanning diverse environmental and biome conditions in the United States across three years of data (2019-2021). Daily ET is reported in both energy units (MJ m⁻² day⁻¹) and equivalent water depth (mm day⁻¹), assuming a constant latent heat of vaporization of 2.45 MJ/kg. The primary method uses a hybrid recurrent neural network–Penman–Monteith framework (RNN-PM), which integrates physically based surface energy balance constraints with data-driven learning to partition ET into transpiration and evaporation components. Model inputs include in situ meteorological observations (air temperature, vapor pressure deficit, wind speed, and radiation) combined with satellite-derived land surface temperature, leaf area index, and soil moisture. For benchmarking and uncertainty assessment, T/ET estimates from seven additional models are included: Priestley-Taylor Jet Propulsion Laboratory (PT-JPL), Penman-Monteith (P-M), Two-Source Energy Balance (TSEB), Support Vector Regression (SVR), and Categorical Boosting (CatBoost), among others—spanning empirical, machine-learning, and process-based approaches (see methods section or linked publication for detailed descriptions). Data Package Contents: The dataset a csv files containing daily ET and T/ET estimates for each site and model, along with associated metadata files these variables. Data can be accessed using common spreadsheet software (e.g., Microsoft Excel, LibreOffice) or programming environments such as R or Python. Together, these data support cross-site comparisons of ecosystem water use, evaluation of ET partitioning methods, and development of improved land–atmosphere exchange models.

EARTH SCIENCE > ATMOSPHERE↗

Energy Transitions: Local Water Concerns and Climate Impacts

This report summarizes important nuances in local water concerns and potential climate impacts that could influence the roll-out of technologies associated with energy transitions. Current investments in clean energy technologies are very high, which is driving a lot of investments in related manufacturing (i.e., hydrogen, solar, wind, and batteries) and mining (e.g., lithium, copper, and graphite) around the world. To understand how water and climate dynamics could be influencing these activities, we conducted a phased literature review for three countries: China, Germany, and France. China was selected due to its global dominance in manufacturing of solar panels, batteries, and electrolyzers as well as production of rare earth elements while Germany and France were selected due to their emerging leadership in energy transitions-related manufacturing within the European Union. For each of these three nations, we identified areas where manufacturing is occurring within the country and then evaluated relevant water resources and climate impacts. Multiple sources were consulted for this review, including BloombergNEF, international reports, industry sources, peer-reviewed literature, climate data, and media coverage.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Evaluation of Ultrafiltration for Spacecraft Water Reuse

Ultrafiltration is examined for use as the first stage of a primary treatment process for spacecraft wastewater. It is hypothesized that ultrafiltration can effectively serve as pretreatment for a reverse osmosis system, removing the majority of organic material in a spacecraft wastewater. However, it is believed that the interaction between the membrane material and the surfactant found in the wastewater will have a significant impact on the fouling of the ultrafiltration membrane. In this study, five different ultrafiltration membrane materials are examined for the filtration of wastewater typical of that expected to be produced onboard the International Space Station. Membranes are used in an unstirred batch cell. Flux, organic carbon rejection, and recovery from fouling are measured. The results of this evaluation will be used to select the most promising membranes for further study.

Pickering, Karen D.↗

The effect of electron collisions on rotational populations of cometary water

The e-H2O collisional rate for exciting rotational transitions in cometary water is evaluated for conditions found in Comet Halley during the Giotto spacecraft encounter. In the case of the 0(00)-1(11) rotational transition, the e-H2O collisional rate exceeds that for excitation by neutral-neutral collisions at distances exceeding 3000 km from the cometary nucleus. The estimates are based on theoretical and experimental studies of e-H2O collisions, on ion and electron parameters acquired in situ by instruments on the Giotto and Vega spacecraft, and on results obtained from models of the cometary ionosphere. Thus, the rotational temperature of the water molecule in the intermediate coma may be controlled by collisions with electrons rather than with neutral molecules, and the rotational temperature retrieved from high-resolution IR spectra of water in Comet Halley may reflect electron temperatures rather than neutral gas temperatures in the intermediate coma.

Xie, Xingfa↗

Use of GOES, SSM/I, TRMM Satellite Measurements Estimating Water Budget Variations in Gulf of Mexico - Caribbean Sea Basins

This study presents results from a multi-satellite/multi-sensor retrieval system designed to obtain the atmospheric water budget over the open ocean. A combination of 3ourly-sampled monthly datasets derived from the GOES-8 5-channel Imager, the TRMM TMI radiometer, and the DMSP 7-channel passive microwave radiometers (SSM/I) have been acquired for the combined Gulf of Mexico-Caribbean Sea basin. Whereas the methodology has been tested over this basin, the retrieval system is designed for portability to any open-ocean region. Algorithm modules using the different datasets to retrieve individual geophysical parameters needed in the water budget equation are designed in a manner that takes advantage of the high temporal resolution of the GOES-8 measurements, as well as the physical relationships inherent to the TRMM and SSM/I passive microwave measurements in conjunction with water vapor, cloud liquid water, and rainfall. The methodology consists of retrieving the precipitation, surface evaporation, and vapor-cloud water storage terms in the atmospheric water balance equation from satellite techniques, with the water vapor advection term being obtained as the residue needed for balance. Thus, the intent is to develop a purely satellite-based method for obtaining the full set of terms in the atmospheric water budget equation without requiring in situ sounding information on the wind profile. The algorithm is validated by cross-checking all the algorithm components through multiple- algorithm retrieval intercomparisons. A further check on the validation is obtained by directly comparing water vapor transports into the targeted basin diagnosed from the satellite algorithms to those obtained observationally from a network of land-based upper air stations that nearly uniformly surround the basin, although it is fair to say that these checks are more effective m identifying problems in estimating vapor transports from a leaky operational radiosonde network than in verifying the transport estimates determined from the satellite algorithm system Total columnar atmospheric water budget results are presented for an extended annual cycle consisting of the months of October-97, January-98, April-98, July-98,October-98, and January 1999. These results are used to emphasize the changing relationship in E-P, as well as in the varying roles of storage and advection in balancing E-P both on daily and monthly time scales and on localized and basin space scales. Results from the algorithm-to-algorithm intercomparisons are also presented in the context of sensitivity testing to help understand the intrinsic uncertainties in evaluating the water budget terms by an all-satellite algorithm approach.

Smith, Eric A.↗

Monthly-Diurnal Water Budget Variability Over Gulf of Mexico-Caribbean Sea Basin from Satellite Observations

This study presents results from a multi-satellite/multi-sensor retrieval system design d to obtain the atmospheric water budget over the open ocean. A combination of hourly-sampled monthly datasets derived from the GOES-8 5-channel Imager, the TRMM TMI radiometer, and the DMSP 7-channel passive microwave radiometers (SSM/I) have been acquired for the combined Gulf of Mexico-Caribbean Sea basin. Whereas the methodology has been tested over this basin, the retrieval system is designed for portability to any open-ocean region. Algorithm modules using the different datasets to retrieve individual geophysical parameters needed in the water budget equation are designed in a manner that takes advantage of the high temporal resolution of the GOES-8 measurements, as well as the physical relationships inherent to the TRMM and SSM/I passive microwave measurements in conjunction with water vapor, cloud liquid water, and rainfall. The methodology consists of retrieving the precipitation, surface evaporation, and vapor-cloud water storage terms in the atmospheric water balance equation from satellite techniques, with the water vapor advection term being obtained as the residue needed for balance. Thus, the intent is to develop a purely satellite-based method for obtaining the full set of terms in the atmospheric water budget equation without requiring in situ sounding information on the wind profile. The algorithm is validated by cross-checking all the algorithm components through multiple-algorithm retrieval intercomparisons. A further check on the validation is obtained by directly comparing water vapor transports into the targeted basin diagnosed from the satellite algorithms to those obtained observationally from a network of land-based upper air stations that nearly uniformly surround the basin, although it is fair to say that these checks are more effective in identifying problems in estimating vapor transports from a "leaky" operational radiosonde network than in verifying the transport estimates determined from the satellite algorithm system. Total columnar atmospheric water budget results are presented for an extended annual cycle consisting of the months of October-97, January-98, April-98, July-98,October-98, and January- 1999. These results are used to emphasize the changing relationship in E-P, as well as in the varying roles of storage and advection in balancing E-P both on daily and monthly time scales and on localized and basin space scales. Results from the algorithm-to-algorithm intercomparisons are also presented in the context of sensitivity testing to help understand the intrinsic uncertainties in evaluating the water budget terms by an all-satellite algorithm approach.

Smith, E. A.↗

Dynamic response of a freely rotating butterfly valve in the advanced test reactor − dynamic coefficients modeling

Here, in evaluating the water hammer issue pertaining to the primary-coolant-regulating butterfly valve in the Advanced Test Reactor, the dynamic fluid body interaction (DFBI) approach was implemented in the analysis covered in Part I. Although DFBI modeling accurately and simultaneously solved the dynamic motion of the valve’s disk along with the flow field of the surrounding fluid, it shed little light on the reason behind such motion. For Part II, the reacting torque of the fluid on the disk was decomposed into representations of the dynamic coefficients in terms of stiffness, damping, and added mass. These were evaluated via simulations with steady-state static (stiffness), constant angular speed (damping), and variable angular speed (added mass) disks. Substituting the dynamic coefficients into Newton’s second law enabled the response trajectories to be obtained. Stable (by average) and unstable equilibrium positions and thrust tendencies of the valve were determined based on the stiffness coefficient (or static torque), the response amplitude was dampened or enlarged by the damping coefficient (minorly affected by added mass), and the response frequency was altered by the damping and added mass coefficients. Although the dynamic coefficient approach renders slightly different trajectories, due to the averaging effect of the torque in comparison to the DFBI method, the overall trend of the response aligns with the DFBI simulation, thus confirming the conclusion in Part I that a fix to the current butterfly valve is necessary.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

The effect of electron collisions on rotational excitation of cometary water

The e-H2O collisional rate for exciting rotational transitions in cometary water is evaluated for conditions found in Comet Halley. The e-H2O collisional rate exceeds that for excitation by neutral-neutral collisions at distances exceeding 3000 km from the cometary nucleus, in the case of the O sub 00 yields 1 sub 11 transition. The estimates are based on theoretical and experimental studies of e-H2O collisions, on ion and electron parameters acquired in-situ by instruments on the Giotto and Vega spacecraft, and on results obtained from models of the cometary ionosphere. The contribution of electron collisions may explain the need for large water-water cross-sections in models which neglect the effect of electrons. The importance of electron collisions is enhanced for populations of water molecules in regions where their rotational lines are optically thick.

Xie, Xingfa↗

Tools for Water Ingress Testing

The Safety Storage and Engineering Team, as part of the Production Support Services division (PSS-2), is tasked with ensuring the safety of containers used for handling and storage of nuclear materials. As part of this work, water ingress tests are conducted to evaluate the water-tightness of containers intended for in-glovebox use. In collaboration, the statistics group of the Computer and Computational Sciences Division (CCS-6) provided support in developing a statistically defensible approach for determining appropriate sample sizes for water ingress testing. Water ingress testing involves multiple measurements on multiple containers. Our approach uses a simple random effects model to analyze a pilot data set, implementing prediction limits to evaluate the efficacy of collecting additional data. Although this study capitalizes on available data, our approach can be used with estimates of the ratio of between and within variability and average values, often available from past testing or expert knowledge. An interactive Shiny tool was developed as a final user-friendly product for future testing. The Shiny interface is an open-source package providing a framework for building web applications. Raw data exploration and prediction interval-based sample size assessments can quickly be conducted by the engineering team without needing to interact with the underlying code.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Preventing leaching from lead water pipes with electrochemistry: an exploratory study

Toxic levels of lead leaching from ageing water distribution infrastructure affect over 5000 public drinking water systems in the US. Pipe replacement, the most effective solution to this problem, is prohibitively expensive. Additionally, chemical conditioning of drinking water using orthophosphates, although cost-effective, does not quickly stop lead leaching once it has started. We propose a novel approach to stop lead leaching: to rapidly form an insoluble scale within lead pipes using an external power supply. We report on the feasibility of this approach by first anodizing lead coupons and lead pipes reclaimed from a local water distribution using a phosphate electrolyte and different potentials, pH values, and phosphate concentrations. We subsequently exposed these anodized lead coupons and pipes to synthetic tap water to evaluate their lead leaching rates. We found that polarizing lead coupons in the presence of a 0.05 M phosphate solution decreased lead leaching by up to a 100-fold, relative to leaching from polished bare lead. Similarly, polarizing the reclaimed lead pipes (with a preexisting scale) decreased lead leaching from an average of 36 ppb to 7 ppb. These results were observed when applying potentials that favor Pb(IV) formation, which resulted in the buildup of PbO 2 and Pb 5 (PO 4 ) 3 OH in both lead coupons and pipes. Our findings indicate that this novel technology has the potential to rapidly decrease equilibrium lead levels in tap water below the EPA action limit of 15 ppb, and thus deserves further exploration.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of a Human Modeling Software Tool in the Prediction of Extra Vehicular Activity Tasks for an International Space Station Assembly Mission

The difficulty of accomplishing work in extravehicular activity (EVA) is well documented. It arises as a result of motion constraints imposed by a pressurized spacesuit in a near-vacuum and of the frictionless environment induced in microgravity. The appropriate placement of foot restraints is crucial to ensuring that astronauts can remove and drive bolts, mate and demate connectors, and actuate levers. The location on structural members of the foot restraint sockets, to which the portable foot restraint is attached, must provide for an orientation of the restraint that affords the astronaut adequate visual and reach envelopes. Previously, the initial location of these sockets was dependent upon the experienced designer's ability to estimate placement. The design was tested in a simulated zero-gravity environment; spacesuited astronauts performed the tasks with mockups while submerged in water. Crew evaluation of the tasks based on these designs often indicated the bolt or other structure to which force needed to be applied was not within an acceptable work envelope, resulting in redesign. The development of improved methods for location of crew aids prior to testing would result in savings to the design effort for EVA hardware. Such an effort to streamline EVA design is especially relevant to International Space Station construction and maintenance. Assembly operations alone are expected to require in excess of four hundred hours of EVA. Thus, techniques which conserve design resources for assembly missions can have significant impact. We describe an effort to implement a human modelling application in the design effort for an International Space Station Assembly Mission. On Assembly Flight 6A, the Canadian-built Space Station Remote Manipulator System will be delivered to the U.S. Laboratory. It will be released from its launch restraints by astronauts in EVA. The design of the placement of foot restraint sockets was carried out using the human model Jack, and the modelling results were compared with actual underwater test results. The predicted locations of the sockets was found to be acceptable for 94% of the tasks attempted by the astronauts, This effort provides confidence in the capabilities of this package to accurately model tasks. It therefore increases assurance that the tool maybe used early in the design process.

Dischinger, H. Charles↗

Effects of water recirculation on microalgae assemblage and corresponding sustainability of the photobioreactor cultivation system

An algae photobioreactor (APB) was used to determine the effect of water recirculation on the growth of algal assemblage. CO 2 in the flue gas from a power plant was the carbon source. Boiler water was used as the source water. The results showed that microalgae cultivation under recirculation conditions was stable over a period of four months. Biomass productivities during the 1st through 4th months of recirculation (0.26, 0.23, 0.20, and 0.18 g L –1 d –1 , respectively) were not significantly different than freshwater (0.22 g L –1 d –1 ). Furthermore, the relationship between eukaryotic and bacterial domains in the assemblage remained consistent throughout the four months of recirculation (80.7, 87.1, 83.1, and 82.1%, respectively, and 19.2, 12.8, 16.9, and 17.8%, respectively). This was not significantly different than the abundance of each domain in the control freshwater cultivation (83.7% eukaryotic and 16.2% bacterial). A 1 m 3 photobioreactor was then envisioned for a mass, energy, and exergy analysis to evaluate the water recirculation on sustainability of the culture system. The mass balance analysis concluded that 98% reduction in water usage, 25% reduction in nitrogen, and 12.5% reduction in phosphorus could be achieved during cultivation operating under recirculation for one year, while maintaining biomass productivity of 1.2 kg wet algal biomass and sequestration of 0.4 kg CO 2 per day. Furthermore, the exergy balance analysis concluded that without considering solar irradiation, the culture with water recirculation greatly enhanced the rational exergy efficiency, which represents a more sustainable cultivation system for CO 2 capture and utilization.

59 BASIC BIOLOGICAL SCIENCES↗