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DOE OSTI2022

Dissolving salt is not equivalent to applying a pressure on water

Abstract Salt water is ubiquitous, playing crucial roles in geological and physiological processes. Despite centuries of investigations, whether or not water’s structure is drastically changed by dissolved ions is still debated. Based on density functional theory, we employ machine learning based molecular dynamics to model sodium chloride, potassium chloride, and sodium bromide solutions at different concentrations. The resulting reciprocal-space structure factors agree quantitatively with neutron diffraction data. Here we provide clear evidence that the ions in salt water do not distort the structure of water in the same way as neat water responds to elevated pressure. Rather, the computed structural changes are restricted to the ionic first solvation shells intruding into the hydrogen bond network, beyond which the oxygen radial-distribution function does not undergo major change relative to neat water. Our findings suggest that the widely cited pressure-like effect on the solvent in Hofmeister series ionic solutions should be carefully revisited.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2024

Jefferson County Ecological Conservation: Quantifying the Effects of Hydrologic Restoration in the Camas National Wildlife Refuge and Mud Lake Wildlife Management Area

Wetlands in the Camas National Wildlife Refuge and Mud Lake Wildlife Management Area, a rare landscape feature in the Intermountain West, are crucial for migratory birds along the Pacific Flyway, yet these wetlands have experienced a noticeable decline in extent and inundation over the last 40+ years. Partners at the U.S. Fish and Wildlife Service and Idaho Department of Fish and Game have ongoing restoration efforts that are yet to be quantified. To assist these partners, we used NASA Earth observations to quantify change in wetland extent and determine if the restoration projects met the intended impact. The QA_PIXEL band from Landsat 5 Thematic Mapper (TM) and Landsat 8 Operational Land Imager (OLI) was used to identify water. Landsat 8 OLI imagery was also used for classifying landcover in ArcGIS Pro for 2016 and 2020 and to forecast landcover in 2060 using TerrSet’s Land Change Modeler. We also compared lidar data from 2011 and 2019 to detect changes in vegetation height, ground elevation, and surface water levels, and Sentinel-2 Multispectral Instrument (MSI) imagery to detect changes in vegetation health. Classification results indicated overall accuracies over 84% and Kappa indices above 0.80, well surpassing random classification performance. From 2016 to 2020 our classifications showed an 825 acre increase in wetland extent, and our forecasted 2060 model showed a 2795 acre decrease. Combining our partners’ knowledge of the area with our analyses, we created a remote sensing workflow to enhance future monitoring and decision-making. This study demonstrated the feasibility of NASA Earth observations in quantifying wetlands, informing restoration projects, and supporting avian conservation.

Cassidy Bromka↗

DOE OSTI2022

N and P constrain C in ecosystems under climate change: Role of nutrient redistribution, accumulation, and stoichiometry

Abstract We use the Multiple Element Limitation (MEL) model to examine responses of 12 ecosystems to elevated carbon dioxide (CO 2 ), warming, and 20% decreases or increases in precipitation. Ecosystems respond synergistically to elevated CO 2 , warming, and decreased precipitation combined because higher water‐use efficiency with elevated CO 2 and higher fertility with warming compensate for responses to drought. Response to elevated CO 2 , warming, and increased precipitation combined is additive. We analyze changes in ecosystem carbon (C) based on four nitrogen (N) and four phosphorus (P) attribution factors: (1) changes in total ecosystem N and P, (2) changes in N and P distribution between vegetation and soil, (3) changes in vegetation C:N and C:P ratios, and (4) changes in soil C:N and C:P ratios. In the combined CO 2 and climate change simulations, all ecosystems gain C. The contributions of these four attribution factors to changes in ecosystem C storage varies among ecosystems because of differences in the initial distributions of N and P between vegetation and soil and the openness of the ecosystem N and P cycles. The net transfer of N and P from soil to vegetation dominates the C response of forests. For tundra and grasslands, the C gain is also associated with increased soil C:N and C:P. In ecosystems with symbiotic N fixation, C gains resulted from N accumulation. Because of differences in N versus P cycle openness and the distribution of organic matter between vegetation and soil, changes in the N and P attribution factors do not always parallel one another. Differences among ecosystems in C‐nutrient interactions and the amount of woody biomass interact to shape ecosystem C sequestration under simulated global change. We suggest that future studies quantify the openness of the N and P cycles and changes in the distribution of C, N, and P among ecosystem components, which currently limit understanding of nutrient effects on C sequestration and responses to elevated CO 2 and climate change.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2025

In situ atomic-resolution imaging of water vapor–driven multistep oxidation dynamics in strontium cobaltite

Understanding how water vapor interacts with transition metal oxides (TMOs) is critical for tailoring material properties to improve performance and enable new technologies. Despite extensive research efforts, atomic-scale mechanisms underpinning dynamic reactions and reaction-induced phase transitions remain elusive. Here, we use in situ environmental transmission electron microscopy to investigate how water vapor oxidizes vacancy-ordered SrCoO 2.5 at moderately elevated temperatures, demonstrating that water molecules can initiate oxidation more effectively than oxygen under comparable conditions. We discover a distinct “staging” behavior during the oxidation process: A fully ordered intermediate phase, SrCoO 2.75 , forms before transitioning into a near-perovskite SrCoO 3−δ . In addition, antiphase boundaries, originating at step terraces of SrTiO 3 , alleviate strain by creating reversible nanoscale “gaps” during lattice contraction under oxidation, providing a pathway for preserving structural integrity throughout redox cycling. This work provides atomic-level guidance for engineering TMOs by leveraging water vapor to control their redox behavior and tailor functional properties.

Science & Technology - Other Topics↗

DOE OSTI2025

Geothermal Reservoir Simulation Analysis in Support of Electricity Co-Production Feasibility Study at the Blackburn Oil Field, Nevada

Geothermal electricity co-production is a viable option for oil reservoirs producing large water cuts with elevated wellhead temperatures. Repurposing existing oil wells significantly reduces initial investment costs historically associated with geothermal resource utilization. The National Renewable Energy Laboratory (NREL), partnering with Gradient Geothermal, Inc. (formerly known as Transitional Energy) and Grant Canyon Oil and Gas, has been tasked to evaluate the feasibility of geothermal electricity co-production at the Blackburn Oil Field with Organic Rankine Cycle (ORC) generators. The Devonian steady-state reservoir has historically been producing high water cuts of 240 degrees F (115.6 degrees C) observed at the wellhead without documented pressure drawdown or thermal breakthrough. An estimated initial reservoir temperature of approx. 260 degrees F (126.7 degrees C) has been observed in the field and history-matched in a wellbore production analysis and reservoir simulation. Our objective was to develop a conceptual geological model of the subsurface, simulate a natural-state reservoir, model production scenarios, and complete a technical feasibility analysis to accomplish this task. Through extensive modeling and the use of available proprietary and public data, it was possible simulate three scenarios that indicated minimal thermal decline over the duration of a simulated ten-year production and re-injection scheme.

Blackburn Nevada↗

DOE OSTI2024

Geothermal Reservoir Simulation Analysis in Support of Electricity Co-Production Feasibility Study at the Blackburn Oil Field, Nevada: Preprint

Geothermal electricity co-production is a viable option for oil reservoirs producing large water cuts with elevated wellhead-observed temperatures. Repurposing existing oil wells significantly reduces initial investment costs historically associated with geothermal resource utilization. The National Renewable Energy Laboratory (NREL), partnering with Gradient Geothermal, Inc. (formerly known as Transitional Energy) and Grant Canyon Oil and Gas, has been tasked to evaluate the feasibility of geothermal electricity co-production at the Blackburn Oil Field with Organic Rankine Cycle (ORC) generators. The Devonian steady-state reservoir has historically been producing high water cuts of 240 degrees F (115.6 degrees C) observed at the wellhead without documented pressure drawdown or thermal breakthrough. An estimated initial reservoir temperature of approx. 260degreesF (126.7 degrees C) has been observed in the field and history-matched in a wellbore production analysis and reservoir simulation. Our objective was to develop a conceptual geological model of the subsurface, simulate a natural-state reservoir, model production scenarios, and complete a technical feasibility analysis to accomplish this task. Through extensive modeling and the use of available proprietary and public data, it was possible simulate three scenarios that indicated minimal thermal decline over the duration of a simulated ten-year production and re-injection scheme.

Blackburn Nevada↗

NASA NTRS2018

A Predictive Model for Lake Chad Total Surface Water Area Using Remotely Sensed and Modeled Hydrological and Meteorological Parameters and Multivariate Regression Analysis

Lake Chad is an endorheic lake in the Sahel region of Africa at the southern edge of the Sahara Desert. The lake, which is well known for its dramatic decrease in surface area during the 1970s and 1980s, experiences an annual flood resulting in a maximum total surface water area generally during February or March, though sometimes earlier or later. People along the shores of Lake Chad make their living fishing, farming, and raising livestock and have a vested interest in knowing when and how extensive the annual flooding will be, particularly those practicing recession farming in which the fertile ground of previously flooded area is used for planting crops. In this study, the authors investigate the relationship between lake and basin parameters, including rainfall, basin evapotranspiration, lake evapotranspiration, lake elevation, total surface water area, and the previous year’s total surface water area, and develop equations for each dry season month (except November) linking total surface water area to the other parameters. The resulting equations allow the user to estimate the December average monthly total surface water area of the lake in late November, and to make the estimates for January to May in early December. Based on the results of a Leave One Out Cross Validation analysis, the equations for lake area are estimated to have an average absolute error ranging from 5.3 percent (for February estimates) to 7.6 percent (for May estimates).

Lake Chad↗

NASA NTRS2021

The sensitivity of runoff generation to spatial snowpack uniformity in an alpine watershed: Green Lakes Valley, Niwot Ridge Long-Term Ecological Research station

Seasonal water storage in high-elevation alpine catchments are critical sources of water for mountainous regions like the western U.S. The spatial distribution of snow in these topographically complex catchments is primarily governed by orography, solar radiation, and wind redistribution. While the effect of solar shading is relatively consistent from year-to-year, the redistribution of snow due to wind is more variable–capable of producing snowpacks that have varying degrees of uniformity across these hydrologically-important catchments. A reasonable hypothesis is that a warmer climate will cause snowfall to become more dense (i.e. wetter and heavier), possibly leading to less wind redistribution and thus produce a more uniformly distributed snowpack across the landscape. In this study, we investigate the role of increasingly uniform spatial snowpack distributions on streamflow generation in the Green Lakes Valley Niwot Ridge Long Term Ecological Research station, within the headwaters of the Boulder Creek watershed in Colorado. A set of idealized hydrologic simulation experiments driven by reconstructed snowpacks spanning 2001–2014 show that more a more uniform spatial snowpack distribution leads to an earlier melt-out of31 days on average and tends to produce less total streamflow, with maximum decreases as large as 7.5%. Isolating the role of snowpack heterogeneity from melt-season precipitation, we find that snowpack uniformity reduces total streamflow by as much as 13.2%. Reductions in streamflow are largely explained by greater expo-sure to solar radiation in the uniformly distributed case relative to a more heterogeneous snowpack, with this exposure driving shifts towards earlier snowmelt and changes in soil water storage. Overall, we find that the runoff efficiency from shallower snowpacks is more sensitive to the effects of uniformity than deeper snowpacks, which has potential implications for a warming climate where shallower snowpacks and enhanced sensitivities may be present.

Alpine catchment↗

NASA NTRS2000

Space Elevators: Building a Permanent Bridge for Space Exploration and Economic Development

A space elevator is a physical connection from the surface of the Earth to a geo-stationary orbit above the Earth approximately 35,786 km in altitude. Its center of mass is at the geo-stationary point such that it has a 24-hour orbit, and stays over the same point above the equator as the Earth rotates on its axis. The structure is utilized as a transportation and utility system for moving payloads, power, and gases between the surface of the Earth and space. It makes the physical connection from Earth to space in the same way a bridge connects two cities across a body of' water. The space elevator may be an important concept for the future development of space in the latter part of the 21th century. It has the potential to provide mass-transportation to space in the same way highways, railroads, power lines, and pipelines provide mass-transportation across the Earth's surface. The low energy requirements for moving payloads up and down the elevator make it one of only a few concepts that has the potential of lowering the cost to orbit to less than $10 per kilogram. This paper will summarize the findings from a 1999 NASA workshop on Space Elevators held at the NASA Marshall Space Flight Center (MSFC). The workshop was sponsored by the Advanced Projects Office in the Flight Projects Directorate at MSFC, and was organized in cooperation with the Advanced Space Transportation Program at MSFC and the Advanced Concepts Office in the Office of Space Flight at NASA Headquarters. New concepts will be examined for space elevator construction and a number of issues will be discussed that has helped to bring the space elevator concept out of the realm of science fiction and into the realm of possibility. In conclusion, it appears that the space elevator concept may well he possible in the latter part of the 21st century if proper planning and technology development is emphasized to resolve key issues in the development of this advanced space infrastructure concept.

Smitherman, David V., Jr.↗

NASA NTRSDate not supplied

Evaluating Plant Suberin Mutants for Enhanced Water and Nutrient Uptake to Increase Biomass Production Under Elevated CO2 Concentrations

Spaceflight cabin environments such as the International Space Station (ISS) typically have elevated CO2(1500-7000 μmol mol-1), which can affect plant growth and development. On earth, findings from FACE (Free-Air CO2Enrichment) and climate change studies have shown that plants grown at elevated (~ 700 μmol mol-1) CO2contain reduced levels of essential elements such as nitrogen, zinc, and iron. We hypothesized that spacecraft environments with elevated CO2 might likewise result in less nutritious crops for human consumption. Literature showed that quantitative differences in root suberin content could determine the permeability of the internal plant tissues to both water and solutes. To evaluate if there was a correlation between growth under elevated CO2and root suberin content we grew Arabidopsis thaliana, wild type (WT)(col-0), esb1(Enhanced Suberin 1) and horst1(Hydroxylase of Root Suberized Tissue)under ambient (~ 420± 25μmol mol-1) and elevated (800 ± 25, 1600 ± 25, 4000 ± 25 μmol mol-1) CO2concentrations. Comparing the growth of esb1and horst1plants to WT under ambient and elevated CO2concentrations, esb1showed significantly (P-value < 0.05) lower total fresh biomass whereas the horst1exhibited no significant difference. RNA sequencing revealed genes related to water uptake or nutrient availability stress upregulated due to the exposure to 800 and 1600 μmol mol-1CO2.Comparing the elemental composition of leaf tissue between WT and horst1plants grown under elevated CO2,we found an overall decrease in elemental composition for WT, whereas horst1showed an average increase of 30-60 % in the elemental contentsat1600 μmol mol-1compared to plants grown at ambient CO2. In conclusion, our results showed that horst1like modification to edible crops could improve the nutritional (elemental) content to supplement astronaut’s diet.

Anirudha R Dixit↗

NASA NTRS1976

Water resources planning for rivers draining into mobile bay

A hydrodynamic model describing water movement and tidal elevation is formulated, computed, and used to provide basic data about water quality in natural systems. The hydrodynamic model is based on two-dimensional, unsteady flow equations. The water mass is considered to be reasonably mixed such that integration (averaging) in the depth direction is a valid restriction. Convective acceleration, the Coriolis force, wind and bottom interactions are included as contributing terms in the momentum equations. The solution of the equations is applied to Mobile Bay, and used to investigate the influence that river discharge rate, wind direction and speed, and tidal condition have on water circulation and holdup within the bay. Storm surge conditions, oil spill transport, artificial island construction, dredging, and areas subject to flooding are other topics which could be investigated using the mathematical modeling approach.

Ng, S.↗

NASA NTRS2004

ICESat Observations of Inland Surface Water Stage, Slope, and Extent: a New Method for Hydrologic Monitoring

River discharge and changes in lake, reservoir and wetland water storage are critical terms in the global surface water balance, yet they are poorly observed globally and the prospects for adequate observations from in-situ networks are poor (Alsdorf et al., 2003). The NASA-sponsored Surface Water Working Group has established a framework for advancing satellite observations of river discharge and water storage changes which focuses on obtaining measurements of water surface height (stage), slope, and extent. Satellite laser altimetry, which can achieve centimeter-level elevation precision for single, small laser footprints, provides a method to obtain these inland water parameters and contribute to global water balance monitoring. Since its launch in January, 2003 the Ice, Cloud, and land Elevation Satellite (ICESat), a NASA Earth Observing System mission, has achieved over 540 million laser pulse observations of ice sheet, ocean surface, land topography, and inland water elevations and cloud and aerosol height distributions. By recording the laser backscatter from 80 m diameter footprints spaced 175 m along track, ICESat acquires globally-distributed elevation profiles, using a 1064 nm laser altimeter channel, and cloud and aerosol profiles, using a 532 nm atmospheric lidar channel. The ICESat mission has demonstrated the following laser altimeter capabilities relevant to observations of inland water: (1) elevation measurements with a precision of 2 to 3 cm for flat surfaces, suitable for detecting river surface slopes along long river reaches or between multiple crossings of a meandering river channel, (2) from the laser backscatter waveform, detection of water surface elevations beneath vegetation canopies, suitable for measuring water stage in flooded forests, (3) single pulse absolute elevation accuracy of about 50 cm (1 sigma) for 1 degree sloped surfaces, with calibration work in progress indicating that a final accuracy of about 12 cm (1 sigma) will be achieved for clear atmosphere conditions, suitable for detection of stage changes through time, (4) ability to precisely point the spacecraft so as to position the laser profile on the Earth the surface with a cross-track accuracy of 50 m (1 sigma), enabling small water bodies and specific locations to be targeted and re-observed through time, (5) adequate signal levels from specular water surfaces up to 5 degrees off-nadir, enabling complete global access to any location on the Earth's surface from the ICESat repeat orbit by off-nadir pointing, and (6) day and night operation with successful laser ranging to the Earth's surface through thin to moderate cloud cover, enabling more frequent measurements than can be achieved by passive optical sensors. Here we illustrate these capabilities by showing ICESat observations through time for selected river and lake locations.

Harding, David J.↗

DOE OSTI2020

Impacts of anthropogenic gadolinium on the activity of the ammonia oxidizing bacterium Nitrosomonas europaea

Widespread use of gadolinium-based contrast agents in medical imaging has resulted in increased Gd inputs to municipal wastewater treatment plants. Others have reported that typical wastewater treatment does not attenuate Gd, resulting in discharges to natural waters. However, whether elevated Gd impacts the performance of biological treatment has not been investigated. We examined whether gadolinium chloride or Gd chelated with diethylenetriaminepentaacetic acid (DTPA) affected the activity of the model nitrifying bacterium Nitrosomonas europaea. At nominal GdCl 3 additions ranging from 1 to 500 µM, no impact was observed compared to the control. Most (>98%) of the added Gd precipitated, and extracellular GdPO 4 nanoparticles were observed. When chelated with DTPA, Gd remained soluble, but no statistically significant impact on ammonia oxidation was observed until the highest concentrations tested. At 300 and 500 µM Gd-DTPA, a temporary reduction of nitrite production relative to the control (effect size 1.3 mg l -1 and 1.5 mg l -1 , respectively, at 24 h) was seen. By itself, DTPA was highly inhibitory. Modeling suggested that DTPA likely chelated other metals, but adjusting the concentrations of the most abundant metals in the medium, calcium and magnesium, indicated that lowering their free ion activities was probably not the cause of inhibition. Complexation of other essential metals was more likely. Furthermore, our studies indicate that while the low bioavailability of Gd may limit its ecosystem impacts, the role of synthetic ligands used with Gd and other rare earth elements should e considered as the production, use and disposal of these elements increases.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2024

Unveiling the effect of composition on nuclear waste immobilization glasses’ durability by nonparametric machine learning

Abstract Ensuring the long-term chemical durability of glasses is critical for nuclear waste immobilization operations. Durable glasses usually undergo qualification for disposal based on their response to standardized tests such as the product consistency test or the vapor hydration test (VHT). The VHT uses elevated temperature and water vapor to accelerate glass alteration and the formation of secondary phases. Understanding the relationship between glass composition and VHT response is of fundamental and practical interest. However, this relationship is complex, non-linear, and sometimes fairly variable, posing challenges in identifying the distinct effect of individual oxides on VHT response. Here, we leverage a dataset comprising 654 Hanford low-activity waste (LAW) glasses across a wide compositional envelope and employ various machine learning techniques to explore this relationship. We find that Gaussian process regression (GPR), a nonparametric regression method, yields the highest predictive accuracy. By utilizing the trained model, we discern the influence of each oxide on the glasses’ VHT response. Moreover, we discuss the trade-off between underfitting and overfitting for extrapolating the material performance in the context of sparse and heterogeneous datasets.

36 MATERIALS SCIENCE↗

DOE OSTI2025

LiCl–Based Aqueous Electrolytes for Efficient Iron Electrodeposition

This study investigates room temperature, aqueous electrolytes for efficient iron electrodeposition. Specifically, a novel lithium chloride-based electrolyte was identified to suppress hydrogen evolution while promoting fast kinetics of iron electrodeposition, achieving high coulombic efficiency (>90%) at high current densities (>400 mA cm −2 ). Electrochemical analysis of the partial current densities of iron deposition and hydrogen co-evolution revealed that water reduction is kinetically suppressed in this electrolyte, resulting in an increase in the measured coulombic efficiency. Furthermore, a detailed investigation of the iron speciation and their complexation was performed, which revealed that, in concentrated LiCl-containing electrolytes, the ferrous (Fe 2+ ) species coordinate with chloride rather than water, enhancing deposition kinetics. The combined effect of enhanced electrodeposition kinetics and suppressed water activity provide elevated coulombic efficiency. Overall, this paper develops an understanding of anion and cation effects on the mechanism of electrodeposition and hydrogen co-evolution in concentrated electrolytes in search of improved aqueous media (e.g., concentrated LiCl) for efficient metal electro-synthesis.

Lvovich, William [Case Western Reserve University,↗

DOE OSTI2022

Physical Modeling of Coupled Thermohydraulic Behavior of Compacted MX80 Bentonite during Heating

Abstract This paper describes a tank-scale test setup and experimental methodology used to investigate coupled heat transfer and water flow processes during heating of compacted MX80 bentonite to high temperatures. Specifically, a temperature of 200°C was maintained by a cylindrical heating element at the center of a compacted bentonite layer containing an array of temperature, dielectric, and relative humidity sensors. In addition to providing an evaluation of the spatiotemporal variations in temperature, relative humidity, degree of saturation, and global volume, the coupled thermohydraulic properties of the bentonite were assessed. A wetting front was initially observed to move away from the central heater, followed by a drying process until reaching thermohydraulic equilibrium. The soil–water retention curve (SWRC) of the bentonite followed a wetting scanning path before following the primary drying path exhibiting a shift in water retention with elevated temperature. Results from the tank-scale test can be used for validation of numerical simulations of drying processes in the engineered barrier system of a high-level radioactive waste geological disposal repository and confirm that a temperature-dependent hysteretic SWRC with scanning paths is required to accurately capture the bentonite response.

Engineering↗

DOE OSTI2021

Construction Support for New Slab Creek Powerhouse Project (Final Technical Report)

The Sacramento Municipal Utility District (SMUD) has constructed a new powerhouse and Boating Flow Release Facility (BFRF) ¼ mile downstream of the existing Slab Creek Dam with the assistance of grant funding from the Department of Energy in the amount of $1.5 million. Slab Creek Dam impounds 16,600 acre-feet of storage and has a normal full pool elevation of 1850ft. Water is conveyed from Slab Creek Reservoir through a 4.9 mile power tunnel to the 224 MW White Rock Powerhouse which discharges into Chili Bar Reservoir. A small 450 kW powerhouse located at Slab Creek Dam utilizes the original license in-stream flow requirement. The new license (FERC Project No. 2101-084) requires significantly more instream flows immediately below the dam for aquatic preservation and recreational flows over the original license. The terms of the new license allow the Slab Creek Powerhouse to utilize the original required dam releases, while the new South Fork Powerhouse will use the new instream flow requirements above the original license requirement. The South Fork Powerhouse routes flows back to the South Fork of the American River via a new penstock that is tied into the White Rock Tunnel at Adit #3. This new penstock bifurcates at the Adit #3 portal with one leg going to the BFRF and the other to the new powerhouse. The South Fork Powerhouse is a single generating unit with a capacity of 2.98 kVA. The BFRF is valve house with an energy dissipation chamber for a 60” fixed cone valve capable of passing 1,300 cfs for meeting the recreational flow requirements of the license.

power tunnel↗

NASA NTRS1983

Sedimentary processes and crustal cycling on Venus

Sediment exists on the Venus surface. It is observed in Venera images between outcrops and boulders of sedimentary rocks. Sediment is produced by pyroclastic volcanism and chemical weathering. Chemical weathering is driven by an enhanced activity of water and an elevated surface temperature. Sediment is transported by wind action and lithified by cementration and diagenesis. Cementation may be by carbonate or silica cement; diagenesis may be products of chemical weathering acting as cement, or by compaction and recrystallization of sediment into a texture with interlocking grains. Sediment may be transported from the top of sialic continents (such as Ishtar) to the modal plains where it is deposited, lithified, and integrated into thy local crust. As new layers are added, the bottom of the crust melts and is, in part, returned to the mantle. A steady-state chemical exchange might exist by this mechanism of crustal cycling that links atmosphere, continents, modal plains, and mantle.

Warner, J. L.↗