Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “tunable”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Stratospheric species measurements with tunable diode laser absorption spectroscopy

A balloon-borne instrument for stratospheric research has been developed with the capability to simultaneously measure several chemically related species in situ, for a full diurnal cycle. The instrument utilizes tunable infrared diode lasers (TDLs) to provide the radiation in selected wavelength regions for sensitive absorption spectroscopy over a one-km round-trip path. The TDL radiation is directed to a remote retroreflector which is lowered 500 m below the instrument gondola. A HeNe laser and co-aligned TV camera with CID imaging are used for retroreflector tracking. Currently the instrument operates with two TDLs, and the capability exists to measure four stratospheric species: NO, NO2, O3, and H2O. The number of operating TDLs can be expanded to four, resulting in the possibility of measuring several additional trace species.

Menzies, R. T.↗
NASA NTRS1983

Heterodyne frequency measurements and frequency calibration standards for tunable diode lasers

New frequency calibration tables are required to keep abreast of the resolution attainable by currently available tunable lasers. One key to the generation of tables with requisite accuracy involves accurate heterodyne frequency measurements; another key consists of reliable fitting and analysis. Coordinated activity in NBS involves selection of suitable molecular calibration candidates, their frequency measurement and analysis, and dissemination of the results in the form of frequency calibration tables. Current status of these efforts is described.

Wells, J. S.↗
NASA NTRS1983

Tunable diode laser optogalvanic spectroscopy of molecules

The laser optogalvanic (LOG) technique for studying molecular spectra has been extended for the first time to the infrared wavelength region. Portions of the NH3 nu-2 band at 9.5 microns and the NO2 nu-3 band at 6.2 microns have been recorded at Doppler-limited resolution using CW tunable diode lasers to probe dc electrical discharges in pure NH3 and an NO2/He gas mixture. Using adjustable electrode positions and an orthogonal geometry between the probe laser and the discharge axis, two contributions to the optogalvanic signal are identified: one which corresponds to an increase in discharge impedance and is seen only for irradiation of the negative glow region; and a second which corresponds to a decrease in discharge impedance and is seen for irradiation of all other discharge regions.

Webster, C. R.↗
NASA NTRS1983

A tunable coherent CO2 lidar for measurements of atmospheric aerosol backscatter and attenuation

A coherent laser radar system using a grating-tunable, injection-locked TEA-CO2 transmitter is being used to measure the altitude dependence of atmospheric aerosol backscatter and attenuation at a variety of CO2 laser wavelengths in the 9-11 micron region. Injection control of the TEA-CO2 laser allows one to obtain Single-Longitudinal-Mode (SLM) pulses which will follow the frequency of the injected radiation if the TEA laser cavity length is adjusted so that a cavity resonance is in proximity with the injected signal frequency, and if various additional conditions are satisfied. Requirements for generation of SLM pulses in this manner from a TEA CO2 laser with an unstable resonator cavity will be discussed. Procedures used for quantitative range-gated measurements of aerosol backscatter and attenuation will also be discussed.

Menzies, R. T.↗
NASA NTRS1985

High sensitivity detection of trace gases at atmospheric pressure using tunable diode lasers

A detailed study of the detection of trace gases at atmospheric pressure using tunable diode lasers is described. The influence of multipass cells, retroreflectors and topographical targets is examined. The minimum detectable infrared absorption ranges from 0.1 percent for a pathlength of 1.2 km to 0.01 percent over short pathlengths. The factors which limit this sensitivity are discussed, and the techniques are illustrated by monitoring atmospehric CO2 and CH4.

Reid, J.↗
NASA NTRS1985

Brewster-plate spoiler - A novel method for reducing the amplitude of interference fringes that limit tunable-laser absorption sensitivities

A simple method is described for substantially reducing the amplitude of interference fringes that limit the sensitivities of tunable-laser high-resolution absorption spectrometers. A lead-salt diode laser operating in the 7-micron region is used with a single Brewster-plate spoiler to reduce the fringe amplitude by a factor of 30 and also to allow the detection of absorptances 0.001 percent in a single laser scan without subtraction techniques, without complex frequency modulation, and without distortion of the molecular line-shape signals. Application to multipass-cell spectrometers is described.

Webster, C. R.↗
NASA NTRS1985

Tunable diode laser mesurements of widths of air- and nitrogen-broadened lines in the nu(4) band of C-13H4

Tunable diode laser measurements of air-broadened and N2-broadened halfwidths are reported for 23 lines in the nu(4) band of C-13H4, between 1260 and 1360/cm. For all lines, at least three scans of each of four or more pressures were recorded. The experimental halfwidths presently obtained for C-13H4 are both larger and smaller than the U.S. Air Force Geophysics Laboratory values.

Devi, V. M.↗
NASA NTRS1986

Rotational collisional narrowing in an infrared CO2 Q branch studied with a tunable-diode laser

A tunable diode laser has been used to observe rotational collisional narrowing or line mixing in the IR absorption spectrum of the Q branch of the (1 1 exp-1 0,0 3 exp-1 0) sub II - 0 0 exp-0 0 band of CO2 at 1932.47/cm over the 100-745 Torr pressure range. The observed absorption coefficients below the band origin are up to 80 percent lower than those calculated on the basis of an isolated Lorentz line approxmation. A simple fitting law is derived for the state-to-state, rotationally inelastic rate constants, on the basis of the known line broadening coefficients; a calculation of the mixing using these rates agrees with observed absorption coefficients to within several percent.

Strow, L. L.↗
NASA NTRS1986

Tunable diode laser measurements of air- and N2-broadened halfwidths in the nu2 band of D2O

The first experimental measurements of air- and N2-broadened halfwidths of single lines in the nu2 band of D2O were obtained at room temperature, using a semiconductor tunable diode laser operating in the 1250-1340/cm region. The difference observed between air- and N2-broadened halfwidths may be attributed to the different quadrupole moments of the perturbing gas constituents. It is noted that both the airand N2-broadened halfwidths for the two ortho-para doublets are the same, within the present experimental uncertainties.

Devi, V. M.↗
NASA NTRS1986

Tunable diode laser measurements of air-broadened linewidths in the nu6 band of H2O2

Air-broadened half-widths of 18 transitions in the nu6 band of H2O2 between 1252/cm and 1291/cm have been determined from spectra recorded at room temperature using a tunable diode laser spectrometer. The preparation of the H2O2 gas samples for the measurements is described, and the data analysis is discussed, including the derivation of Lorentz broadening coefficients and the contribution of molecular collisions to the measured Lorentz half-widths. For the 18 transitions, the half-widths varied from 0.0923/cm/atm to 0.1155/cm/atm at 296 K, with a mean value of 0.1020/cm/atm. An error of less than 10 percent is estimated for these results.

Malathy Devi, V.↗
NASA NTRS1986

Absolute intensities and self-, N2-, and air-broadened Lorentz halfwidths for selected lines in the nu3 band of (C-12)H3D from measurements with a tunable diode laser spectrometer

Absolute intensities and self-, air- and N2-broadened half-widths have been determined for the first time for individual lines in the nu3(A1) band of (C-12)H3D near 7.6 microns from measurements of individual vibration-rotation lines using a tunable diode laser spectrometer. The intensity measurements are believed to be accurate to within three percent. Within experimental uncertainties, equal broadening efficiencies are found for both air and nitrogen. Self-broadened half-widths determined for three transitions yield an average half-width value of 0.803 + or -0.0010/cm/atm at 296 K.

Malathy Devi, V.↗
NASA NTRS1985

Tunable diode laser Stark modulation spectroscopy for rotational assignment of the HNO3 7.5-micron band

The technique of Stark modulation spectroscopy for unraveling and assigning rotationally resolved dense molecular spectra has been employed using a tunable diode laser (TDL) source. Doppler-limited absorption and Stark modulation spectra of the HNO3 7.5-micron band near the 1326/cm band origin are presented with preliminary values of the excited-state rovibrational constants derived from both TDL and Bomem Fourier transform IR spectra.

Webster, C. R.↗
NASA NTRS1986

Tunable solid-state laser technology for applications to scientific and technological experiments from space

Current plans for the Earth Observing System (EOS) include development of a lidar facility to conduct scientific experiments from a polar orbiting platforms. A recommended set of experiments were scoped, which includes techniques of atmospheric backscatter (Lidar), Differential Absorption Lidar (DIAL), altimetry, and retroranging. Preliminary assessments of the resources (power, weight, volume) required by the Eos Lidar Facility were conducted. A research program in tunable solid state laser technology was developed, which includes laser materials development, modeling and experiments on the physics of solid state laser materials, and development of solid state laser transmitters with a strong focus on Eos scientific investigations. Some of the system studies that were conducted which highlight the payoff of solid state laser technology for the Eos scientific investigations will be discussed. Additionally, a summary of some promising research results which have recently emerged from the research program will be presented.

Allario, F.↗
NASA NTRS1986

Airborne Lidar measurements of the atmospheric pressure profile with tunable Alexandrite lasers

The first remote measurements of the atmospheric pressure profile made from an airborne platform are described. The measurements utilize a differential absorption lidar and tunable solid state Alexandrite lasers. The pressure measurement technique uses a high resolution oxygen A band where the absorption is highly pressure sensitive due to collision broadening. Absorption troughs and regions of minimum absorption were used between pairs of stongly absorption lines for these measurements. The trough technique allows the measurement to be greatly desensitized to the effects of laser frequency instabilities. The lidar system was set up to measure pressure with the on-line laser tuned to the absorption trough at 13147.3/cm and with the reference laser tuned to a nonabsorbing frequency near 13170.0/cm. The lidar signal returns were sampled with a 200 range gate (30 vertical resoltion) and averaged over 100 shots.

Korb, C. L.↗
NASA NTRS1986

Multifrequency dial sensing of the atmospheric gaseous constituents using the first and second harmonics of a tunable CO2 laser radiation

The results of field measurements of concentration of some gaseous components of the atmosphere along the paths, in Sofia, Bulgaria, using a gas analyzer based on the use of a CO2 laser radiation frequency-doubled with ZnGeP2 monocrystals are presented. The gas analyzer is a traditional long path absorption meter. Radiation from the tunable CO2 laser of low pressure and from an additional He-Ne laser is directed to a colliminating hundredfold Gregori telescope with a 300 mm diameter of the principal mirror. The dimensions of the mirrors of a retroreflector 500 x 500 mm and a receiving telescope allow one to totally intercept the beam passed through the atmospheric layer under study and back.

Zuev, V. E.↗
NASA NTRS1986

Tunable-diode laser absorption spectrometry

Tunable-diode laser absorption spectrometry (TDLAS) affords a number of advantages for atmospheric measurements. It is a universal method, applicable, in principle, to all gases of atmospheric interest. Because of its extremely high spectral resolution it provides unequivocal identification of the target species, with no interferences from other gases. It provides real-time, in situ measurements with time resolutions better than 1 minute. The sensitivity of the current TDLAS system is marginally capable of measuring HO2. This species exists in the troposphere at concentrations which are up to 2 orders of magnitude higher than those of HO and, in addition, is much less susceptible to removal by the surfaces of the instrument and its sampling system. HO2 is an important HO sub x species in its own right but can also give direct information on the HO concentration by virtue of the rapid partitioning between these two species. The addition of the high-frequency modulation technique to the TDLAS system would ensure its ability to measure HO2 under most atmospheric conditions. The ability of the TDLAS to measure hydrogen peroxide (H2O2) in the ambient atmosphere was also demonstrated. H2O2 measurements give a clear indication of HO sub x mixing ratios and are also important as a photolytic source of HO and as an important oxidant for other atmospheric consitituents such as SO2.

Schiff, H. I.↗
NASA NTRS1987

Precision tunable resonant microwave cavity

A tunable microwave cavity containing ionizable metallic vapor or gases and an apparatus for precisely positioning a microwave coupling tip in the cavity and for precisely adjusting at least one dimension of the cavity are disclosed. With this combined structure, resonance may be achieved with various types of ionizable gases. A coaxial probe extends into a microwave cavity through a tube. One end of the tube is retained in a spherical joint attached in the cavity wall. This allows the coaxial probe to be pivotally rotated. The coaxial probe is slideable within the tube thus allowing the probe to be extended toward or retracted from the center of the cavity.

Nakanishi, Shigeo↗
NASA NTRS1986

Laboratory measurement of the rotational spectrum of the OH radical with tunable far-infrared research

Rotational and fine-structure transitions between the low rotational levels of the OH radical in its X 2Pi state have been observed in absorption in the laboratory. It has thus been possible to measure the frequencies of these transitions directly. The observations were made with tunable far-infrared radiation generated by mixing two chosen CO2 laser frequencies in a metal-insulator-metal diode; the far-infrared difference frequency was radiated from the diode's whisker antenna. The measurements have an accuracy of a few hundred kHz. They both confirm and improve on the best previous estimates, which were obtained by extrapolation of laser magnetic resonance data.

Brown, J. M.↗