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NASA NTRS1992

EC 19314 - 5915 - A bright, eclipsing cataclysmic variable from the Edinburgh-Cape Blue Object Survey

A deeply eclipsing cataclysmic variable, with an orbital period of 4.75 hr, has been discovered in the southern Edinburgh-Cape Blue Object Survey. The star, EC 19314 - 5915, lies close to the positional constraints of a previously unidentified HEAO-1 hard X-ray source, 1H1930 - 5989. Its optical spectrum is unusual in that it shows, apart from the emission lines characteristic of a novalike, or dwarf nova cataclysmic variable (Balmer, He I and He II), metallic absorption lines typical of a late-G star. The individual time-resolved spectra, with the tertiary absorption lines removed, show absorption reversals in the Balmer emission lines, increasing in strength for the higher series. The Balmer emission radial velocities are therefore severely distorted in comparison to the He II 4686-A emission and He I 4471-A absorption radial velocity curves. An independent distance estimate of about 600 pc is derived for EC19314 - 5915, from the spectroscopic parallax of the third star.

Buckley, D. A. H.↗

NASA NTRS1993

Photothermal Monitoring Of Curing Of Polymers

Time-resolved infrared radiometry (TRIR) adapted to monitoring curing of some polymers in production. Proposal part of continuing effort to perfect production of hydroxy-terminated polybutadiene for use in liners of solid-fuel rocket motors. Applicable to monitoring changing states of many other materials in process. TRIR, non-contact technique implemented with remotely situated equipment and better suited to use in production.

Rooney, Michael↗

NASA NTRS1992

Experimental investigation of a simulated LOX injector flow field and other nonintrusive measurement efforts

Efforts to improve the characteristics of fuel-oxidizer mixing in liquid rocket combustors have lead to a swirl element design for a liquid oxygen injector which is being considered for use on the STME. For the design which is the subject of this investigation, the oxygen enters the injector element perpendicular to the injector axis and nearly tangent to the circular injector wall. This swirl element is at one end of a tube and the injector exit is at the other. This geometric configuration creates a plume in the shape of a conical sheet. This sheet is either primarily contiguous liquid or droplets depending on the pressure drop in the injector and the distance from the injector exit. Probe-based devices such as two-dimensional grid patternators have been used to investigate simulated LOX injector flow fields (Hulka). The primary work described herein is an effort to use optical techniques to investigate the plume of a swirl injector element. For this investigation, a high pressure (500 psig) cold flow test facility was constructed. Water was used as the LOX simulate and air pressure was used to drive the injector flow field. Laser-induced fluorescence (LIF) from dye seeded into the water was used to obtain quantitative measurements of the time-averaged water concentration distribution in the plume. Scattered laser light and LIF were used for time averaged plume visualization and scattered light from a strobe with a 1 microsecond pulse was used for time-resolved plume visualization. During the Summer Faculty Fellowship for which this report was developed, an additional effort, unrelated to the swirl injector investigation, was made to resolve fluctuations in the combustion product composition in the exhaust of a hybrid rocket motor. A brief description of this effort is included herein.

Hartfield, Roy J., Jr.↗

NASA NTRS1992

Ground-based observations of 951 Gaspra: CCD lightcurves and spectrophotometry with the Galileo filters

This paper reports the observations of 951 Gaspra carried out at the European Southern Observatory (La Silla, Chile) during the 1991 apparition, using the DLR CCD Camera equipped with a spare set of the Galileo SSI filters. Time-resolved spectrophotometric measurements are presented. The occurrence of spectral variations with rotation suggests the presence of surface variegation.

Mottola, Stefano↗

NASA NTRS1992

Wake-induced unsteady stagnation-region heat-transfer measurements

Results of an experimental investigation of wake-induced unsteady heat transfer in the stagnation region of a cylinder are presented. A quasi-steady representation of the stator/rotor interaction in a gas turbine using two stationary cylinders in crossflow is created. Time-averaged and time-resolved heat-transfer results are obtained over a wide range of Reynolds numbers at two Mach numbers: one incompressible and one transonic. The augmentation of the heat transfer in the stagnation region due to wake unsteadiness is documented by comparison with isolated cylinder tests. The time-averaged heat-transfer rate at the stagnation line, expressed in terms of the Frossling number, is found to reach a maximum independent of the Reynolds number. The power spectra and cross correlation of the heat-transfer signals in the stagnation region reveal the importance of large vortical structures shed from the upstream wake generator.

Magari, P. J.↗

NASA NTRS1991

Development of a Rayleigh scattering system for temperature measurements in combustor flows

A dual line laser induced Rayleigh scattering system has been developed to be used in high temperature gas flows such as in combustors, and preliminary tests have been performed in a hot air jet. The qualification measurements included the collection and analysis of Rayleigh signal for time-resolved gas temperature over the two lines of a copper-vapor laser. The dual line signal collection technique is a feature to be used in detecting and discriminating the surface scattered laser light in the Rayleigh signal. Optical fibers are used to transmit the laser beam to the optical probe bench and to carry the collected signal from the bench to the housing of the signal sensors. Incident laser intensity at the probe volume is measured for both lines at each pulse of the laser. This information is used to normalize the signal. Good agreement has been obtained between the two line Rayleigh scattering and thermocouple results in the particle free co-flowing air jet.

Otugen, M. V.↗

NASA NTRS1993

A ROSAT observation of NGC 5548

We present a detailed spectral and temporal analysis of a long ROSAT PSPC pointing centered on the bright Seyfert 1 galaxy NGC 5548. The spectrum is particularly complex, with a two-component model favored, confirming the existence of the soft excess in this source. In addition, an absorption feature arising from highly ionized oxygen in the line of sight has been detected, consistent with an origin in the 'warm absorber' which has been found to be a common feature in Seyfert galaxies observed by Ginga. The energy and depth of the feature should allow us to constrain the density and geometry of the absorbing gas, which may lie close to the central continuum source. NGC 5548 was in a low X-ray state during the observation, brightening by a factor of about 2 on a time-scale of about 2 d. Time-resolved spectral analysis shows a change in the ratio of the hard and soft fluxes, consistent with reprocessing models.

Nandra, K.↗

NASA NTRS1993

The reaction of atomic hydrogen with germane - Temperature dependence of the rate constant and implications for germane photochemistry in the atmospheres of Jupiter and Saturn

Studies of the formation and loss processes for GeH4 are required in order to provide data to help determine the major chemical form in which germanium exists in the atmospheres of Jupiter and Saturn. The reaction of hydrogen atoms with germane is one of the most important of these reactions. The absolute rate constant for this reaction as a function of temperature and pressure is studied. Flash photolysis of dilute mixtures of GeH4 in argon, combined with time-resolved detection of H atoms via Lyman alpha resonance fluorescence, is employed to measure the reaction rate. The reaction is shown to be moderately rapid, independent of total pressure, but possessing a positive temperature dependence.

Nava, David F.↗

NASA NTRS1992

Chemistry and kinetics of I2 loss in urine distillate and humidity condensate

Time-resolved molecular absorption spectrophotometry of iodinated ersatz humidity condensates and iodinated ersatz urine distillates across the UV and visible spectral regions are used to investigate the chemistry and kinetics of I2 loss in urine distillate and humidity condensate. Single contaminant systems at equivalent concentrations are also employed to study rates of iodine. Pseudo-first order rate constants are identified for ersatz contaminant model mixtures and for individual reactive constituents. The second order bimolecular reaction of elemental iodine with formic acid, producing carbon dioxide and iodine anion, is identified as the primary mechanism underlying the decay of residual I2 in ersatz humidity concentrate.

Atwater, James E.↗

NASA NTRS1992

Radiative lifetimes in B I using ultraviolet and vacuum-ultraviolet laser-induced fluorescence

Radiative lifetimes of the eight lowest even parity levels in the doublet system of B I are measured using time-resolved laser-induced fluorescence in the UV and VUV on an atomic beam of boron. The accurate lifetimes provide a base for improved determination of absolute transition probabilities in B I. The techniques described are broadly applicable to measurement of lifetimes of levels with transitions in the visible, UV, and VUV in almost any element.

O'Brian, T. R.↗

NASA NTRS1991

Kinetics of the reactions of alkyl radicals with HBr and DBr

The kinetics of the reactions CH3 + HBr, CD3 + HBr, CH3 + DBr, C2H5 + HBr, C2H5 + DBr, t-C4H9 + HBr, and t-C4H9 + DBr is studied as a function of temperature (257-430 K) and pressure (10-300 Torr of N2). Time-resolved resonance fluorescence detection of Br atom appearance following laser flash photolysis of RI was used in the experiments. Results show that the rates of all reactions increased as the temperature decreased.

Nicovich, J. M.↗

NASA NTRS1992

Role of a microbore capillary column in the development of a portable gas chromatograph-mass spectrometer

An approach to the development of a high-performance, field portable gas chromatograph-mass spectrometer is presented which is based on a combination of a short microbore capillary column and a miniaturized, light-weight focal plane mass spectrograph. Performance results of the short microbore column for the mixture separation of the major pollutants and data on time-resolved mass spectral measurements of overlapped gas chromatograph peaks are reported.

Sinha, Mahadeva P.↗

NASA NTRS1993

General technique for discrete retardation-modulation polarimetry

The general theory and rigorous solutions of the Stokes parameters of light of a new technique in time-resolved ellipsometry are outlined. In this technique the phase of the linear retarder is stepped over three discrete values over a time interval for which the Stokes vector is determined. The technique has an advantage over synchronous detection techniques, as it can be implemented as a digitizable system.

Saxena, Indu↗

NASA NTRS1993

Laser flash photolysis studies of atmospheric free radical chemistry using optical diagnostic techniques

Some recent studies carried out in our laboratory are described where laser flash photolytic production of reactant free radicals has been combined with reactant and/or product detection using time-resolved optical techniques to investigate the kinetics and mechanisms of important atmospheric chemical reactions. Discussed are (1) a study of the radical-radical reaction O + BrO yields Br + O2 where two photolysis lasers are employed to prepare the reaction mixture and where the reactants O and BrO are monitored simultaneously using atomic resonance fluorescence to detect O and multipass UV absorption to detect BrO; (2) a study of the reaction of atomic chlorine with dimethylsulfide (CH3SCH3) where atomic resonance fluorescence detection of Cl is employed to elucidate the kinetics and tunable diode laser absorption spectroscopy is employed to investigate the HCl product yield; and (3) a study of the aqueous phase chemistry of Cl2(-) radicals where longpath UV absorption spectroscopy is employed to investigate the kinetics of the Cl2(-) + H2O reaction.

Wine, Paul H.↗

NASA NTRS1979

Experimental Studies of Radiative Base Heating of a Jovian Entry Model

To verify the validity of the theoretical predictions of Park on radiative base heating rates, two types of models are tested in the absence of ablation in shock tube flows which simulate the Jovian entry environments. The radiative fluxes are measured by pyroelectric radiometers imbedded in the models in a stream consisting of 10% hydrogen in a bath of either neon or argon. In addition, time-resolved photographs are taken to obtain information on the structure of base flows needed in Park's theory. The experimental data show that the radiative base heat fluxes are significant fractions of the radiative fluxes at the front stagnation point, the ratio being dependent upon Mach number and the configuration of the models. When the effects of the model geometry and Mach number are accounted for, the present experimental results agree with the theoretical predictions of Park.

Shirai, Hiroyuki↗

NASA NTRS1992

Pathways of proton release in the bacteriorhodopsin photocycle

The pH dependencies of the rate constants in the photocycles of recombinant D96N and D115N/D96N bacteriorhodopsins were determined from time-resolved difference spectra between 70 ns and 420 ms after photoexcitation. The results were consistent with the model suggested earlier for proteins containing D96N substitution: BR hv----K----L----M1----M2----BR. Only the M2----M1 back-reaction was pH-dependent: its rate increased with increasing [H+] between pH 5 and 8. We conclude from quantitative analysis of this pH dependency that its reverse, the M1----M2 reaction, is linked to the release of a proton from a group with a pKa = 5.8. This suggests a model for wild-type bacteriorhodopsin in which at pH greater than 5.8 the transported proton is released on the extracellular side from this as yet unknown group and on the 100-microseconds time scale, but at pH less than 5.8, the proton release occurs from another residue and later in the photocycle most likely directly from D85 during the O----BR reaction. We postulate, on the other hand, that proton uptake on the cytoplasmic side will be by D96 and during the N----O reaction regardless of pH. The proton kinetics as measured with indicator dyes confirmed the unique prediction of this model: at pH greater than 6, proton release preceded proton uptake, but at pH less than 6, the release was delayed until after the uptake. The results indicated further that the overall M1----M2 reaction includes a second kinetic step in addition to proton release; this is probably the earlier postulated extracellular-to-cytoplasmic reorientation switch in the proton pump.

NASA Discipline Exobiology↗

NASA NTRS1992

Reaction cycle and thermodynamics in bacteriorhodopsin

Light causes the all-trans to 13-cis isomerization of the retinal in bacteriorhodopsin; the thermal relaxation leading back to the initial state drives proton transport first via proton transfer between the retinal Schiff base and D85 and then between the Schiff base and D96. The reaction sequence and thermodynamics of this photocycle are described by measuring time-resolved absorption changes with a gated multichannel analyzer between 100 ns and 100 ms, at six temperatures between 5 degrees C and 30 degrees C. Analysis of the energetics of the chromophore reaction sequence is on the basis of a recently proposed model (Varo & Lanyi, Biochemistry 30, 5016-5022, 1991) which consists of a single cycle and many reversible reactions: BR -hv-->K<==>L<==>M1-->M2<==>N<==>O-->BR. The existence of the M1-->M2 reaction, which functions as the switch in the proton transfer, is confirmed by spectroscopic evidence. The calculated thermodynamic parameters indicate that the exchange of free energy between the protein and the protons is at the switch step. Further, a large entropy decrease at this reaction suggests a protein conformation change which will conserve delta G for driving the completion of the reaction cycle. The results provide insights to mechanism and energy coupling in this system, with possible relevance to the general question of how ion pumps function.

Review↗

NASA NTRS1992

MBE growth technology for high quality strained III-V layers

III-V films are grown on large automatically perfect terraces of III-V substrates which have a different lattice constant, with temperature and Group II and V arrival rates chosen to give a Group III element stable surface. The growth is pulsed to inhibit Group III metal accumulation to low temperature, and to permit the film to relax to equilibrium. The method of the invention 1) minimizes starting step density on sample surface; 2) deposits InAs and GaAs using an interrupted growth mode (0.25 to 2 mono-layers at a time); 3) maintains the instantaneous surface stoichiometry during growth (As-stable for GaAs, In-stable for InAs); and 4) uses time-resolved RHEED to achieve aspects (1)-14 (3).

Grunthaner, Frank J.↗