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At least 181 records · Page 10

Time-dependent non-equilibrium dielectric response in QM/continuum approaches

The Polarizable Continuum Models (PCMs) are some of the most inexpensive yet successful methods for including the effects of solvation in quantum-mechanical calculations of molecular systems. However, when applied to the electronic excitation process, these methods are restricted to dichotomously assuming either that the solvent has completely equilibrated with the excited solute charge density (infinite-time limit), or that it retains the configuration that was in equilibrium with the solute prior to excitation (zero-time limit). This renders the traditional PCMs inappropriate for resolving time-dependent solvent effects on non-equilibrium solute electron dynamics like those implicated in the instants following photoexcitation of a solvated molecular species. To extend the existing methods to this non-equilibrium regime, we herein derive and apply a new formalism for a general time-dependent continuum embedding method designed to be propagated alongside the solute’s electronic degrees of freedom in the time domain. Given the frequency-dependent dielectric constant of the solvent, an equation of motion for the dielectric polarization is derived within the PCM framework and numerically integrated simultaneously with the time-dependent Hartree fock/density functional theory equations. Results for small molecular systems show the anticipated dipole quenching and electronic state dephasing/relaxation resulting from out-of-phase charge fluctuations in the dielectric and embedded quantum system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Developments in time-resolved x-ray research at APS beamline 7ID

The 7ID beamline of the Advanced Photon Source (APS) is dedicated to time-resolved research using x-ray imaging, scattering, and spectroscopy techniques. Time resolution is achieved via gated detectors and/or mechanical choppers in conjunction with the time structure of the x-ray beam. Three experimental hutches allow for a wide variety of experimental setups. Major areas of research include atomic, molecular, and optical physics; chemistry; condensed matter physics in the bulk, thin film, and surface regimes; and fluid-spray dynamics. Recent developments in facilities at 7ID include a high-power, high-repetition-rate picosecond laser to complement the 1 kHz ultrafast laser. For the ultrafast laser, a newly commissioned optical parametric amplifier provides pump wavelength from 0.2 to 15 µm with energy per pulse up to 200 µJ. A nanodiffraction station has also been commissioned, using Fresnel zone-plate optics to achieve a focused x-ray spot of 300 nm. This nanoprobe is not only used to spatially resolve the evolution of small features in samples after optical excitation, but also has been combined with an intense THz source to study material response under ultrafast electric fields.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Precision cosmology with time delay lenses: High resolution imaging requirements

Lens time delays are a powerful probe of cosmology, provided that the gravitational potential of the main deflector can be modeled with sufficient precision. Recent work has shown that this can be achieved by detailed modeling of the host galaxies of lensed quasars, which appear as ``Einstein Rings'' in high resolution images. The distortion of these arcs and counter-arcs, as measured over a large number of pixels, provides tight constraints on the difference between the gravitational potential between the quasar image positions, and thus on cosmology in combination with the measured time delay. We carry out a systematic exploration of the high resolution imaging required to exploit the thousands of lensed quasars that will be discovered by current and upcoming surveys with the next decade. Specifically, we simulate realistic lens systems as imaged by the Hubble Space Telescope (HST), James Webb Space Telescope (JWST), and ground based adaptive optics images taken with Keck or the Thirty Meter Telescope (TMT). We compare the performance of these pointed observations with that of images taken by the Euclid (VIS), Wide-Field Infrared Survey Telescope (WFIRST) and Large Synoptic Survey Telescope (LSST) surveys. We use as our metric the precision with which the slope γ' of the total mass density profile ρ tot ∝ r–γ' for the main deflector can be measured. Ideally, we require that the statistical error on γ' be less than 0.02, such that it is subdominant to other sources of random and systematic uncertainties. We find that survey data will likely have sufficient depth and resolution to meet the target only for the brighter gravitational lens systems, comparable to those discovered by the SDSS survey. For fainter systems, that will be discovered by current and future surveys, targeted follow-up will be required. Furthermore, the exposure time required with upcoming facilitites such as JWST, the Keck Next Generation Adaptive Optics System, and TMT, will only be of order a few minutes per system, thus making the follow-up of hundreds of systems a practical and efficient cosmological probe.

79 ASTRONOMY AND ASTROPHYSICS↗

ETROC1: the first full chain precision timing prototype ASIC for CMS MTD endcap timing layer upgrade

We present the design and characterization of the first fullchain precision timing prototype ASIC, named ETL Readout Chipversion 1 (ETROC1) for the CMS MTD endcap timing layer (ETL)upgrade. The ETL utilizes Low Gain Avalanche Diode (LGAD) sensors todetect charged particles, with the goal to achieve a time resolutionof 40–50 ps per hit, and 30–40 ps per track with hits from twodetector layers. The ETROC1 is composed of a 5 × 5 pixelarray and peripheral circuits. The pixel array includes a4 × 4 active pixel array with an H-tree shaped networkdelivering clock and charge injection signals. Each active pixel iscomposed of various components, including a bump pad, a chargeinjection circuit, a pre-amplifier, a discriminator, adigital-to-analog converter, and a time-to-digital converter. Thesecomponents play essential roles as the front-end link in processingLGAD signals and measuring timing-related information. Theperipheral circuits provide clock signals and readoutfunctionalities. The size of the ETROC1 chip is7 mm× 9 mm. ETROC1 has been fabricated in a 65 nmCMOS process, and extensively tested under stimuli of chargeinjection, infrared laser, and proton beam. The time resolution ofbump-bonded ETROC1 + LGAD chipsets reaches 42–46 ps per hit in thebeam test.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Practical Implementation of Synchrophasor Based Real-Time Contingency Analysis

Synchrophasor technology is increasingly accepted and adopted by the power industry. Linear State Estimator (LSE) is a recent development in the synchrophasor industry, and has been integrated and deployed at control centers, providing improved coverage and greater reliability from synchrophasor systems. This paper describes a first-of-a-kind synchrophasor based real-time contingency analysis (RTCA), which takes the LSE solved case as input, and then solves the what-if cases to provide timely information about impending grid problems to system operators. Test results on IEEE 39 bus and 300 bus system demonstrate the accuracy of the method for solving the RTCA problem using synchrophasor data. With this the synchrophasor measurement system provides an independent real-time monitoring and operation system which utilizes PMU data alone.

Nayak, Neeraj↗

Design of a free-space image-relay optical time-domain reflectometer to measure fiber-optic time delays at inertial confinement fusion relevant wavelengths

Fiber optics are an integral part of data collection, often used to transport visible and UV light to streaked spectrometers and photodetectors. Precisely measuring fiber-optic time delay (FOTD) is necessary for absolute data timing or fiber replacement. An optical time domain reflectometer (OTDR) can be used to measure the fiber-optic time delay. Commercial OTDR’s measure only the fiber in telecommunications wavelengths in the IR. To measure fibers at relevant wavelengths for inertial confinement fusion experiments, a solution using a free-space image relay was devised at the University of Rochester’s Laboratory for Laser Energetics (LLE), where readily available equipment has been used to measure the FOTD to within 2 ps at 526.5 nm as well as 351 nm, which is an order of magnitude better than the timing jitter between LLE’s Hardware Timing System and second-harmonic (526.5-nm) fiducial laser pulses.

47 OTHER INSTRUMENTATION↗

NASA Provides the Capability to Deliver Near Real-Time JPSS Data to Users in Order to Monitor Time-Sensitive Applications Such as Wildfires, Floods, Volcanic Eruptions, Tropical Cyclones and Extreme Weather Events

NASA's Land, Atmosphere Near real-time Capability for EOS (Earth Observing System) (LANCE https://earthdata.nasa.gov/lance) serves near real time (NRT) data to monitor time sensitive applications such as monitoring wildfires, floods, volcanic eruptions, tropical cyclones and extreme weather events. It currently serves data and imagery from the Visible Infrared Imager Radiometer Suite (VIIRS) and Ozone Mapping and Profiler Suite (OMPS) S NPP (Suomi National Polar-orbiting Partnership) instruments and is in the process of integrating continuity data products from VIIRS and OMPS onboard the Joint Polar Satellite System (JPSS), via the JPSS data Hub, to continue to meet the needs of agencies, scientists and members of the general public. NASA's Earth Science Division (ESD) sponsored the EOSDIS development of LANCE in 2009 to provide a central point of access to high quality NRT data products and imagery for applications users. LANCE makes data available to the public within 3 hours of satellite observation and imagery within 4-5 hours of satellite observation. Full resolution browse imagery from LANCE are provided through the Global Imagery Browse Services (GIBS) which also fuels NASA's Worldview tool so that users can interactively browse near real time data. This data supports time critical applications and allows users to view current natural hazards and events and animate the imagery over time.

Near real time↗

Determination of the thermal diffusivity of bulk and layered samples by time domain thermoreflectance: Interest of lateral heat diffusion investigation in nanoscale time range

We report on thermal investigations performed in a time resolved experimental scheme. The time domain thermoreflectance (TDTR) is applied in an unusual geometry where the pump and probe beams are not superimposed but focused and shifted. In this way, the determination of the in-plane thermal diffusivity is achieved from temperature snapshots at different time delays. In the first part, taking into account the specific generation process and the detection inherent to the time domain thermoreflectance approach, an analytical solution for the temperature field is obtained for bulk samples, and compared to experimental data. A comparison with the frequency domain thermoreflectance microscopy is also outlined. In Part II section, the lateral heat diffusion in a layered structure is investigated. The comparison of the heat diffusion spreading in case of a highly conductive layer deposited on an insulator substrate and the reverse situation are carefully studied. Finally, we show how the time dependence is efficient to probe and identify material thermal properties or thermal interfacial resistance.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗