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At least 181 records · Page 10

Non-flammable polyimide materials for commercial application

Thermally-stable, fire-resistant polyimide foams developed for use as fire protection in aircraft, spacecraft and ground applications are presented. Polyimide precursors, synthesized by the reaction of 3, 3', 4, 4'-benzophenone tetracarboxylic acid dianhydride with a mixture of two diamines, can be processed into foams by indirect or direct heating techniques. Flexible resilient foams and thermal acoustical foams produced by the microwave heating of polyimide precursors are shown to conform to requirements for aircraft seating foams and thermal and acoustical insulation materials, respectively. Rigid polyimide foams reinforced by carbon mat, chopped carbon mat and chopped glass strand fillers and prepared by the microwave heating of a continuous mat, followed by its compression, or by filling a honeycomb structure with low density foam, are found to exhibit outstanding fire resistance and have mechanical properties approaching those desired for structural materials.

Gagliani, J.↗

Advanced Liquid-Cooling Garment Using Highly Thermally Conductive Sheets

This design of the liquid-cooling garment for NASA spacesuits allows the suit to remove metabolic heat from the human body more effectively, thereby increasing comfort and performance while reducing system mass. The garment is also more flexible, with fewer restrictions on body motion, and more effectively transfers thermal energy from the crewmember s body to the external cooling unit. This improves the garment s performance in terms of the maximum environment temperature in which it can keep a crewmember comfortable. The garment uses flexible, highly thermally conductive sheet material (such as graphite), coupled with cooling water lines of improved thermal conductivity to transfer the thermal energy from the body to the liquid cooling lines more effectively. The conductive sheets can be layered differently, depending upon the heat loads, in order to provide flexibility, exceptional in-plane heat transfer, and good through-plane heat transfer. A metal foil, most likely aluminum, can be put between the graphite sheets and the external heat source/sink in order to both maximize through-plane heat transfer at the contact points, and to serve as a protection to the highly conductive sheets. Use of a wicking layer draws excess sweat away from the crewmember s skin and the use of an outer elastic fabric ensures good thermal contact of the highly conductive underlayers with the skin. This allows the current state of the art to be improved by having cooling lines that can be more widely spaced to improve suit flexibility and to reduce weight. Also, cooling liquid does not have to be as cold to achieve the same level of cooling. Specific areas on the human body can easily be targeted for greater or lesser cooling to match human physiology, a warmer external environment can be tolerated, and spatial uniformity of the cooling garment can be improved to reduce vasoconstriction limits. Elements of this innovation can be applied to other embodiments to provide effective heat transfer over a flexible and surface-conformable fashion without the limitation of fluid freeze points.

Ruemmele, Warren P.↗

Flexible Polyimide Aerogel Cross-linked by Poly(maleic Anhydride-alt-alkylene)

Aerogels are potential materials for aerospace applications due to their lower thermal conductivity, lighter weight, and low dielectric constant. However, silica aerogels are restricted due to their inherent fragility, hygroscopic nature, and poor mechanical properties, especially in extreme aerospace environments. In order to fit the needs of aerospace applications, developing new thermal insulation materials that are flexible, and moisture resistant is needed. To this end, we fabricated a series of polyimide aerogels crosslinked with different poly(maleic anhydride-alt-alkylene)s as seen in Scheme 1. The polyimide oligomers were made with 3,3,4,4-biphenyltetracarboxylic dianhydride (BPDA), and different diamines or diamine combinations. The resulting aerogels have low density (0.06 gcm3 to 0.16 gcm3) and high surface area (240-440 m2g). The effect of the different backbone structures on density, shrinkage, porosity, surface area, mechanical properties, moisture resistance and thermal properties will be discussed. These novel polyalkylene-imide aerogels may be potential candidates for applications such as space suit insulation for planetary surface missions, insulation for inflatable structures for habitats, inflatable aerodynamic decelerators for entry, descent and landing (EDL) operations, and cryotank insulation for advance space propulsion systems. Scheme 1. Network of polyimide aerogels crosslinked with deifferent poly(maleic anhydride).

cross-link↗

Thermally Conductive Metal-Tube/Carbon-Composite Joints

An improved method of fabricating joints between metal and carbon-fiber-based composite materials in lightweight radiators and heat sinks has been devised. Carbon-fiber-based composite materials have been used in such heat-transfer devices because they offer a combination of high thermal conductivity and low mass density. Metal tubes are typically used to carry heat-transfer fluids to and from such heat-transfer devices. The present fabrication method helps to ensure that the joints between the metal tubes and the composite-material parts in such heat-transfer devices have both (1) the relatively high thermal conductances needed for efficient transfer of heat and (2) the flexibility needed to accommodate differences among thermal expansions of dissimilar materials in operation over wide temperature ranges. Techniques used previously to join metal tubes with carbon-fiber-based composite parts have included press fitting and bonding with epoxy. Both of these prior techniques have been found to yield joints characterized by relatively high thermal resistances. The present method involves the use of a solder (63 percent Sn, 37 percent Pb) to form a highly thermally conductive joint between a metal tube and a carbon-fiber-based composite structure. Ordinarily, the large differences among the coefficients of thermal expansion of the metal tube, solder, and carbon-fiber-based composite would cause the solder to pull away from the composite upon post-fabrication cooldown from the molten state. In the present method, the structure of the solder is modified (see figure) to enable it to deform readily to accommodate the differential thermal expansion.

Copeland, Robert J.↗

Large space telescope engineering scale model optical design

The objective is to develop the detailed design and tolerance data for the LST engineering scale model optical system. This will enable MSFC to move forward to the optical element procurement phase and also to evaluate tolerances, manufacturing requirements, assembly/checkout procedures, reliability, operational complexity, stability requirements of the structure and thermal system, and the flexibility to change and grow.

Facey, T. A.↗

Development of an optimized intumescent coating

Intumescent coatings for small diameter air launched missiles were studied. An aerodynamically smooth, moderately flexible coating, with excellent thermal efficiency was developed.

Bilow, N.↗

Vacuum-jacketed line spacer

Device has three integral, equally spaced leaf springs. Springs separate outer vacuum jacket from fluid carrying line, yet minimize conductive heat leaks and liquid boiloff. One-piece heat spring has sufficient flexibility to accommodate differential thermal expansion of inner and outer line.

Houte, F. A.↗

Flexible heat-and-pressure seal

Device withstands both heat and pressure and accomodates relative motion between seated surfaces. Seal consists of flexible tube filled with thermally insulating material and coated with pressure resistant materials.

Bellavia, J., Jr.↗

Improved Cure-in-Place Silicone Adhesives

Two improved cure-in-place silicone-elastomer-based adhesives have low thermal expansion and low thermal conductivity. Adhesives are flexible at low temperature and withstand high temperatures without disintegrating. New ablative compounds were initially developed for in-flight repair of insulating tile on Space Shuttle orbiter. Could find use in other applications requiring high-performance adhesives, such as sealants for solar collectors.

Blevins, C. E.↗

High-Performance Filleting and Channel Sealants

Filleting and channel sealants developed for sealing cavities in wings and fusealage of aircraft. Both sealants function well at 177 degrees C, as required in current specifications for supersonic aircraft. Sealants have excellent resistance to fuel and other solvents. They stay flexible, resistant to vibrational, thermal, and mechanical stresses, and adhere well to aluminum. Prove useful in industrial applications requiring resistance to solvents at high temperatures.

Rosser, R. W.↗

Project SPARC: Space-Based Aeroassisted Reusable Craft

Future United States' space facilities include a Space Station in low Earth orbit (LEO) and a Geosynchronous Operations Support Center, or GeoShack, in geosynchronous orbit (GEO). One possible mode of transfer between the two orbits is an aerobraking vehicle. When traveling from GEO to LEO, the Earth's atmosphere can be used to aerodynamically reduce the velocity of the vehicle, which reduces the amount of propulsive change in velocity required for the mission. An aerobrake is added to the vehicle for this purpose, but the additional mass increases propellant requirements. This increase must not exceed the amount of propellant saved during the aeropass. The design and development of an aerobraking vehicle that will transfer crew and cargo between the Space Station and GeoShack is examined. The vehicle is referred to as Project SPARC, a SPace-based Aeroassisted Reusable Craft. SPARC consists of a removable 45 ft diameter aerobrake, two modified Pratt and Whitney Advanced Expander Engines with a liquid oxygen/liquid hydrogen propellant, a removable crew module with a maximum capacity of five, and standard sized payload bays providing a maximum payload capacity of 28,000 lbm. The aerobrake, a rigid, ellipsoidally blunted elliptical cone, provides lift at zero angle-of-attack due to a 73 deg rake angle, and is covered with a flexible multi-layer thermal protection system. Maximum dry mass of the vehicle without payload is 20,535 lbm, and the maximum propellant requirement is 79,753 lbm at an oxidizer to fuel ratio of 6/1. Key advantages of SPARC include its capability to meet mission changes, and its removable aerobrake and crew module.

Source record↗

Liquid Annular Seal Research

This paper highlights the accomplishments on a joint effort between NASA - Marshall Space Flight Center and Texas A and M University to develop accurate seal analysis software for use in rocket turbopump design, design audits and trouble shooting. Results for arbitrary clearance profile, transient simulation, thermal effects solution and flexible seal wall model are presented. A new solution for eccentric seals based on cubic spline interpolation and ordinary differential equation integration is also presented.

Palazzolo, Alan B.↗

The Upper Atmosphere Research Satellite In-Flight Dynamics

Upper Atmosphere Research Satellite flight data from the first 737 days after launch (September 1991) was used to investigate spacecraft disturbances and responses. The investigation included two in-flight dynamics experiments (approximately three orbits each). Orbital and configuration influences on spacecraft dynamic response were also examined. Orbital influences were due to temperature variation from crossing the Earth's terminator and variation of the solar incident energy as the orbit precessed. During the terminator crossing, the rapid ambient temperature change caused the spacecraft's two flexible appendages to experience thermal elastic bending (thermal snap). The resulting response was dependent upon the orientation of the solar array and the solar incident energy. Orbital influences were also caused by on-board and environmental disturbances and spacecraft configuration changes resulting in dynamic responses which were repeated each orbit. Configuration influences were due to solar array rotation changing spacecraft modal properties. The investigation quantified the spacecraft dynamic response produced by the solar array and high gain antenna harmonic drive disturbances. The solar array's harmonic drive output resonated two solar array modes. Friction in the solar array gear drive provided sufficient energy dissipation which prevented the solar panels from resonating catastrophically; however, the solar array vibration amplitude was excessively large. The resulting vibration had a latitude-specific pattern.

Woodard, Stanley E.↗

Organopolysiloxane Waterproofing Treatment for Porous Ceramics

Rigid and flexible porous ceramics, including thermal insulation of a type used on space vehicles, are waterproofed by a treatment which comprises applying an aqueous solution of an organopolysiloxane water-proofing agent having reactive silanol groups to the surface of the ceramic and then heating the treated ceramic to form a waterproofed ceramic. The organopolysiloxane is formed by the hydrolysis and partial condensation of di- and trialkoxyfunctional alkylalkoxysilanes having 1-10 carbon atom hydrocarbyl groups.

Leiser, Daniel B.↗

Analysis of a New Rocket-Based Combined-Cycle Engine Concept at Low Speed

An analysis of the Independent Ramjet Stream (IRS) cycle is presented. The IRS cycle is a variation of the conventional ejector-Ramjet, and is used at low speed in a rocket-based combined-cycle (RBCC) propulsion system. In this new cycle, complete mixing between the rocket and ramjet streams is not required, and a single rocket chamber can be used without a long mixing duct. Furthermore, this concept allows flexibility in controlling the thermal choke process. The resulting propulsion system is intended to be simpler, more robust, and lighter than an ejector-ramjet. The performance characteristics of the IRS cycle are analyzed for a new single-stage-to-orbit (SSTO) launch vehicle concept, known as "Trailblazer." The study is based on a quasi-one-dimensional model of the rocket and air streams at speeds ranging from lift-off to Mach 3. The numerical formulation is described in detail. A performance comparison between the IRS and ejector-ramjet cycles is also presented.

Yungster, S.↗

Aerogels: Overview and Outlook for Future Space and Terrestrial Applications at NASA

Aerogels are a class of porous solids which exhibit many extreme properties originating from a nanoporous skeletal architecture. One class of aerogel, polyimide-based, possesses low dielectric constants, low thermal conductivities, high porosity, flexibility and low densities with outstanding mechanical properties. Due to their wide array of interesting and useful material properties, they are being employed in many new applications as an enabling technology. In this presentation, I will be giving an overview into the history, properties, and synthesis of aerogels along with a few successful projects at NASA involving the synthesis of novel aerogel formulations.

Nanoporous↗

Polyurea-Based Aerogel Monoliths and Composites

aerogel insulation material was developed that will provide superior thermal insulation and inherent radiation protection for government and commercial applications. The rubbery polyureabased aerogel exhibits little dustiness, good flexibility and toughness, and durability typical of the parent polyurea polymer, yet with the low density and superior insulation properties associated with aerogels. The thermal conductivity values of polyurea-based aerogels at lower temperature under vacuum pressures are very low and better than that of silica aerogels. Flexible, rubbery polyurea-based aerogels are able to overcome the weak and brittle nature of conventional inorganic and organic aerogels, including polyisocyanurate aerogels, which are generally prepared with the one similar component to polyurethane rubber aerogels. Additionally, with higher content of hydrogen in their structures, the polyurea rubber-based aerogels will also provide inherently better radiation protection than those of inorganic and carbon aerogels. The aerogel materials also demonstrate good hydrophobicity due to their hydrocarbon molecular structure. There are several strategies to overcoming the drawbacks associated with the weakness and brittleness of silica aerogels. Development of the flexible fiber-reinforced silica aerogel composite blanket has proven to be one promising approach, providing a conveniently fielded form factor that is relatively robust in industrial environments compared to silica aerogel monoliths. However, the flexible, silica aerogel composites still have a brittle, dusty character that may be undesirable, or even intolerable, in certain application environments. Although the cross - linked organic aerogels, such as resorcinol- formaldehyde (RF), polyisocyanurate, and cellulose aerogels, show very high impact strength, they are also very brittle with little elongation (i.e., less rubbery). Also, silica and carbon aerogels are less efficient radiation shielding materials due to their lower content of hydrogen element. The invention involves mixing at least one isocyanate resin in solvent along with a specific amount of at least one polyamine hardener. The hardener is selected from a group of polyoxyalkyleneamines, amine-based polyols, or a mixture thereof. Mixing is performed in the presence of a catalyst and reinforcing inorganic and/or organic materials, and the system is then subjected to gelation, aging, and supercritical drying. The aerogels will offer exceptional flexibility, excellent thermal and physical properties, and good hydrophobicity. The rubbery polyurea-based aerogels are very flexible with no dust and hydrophobic organics that demonstrated the following ranges of typical properties: densities of 0.08 to 0.293 g/cu cm, shrinkage factor (raerogel/rtarget) = 1.6 to 2.84, and thermal conductivity values of 15.2 to 20.3 mW/m K.

Lee, Je Kyun↗