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Impact resistance and interlaminar fracture toughness of through-the-thickness reinforced graphite/epoxy

Five through-the-thickness stitch configurations are analyzed to determine the effect of impact resistance and interlaminar fracture toughness on T3000/3501-6 graphite/epoxy. The test specimens were stitched with either polyester or Kevlar yarns and with various stitch parameters. Tension and compression mechanical, impact and compression-after-impact, and double cantilever beam tests were conducted. It is observed that the stitched laminates have tension and compression strengths 20-25 percent lower than the strengths of unstitched laminates, the tension strength of stitched laminates is reduced with increasing number of stitches, and the compression strength increases as the number of stitches are increased. The impact data reveal that the Kevlar stitched laminates have less damage than unstitched laminates; the most effective configuration for suppressing impact damage and improving interlaminar fracture toughness consists of Kevlar yarns 1/4 inch apart with eight stitches per inch. The mode 1 critical strain energy release rate for the 1/4 inch Kevlar eight stitch laminate was calculated as 30 times higher than that of the unstitched.

Dexter, H. B.↗

Effects of temperature and humidity cycling on the strengths of textile reinforced carbon/epoxy composite materials

Results are presented from an experimental evaluation of the combined effects of temperature and humidity cycling on AS4/3501-6 composites (unstitched, Kevlar 29 stitched, and S-2 glass stitched uniweave fabric) and AS4/E905L composites (2-D, S-2 glass stitched 2-D, and 3-D braided fabric). The AS4/3501-6 uniweave material had a quasi-isotropic layup, whereas the AS4/E905L materials were braided in a (+/-30 deg/0 deg)(sub s) orientation. Data presented include compression strengths and compression-compression fatigue results for uncycled composites and cycled composites (160, 480, 720, and 1280 cycles from 140 deg F at 95 percent relative humidity to -67 deg F). To observe the presence of microcracking within the laminates, photomicrographs were taken of each material type at the end of each cycling period. Microcracks were found to be more prevalent within stitched laminates, predominantly around individual stitches. The glass stitched laminates showed significant microcracking even before cycling. Less microcracking was evident in the Kevlar stitched materials, whereas the unstitched uniweave material developed microcracks only after cycling. The 3-D braid did not develop microcracks. The static compression strengths of the unstitched and Kevlar stitched uniweave materials were degraded by about 10 percent after 1280 temperature/humidity cycles, whereas the reduction in compression strength for the glass stitched uniweave was less than 3 percent. The reduction in compression strength for the glass stitched 2-D braid was less than 8 percent. The unstitched 2-D and 3-D braids did not lose strength from temperature/humidity cycling. The compression-compression fatigue properties of all six material types were not affected by temperature/humidity cycling.

Cano, Roberto J.↗

A designed experiment in stitched/RTM composites

The damage tolerance of composite laminates can be significantly improved by the addition of through-the-thickness fibrous reinforcement such as stitching. However, there are numerous stitching parameters which can be independently varied, and their separate and combined effects on mechanical properties need to be determined. A statistically designed experiment (a 2(sup 5-1) fractional factorial, also known as a Taguchi L16 test matrix) used to evaluate five important parameters is described. The effects and interactions of stitch thread material, stitch thread strength, stitch row spacing and stitch pitch are examined for both thick (48 ply) and thin (16 ply) carbon/epoxy (AS4/E905L) composites. Tension, compression and compression after impact tests are described. Preliminary results of completed tension testing are discussed. Larger threads decreased tensile strength. Panel thickness was found not to be an important stitching parameter for tensile properties. Tensile modulus was unaffected by stitching.

Dickinson, Larry C.↗

Automated Identification of Nucleotide Sequences

STITCH is a computer program that processes raw nucleotide-sequence data to automatically remove unwanted vector information, perform reverse-complement comparison, stitch shorter sequences together to make longer ones to which the shorter ones presumably belong, and search against the user s choice of private and Internet-accessible public 16S rRNA databases. ["16S rRNA" denotes a ribosomal ribonucleic acid (rRNA) sequence that is common to all organisms.] In STITCH, a template 16S rRNA sequence is used to position forward and reverse reads. STITCH then automatically searches known 16S rRNA sequences in the user s chosen database(s) to find the sequence most similar to (the sequence that lies at the smallest edit distance from) each spliced sequence. The result of processing by STITCH is the identification of the most similar well-described bacterium. Whereas previously commercially available software for analyzing genetic sequences operates on one sequence at a time, STITCH can manipulate multiple sequences simultaneously to perform the aforementioned operations. A typical analysis of several dozen sequences (length of the order of 103 base pairs) by use of STITCH is completed in a few minutes, whereas such an analysis performed by use of prior software takes hours or days.

Osman, Shariff↗

Fiber Reinforcement Architectures of PMCs on the Hygrothermal-Mechanical Performance for Aeropropulsion Applications

A rigid lightweight sandwich support structure, for the combustor chamber of a new generation liquid propellant rocket engine, was designed and fabricated using Polymer Matric Composite (PMC) facesheet on a Ti honeycomb or Carbon foam core. The facesheet consisted of high stiffness carbon fiber, M40JB, and high temperature Polyimides, such as PMR-11-50 and HFPE-II. Six different fiber architectures; 4HS woven fabric, uni-fabric, woven-uni hybrid, stitched woven fabric, stitched uni-fabric and tri-axial braided structures have been investigated for optimum stiffness-thickness-weight-performance design criteria for the hygrothermal-mechanical propulsion service exposure conditions including rapid heating up to 200 F/sec, maximum operating temperature of 600 F, internal pressure up to 100 psi. An extensive property and performance database including dry-wet mechanical properties at both 25 F and 600 F in various loading modes, thermal and physical properties including blistering onset condition was developed for fiber architecture down-selection and design guidelines. Various optimized process methods including vacuum bag compression molding, solvent assistant RTM (SaRTM), resin film infusion (RFI) were utilized for PMC panel fabrication depending on the architecture type. In the case of stitched woven fabric architecture, the optimal stitch pattern was chosen in terms of stitch density and yarn size, based on both in-plane mechanical properties and blistering performance. Potential reduction of the in-plane properties transverse to the line of stitching was also evaluated. Attempt to correlate the experimental results with theoretical micro-mechanics predictions will be presented.

Shin, Eugene↗

Effects of Fiber Reinforcement Architecture on the Hygrothermal-Mechanical Performance of Polyimide Matrix Composites for Aeropropulsion Applications

A lightweight sandwich support structure, for the combustor chamber of a new generation liquid propellant rocket engine, was designed and fabricated using a polymer matrix composite (PMC) facesheet on a Ti honeycomb core. The PMC facesheet consisted of high stiffness carbon fiber, M40JB, and high temperature Polyimides, such as PMR-II-50 and HFPE-II-52. Six different fiber architectures; four harness satin (4HS) woven fabric, uni-tape, woven-uni hybrid, stitched woven fabric, stitched uni-tape and triaxial braided structures have been investigated for optimum stiffness-thickness-weight-hygrothermal performance design criteria for the hygrothermal-mechanical propulsion service exposure conditions including rapid heating up to 200 F/sec, maximum operating temperature of 600 F, internal pressure up to 100 psi. One of the specific objectives in this study is to improve composite blistering resistance in z-direction at minimum expense of in-plane mechanical properties. An extensive property-performance database including dry-wet mechanical properties at various temperatures, thermal-physical properties, such as blistering onset condition was generated for fiber architecture down-selection and design guidelines. Various optimized process methods such as vacuum bag compression molding, solvent assistant resin transfer molding (SaRTM), resin film infusion (RFI) and autoclaving were utilized for PMC panel fabrication depending on the architecture type. In the case of stitched woven fabric architecture, the stitch pattern in terms of stitch density and yarn size was optimized based on both in-plane mechanical properties and blistering performance. Potential reduction of the in-plane properties transverse to the line of stitching was also evaluated. Efforts have been made to correlate the experimental results with theoretical micro-mechanics predictions. Changes in deformation mechanism and failure sequences in terms of fiber architecture will be discussed.

Shin, E. Eugene↗

ISAAC Integrated Structural Assembly of Advanced Composites

The NASA Langley Research Center obtained the Integrated Structural Assembly of Advanced Composites (ISAAC) robotic system in 2014 to add state-of-the-art automated manufacturing of composites to our traditional in-house design, analysis, and experimentation capabilities. ISAAC is used to explore fabrication of parts with novel designs and for research into new composite manufacturing techniques. Automated fiber placement (AFP) was the initial manufacturing capability on ISAAC and has been used to support a range of aeronautics and space projects including the Advanced Composites Project (ACP), Composites for Exploration Upper Stage (CEUS), and Advanced Air Transportation Technologies (AATT). In addition to AFP, ISAAC can now provide through-thickness reinforcement of composites by adding stitches through dry fabric prior to resin infusion. Stitching is of interest since it can improve damage tolerance, reduce final assembly time, and reduce inspection requirements. ISSAC can stitch traditional single-needle seams and perform stitching operations using two needles when access is only available to one side of the part. Stitching capability is being advanced in the High-Rate Composites Aircraft Manufacturing (HiCAM) project today. This lecture will describe the work with ISAAC today and new exciting plans for the future.

automated fiber placement↗

Scaling-Up of Nano-Architected Microstructures: A Mechanical Assessment

Nano– and micro–architected materials generated by ultra–high–resolution 3D printing techniques, such as two–photon polymerization direct laser writing (TPP–DLW) or projection micro–stereolithography (PμSL), have garnered great interest due to their ability to achieve exceptional combinations of material properties. The scalability of these materials, however, remains a crucial challenge as larger high–resolution samples require stitching smaller blocks of the structure of interest together. Herein, scaling techniques and testing methodologies to investigate the effect of stitching on the integrity and mechanical behavior of TPP–DLW parts under tensile load are explored. Specifically, stitched log–pile I–beam specimens with relative densities of 21.5% and 54.7% are tested herein. The micro–tensile tests reveal that the higher–density log–pile samples exhibit brittle behavior with fracture loads at least four times higher than those of lower–density samples. The location of sample failure depends on the type of stitch introduced in the sample, as well as on the relative sample density. Altogether, this study highlights the importance of stitching techniques and relative density for the design of nano– and micro–architected materials.

36 MATERIALS SCIENCE↗

Hybrid Inflatable Pressure Vessel

Figure 1 shows a prototype of a large pressure vessel under development for eventual use as a habitable module for long spaceflight (e.g., for transporting humans to Mars). The vessel is a hybrid that comprises an inflatable shell attached to a rigid central structural core. The inflatable shell is, itself, a hybrid that comprises (1) a pressure bladder restrained against expansion by (2) a web of straps made from high-strength polymeric fabrics. On Earth, pressure vessels like this could be used, for example, as portable habitats that could be set up quickly in remote locations, portable hyperbaric chambers for treatment of decompression sickness, or flotation devices for offshore platforms. In addition, some aspects of the design of the fabric straps could be adapted to such other items as lifting straps, parachute straps, and automotive safety belts. Figure 2 depicts selected aspects of the design of a vessel of this type with a toroidal configuration. The bladder serves as an impermeable layer to keep air within the pressure vessel and, for this purpose, is sealed to the central structural core. The web includes longitudinal and circumferential straps. To help maintain the proper shape upon inflation after storage, longitudinal and circumferential straps are indexed together at several of their intersections. Because the web is not required to provide a pressure seal and the bladder is not required to sustain structural loads, the bladder and the web can be optimized for their respective functions. Thus, the bladder can be sealed directly to the rigid core without having to include the web in the seal substructure, and the web can be designed for strength. The ends of the longitudinal straps are attached to the ends of the rigid structural core by means of clevises. Each clevis pin is surrounded by a roller, around which a longitudinal strap is wrapped to form a lap seam with itself. The roller is of a large diameter chosen to reduce bending of the fibers in the strap. The roller also serves to equalize the load in the portions of the strap on both sides of the clevis pin. The lap seam is formed near the clevis by use of a tapered diamond stitch: This stitch is designed specifically to allow fibers in the stitch and strap to relax under load in such a manner that the load becomes more nearly evenly distributed among all fibers in the stitch region. Thus, the tapered diamond stitch prevents load concentrations that could cause premature failure of the strap and thereby increases the strength of the strap/structural-core joint. The lap seam can be rated at >90 percent of the strength of the strap material.

Raboin, Jasen↗

NDE Evidence for the Damage Arrestment Performance of PRSEUS Composite Cube During High-Pressure Load Test

As an approach to light-weight, cost-effective and manufacturable structures required to enable the hybrid wing body aircraft, The Boeing Company, Inc. and NASA have developed the Pultruded Rod Stitched Efficient Unitized Structure (PRSEUS) concept. A PRSEUS pressure cube was developed as a risk reduction test article to examine a new integral cap joint concept as part of a building block approach for technology development of the PRSEUS concept. The overall specimen strength exceeded the 18.4 psi load requirement as testing resulted in the cube reaching a final pressure load of around 48 psi prior to catastrophic failure. The cube pressure test verified that the joints and structure were capable of sustaining the required loads, and represented the first testing of joined PRSEUS structure. This paper will address the damage arrestment performance of the stitched PRSEUS structure. Following catastrophic failure of the cube, ultrasonic pulse-echo inspection found that the localized damage, surrounding a barely-visible impact damage site, did not change noticeably between just after impact and catastrophic failure of the cube, and did not play a role in the catastrophic failure event. Ultrasonic inspection of the remaining intact cube panels presented three basic types of indications: delaminations between laminae parallel to the face sheets, lying between face sheet and tear strap layers, or between tear strap and flange layers; delaminations above the noodles of stringers, frames or integral caps, lying within face sheet or tear strap layers; and delaminations between the laminae in the inner fillets of the integral caps, where pulloff stresses were expected to be highest. Delaminations of all three types were predominantly contained by the first row of stitches encountered. For the small fraction of delaminations extending beyond the first row of stitches, all were contained by the second stitch row.

Johnston, Patrick H.↗

Parallel-scanning tomosynthesis using a slot scanning technique: Fixed-focus reconstruction and the resulting image quality

Purpose: Parallel-scanning tomosynthesis (PS-TS) is a novel technique that fuses the slot scanning technique and the conventional tomosynthesis (TS) technique. This approach allows one to obtain long-view tomosynthesis images in addition to normally sized tomosynthesis images, even when using a system that has no linear tomographic scanning function. The reconstruction technique and an evaluation of the resulting image quality for PS-TS are described in this paper. Methods: The PS-TS image-reconstruction technique consists of several steps (1) the projection images are divided into strips, (2) the strips are stitched together to construct images corresponding to the reconstruction plane, (3) the stitched images are filtered, and (4) the filtered stitched images are back-projected. In the case of PS-TS using the fixed-focus reconstruction method (PS-TS-F), one set of stitched images is used for the reconstruction planes at all heights, thus avoiding the necessity of repeating steps (1)–(3). A physical evaluation of the image quality of PS-TS-F compared with that of the conventional linear TS was performed using a R/F table (Sonialvision safire, Shimadzu Corp., Kyoto, Japan). The tomographic plane with the best theoretical spatial resolution (the in-focus plane, IFP) was set at a height of 100 mm from the table top by adjusting the reconstruction program. First, the spatial frequency response was evaluated at heights of −100, −50, 0, 50, 100, and 150 mm from the IFP using the edge of a 0.3-mm-thick copper plate. Second, the spatial resolution at each height was visually evaluated using an x-ray test pattern (Model No. 38, PTW Freiburg, Germany). Third, the slice sensitivity at each height was evaluated via the wire method using a 0.1-mm-diameter tungsten wire. Phantom studies using a knee phantom and a whole-body phantom were also performed. Results: The spatial frequency response of PS-TS-F yielded the best results at the IFP and degraded slightly as the distance from the IFP increased. A visual evaluation of the spatial resolution using the x-ray test pattern indicated that the resolution was 1.8 lp/mm at the IFP and 1.2 lp/mm at heights of −100 and 100 mm from the IFP. The authors demonstrated that a spatial resolution of 1.2–1.8 lp/mm could be obtained within heights of 200 mm of the IFP. The slice sensitivity varied between 11.1 and 13.8 mm for heights between −50 and 100 mm, and there was no critical change in the slice sensitivity within a height range of 150 mm around the IFP. The phantom results demonstrated that tomosynthesis and long-view images could be reconstructed. Conclusions: PS-TS-F provides tomosynthesis images while using low-cost systems that have no tomographic scanning function, such as tableside-controlled universal R/F systems or universal radiographic systems.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Evaluation of the impact response of textile composites

An evaluation of the impact damage resistance and impact damage tolerance of stitched and unstitched uniweaves, 2-D braids, and 3-D weaves was conducted. Uniweave laminates were tested at four thicknesses to determine the sensitivity of the tests to this parameter. Several braid and weave parameters were also varied to establish their velocity (large mass) impacts and then loaded in tension or compression to measure residual strength. Experimental results indicate that stitching significantly improves the uniweaves' damage resistance. The 2-D braids and 3-D weaves offered less damage resistance than the stitched materials. Stitching also improved the compression after impact (CAI) and tension after impact (TAI) strengths of the uniweave materials.

Portanova, M. A.↗

Notched Strength Allowables and Inplane Shear Strength of AS4/VRM-34 Textile Laminates

Notched and unnotched strength allowables were developed for a textile composite to provide input data to analytical structural models based on the Pultruded Rod Stiffened Efficient Unitized Structure (PRSEUS) concept. Filled-hole tensile strength, filled-hole compressive strength, and inplane shear strength along stitch lines have been measured. The material system evaluated in this study is based on warp-knitted preforms of AS4 carbon fibers and VRM-34 epoxy resin, which have been processed via resin infusion and oven curing. All specimens were tested in as-fabricated (dry) condition. Filled-hole strengths were evaluated with and without through-thickness stitching. The effects of scaling on filled-hole tensile strength were evaluated by testing specimens in two widths, but with identical width / hole-diameter ratios. Inplane shear specimens were stitched in two configurations, and two specimen thicknesses were tested for each stitch configuration.

Grenoble, Ray W.↗

PRSEUS Panel Fabrication Final Report

NASA and the Boeing Company have been working together under the Environmentally Responsible Aviation Project to develop stitched unitized structure for reduced weight, reduced fuel burn and reduced pollutants in the next generation of commercial aircraft. The structural concept being evaluated is PRSEUS (Pultruded Rod Stitched Efficient Unitized Structure). In the PRSEUS concept, dry carbon fabric, pultruded carbon rods, and foam are stitched together into large preforms. Then these preforms are infused with an epoxy resin into large panels in an out-of-autoclave process. These panels have stiffeners in the length-wise and width-wise directions but contain no fasteners because all stiffeners are stitched to the panel skin. This document contains a description of the fabrication of panels for use in the 30-foot-long Multi-Bay Box test article to be evaluated at NASA LaRC.

Linton, Kim A.↗

Fabrication of Lower Section and Upper Forward Bulkhead Panels of the Multi-Bay Box and Panel Preparation

NASA and the Boeing Co. have been working together under the Environmentally Responsible Aviation Project to develop stitched unitized structure for reduced weight, reduced fuel burn and reduced pollutants in the next generation of commercial aircraft. The structural concept being evaluated is PRSEUS (Pultruded Rod Stitched Efficient Unitized Structure). In the PRSEUS concept, dry carbon fabric, pultruded carbon rods, and foam are stitched together into large preforms. Then these preforms are infused with an epoxy resin into large panels in an out-of-autoclave process. These panels have stiffeners in the length-wise and width-wise directions but contain no fasteners because all stiffeners are stitched to the panel skin. This document contains a description of the fabrication of panels for use in the 30-foot-long Multi-Bay Box test article to be evaluated at NASA LaRC. The document also describes a panel which explores new PRSEUS concepts for applications beyond the Multi-Bay Box.

Velicki, Alexander↗

TPSAS-NF1676L-13678-DND

An area that shows promise in enhancing structural integrity of aircraft and aerospace structures is integral stitched composite technology. The most recent generation of this technology is the Pultruded Rod Stitched Efficient Unitized Structure (PRSEUS) concept. The goal of the PRSEUS concept is to provide damage-containment capability for composite structures while reducing overall structural weight. The National Aeronautics and Space Administration, the Boeing Company, and the Federal Aviation Administration (FAA) have partnered in an effort to assess the damage-containment features of a full-scale curved PRSEUS panel using the FAA Full-Scale Aircraft Structural Test Evaluation and Research facility. The background, test plan, fixture modifications, pre-test analysis, and planned experimental procedure were presented at the 2011 Aircraft Airworthiness and Sustainment Conference. This follow-on paper and presentation will provide details of the experimental procedure, test results, nondestructive inspection results, and preliminary test analysis comparison. The test program included three phases of loading and inspections: Phase I, as-built; Phase II, with barely visible impact damage (BVID); and Phase III, with a two-bay notch severing the central stiffener. Axial tension, internal pressure, and combined axial tension and internal pressure load conditions were applied during each phase using load levels that demonstrate compliance with the strength, deformation, and damage-tolerance requirements of Title 14 Code of Federal Regulations Part 25. Pressure loads were based on an operating pressure of 9.2 psi, designated as 1P, and the axial loads were based on a design limit load (DLL) of 227 kip. The Phase I test results provided a baseline. First, 50 percent limit-load levels were applied for each of the three load cases to verify proper load introduction and repeatability by examining strain and displacement results. Next, three limit-load cases were applied: limit pressure of 12.2 psi (1.33 P), axial DLL of 227 kip, and combined 1P pressure and axial DLL. Linear strain and displacement results were observed in all load cases. For Phase-II testing, the panel was impacted to introduce BVID with an energy of 40 ft-lb, with the impact located between the central stringer stitch line and flange edge. The impact created non-penetrating visual damage with fiber breaks and delamination between the skin and stringer flange. Limit-load conditions were applied followed by pressure overload of 18.4 psi (2P) and ultimate load conditions, defined as 1.5 times DLL. Inspections were performed after each load case; no damage growth was observed. For Phase-III testing, a two-bay notch was machined severing the central stiffener. The panel was then subjected to limit-load conditions, followed by combined 1P pressure while increasing axial tension load to catastrophic failure. As limit combined loads were approached, damage initiation was observed in the form of 45? splitting at 1P + 79% DLL. Axial loading was increased to 1P + 150 percent DLL causing damage to propagate to the adjacent stringer flanges. Damage was contained within the two-bay region by the stitching rows up to 1P + 176% DLL. Axial load was further increased until catastrophic failure, when a stringer rod failed at 1P + 192% DLL. These test results further verify the damage containment features of the PRSEUS concept and suggest its appropriateness for future flight vehicles.

Andrew Bergan↗

Engineering the Kinetics of Directed Self-Assembly of Block Copolymers toward Fast and Defect-Free Assembly

Directed self-assembly (DSA) of block copolymers (BCPs) can achieve perfectly aligned structures at thermodynamic equilibrium, but the self-assembling morphology can become kinetically trapped in defective states. Understanding and optimizing the kinetic pathway toward domain alignment is crucial for enhancing process throughput and lowering defectivity to levels required for semiconductor manufacturing, but there is a dearth of experimental, three-dimensional studies of the kinetic pathways in DSA. Here, we combined arrested annealing and TEM tomography to probe the kinetics and structural evolution in the chemoepitaxy DSA of PS-b-PMMA with density multiplication. During the initial stages of annealing, BCP domains developed independently at first, with aligned structures at the template interface and randomly oriented domains at the top surface. As the grains coarsened, the assembly became cooperative throughout the film thickness, and a metastable stitch morphology was formed, representing a kinetic barrier. The stitch morphology had a three-dimensional structure consisting of both perpendicular and parallel lamellae. On the basis of the mechanistic information, we studied the effect of key design parameters on the kinetics and evolution of structures in DSA. Three types of structural evolutions were observed at different film thicknesses: (1) immediate alignment and fast assembly when thickness 1.64L(0). We found that the DSA kinetics can be significantly improved by avoiding the formation of the metastable stitch morphology. Increasing template topography also enhanced the kinetics by increasing the PMMA guiding surface area. A combination of 0.75L(0) BCP thickness and 0.50L(0) template topography achieved perfect alignment over 100 times faster than the baseline process. This research demonstrates that an improved understanding of the evolution of structures during DSA can significantly improve the DSA process.

Ren, Jiaxing↗

Atomic-Scale Insights into the Lateral and Vertical Epitaxial Growth in Two-Dimensional Pd 2 Se 3 –MoS 2 Heterostructures

Two-dimensional (2D) materials form heterostructures in both the lateral and vertical directions when two different materials are interfaced, but with totally different bonding mechanisms of covalent in-plane to van der Waal’s layered interactions. Understanding how the competition between lateral and vertical forces influences the epitaxial growth is important for future materials development of complex mixed layered heterostructures. In this study, we use atomic-resolution annular dark-field scanning transmission electron microscopy to study the detailed atomic arrangements at mixed 2D heterostructure interfaces composed of two semiconductors with distinctly different crystal symmetry and elemental composition, Pd 2 Se 3 :MoS 2 , in order to understand the role of different chemical bonds on the resultant epitaxy. Pd 2 Se 3 is grown off the step edge in bilayer MoS 2 , and the vertical and lateral epitaxial relationships of the Pd 2 Se 3 –MoS 2 heterostructures are investigated. We find that the similarity of geometry at the interface with one metal (Pd or Mo) atoms bonded with two chalcogens (S or Se) are the crucial factors to make the atomically stitched lateral junction of 2D heterostructures. In addition, the vertical van der Waal interactions that are normally dominant in layered materials can be overcome by in-plane forces if the interfacial atomic stitching is high in quality and low in defect density. This knowledge should help guide the approaches for improving the epitaxy in mixed 2D heterostructures and seamless stitching of in-plane 2D heterostructures with various complex monolayer structures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗