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At least 181 records · Page 10

Classification of gaseous UF 6 assay by femtosecond LIBS in the 424.4 nm spectral region using numerical HOGSVD-DTW features

This technical note presents experimental results using numerical features of fs-LIBS data to classify the assay value of a gaseous UF 6 material. Here, the data-driven feature vectors are computed by Higher Order Generalized Singular Value Decomposition (HOGSVD) and Dynamic Time Warp (DTW). The method achieves 96.97% accuracy in spectral classification testing with fs-LIBS samples obtained from a UF 6 material with five known assay values ranging from 0.287% to 61.740%, with 100% accuracy for the four largest assay values ranging from 4.615% to 61.740%.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Improving 3D Wavelet-Based Compression of Hyperspectral Images

Two methods of increasing the effectiveness of three-dimensional (3D) wavelet-based compression of hyperspectral images have been developed. (As used here, images signifies both images and digital data representing images.) The methods are oriented toward reducing or eliminating detrimental effects of a phenomenon, referred to as spectral ringing, that is described below. In 3D wavelet-based compression, an image is represented by a multiresolution wavelet decomposition consisting of several subbands obtained by applying wavelet transforms in the two spatial dimensions corresponding to the two spatial coordinate axes of the image plane, and by applying wavelet transforms in the spectral dimension. Spectral ringing is named after the more familiar spatial ringing (spurious spatial oscillations) that can be seen parallel to and near edges in ordinary images reconstructed from compressed data. These ringing phenomena are attributable to effects of quantization. In hyperspectral data, the individual spectral bands play the role of edges, causing spurious oscillations to occur in the spectral dimension. In the absence of such corrective measures as the present two methods, spectral ringing can manifest itself as systematic biases in some reconstructed spectral bands and can reduce the effectiveness of compression of spatially-low-pass subbands. One of the two methods is denoted mean subtraction. The basic idea of this method is to subtract mean values from spatial planes of spatially low-pass subbands prior to encoding, because (a) such spatial planes often have mean values that are far from zero and (b) zero-mean data are better suited for compression by methods that are effective for subbands of two-dimensional (2D) images. In this method, after the 3D wavelet decomposition is performed, mean values are computed for and subtracted from each spatial plane of each spatially-low-pass subband. The resulting data are converted to sign-magnitude form and compressed in a manner similar to that of a baseline hyperspectral- image-compression method. The mean values are encoded in the compressed bit stream and added back to the data at the appropriate decompression step. The overhead incurred by encoding the mean values only a few bits per spectral band is negligible with respect to the huge size of a typical hyperspectral data set. The other method is denoted modified decomposition. This method is so named because it involves a modified version of a commonly used multiresolution wavelet decomposition, known in the art as the 3D Mallat decomposition, in which (a) the first of multiple stages of a 3D wavelet transform is applied to the entire dataset and (b) subsequent stages are applied only to the horizontally-, vertically-, and spectrally-low-pass subband from the preceding stage. In the modified decomposition, in stages after the first, not only is the spatially-low-pass, spectrally-low-pass subband further decomposed, but also spatially-low-pass, spectrally-high-pass subbands are further decomposed spatially. Either method can be used alone to improve the quality of a reconstructed image (see figure). Alternatively, the two methods can be combined by first performing modified decomposition, then subtracting the mean values from spatial planes of spatially-low-pass subbands.

Klimesh, Matthew↗

Landsat analysis of tropical forest succession employing a terrain model

Landsat multispectral scanner (MSS) data have yielded a dual classification of rain forest and shadow in an analysis of a semi-deciduous forest on Mindonoro Island, Philippines. Both a spatial terrain model, using a fifth side polynomial trend surface analysis for quantitatively estimating the general spatial variation in the data set, and a spectral terrain model, based on the MSS data, have been set up. A discriminant analysis, using both sets of data, has suggested that shadowing effects may be due primarily to local variations in the spectral regions and can therefore be compensated for through the decomposition of the spatial variation in both elevation and MSS data.

Barringer, T. H.↗

Does The Nile Reflect Solar Variability?

Historical records of the Nile water level provide a unique opportunity to investigate the possibility that solar variability influences the Earth's climate. Particularly important are the annual records of the water level, which are uninterrupted for the years 622-1470 A.D. These records are non-stationary, so that standard spectral analyses cannot adequately characterize them. Here the Empirical Mode Decomposition technique, which is designed to deal with nonstationary, nonlinear time series, becomes useful. It allows the identification of two characteristic time scales in the water level data that can be linked to solar variability: the 88 year period and a time scale of about 200 years. These time scales are also present in the concurrent aurora data. Auroras are driven by coronal mass ejections and the rate of auroras is an excellent proxy for solar variability. Analysis of auroral data contemporaneous with the Nile data shows peaks at 88 years and about 200 years. This suggests a physical link between solar variability and the low frequency variations of the Nile water level. The link involves the influence of solar variability on the North Annual Mode of atmospheric variability and its North Atlantic and Indian Oceans patterns that affect rainfall over Eastern Equatorial Africa where the Nile originates.

statistical methods↗

Prediction of radio structure in the two largest redshift QSOs

The radio spectral data of OH471 and OQ172 are shown in a graph along with decompositions of the spectra into canonical self-absorbed synchrotron components. The minimum number of canonical components consistent with the data is used. Theoretically expected angular radii and time scales are presented in a table. The estimation of the angular size of a compact radio source with known spectral form rests upon the establishment of its maximum brightness temperature.

Jones, T. W.↗

Interstellar and Ejecta Dust in the Cas A Supernova Remnant

The ejecta of the Cas A supernova remnant has a complex morphology, consisting of dense fast-moving line emitting knots and diffuse X-ray emitting regions that have encountered the reverse shock, as well as more slowly expanding, unshocked regions of the ejecta. Using the Spitzer 5-35 micron IRS data cube, and Herschel 70, 100, and 160 micron PACS data, we decompose the infrared emission from the remnant into distinct spectral components associated with the different regions of the ejecta. Such decomposition allows the association of different dust species with ejecta layers that underwent distinct nuclear burning histories, and determination of the dust heating mechanisms. Our decomposition identified three characteristic dust spectra. The first, most luminous one, exhibits strong emission features at approx. 9 and 21 micron, and a weaker 12 micron feature, and is closely associated with the ejecta knots that have strong [Ar II] 6.99 micron and [Ar III] 8.99 micron emission lines. The dust features can be reproduced by magnesium silicate grains with relatively low MgO-to-SiO2 ratios. A second, very different dust spectrum that has no indication of any silicate features, is best fit by Al2O3 dust and is found in association with ejecta having strong [Ne II] 12.8 micron and [Ne III] 15.6 micron emission lines. A third characteristic dust spectrum shows features that best matched by magnesium silicates with relatively high MgO-to-SiO2 ratio. This dust is primarily associated with the X-ray emitting shocked ejecta and the shocked interstellar/circumstellar material. All three spectral components include an additional featureless cold dust component of unknown composition. Colder dust of indeterminate composition is associated with [Si II] 34.8 micron emission from the interior of the SNR, where the reverse shock has not yet swept up and heated the ejecta. The dust mass giving rise to the warm dust component is about approx. 0.1solar M. However, most of the dust mass is associated with the unidentified cold dust component. Its mass could be anywhere between 0.1 and 1 solar M, and is primarily limited by the mass of refractory elements in the ejecta. Given the large uncertainty in the dust mass, the question of whether supernovae can produce enough dust to account for ISM dust masses in the local and high-z universe remains largely unresolved.

Interstellar↗

Application of a two-stream radiative transfer model for leaf lignin and cellulose concentrations from spectral reflectance measurements, part 1

Lignin and nitrogen contents of leaves constitute the primary rate-limiting parameters for the decomposition of forest litter, and are determinants of nutrient- and carbon-cyclic rates in forest ecosystems (Melillo et al., 1982). Wessman et al. (1988a) developed empirical multivariate relationships between forest canopy lignin amount and the (first-difference) AIS spectral response in three bands spread over the wavelength interval 1256-1555 nm. Wessman et al. (1988b) and McLellan et al. (1991) developed similar regression relationships from laboratory reflectance measurements on dried samples prepared in a standard fashion. They used four to six infrared bands for analysis of nitrogen, lignin and cellulose content of foliage in forest and prairie species. In the present article (Parts 1 and 2) the feasibility of compositional determinations is explored using positions of composite absorption bands that originate from mixtures of lignin, cellulose, and possibly other chemical constituents in the spectral reflectance of green leaves. To carry out this program, we employ full-spectral-resolution single-leaf diffuse reflectance measurements made with a laboratory spectrometer and integrating sphere. The leaf and other chemical reflectance data compiled by Elvidge (1990) have also been utilized extensively.

Conel, James E.↗

Data-Centric Approach to Capture Non-Polynomial Nonlinear Dynamics

We propose an analytical construction of observable functions in the extended dynamic mode decomposition (EDMD) algorithm. EDMD is a numerical method for approximating the spectral properties of the Koopman operator. The choice of observable functions is fundamental for applying EDMD to nonlinear problems arising in systems and control. Existing methods either start from a set of dictionary functions and look for the subset that best fits the underlying nonlinear dynamics or rely on machine learning algorithms to “learn” observable functions. Conversely, in this paper, we start from the dynamical system model and lift it through the Lie derivatives, rendering it into a polynomial form. This proposed transformation into a polynomial form is exact and provides an adequate set of observable functions. The strength of the proposed approach is its applicability to a broader class of nonlinear dynamical systems, particularly those with nonpolynomial functions and compositions thereof. Moreover, it retains the physical interpretability of the underlying dynamical system and can be readily integrated into existing numerical libraries. We demonstrate the proposed approach with an application to electric power systems. The modeled system consists of a single generator connected to an infinite bus, where nonlinear terms include sine and cosine functions. The results demonstrate the effectiveness of the proposed procedure in off-attractor nonlinear dynamics for estimation and prediction; the observable functions obtained from the proposed construction outperform methods that use dictionary functions comprising monomials or radial basis functions.

extended dynamic mode decomposition↗

A high accuracy/resolution spectral element/Fourier–Galerkin method for the simulation of shoaling non-linear internal waves and turbulence in long domains with variable bathymetry

A high-order hybrid continuous-Galerkin numerical method, designed for the simulation of non-linear, non -hydrostatic internal waves and turbulence in long computational domains with complex bathymetry, is presented. The spatial discretization in the non-periodic wave-propagating directions, utilizes the nodal spectral element method. Such a high-order element-based discretization allows the highly accurate representation of complex domain geometry along with the flexibility of concentrating resolution in areas of interest. Under the assumption of the normal-to-isobath propagation of non-linear internal waves, a third periodic direction is incorporated via a Fourier-Galerkin discretization. The distinct non-hydrostatic nature of non-linear internal waves and, any instabilities and turbulence therein, necessitates the numerically challenging solution of the pressure Poisson problem. A defining feature of this work is the application of a domain decomposition approach, combined with block-Jacobi/deflation-based preconditioning to the pressure Poisson problem. Such a combined approach is particularly suitable for the long high aspect-ratio complex domains of interest and enables the efficient high-accuracy reproduction of the non-hydrostatic dynamics of non-linear internal waves. Implementation details are also described in the context of the stability of the solver and its parallelization strategy. A series of benchmarks of increasing complexity demonstrate the robustness of the flow solver. The benchmarks culminate with the three-dimensional simulation of a convectively breaking mode-one non-linear internal wave over a realistic South-China-Sea bathymetric transect and background current/stratification profiles.

Deflation↗

Infrared Galaxies Detected by the Atacama Cosmology Telescope

We report on 167 infrared (IR) galaxies selected by AKARI and IRAS and detected in the Atacama Cosmology Telescope (ACT) Data Release 5 (DR5) sky maps at the 98, 150, and 220 GHz frequency bands. Of these detections, 134 (80%) of the millimeter counterparts are first-time identifications with ACT. We expand the previous ACT extragalactic source catalogs, by including new 98 GHz detections and measurements from ACT DR5. We also report flux density measurements at the 98, 150, and 220 GHz frequency bands. We compute α 98-150 , α 98-220 , and α 150-220 millimeter-wave spectral indices and far-IR to millimeter-wave spectral indices between 90 μm and 98, 150, and 220 GHz. We specify the galaxy type, based on α 150-220 . We combine publicly available multiwavelength data—including ultraviolet, optical, near-IR, mid-IR, far-IR, and the millimeter measurements obtained in this work—and perform spectral energy distribution (SED) fitting with CIGALE. With the radio emission decomposition advantage of CIGALE V2022.0, we identify the origins of the millimeter emissions for 69 galaxies in our sample. Our analysis also shows that millimeter data alone indicates the need for a radio synchrotron component in the SEDs that are produced by active galactic nuclei (AGNs) and/or star formation. We present SEDs and measured physical properties of these galaxies, such as the dust luminosity, AGN luminosity, the total IR luminosity, and the ratio of the IR and radio luminosity. We quantify the relationships between the total IR luminosity and the millimeter-band luminosities, which can be used in the absence of SED analysis.

79 ASTRONOMY AND ASTROPHYSICS↗

Numerical simulation of spatially-evolving instability

A computational study of the spatial stability of plane Poiseuille flow is presented. The numerical scheme employs a time-splitting method to integrate the full Navier-Stokes equations using spectral collocation/finite-difference discretization on a non-staggered mesh. The eigenvalue decomposition procedure is applied for the solution of the Poisson equations using the capacitance matrix technique. The buffer domain method is incorporated for the outflow boundary conditions. The input perturbation velocities are obtained by solving the Orr-Sommerfeld equation for the nonlinear eigenvalue problem employing the companion matrix method. Computational results are compared with the linear theory for two-dimensional disturbances.

Danabasoglu, G.↗

On determining the spectrum of primordial inhomogeneity from the COBE DMR sky maps: Method

The natural approach to a spectral analysis of data distributed on the sky employs spherical harmonic decomposition. A common problem encountered in practical astronomy is the lack of full sky coverage in the available data. For example, the removal of the Galactic plane data from the Cosmic Background Explorer (COBE) Differential Microwave Radiometer (DMR) sky maps compromises Fourier analysis of the cosmic microwave background (CMB) temperature distribution due to the loss of orthogonality of the spherical harmonics. An explicit method for constructing orthonormal functions on an incomplete (e.g., Galaxy-cut) sphere is presented. These functions should be used in the proper Fourier analysis of the COBE DMR sky maps to provide the correct input for the determination of the spectrum of primordial inhomogeneity. The results of such an analysis are presented in an accompanying Letter. A similar algebraic construction of appropriate functions can be devised for other astronomical applications.

Gorski, Krzysztof M.↗

A natural basis for efficient brain-actuated control

The prospect of noninvasive brain-actuated control of computerized screen displays or locomotive devices is of interest to many and of crucial importance to a few 'locked-in' subjects who experience near total motor paralysis while retaining sensory and mental faculties. Currently several groups are attempting to achieve brain-actuated control of screen displays using operant conditioning of particular features of the spontaneous scalp electroencephalogram (EEG) including central mu-rhythms (9-12 Hz). A new EEG decomposition technique, independent component analysis (ICA), appears to be a foundation for new research in the design of systems for detection and operant control of endogenous EEG rhythms to achieve flexible EEG-based communication. ICA separates multichannel EEG data into spatially static and temporally independent components including separate components accounting for posterior alpha rhythms and central mu activities. We demonstrate using data from a visual selective attention task that ICA-derived mu-components can show much stronger spectral reactivity to motor events than activity measures for single scalp channels. ICA decompositions of spontaneous EEG would thus appear to form a natural basis for operant conditioning to achieve efficient and multidimensional brain-actuated control in motor-limited and locked-in subjects.

NASA Discipline Space Human Factors↗

Inertial transfers in the helical decomposition

The directions of the triadic energy transfers assumed in a previous paper agree with the spectral closures, in a similarity range, if the exponent of the power-law energy spectrum is less than unity. The helical interactions showing a strong local energy transfer when the triad is nonlocal, sum up to a reverse cascade unless the spectrum falls off faster than a -7/3 power of the wave number. The energy cascades from each type of helical interaction are calculated for a -5/3 inertial range using the eddy damped quasinormal Markovian model. One type of interaction is responsible for 86 percent of the cascade. The contributions of the two classes of helical interactions to the subgrid-scale eddy viscosity are presented, together with the contributions from the forward and reverse cascading interactions. An application of the assumption on the triadic energy transfers to turbulence under rapid rotation gives a simple argument for the tendency toward nonlinear two-dimensionalization of the flow.

Waleffe, Fabian↗

Solar photochemistry using the space shuttle

A continuing source of difficulty in cometary astrophysics is understanding the origin of C2, C3, NH and CO(+) species in comets. An experiment is proposed to investigate these problems by continuously releasing suspected parent gases from the space shuttle and using a dye laser to selectively excite fragments produced as a result of solar photochemical decomposition of the molecules. The backscattered fluorescence is gathered by a telescope, spectrally filtered, and measured as a function of time after the laser pulse.

Jackson, W. M.↗

Understanding the speciation of molten iodide salts via spectro-electrochemistry

Iodine is a high yield fission product of concern for the environmental effects due to its high volatility and biological impacts to the human body. Iodine speciation in molten salts, specifically iodide salts, is not well understood due to its reactivity at higher temperature domains. UV-Vis spectroscopy indicates a change in the speciation of the molten iodide salts starting at 500oC based on the decomposition of the salt itself, forming I3- ions. This work investigated the spectral changes of I- ions in molten LiI-KI and LiI-KI-NiI2 while manipulating the salts electrochemically using an inert graphite electrode at 400oC.The Li+/Li(s) and the Ni2+/Ni(s) transitions were studied using cyclic voltammetry, chronoamperometry/chronopotentiometry to characterize the respective reduction-oxidation waves. As cyclic voltammetry was applied, the UV-Vis spectroscopy showed a change in the characteristic signal of molten LiI-KI, indicating a disproportionation reaction in the molten salt, leading to formation of I3- ions and I2 gas.

36 - MATERIALS SCIENCE↗

Rethinking the ill-posedness of the spectral function reconstruction — Why is it fundamentally hard and how Artificial Neural Networks can help

Reconstructing hadron spectral functions through Euclidean correlation functions are of the important missions in lattice QCD calculations. However, in a Källen–Lehmann (KL) spectral representation, the reconstruction is observed to be ill-posed in practice. It is usually ascribed to the fewer observation points compared to the number of points in the spectral function. In this paper, by solving the eigenvalue problem of continuous KL convolution, we show analytically that the ill-posedness of the inversion is fundamental and it exists even for continuous correlation functions. We discussed how to introduce regulators to alleviate the predicament, in which include the Artificial Neural Networks (ANNs) representations recently proposed by the Authors in another study. The uniqueness of solutions using ANNs representations is manifested analytically and validated numerically. Reconstructed spectral functions using different regularization schemes are also demonstrated, together with their eigen-mode decomposition. We observe that components with large eigenvalues can be reliably reconstructed by all methods, whereas those with low eigenvalues need to be constrained by regulators.

97 MATHEMATICS AND COMPUTING↗

Structural analysis and design of multivariable control systems: An algebraic approach

The application of algebraic system theory to the design of controllers for multivariable (MV) systems is explored analytically using an approach based on state-space representations and matrix-fraction descriptions. Chapters are devoted to characteristic lambda matrices and canonical descriptions of MIMO systems; spectral analysis, divisors, and spectral factors of nonsingular lambda matrices; feedback control of MV systems; and structural decomposition theories and their application to MV control systems.

Tsay, Yih Tsong↗