SEARCH · Engineering Papers
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
This work investigates multipactor discharge in coaxial geometry with two-frequency rf electric field Vrf [sin(𝜔𝑡+𝜃)+𝛽 sin(n(𝜔𝑡+𝜃)+𝛾)], where Vrf is the peak voltage, 𝛽 is the field strength of the second car-rier mode relative to fundamental mode, n is the ratio of two carrier fre-quencies and 𝛾 is the relative phase of second carrier mode.
Abstract We report the first experimental evidence for rapid formation of hydrogen clathrates under mild pressure and temperature conditions within the cavities of a zirconium‐metalloporphyrin framework, specifically PCN‐222. PCN‐222 has been selected for its 1D mesoporous channels, high water‐stability, and proper hydrophilic behavior. Firstly, we optimize a microwave (MW)‐assisted method for the synthesis of nanosized PCN‐222 particles with precise structure control (exceptional homogeneity in morphology and crystalline phase purity), taking advantage of MW in terms of rapid/homogeneous heating, time and energy savings, as well as potential scalability of the synthetic method. Second, we explore the relevance of the large mesoporous 1D open channels within the PCN‐222 to promote the nucleation and growth of confined hydrogen clathrates. Experimental results show that PCN‐222 drives the nucleation process at a lower pressure than the bulk system (1.35 kbar vs 2 kbar), with fast kinetics (minutes), using pure water, and with a nearly complete water‐to‐hydrate conversion. Unfortunately, PCN‐222 cannot withstand these high pressures, which lead to a significant alteration of the mesoporous structure while the microporous network remains mainly unchanged.
Abstract We report the first experimental evidence for rapid formation of hydrogen clathrates under mild pressure and temperature conditions within the cavities of a zirconium‐metalloporphyrin framework, specifically PCN‐222. PCN‐222 has been selected for its 1D mesoporous channels, high water‐stability, and proper hydrophilic behavior. Firstly, we optimize a microwave (MW)‐assisted method for the synthesis of nanosized PCN‐222 particles with precise structure control (exceptional homogeneity in morphology and crystalline phase purity), taking advantage of MW in terms of rapid/homogeneous heating, time and energy savings, as well as potential scalability of the synthetic method. Second, we explore the relevance of the large mesoporous 1D open channels within the PCN‐222 to promote the nucleation and growth of confined hydrogen clathrates. Experimental results show that PCN‐222 drives the nucleation process at a lower pressure than the bulk system (1.35 kbar vs 2 kbar), with fast kinetics (minutes), using pure water, and with a nearly complete water‐to‐hydrate conversion. Unfortunately, PCN‐222 cannot withstand these high pressures, which lead to a significant alteration of the mesoporous structure while the microporous network remains mainly unchanged.
There are specific risks to the crew of the manned Mars mission from energetic particles generated by solar activity. Therefore, mission planning must provide for solar monitoring and solar activity forecasts. The main need is to be able to anticipate the energetic particle events associated with some solar flares and, occasionally, with erupting filaments. A second need may be for forecasts of solar interference with radio communication between the manned Mars mission (during any of its three phases) and Earth. These two tasks are compatible with a small solar observatory that would be used during the transit and orbital phases of the mission. Images of the Sun would be made several times per hour and, together with a solar X-ray detector, used to monitor for the occurrence of solar activity. The data would also provide a basis for research studies of the interplanetary medium utilizing observations covering more of the surface of the Sun than just the portion facing Earth.
The purpose of this paper is to exhibit the advantages and limitations to infrared astronomical observations form the moon. The most obvious apparent advantage is the lack of a lunar atmosphere; radiation arriving from the universe is neither extinguished nor refracted as it approaches the lunar surface. However, the Earth's atmosphere's protection against cosmic rays is also lost, and infrared detectors are highly sensitive to irradiation by energetic particles. A second apparent advantage is the relative ease with which beams from an array of telescopes can be interferometrically combined; again the vacuum environment with constant refractive index of unity throughout, permits combination without phase delay across the entire spectral range. But thermal radiation from optical components and stray radiation from the lunar environment, just outside the light path, tend to lessen that advantage, except in narrow-spectral-band spatial interferometry, in which only the radiation in individual spectral lines is mapped, and broad-band thermal emission can be effectively filtered out. On the Moon's night side, and in polar craters on the Moon, radiative cooling should permit the attainment of high sensitivity with large telescopes. Just as the proposed Edison spacecraft primary mirror is expected to reach temperatures around 40 K, so also large lunar primary mirrors might be expected to reach temperatures in that range, making the zodiacal glow the main source of noise at wavelengths shortward of 25 micrometers. The slow rota tion of the Moon, and the lack of vibrations from natural sources such as winds, should provide advantages in guiding on specific astronomical sources. To learn as much as possible about the difficulties of remote observations in a hostile environment, Antarctic observatories should be used as test beds for the rigors of lunar observations. The strenuous requirements for successful astronomical observations from the South Pole are similar to those expected to be encountered in observations conducted from the Moon.
The Electromagnetic Calorimeter (ECAL) is one of the subdetectors of the Compact Muon Solenoid (CMS), a general-purpose particle detector at the CERN Large Hadron Collider (LHC). The CMS ECAL Detector Control System (DCS) and the CMS ECAL Safety System (ESS) have supported the detector operations and ensured the detector’s integrity since the CMS commissioning phase, more than 10 years ago. Over this long period, several changes to both systems were necessary to correct issues, extend functionality and keep them in-line with current hardware technologies and the evolution of software platforms. Due to the constraints imposed on significant changes to a running system, major hardware and software upgrades were therefore deferred to the second LHC Long Shutdown (LS2). This paper presents the architectures of the CMS ECAL control and safety systems, discusses the ongoing and planned upgrades, details implementation processes and validation methods and highlights the expectations for the post-LS2 systems.
Extensive hard X-ray (HXR)/gamma-ray (GR) observations of solar flares, performed during solar cycles 21 and 22 have led to important new discoveries. These data, combined with observations obtained in other parts of the electromagnetic spectrum (soft X-ray, Hard X-ray, optical, and radio) largley contributed to get a better understanding and to develop new ideas on particle acceleration and transport during solar flares. This review presents new observational facts relevant to hard X-ray/gamma-ray producing flares. Among these are the frequent presence of sub-second time structure in the hard X-ray emission, the variability in hard X-ray and radio spatial distributions during a flare and from flare to flare, the evidence for strong gamma-ray line emission from the Corona and the existence of extended phases of the gamma-ray emission lasting for several hours after the flare onset. This ensemble of observations indicates that particle acceleration takes place at different sites in a complex and dynamic magnetic field environment.
This study presents a comprehensive investigation of two-surface multipactor discharge in coaxial transmission lines under two-frequency radio frequency (RF) excitation using one-dimensional Monte Carlo simulations validated against three-dimensional particle-in-cell simulations and experimental data. The results show that introducing a second carrier mode can suppress multipactor by reshaping and shrinking the susceptibility region, with the extent and location of suppression strongly dependent on the device's aspect ratio and the relative phase of the second carrier mode. Distinct suppression patterns are observed across different fd regimes, while in some cases, susceptibility expansion also occurs under two-frequency operation. A key outcome is the identification and delineation of pure and mixed multipactor modes in coaxial geometry, where analytical mode boundaries are not readily available. Unlike planar geometries, pure-mode regions in coaxial systems overlap with mixed-mode domains, complicating mode identification. Additionally, image charge forces are found to have negligible influence on susceptibility thresholds but strongly affect electron growth rates. These findings offer valuable insights into the use of waveform engineering for controlling multipactor in high-power RF systems.
Abstract Non‐linear optical materials must possess a balanced combination of laser‐induced damage threshold (LDT) and second‐harmonic generation (SHG) and be phase matchable. In our previous work, chiral and polar La 3 CuGeS 7 was identified as a promising non‐linear optical material. Herein, we report the optimization of non‐linear optical properties through replacement of La with smaller lanthanides. It is determined that Gd 3 CuGeS 7 exhibits the best combination of SHG (1.6× AgGaS 2 at 88–105 μm particle size) and LDT (3× AgGaS 2 , 89 MW/cm 2 ) and is phase matchable. Based on changes in metal‐sulfur bond lengths and angles, we further propose structural optimization through solid‐solution formation and doping.
Explore the source record for details and available documents.
We investigate the charge-density wave (CDW) transition for one-dimensional spinless fermions at half band filling with nearest-neighbor electron transfer amplitude t and interaction V. The model is equivalent to the anisotropic XXZ Heisenberg model for which the Bethe Ansatz provides an exact solution. For V>V c =2t, the CDW order parameter and the single-particle gap are finite but exponentially small, as is characteristic for a Kosterlitz-Thouless transition. It is notoriously difficult to locate such infinite-order phase transitions in the phase diagram using approximate analytical and numerical approaches. Second-order Hartree-Fock theory is qualitatively applicable for all interaction strengths, and predicts the CDW transition to occur at V$^{(2)}_{c,2}$≈1.5t. Second-order Hartree Fock theory is almost variational because the density of quasiparticle excitations is small. We apply the density-matrix renormalization group (DMRG) for periodic boundary conditions for system sizes up to 514 sites, which permits a reliable extrapolation of all physical quantities to the thermodynamic limit, apart from the critical region. We investigate the ground-state energy, the gap, the order parameter, the momentum distribution, the quasiparticle density, and the density-density correlation function to locate V c from the DMRG data. In conclusion, tracing the breakdown of the Luttinger liquid and the peak in the quasiparticle density at the band edge permits us to reproduce V c with an accuracy of one percent.
The applicability of eigenfunction methods to the theory of magnetospheric radial diffusion is investigated analytically, with a focus on the operator (Lambda) for radiation-belt and ring-current particles. It is shown that the eigenfunctions of Lambda can be expressed in terms of a linear combination of ordinary Bessel functions of the first and second kinds, and that the solution for the drift-averaged phase-space density can be expressed as the sum of a quasi-static solution and a time-dependent superposition of the eigenfunctions of Lambda. Results for illustrative and practical sample problems are presented in extensive tables and graphs and discussed in detail.
XD synthesis, powder blending, and hot pressing techniques have been utilized to produce NiAl composites containing 4, 7.5, 15, and 25 vol pct alumina whiskers and hybrid composite materials with 15 vol pct Al2O3 + 10 or 20 vol pct, nominally 1 micron TiB2 particles. The resistance to slow plastic flow was determined at 1200 and 1300 K via compression testing in air under constant velocity conditions. The stress-strain behavior of the intermetallic composites depended on the fraction of second phases where the 4 and 7.5 percent Al2O3 materials flowed at a nominally constant stress after about 2 percent deformation, while all the other composites exhibited diffuse yielding followed by strain softening. The flow stress-strain rate properties increased with volume fraction of Al2O3 whiskers except for the 4 and 7.5 percent materials, which had similar strengths. The hybrid composite NiAl + 15Al2O3 + 10TiB2 was substantially stronger than the materials simply containing alumina. Deformation in these composites can be described by the Kelly and Street model of creep in perfectly bonded, rigid, discontinuous fiber materials.
Through an intensive collection and assimilation effort of Solid Rocket Motor (SRM) related data and resources, the author offers a resolution to the uncertainties surrounding SRM particulate generation, sufficiently so to enable a first-order incorporation of SRMs as a source term in space debris environment definition. The following five key conclusions are derived: 1) the emission of particles in the size regime of greatest concern from an orbital debris hazard perspective (D > 100 micron), and in significant quantities, occurs only during the Tail-off phase of SRM burn activity, 2) the velocity of these emissions is correspondingly small - between 0 and 100 m/s, 3) the total Tail-off emitted mass is between approximately 0.04 and 0.65% of the initial propellant mass, 4) the majority of Tail-off emissions occur during the 30 second period that begins as the chamber pressure declines below approximately 34.5 kPa (5 psia) and 5) the size distribution for the emitted particles ranges from 100 micron <D< 5cm.
The exhibition of an opposition effect is a phenomenon common to all atmosphereless bodies in the solar system. This effect involves a nonlinear surge in brightness for solar phase angles, alpha, less than about 7 deg, and a nonlinear drop-off in brightness at large phase angles. Except for the moon, Mercury, and close-earth-approaching asteroids, atmosphereless bodies can be observed from earth only in a limited phase angle range. Lumme and Bowell (1981) developed a radiative transfer formalism and showed that multiple scattering between the regolith particles represents an essential factor. It was found that all the phase curves can be generated by only two standard functions with two unknown parameters. The first function is due to single scattering processes in the regolith and the second function is due to multiply scattered light. Another purely empirical approach was also investigated by Lumme et al. (1984). A summary of the fit of an empirical model to 13 objects is provided in the paper.
An analysis of data obtained with the vertical underground muon telescope at Embudo, NM shows that the solar diurnal variation in cosmic ray intensity is a persistent phenomenon over the 1973-1979 period. Assuming that the daily fluctuations in the amplitude and phase of the diurnal variation are random perturbations about the mean vector, the relative magnitude of the random component is determined. In the second part, the Diffusion-Convection model of cosmic ray transport is applied to high rigidity particles detected at the earth in order to deduce the behavior of the heliospheric transport parameters between 1973 and 1979. It is suggested that the diurnal variation observed at Embudo during 1979 may require a contribution from the charged particle drifts.
Linac is the first machine in the Accelerator chain at Fermilab where particles are accelerated from 35 keV to 400 MeV and travel to the Booster where they are stripped of the extra electrons to become protons. Tuning Linac is performed using diagnostics to ensure stable intensity and energy while minimizing uncontrolled particle loss. I have been revisiting diagnostics in the Linac in order to understand their signals and to ensure their data is reliable. I revisited Beam Loss Monitors (BLMs) for the loss data confidence. For the confidence of energy data there were two approaches. The first approach was time-of-flight measurements using Beam Position Monitors (BPMs) and beam velocity stripline pick-up that provides beam phase data. The second approach used the relation between beam position data from BPMs and dispersion values from MAD-X simulation to calculate energy. Our goal after understanding the data from the Linac diagnostics and finding the data reliable is to control the L inac parameters using Machine Learning techniques to increase the reliability and quality of beam delivered from Linac.
The flow field within the mesopores of sorbent particles plays a crucial role in radionuclide diffusion and ion uptake kinetics, thus, impacting the overall performance of porous nuclear waste form materials. To fundamentally understand the influence of microstructures and material properties on the radionuclide absorption and retention processes requires a coupled multi-physics model that considers the advection and diffusion within the flow field, the reaction at liquid-solid interfaces, and finally, the solid-state diffusion within a complex nanoporous medium. Here, this study employs the volumetric lattice Boltzmann method (VLBM) to accurately and efficiently calculate the steady state velocity field inside the mesopores of sorbent particles. The obtained velocity field is then utilized to calculate the advection of ions in the steady flow. A phase field (PF) model of ion uptake is used to describe the reaction occurring at the solid-liquid interface and diffusion inside the porous medium. The integrated PF-VLBM model is verified in terms of the mass conservation and numerical efficiency and validated qualitatively with experimental observation data. Then, it is applied to study the influence of thermodynamic and kinetic properties, as well as flow field conditions on the ion uptake kinetics. The numerical results demonstrate that the ion uptake kinetics in porous particles has three distinct stages, which is in agreement with the observations in continuous flow experiments. In the first stage, the kinetics is predominantly controlled by the flow field and ion diffusivity in the liquid phase. The kinetics in the second stage is primarily governed by ion diffusivity in the solid phase. In the third stage the system reaches a dynamic equilibrium with a net zero uptake flux at the interface. It is also found that porous structures significantly affect the efficiency and capacity of ion uptake. The simulation results can help to understand the physics behind the observed ion uptake kinetics in experiments and to facilitate the development of constitutive equations that can account for heterogeneous microstructures in engineering performance codes.