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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Insights into negative differential resistance in MoS 2 Esaki diodes: A first-principles perspective

MoS 2 is a two-dimensional material with a band gap depending on the number of layers and tunable by an external electric field. The experimentally observed intralayer band-to-band tunneling and interlayer band-to-band tunneling in this material present an opportunity for new electronic applications in tunnel field-effect transistors. However, such a widely accepted concept has yet to be been supported by theoretical investigations based on first principles. In this paper, using density functional theory, in conjunction with nonequilibrium Green's function techniques and our electric field gating method, enabled by a large-scale computational approach, we study the relation between band alignment and transmission in planar and side-stack MoS 2 p–i–n junction configurations. Here, we demonstrate the presence of negative differential resistance for both in-plane and interlayer current, a staple characteristic of tunnel diode junctions, and analyze the physical origin of such an effect. Electrostatic potentials, the van der Waals barrier, and a complex band analysis are also examined for a thorough understanding of Esaki diodes.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2015

Anomalous pressure dependence of magnetic ordering temperature in Tb revealed by resistivity measurements to 141 GPa. Comparison with Gd and Dy

In previous studies the pressure dependence of the magnetic ordering temperature T o of Dy was found to exhibit a sharp increase above its volume collapse pressure of 73 GPa, appearing to reach temperatures well above ambient at 157 GPa. In a search for a second such lanthanide, electrical resistivity measurements were carried out on neighboring Tb to 141 GPa over the temperature range 3.8 - 295 K. Below Tb’s volume collapse pressure of 53 GPa, the pressure dependence T o (P) mirrors that of both Dy and Gd. However, at higher pressures T o (P) for Tb becomes highly anomalous. This result, together with the very strong suppression of superconductivity by dilute Tb ions in Y, suggests that extreme pressure transports Tb into an unconventional magnetic state with an anomalously high magnetic ordering temperature.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2011

Dynamic Control over Mega-Ampere Electron Currents in Metals Using Ionization-Driven Resistive Magnetic Fields

The possibility of dynamically shaping mega-ampere electron currents generated in solids by ultraintense laser pulses in various conductor materials has been investigated. By tuning the target ionization dynamics, which depends both on the target material properties and on the input electron beam characteristics, we can control the growth of resistive magnetic fields that feedback on the current transport. As a result, collimation, hollowing, or filamentation of the electron beam can all be obtained. These results are beneficial for applications such as the production of secondary particles and radiation sources and fast ignition of inertial confinement fusion.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

Pressure-Resistant Intermediate Valence in the Kondo Insulator SmB 6

Resonant x-ray emission spectroscopy was used to determine the pressure dependence of the f-electron occupancy in the Kondo insulator SmB 6 . Applied pressure reduces the f occupancy, but surprisingly, the material maintains a significant divalent character up to a pressure of at least 35 GPa. Thus, the closure of the resistive activation energy gap and onset of magnetic order are not driven by stabilization of an integer valent state. In conclusion, over the entire pressure range, the material maintains a remarkably stable intermediate valence that can in principle support a nontrivial band structure.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Colossal Density-Driven Resistance Response in the Negative Charge Transfer Insulator MnS 2

A reversible density driven insulator to metal to insulator transition in high-spin MnS 2 is experimentally observed, leading with a colossal electrical resistance drop of $10^8$ Omega by 12 GPa. Density functional theory simulations reveal the metallization to be unexpectedly driven by previously unoccupied $S_{2}^{-2}$ $\sigma^{*}_{3p}$ antibonding states crossing the Fermi level. This is a unique variant of the charge transfer insulator to metal transition for negative charge transfer insulators having anions with an unsaturated valence. By 36 GPa the emergence of the low-spin insulating arsenopyrite ($P2_1/c$) is confirmed, and the bulk metallicity is broken with the system returning to an insulative electronic state.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2015

Bypassing Iron Storage in Endodermal Vacuoles Rescues the Iron Mobilization Defect in the natural resistance associated-macrophage protein3natural resistance associated-macrophage protein4 Double Mutant

To improve seed iron (Fe) content and bioavailability, it is crucial to decipher the mechanisms that control Fe storage during seed development. In Arabidopsis ( Arabidopsis thaliana ) seeds, most Fe is concentrated in insoluble precipitates, with phytate in the vacuoles of cells surrounding the vasculature of the embryo. NATURAL RESISTANCE ASSOCIATED-MACROPHAGE PROTEIN3 (AtNRAMP3) and AtNRAMP4 function redundantly in Fe retrieval from vacuoles during germination. When germinated under Fe-deficient conditions, development of the nramp3nramp4 double mutant is arrested as a consequence of impaired Fe mobilization. To identify novel genes involved in seed Fe homeostasis, we screened an ethyl methanesulfonate-mutagenized population of nramp3nramp4 seedlings for mutations suppressing their phenotypes on low Fe. Here, we report that, among the suppressors, two independent mutations in the VACUOLAR IRON TRANSPORTER1 ( AtVIT1 ) gene caused the suppressor phenotype. The AtVIT1 transporter is involved in Fe influx into vacuoles of endodermal and bundle sheath cells. Furthermore, this result establishes a functional link between Fe loading in vacuoles by AtVIT1 and its remobilization by AtNRAMP3 and AtNRAMP4. Furthermore, analysis of subcellular Fe localization indicates that simultaneous disruption of AtVIT1, AtNRAMP3, and AtNRAMP4 limits Fe accumulation in vacuolar globoids.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2017

Simulation of the dynamics of resistive hose instability of a relativistic electron beam propagating in a resistive plasma channel with arbitrary conductivity

The spatial dynamics of the resistive hose instability of a relativistic electron beam has been studied for the case when the charge neutralization time is much longer, on the order of, or much shorter than the current compensation time. It has been found that the growth of this instability has the highest increment when the charge neutralization time is on the order of skin time.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

New Creep-Resistant Cast Alloys with Improved Oxidation Resistance in Water Vapor at 650–800°C

Cast stainless steel CF8C-Plus (19wt%Cr/12%Ni) has excellent creep properties, but limited oxidation resistance above 700 C in environments containing H 2 O. One strategy to improve the alloy oxidation performance is to increase the Cr and Ni concentration. Two new alloys, with, respectively, 21wt%Cr 15wt%Ni and 22wt%Cr 17.5wt%Ni were therefore developed and their long-term oxidation behaviors in humid air were compared with the oxidation behavior of five other cast alloys. Also, at 650 C and 700 C, all the alloys formed internal Cr-rich nodules, and outer nodules or layers rich in Fe and Ni, but they grew a protective Cr-rich inner layer over time. At 750 C, the lower alloyed steels such as CF8C-Plus showed large metal losses, but the two new alloys still exhibited a protective oxidation behavior. The 21Cr 15Ni alloy was severely oxidized in locations at 800 C, but that was not the case for the 22Cr 17.5Ni alloy. Thus, the two new modified alloys represent a potential operating temperature gain of, respectively, 50 C and 100 C in aggressive environments compared with the CF8C-Plus alloy.

36 MATERIALS SCIENCE↗
NASA NTRS1972

Tolerance to external breathing resistance with particular reference to high inspiratory resistance

The ability of men to exercise while breathing through graded inspiratory resistances was studied in order to define acceptable respiratory mouthpiece assembly standards. Experimental results with subjects wearing breathing masks and walking for 30 min on treadmills were used to calculate expiratory work rates. It is concluded that the airflow must be appropriate to the upper limit of minute ventilation likely to be encountered in the men wearing the apparatus.

Bentley, R. A.↗
NASA NTRS1989

Shatter-Resistant, Flame-Resistant Window

Combustion-chamber window combines properties of polycarbonate and sapphire. Inner layer of sapphire, withstands flame in chamber. Outer layer of polycarbonate tough but susceptible to weakening by flame and protected from flame by sapphire layer. Resists flames, shattering, and high pressure. Windows withstand 60 lb/in. to second power (414 kPa) in hydrostatic pressure vessel. Also survives leak test under internal pressure of 2 atm (0.2 MPa) of helium and external pressure of 10 to negative fifth power torr (1.3 mPa). Has transmission density of 0.08 to 0.11 in visible light. In contrast, unbonded layers have transmission density of 0.13 to 0.16.

Richardson, William R.↗
DOE OSTI2015

Controlled surface segregation leads to efficient coke-resistant nickel/platinum bimetallic catalysts for the dry reforming of methane

Surface composition and structure are of vital importance for heterogeneous catalysts, especially for bimetallic catalysts, which often vary as a function of reaction conditions (known as surface segregation). The preparation of bimetallic catalysts with controlled metal surface composition and structure is very challenging. In this study, we synthesize a series of Ni/Pt bimetallic catalysts with controlled metal surface composition and structure using a method derived from surface organometallic chemistry. The evolution of the surface composition and structure of the obtained bimetallic catalysts under simulated reaction conditions is investigated by various techniques, which include CO-probe IR spectroscopy, high-angle annular dark-field scanning transmission electron microscopy, energy-dispersive X-ray spectroscopy, extended X-ray absorption fine structure analysis, X-ray absorption near-edge structure analysis, XRD, and X-ray photoelectron spectroscopy. It is demonstrated that the structure of the bimetallic catalyst is evolved from Pt monolayer island-modified Ni nanoparticles to core–shell bimetallic nanoparticles composed of a Ni-rich core and a Ni/Pt alloy shell upon thermal treatment. As a result, these catalysts are active for the dry reforming of methane, and their catalytic activities, stabilities, and carbon formation vary with their surface composition and structure.

36 MATERIALS SCIENCE↗