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At least 181 records · Page 10

Power Conversion Efficiencies of Perovskite and Dye-Sensitized Solar Cells under Various Solar Radiation Intensities

We present the results of a comparative study on behaviour of the photovoltaic parameters in perovskite (PSC), dye-sensitized (DSC) and crystalline silicon (c-Si) solar cells under various intensities of solar radiation (10–1000 W/m{sup 2}). It was found that unlike c-Si, the power conversion efficiencies of PSC and DSC under low radiation intensities are comparable with the corresponding values observed under standard light intensity of 1000 W/m{sup 2} (AM1.5G). We have shown that high performance of the PSC and DSC at low and diffuse lighting conditions can be explained by the properties of the nanostructured TiO{sub 2}-based photoelectrodes depending on the structure, morphology and the thickness of the TiO{sub 2} layers.

14 SOLAR ENERGY↗

Detailed balance limit of power conversion efficiency for organic photovoltaics

A fundamental difference between inorganic photovoltaic (IPV) and organic photovoltaic (OPV) cells is that charges are generated at the interface in OPV cells, while free charges can be generated in the bulk in IPV cells. In OPV cells, charge generation involves intrinsic energy losses to dissociate excitons at the interface between the donor and acceptor. By taking into account the energy losses, we show the theoretical limits of the power conversion efficiency set by radiative recombination of the carriers on the basis of the detailed balance relation between radiation from the cell and black-body radiation.

14 SOLAR ENERGY↗

ZnCuInS/ZnSe/ZnS Quantum Dot-Based Downconversion Light-Emitting Diodes and Their Thermal Effect

The quantum dot-based light-emitting diodes (QD-LEDs) were fabricated using blue GaN chips and red-, yellow-, and green-emitting ZnCuInS/ZnSe/ZnS QDs. The power efficiencies were measured as 14.0 lm/W for red, 47.1 lm/W for yellow, and 62.4 lm/W for green LEDs at 2.6 V. The temperature effect of ZnCuInS/ZnSe/ZnS QDs on these LEDs was investigated using CIE chromaticity coordinates, spectral wavelength, full width at half maximum (FWHM), and power efficiency (PE). The thermal quenching induced by the increased surface temperature of the device was confirmed to be one of the important factors to decrease power efficiencies while the CIE chromaticity coordinates changed little due to the low emission temperature coefficients of 0.022, 0.050, and 0.068 nm/°C for red-, yellow-, and green-emitting ZnCuInS/ZnSe/ZnS QDs. These indicate that ZnCuInS/ZnSe/ZnS QDs are more suitable for downconversion LEDs compared to CdSe QDs.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Integration Methods for High-Density Integrated Electric Drives (Final Technical Report)

The project goal was to research, design and fabricate high-power-density, high-performance SiC power electronic modules for motor drive inverters in electric vehicles (EVs) to enable the subsequent motor drive to achieve a power density of 100 kW/l. EVs use electric motors instead of internal combustion engines as the prime mover, and their core components are semiconductor-based power electronic modules. Efficient power electronic modules play a vital role in power conversion systems. The performance of power modules directly affects the energy efficiency and overall performance of electric vehicles. Therefore, it is particularly important to develop power modules with high power density and high electrical performance that will perform reliably under EV environmental conditions. To achieve these goals, advanced electronic packaging technologies are required. This report describes a 5-year effort to integrate key aspects surrounding the basic power devices into the module itself to increase power density. These include sensing and sensing readout circuits, gate driver circuits, and two-sided cooling solutions.

33 ADVANCED PROPULSION SYSTEMS↗

Optical fiber sensor having an active core

An optical fiber is provided. The fiber is comprised of an active fiber core which produces waves of light upon excitation. A factor ka is identified and increased until a desired improvement in power efficiency is obtained. The variable a is the radius of the active fiber core and k is defined as 2 pi/lambda wherein lambda is the wavelength of the light produced by the active fiber core. In one embodiment, the factor ka is increased until the power efficiency stabilizes. In addition to a bare fiber core embodiment, a two-stage fluorescent fiber is provided wherein an active cladding surrounds a portion of the active fiber core having an improved ka factor. The power efficiency of the embodiment is further improved by increasing a difference between the respective indices of refraction of the active cladding and the active fiber core.

Egalon, Claudio Oliveira↗

Power and efficiency analysis of a realistic resonant tunneling diode thermoelectric

Low-dimensional systems with sharp features in the density of states have been proposed as a means for improving the efficiency of thermoelectric devices. Quantum dot systems, which offer the sharpest density of states achievable, however, suffer from low power outputs while bulk (3-D) thermoelectrics, while displaying high power outputs, offer very low efficiencies. Here, we analyze the use of a resonant tunneling diode structure that combines the best of both aspects, that is, density of states distortion with a finite bandwidth due to confinement that aids the efficiency and a large number of current carrying transverse modes that enhances the total power output. We show that this device can achieve a high power output (∼0.3 MW∕m{sup 2}) at efficiencies of ∼40% of the Carnot efficiency due to the contribution from these transverse momentum states at a finite bandwidth of kT∕2. We then provide a detailed analysis of the physics of charge and heat transport with insights on parasitic currents that reduce the efficiency. Finally, a comparison between the resonant tunneling diode and a quantum dot device with comparable bandwidth reveals that a similar performance requires ultra-dense areal quantum dot densities of ∼10{sup 12}/cm{sup 2}.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Strong electroluminescence from SiO{sub 2}-Tb{sub 2}O{sub 3}-Al{sub 2}O{sub 3} mixed layers fabricated by atomic layer deposition

We report on the bright green electroluminescence (EL) with power efficiencies up to 0.15% of SiO{sub 2}-Tb{sub 2}O{sub 3}-mixed layers fabricated by atomic layer deposition and partly co-doped with Al{sub 2}O{sub 3}. The electrical, EL, and breakdown behavior is investigated as a function of the Tb and the Al concentration. Special attention has been paid to the beneficial role of Al{sub 2}O{sub 3} co-doping which improves important device parameters. In detail, it increases the maximum EL power efficiency and EL decay time, it nearly doubles the fraction of excitable Tb{sup 3+} ions, it shifts the region of high EL power efficiencies to higher injection currents, and it reduces the EL quenching over the device lifetime by an approximate factor of two. It is assumed that the presence of Al{sub 2}O{sub 3} interferes the formation of Tb clusters and related defects. Therefore, the system SiO{sub 2}-Tb{sub 2}O{sub 3}-Al{sub 2}O{sub 3} represents a promising alternative for integrated, Si-based light emitters.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Traction Drives for Zero Stick-Slip Robots, and Reaction Free, Momentum Balanced Systems

Two differential (dual input, single output) drives (a roller-gear and a pure roller), and a momentum balanced (single input, dual output) drive (pure roller ) were designed, fabricated, and tested. The differential drives are each rated at 295 rad/sec (2800 rpm) input speed, 450 N-m (4,000 in-lbf) output torque. The momentum balanced drive is rated at 302 rad/sec (2880 rpm) input speed, and dual output torques of 434N-m (3840 in-lbf). The Dual Input Differential Roller-Gear Drive (DC-700) has a planetary roller-gear system with a reduction ratio (one input driving the output with the second input fixed) of 29.23: 1. The Dual Input Differential Roller Drive (DC-500) has a planetary roller system with a reduction ratio of approximately 24:1. Each of the differential drives features dual roller-gear or roller arrangements consisting of a sun, four first row planets, four second row planets, and a ring. The Momentum Balanced (Grounded Ring) Drive (DC-400) has a planetary roller system with a reduction ratio of 24:1 with both outputs counterrotating at equal speed. Its single roller cluster consists of a sun, five first and five second row planets, a roller cage or spider and a ring. Outputs are taken from both the roller cage and the ring which counterrotate. Test results reported for all three drives include angular and torque ripple (linearity and cogging), viscous and Coulomb friction, and forward and reverse power efficiency. Of the two differential drives, the Differential Roller Drive had better linearity and less cogging than did the Differential Roller-Gear Drive, but it had higher friction and lower efficiency (particularly at low power throughput levels). Use of full preloading rather than a variable preload system in the Differential Roller Drive assessed a heavy penalty in part load efficiency. Maximum measured efficiency (ratio of power out to power in) was 95% for the Differential Roller-Gear Drive and 86% for the Differential Roller Drive. The Momentum Balanced (Grounded Ring) Drive performed as expected kinematically. Reduction r-atios to the two counterrotating outputs (design nominal=24:1) were measured to be 23.98:1 and 24.12:1 at zero load.. At 25ONm (2200 in-lbf) output torque the ratio changed 2% due to roller creep. This drive was the smoothest of all three as determined from linearity and cogging tests, and maximum measured efficiency (ratio of power out to power in) was 95%. The disadvantages of full preloading as comvared to variable preload were apparent in this drive as in the Differential Roller Drive. Efficiencies at part load were low, but improved dramatically with increases in torque. These were consistent with friction measurements which indicated losses primarily from Coulomb friction. The initial preload level setting was low so roller slip was encountered at higher torques during testing.

Anderson, William J.↗

Doping and energy band modulation of nanoporous electrodes for enhancing power conversion efficiency of dye-sensitized solar cells

Highlights: • Cd and La are co-doped into TiO{sub 2} by sol-gel method. • La dopant modulates particle size to enhance dye adsorption. • Cd dopant causes decrease in band gap of TiO{sub 2} and creates trap sites. • Only small amount of Cd dopant required for the favorable decrease in band gap. • 24% of efficiency increment for 0.1 mol% Cd-La TiO{sub 2} compared to pure TiO{sub 2}. - Abstract: This work report, for the first time, the co-doping of mesoporous TiO{sub 2} with Cd{sup 2+} and La{sup 3+} cations for improved performance of dye-sensitized solar cells (DSSCs). Cd{sup 2+} ions modify the TiO{sub 2} lattice interstitially and lower the band gap enabling better electron injection. La{sup 3+} ions, having a larger ionic radius compared to that of Ti{sup 4+} ions, occupy interstitial sites and modulate particle size which increase surface area, hence the dye adsorption. The result demonstrates that DSSC employed with 0.1 mol% Cd-La co-doped TiO{sub 2} anode an increase in power conversion efficiency of 24% compared to DSSC with pure TiO{sub 2} anode. The doping concentration has to remain low as not to completely transform the morphology of TiO{sub 2} and to decrease the number of oxygen vacancies forming trap sites for recombination. The selection of ionic radius of dopants is significant as they can modify the TiO{sub 2} lattice either by substitution or interstitial of titanium ions.

36 MATERIALS SCIENCE↗

Optimal laser wavelength for efficient laser power converter operation over temperature

A temperature dependent modeling study is conducted on a GaAs laser power converter to identify the optimal incident laser wavelength for optical power transmission. Furthermore, the respective temperature dependent maximal conversion efficiencies in the radiative limit as well as in a practically achievable limit are presented. The model is based on the transfer matrix method coupled to a two-diode model, and is calibrated to experimental data of a GaAs photovoltaic device over laser irradiance and temperature. Since the laser wavelength does not strongly influence the open circuit voltage of the laser power converter, the optimal laser wavelength is determined to be in the range where the external quantum efficiency is maximal, but weighted by the photon flux of the laser.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Improved Reliability of Solid Oxide Fuel Cell Systems. Final scientific/technical report

This program is furthering the development of SOFC technology to meet the durability requirements required by the market for the service life and costs for such a power generation technology. SOFC technology provides an environmentally friendly and highly efficient power generation. LGFCS is developing a 1MW pressurized SOFC system for distributed power generation. The planned commercial product is expected to have an efficiency of ~60% (net AC) and fueled by natural gas. The lower carbon content of natural gas combined with the efficient power generation results in significant environmental benefits (lower CO2 greenhouse emissions). The SOFC technology provides a means for efficient utilization of the large US reserves of natural gas and enhances national energy independence. The SOFC technology will initially serve the distributed power generation market and gain market acceptance and smaller power system sizes. The technology is well suited to carbon sequestration given the separated air and fuel streams. The Department of Energy (DOE) envisions a centralized power generation technology that could use coal gasification as an integrated gasification fuel cell (IGFC) power plant at the >100MW scale with CO2 capture.

25 ENERGY STORAGE↗

Heat engine development for solar thermal power systems

The technical status of three heat engines (Stirling, high-temperature Brayton, and Combined cycle) for use in solar thermal power systems is presented. Performance goals necessary to develop a system competitive with conventional power requirements include an external heated engine output less than 40 kW, and efficiency power conversion subsystem at least 40% at rated output, and a half-power efficiency of at least 37%. Results show that the Stirling engine can offer a 39% efficiency with 100 hours of life, and a 20% efficiency with 10,000 hours of life, but problems with seals and heater heads exist. With a demonstrated efficiency near 31% at 1500 F and a minimum lifetime of 100,000 hours, the Brayton engine does not offer sufficient engine lifetime, efficiency, and maintenance for solar thermal power systems. Examination of the Rankine bottoming cycle of the Combined cycle engine reveals a 30 year lifetime, but a low efficiency. Additional development of engines for solar use is primarily in the areas of components to provide a long lifetime, high reliability, and low maintenance (no more than $0.001/kW-hr).

Pham, H. Q.↗

EVSE Characterization: V2G EVSE Comparison

As part of the U.S. Department of Energy EVs@Scale consortium Next-Generation Profiles project, results and analysis from the characterization of high-power conductive and wireless charging infrastructure are presented. This characterization is conducted over a wide range of direct current (DC) current and DC voltage operation for nominal test conditions and off-nominal test conditions. Test plans and procedures were developed to define the test configurations and requirements, measurement parameters, and test procedures used throughout testing. Results from a 2024 study conducted on electric vehicle supply equipment (EVSE) characterization by the Idaho National Laboratory (INL) include two bi-directional vehicle-to-grid (V2G) capable EVSEs. These EVSE are referred to as V2G-EVSE9 and V2G-EVSE10. Laboratory testing is conducted at nominal test conditions to characterize the power transfer capabilities, efficiency, power factor, and other power quality metrics of the two DC EVSEs capable of V2G bi-directional power transfer. Results from testing show the performance is consistent for V2G-EVSE9 and V2G-EVSE10 when comparing charging to discharging performance, except for V2G-EVSE10 for power transfer when operating above 70% of the rated DC current. V2G-EVSE10 efficiency is >98% while charging and <91% while discharging at the same operating conditions, near maximum-rated current, at 300VDC. In contrast, V2G-EVSE9 results are consistent for charging and discharging. This EVSE is nearly 96% efficient while charging or discharging when operating over 50% of rated AC power. V2G EVSE performance is also characterized during off-nominal AC grid conditions involving AC voltage deviation (426 VAC to 518 VAC), AC frequency deviation of +2% (58.8 Hz to 61.2 Hz), and AC voltage harmonics injection. Many test conditions have little-to-no impact on performance characteristics of the two EVSEs; however, there are a few notable findings with significant power transfer capability impacts. AC voltage harmonics injection resulted in negative impacts on power quality attributes for both EVSEs, but with no impact on power transfer capability. Off-nominal AC voltage and frequency conditions resulted in unstable or lack of power transfer capability for both EVSEs. V2G-EVSE9 is unable to transfer power when AC voltage is >300V L-N. V2G-EVSE10 is unable to transfer power when AC frequency deviation exceeds +0.8%. V2G energy management system transient response and latency are quantified during laboratory testing. V2G-EVSE9 and V2G-EVSE10 utilize cloud-based V2G energy management systems that command the power transfer level between the EVSE and EV. The latency and response characteristics of the entire systems (web-based user interface, V2G energy management system, cellular communications, and EVSE response) are quantified through laboratory testing for V2G-EVSE9 and V2G-EVSE10. V2G-EVSE9 latency ranges from 0.8 to 1.8 seconds, whereas V2G-EVSE10 latency ranges from 3.4 to 8.8 seconds. The ramp rate to a change in power transfer request also differs between the two EVSEs. V2G-EVSE10 ramp rate ranges from 50% to -250% of rated AC power per second, whereas V2G-EVSE9 rate ranges from 95% to -95% of rated AC power per second. At the highest rate of change in power transfer, V2G-EVSE10 can change from full charge power to full discharge power in less than one second. The V2G EVSE characterization presented in this report provides valuable insights and results for use by numerous entities. This includes modeling and simulation organizations, decision makers, fleet planning, industry stakeholders, and many others involved with the development and deployment of electrified transportation technologies. Additional high-power DC chargers, bidirectional chargers, and inductive power transfer EVSE characterization results are anticipated from additional EVSE brands and models, which will be detailed in future publications in support of the U.S. Department of Energy EVs@Scale consortium Next-Gen Profiles project.

25 ENERGY STORAGE↗

Self-powered Heating: Efficiency Analysis

Conventional fuel-fired heating devices such as furnaces, boilers, and water heaters have fuel efficiency less than 100% on the basis of higher heating value. They also require electricity from the electric grid to power parasitic loads such as blowers, pumps, fans, and ignitors. The primary energy efficiency of the device accounts for both fuel used on-site and primary energy used off-site to produce electric power used by the device. This work compares conventional fuel-fired heating devices to two types of self-powered devices. A self-powered device (SPD) integrates a power cycle onboard to eliminate consumption of grid electricity. We assume that all heat rejected by the onboard power cycle is added to the process fluid, so that, compared with a conventional device, the same amount of heat is provided to the process fluid and the same amount of fuel is consumed, but grid electricity consumption is eliminated. The first SPD type is the basic one: exactly the electricity required is generated. The second type considered is the SPD with heat pump (SPD-HP), in which the power cycle generates more electricity than needed for parasitic loads, and the excess electricity is used to power a heat pump. The heat pump extracts additional heat from the ambient to boost efficiency. Both SPD and SPD-HP self-consume all the generated electricity, in contrast to combined heat and power (CHP) systems that export electricity. In this work, equations are derived to express the efficiency of three classes of heating devices: conventional (consuming grid electricity), self-powered (consuming no grid electricity), and self-powered with heat pump. The efficiency of each is derived as a function of up to six factors: (1) the fraction of combustion heat captured, (2) the rate of parasitic power consumption, (3) the fraction of electric energy dissipated as useful heat, (4) the power cycle conversion efficiency, (5) the grid efficiency, when applicable, and (6) the heat pump COP, when applicable. Scenarios are identified in which it is possible to achieve efficiency greater than 100% on a higher heating value basis. Plausible configurations using existing technology options are outlined.

Gluesenkamp, Kyle↗

Process for retrofitting an industrial gas turbine engine for increased power and efficiency

A process for retrofitting an industrial gas turbine engine of a power plant where an old industrial engine with a high spool has a new low spool with a low pressure turbine that drives a low pressure compressor using exhaust gas from the high pressure turbine, and where the new low pressure compressor delivers compressed air through a new compressed air line to the high pressure compressor through a new inlet added to the high pressure compressor. The old electric generator is replaced with a new generator having around twice the electrical power production. One or more stages of vanes and blades are removed from the high pressure compressor to optimally match a pressure ratio split. Closed loop cooling of one or more new stages of vanes and blades in the high pressure turbine is added and the spent cooling air is discharged into the combustor.

Jones, Russell B.↗

AutoTG: Reinforcement Learning-Based Symbolic Optimization for AI-Assisted Power Converter Design

Power converters are pervasive in modern electronic component design. They can be found in all electronic devices from household appliances and cellphone chargers to vehicles. Currently, designing new circuit topologies is hard because it requires human expertise based on experience and is difficult to automate. However, artificial-intelligence-assisted design can significantly facilitate the development of new power converters and/or improve the final result. Intelligently designed highly efficient power converters can have a significant effect on many important attributes, such as power efficiency, layout size, cost, heat dissemination, energy requirements, etc. We propose Autonomous Topology Generator (AutoTG), a reinforcement-learning-based framework that generates power converter topology candidates based on user specifications, optimized for user preferences. By modeling power converter design as a symbolic optimization problem, we sequentially sample components in an autoregressive manner until new topologies are formed, providing both the topology specification and the sizing (magnitude of each component parameter) of the proposed power converter. Here, we provide an empirical evaluation and show that AutoTG is able to generate varied high-efficiency topologies within component restrictions based on user input and show that previously unknown topologies can be found for further evaluation.

(AI)-based design↗

Particle Handling in Particle-Based Pumped Thermal Energy Storage

A particle-based pumped thermal electricity storage system stores high-temperature heat (~1000 degrees C) in low-cost silica sand and generates power through an efficient power cycle. Central to this system is a counterflow direct-contact gas/particle fluidized-bed heat exchanger, which can significantly improve the heat exchange process due to the large heat transfer surface area of particles. To showcase a lab-scale 10- to 20-kWe heat exchange process with particles heating up to 300 degrees C, a comprehensive hydrodynamic analysis of the fluidization condition inside the heat exchanger was conducted. The heat exchanger was designed to target for heat exchange process of 10-20 kW and accommodate an air mass flow rate of 0.3-0.7 kg/s. The fluidization condition was set to maintain stable bubbling fluidization, thereby maximizing the particle-to-air heat transfer. An air distributor was designed to equally distribute air over the bed, which can avoid defluidized zones in the heat exchanger. Additionally, particle handling systems including L-valves, screw conveyors, and pneumatic conveyors were developed for the prototype heat exchanger, efficiently conveying high-temperature particles at 0.2-0.5 kg/s. This work lays the foundation for scaling up the system and integrating it into larger energy storage applications, demonstrating its potential for efficient, high-temperature thermal energy storage and power generation.

25 ENERGY STORAGE↗

Integration of a high oxygen permeability ionomer into polymer electrolyte membrane fuel cell cathodes for high efficiency and power density

In this work, we present a study on the integration of a high oxygen permeability ionomer (HOPI) with high durability carbon supported platinum (Pt/C) catalysts to prepare cathode catalyst layers (CCLs) for polymer electrolyte membrane fuel cells (PEMFCs). A key motivation is the production of PEMFCs with high efficiency and durability for heavy-duty fuel cell vehicles. Our results from integrating a pre-commercial HOPI with robust, state-of-the-art catalysts with medium and low surface area carbon supports show significant increases in specific activities (67% increase over the standard commercial ionomer) at low current densities and reduced oxygen (O 2 ) transport resistances (R O2 ’s) at high current densities, enabling both higher efficiency and peak power density. The reduction in the R O2 with the HOPI is most significant at low relative humidity (RH), due to its more rigid backbone structure resisting compaction at lower water contents. In our ink optimization analysis, we show that the HOPI in this study achieves its peak performance with an ionomer to carbon ratio (I/C) of 0.6 and a moderately alcohol-rich ink solvent when fabricating catalyst layers by the decal method with an automatic wet film coater.

08 HYDROGEN↗