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At least 181 records · Page 10

Measurements of fugitive hydrocarbon emissions with a tunable infrared DIAL

A tunable infrared differential absorption lidar (DIAL) system has been designed and developed at the National Physics Lab (NPL) which is capable of making measurements throughout the spectral region 3.0 to 4.2 micro-m. It is ideally suited to measuring a range of organic and inorganic species including methane, propane, and butane. The system also has an ultraviolet channel that is capable of making simultaneous measurements of aromatic hydrocarbons such as Toluene and benzene. This paper describes the source and detection system, together with some measurements of fugitive hydrocarbon emissions performed at various petrochemical plants.

Milton, M. J. T.↗

Metabolic response of environmentally isolated microorganisms to industrial effluents: Use of a newly described cell culture assay

An environmental application using a microtiter culture assay to measure the metabolic sensitivity of microorganisms to petrochemical effluents will be tested. The Biomedical Operations and Research Branch at NASA JSC has recently developed a rapid and nondestructive method to measure cell growth and metabolism. Using a colorimetric procedure the uniquely modified assay allows the metabolic kinetics of prokaryotic and eukaryotic cells to be measured. Use of such an assay if adapted for the routine monitoring of waste products, process effluents, and environmentally hazardous substances may prove to be invaluable to the industrial community. The microtiter method as described will be tested using microorganisms isolated from the Galveston Bay aquatic habitat. The microbial isolates will be identified prior to testing using the automated systems available at JSC. Sodium dodecyl sulfate (SDS), cadmium, and lead will provide control toxic chemicals. The toxicity of industrial effluent from two industrial sites will be tested. An effort will be made to test the efficacy of this assay for measuring toxicity in a mixed culture community.

Ferebee, Robert N.↗

An analytical investigation of transient effects on rewetting of heated thin flat plates

The rewetting of a hot surface is a problem of prime importance in the microgravity application of heat pipe technology, where rewetting controls the time before operations can be re-established following depriming of a heat pipe. Rewetting is also important in the nuclear industry (in predicting behavior during loss-of-coolant accidents), as well as in the chemical and petrochemical industries. Recently Chan and Zhang have presented a closed-form solution for the determination of the rewetting speed of a liquid film flowing over a finite (but long) hot plate subject to uniform heating. Unfortunately, their physically unreasonable initial conditions preclude a meaningful analysis of start-up transient behavior. A new nondimensionalization and closed-form solution for an infinitely-long, uniformly-heated plate is presented. Realistic initial conditions (step change in temperature across the wetting front) and boundary conditions (no spatial temperature gradients infinitely far from the wetting front) are employed. The effects of parametric variation on the resulting simpler closed-form solution are presented and compared with the predictions of a 'quasi-steady' model. The time to reach steady-state rewetting is found to be a strong function of the initial dry-region plate temperature. For heated plates it is found that in most cases the effect of the transient response terms cannot be neglected, even for large times.

Platt, J. A.↗

Results of ozone measurements in Northern Germany: A case study

At most of the German ozone recording stations which have records over a sufficiently long period, the results of the summer months of 1989 showed the highest values since the beginning of the measurements. One of the reasons for this phenomenon was the high duration of sunshine in that summer; for example, in Potsdam near Berlin in May 1989 the sunshine duration was the highest in May since the beginning of the records in 1893. For that reason we selected this summer for a case study. The basis for the study was mainly the ozone measuring stations of the network of Lower Saxony and the Federal Office of Environment (Umweltbundesamt). The results of these summer measurements point to intense sources of ozone, probably in form of gaseous precursors, in the Middle German industrial areas near Leipzig and Halle and in Northwestern Czechoslovakia, with coal-mining, chemical and petrochemical industries, coking plants and others. The maps of average ozone concentrations, number or days with high ozone maxima, ozone-windroses of the stations, etc., suggest that these areas could be a main source of precursors and of photochemical ozone production in summer smog episodes in Central Europe. Stations on the North Sea coast, at which early ozone measurements were made by our institute in 1973/74 are compared with similarly located stations of the Lower Saxon network in 1989 and the results show a reversal of the ozone-windroses. In 1973/74, the highest ozone concentrations were correlated with wind directions from the sea while in 1989 these concentrations were correlated with directions from the continent. In the recent years, photochemical ozone production on the continent is probably predominant, while in former years the higher ozone content of the maritime subpolar air masses has been explained by stratospheric-tropospheric exchange.

Schmidt, Manfred↗

Hydrogen Annealing Of Single-Crystal Superalloys

Annealing at temperature equal to or greater than 2,200 degrees F in atmosphere of hydrogen found to increase ability of single-crystal superalloys to resist oxidation when subsequently exposed to oxidizing atmospheres at temperatures almost as high. Supperalloys in question are principal constituents of hot-stage airfoils (blades) in aircraft and ground-based turbine engines; also used in other high-temperature applications like chemical-processing plants, coal-gasification plants, petrochemical refineries, and boilers. Hydrogen anneal provides resistance to oxidation without decreasing fatigue strength and without need for coating or reactive sulfur-gettering constituents. In comparison with coating, hydrogen annealing costs less. Benefits extend to stainless steels, nickel/chromium, and nickel-base alloys, subject to same scale-adhesion and oxidation-resistance considerations, except that scale is chromia instead of alumina.

Smialek, James L.↗

Gas Chromatic Mass Spectrometer

Gas chromatograph/mass spectrometer (GC/MS) used to measure and identify combustion species present in trace concentration. Advanced extractive diagnostic method measures to parts per billion (PPB), as well as differentiates between different types of hydrocarbons. Applicable for petrochemical, waste incinerator, diesel transporation, and electric utility companies in accurately monitoring types of hydrocarbon emissions generated by fuel combustion, in order to meet stricter environmental requirements. Other potential applications include manufacturing processes requiring precise detection of toxic gaseous chemicals, biomedical applications requiring precise identification of accumulative gaseous species, and gas utility operations requiring high-sensitivity leak detection.

Wey, Chowen↗

Two-phase flow in helical and spiral coils

Coiled tube heat exchangers involving two-phase flows are used in a variety of application areas, extending from the aerospace industry to petrochemical, refrigeration land power generation industries. The optimal design in each situation requires a fundamental understanding of the heat, mass and momentum transfer characteristic of the flowing two-phase mixture. However, two-phase flows in lengths of horizontal or vertical straight channels with heat transfer are often quite difficult in themselves to understand sufficiently well to permit accurate system designs. The present study has the following general objectives: (1) Observe two-phase flow patterns of air-water and R-113 working fluids over a range of flow conditions, for helical and spiral coil geometries, of circular and rectangular cross-section; (2) Compare observed flow patterns with predictions of existing flow maps; (3) Study criteria for flow regime transitions for possible modifications of existing flow pattern maps; and (4) Measure associated pressure drops across the coiled test sections over the rage of flow conditions specified.

Keshock, Edward G.↗

Effects of Fiber/Matrix Interface and its Composition on Mechanical Properties of Hi Nicalon/Celsian Composites

Fiber-reinforced ceramic matrix composites (CMC) are prospective candidate materials for high temperature structural applications in aerospace, energy conservation, power generation, nuclear, petrochemical, and other industries. At NASA Lewis, we are investigating celsian matrix composites reinforced with various types of silicon carbide fibers. The objective of the present study was to investigate the effects of fiber/matrix interface and its composition on the mechanical properties of silicon carbide (Hi-Nicalon) fiber-reinforced celsian matrix composites.

Bansal, Narottam P.↗

Cyrano "Nose" The Smell of Success

Cyrano Sciences, Inc. has commercialized a simple, accurate, non- invasive tool that enables "machines to smell". The Cyranose 320 is used for quality control purposes in the food and chemical industries. Using a sensor array and onboard pattern recognition algorithms, the lightweight, portable device works by exposing an array of polymer composite sensors to the chemical components in a vapor. When the sensors come in contact with the vapor, the polymer expands like a sponge, changing the resistance of the composites. The change in resistance is measured, and from that measurement, the presence of a pre-trained substance is determined with a quick and accurate diagnosis. This real-time, portable device enables food companies to spot test raw materials for batch-to-batch consistency, spoilage, or contamination. The Cyranose 320 is also used by chemical and petrochemical companies for quick assessment of the chemical status associated with various industrial processes. Profiling a chemical environment in a hazardous materials situation allows emergency crews to accurately select fire retardants, containment strategies, and protective gear. Future applications for the Cyranose 320 are fast growing and other uses of this technology are on the horizon.

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Low Level Leaks

NASA has transferred the improved portable leak detector technology to UE Systems, Inc.. This instrument was developed to detect leaks in fluid systems of critical launch and ground support equipment. This system incorporates innovative electronic circuitry, improved transducers, collecting horns, and contact sensors that provide a much higher degree of reliability, sensitivity and versatility over previously used systems. Potential commercial uses are pipelines, underground utilities, air-conditioning systems, petrochemical systems, aerospace, power transmission lines and medical devices.

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Pressure Measurement Sensor

FFPI Industries Inc. is the manufacturer of fiber-optic sensors that furnish accurate pressure measurements in internal combustion chambers. Such an assessment can help reduce pollution emitted by these engines. A chief component in the sensor owes its seven year- long development to Lewis Research Center funding to embed optical fibers and sensors in metal parts. NASA support to Texas A&M University played a critical role in developing this fiber optic technology and led to the formation of FFPI Industries and the production of fiber sensor products. The simple, rugged design of the sensor offers the potential for mass production at low cost. Widespread application of the new technology is forseen, from natural gas transmission, oil refining and electrical power generation to rail transport and the petrochemical paper product industry.

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Solving Problems With SINDA/FLUINT

SINDA/FLUINT, the NASA standard software system for thermohydraulic analysis, provides computational simulation of interacting thermal and fluid effects in designs modeled as heat transfer and fluid flow networks. The product saves time and money by making the user's design process faster and easier, and allowing the user to gain a better understanding of complex systems. The code is completely extensible, allowing the user to choose the features, accuracy and approximation levels, and outputs. Users can also add their own customizations as needed to handle unique design tasks or to automate repetitive tasks. Applications for SINDA/FLUINT include the pharmaceutical, petrochemical, biomedical, electronics, and energy industries. The system has been used to simulate nuclear reactors, windshield wipers, and human windpipes. In the automotive industry, it simulates the transient liquid/vapor flows within air conditioning systems.

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Process Analyzer

Under a NASA Small Business Innovation Research (SBIR) contract, Axiomatics Corporation developed a shunting Dielectric Sensor to determine the nutrient level and analyze plant nutrient solutions in the CELSS, NASA's space life support program. (CELSS is an experimental facility investigating closed-cycle plant growth and food processing for long duration manned missions.) The DiComp system incorporates a shunt electrode and is especially sensitive to changes in dielectric property changes in materials at measurements much lower than conventional sensors. The analyzer has exceptional capabilities for predicting composition of liquid streams or reactions. It measures concentrations and solids content up to 100 percent in applications like agricultural products, petrochemicals, food and beverages. The sensor is easily installed; maintenance is low, and it can be calibrated on line. The software automates data collection and analysis.

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Pipe Line Control

The array of tanks, pipes and valves in the photo below is a petroleum tank farm in Georgia, part of a petrochemical pipe line system that moves refined petroleum products from Texas and Louisiana to the mid-Eastern seaboard. The same pipes handle a number of different products, such as gasoline, kerosene, jet fuel or fuel oil. The fluids are temporarily stored in tanks, pumped into the pipes in turn and routed to other way stations along the pipe line. The complex job of controlling, measuring and monitoring fuel flow is accomplished automatically by a computerized control and communications system which incorporates multiple space technologies.

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Piping Flexibility

A NASA computer program aids Hudson Engineering Corporation, Houston, Texas, in the design and construction of huge petrochemical processing plants like the one shown, which is located at Ju'aymah, Saudi Arabia. The pipes handling the flow of chemicals are subject to a variety of stresses, such as weight and variations in pressure and temperature. Hudson Engineering uses a COSMIC piping flexibility analysis computer program to analyze stresses and unsure the necessary strength and flexibility of the pipes. This program helps the company realize substantial savings in reduced engineering time.

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Computer Programs for Construction

A NASA computer program aids Hudson Engineering Corporation, Houston, Texas in the design and construction of huge petrochemical processing plants like the one shown, which is located at Ju'aymah, Saud Arabia. The pipes handling the flow of chemicals are subject to a variety of stresses, such as weight and variations in temperature. Hudson Engineering uses a COSMIC piping flexibility analysis computer program to analyze and insure the necessary strength and flexibility of the pipes. This program helps the company realize substantial savings in reduced engineering time.

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Method of Heating a Foam-Based Catalyst Bed

A method of heating a foam-based catalyst bed has been developed using silicon carbide as the catalyst support due to its readily accessible, high surface area that is oxidation-resistant and is electrically conductive. The foam support may be resistively heated by passing an electric current through it. This allows the catalyst bed to be heated directly, requiring less power to reach the desired temperature more quickly. Designed for heterogeneous catalysis, the method can be used by the petrochemical, chemical processing, and power-generating industries, as well as automotive catalytic converters. Catalyst beds must be heated to a light-off temperature before they catalyze the desired reactions. This typically is done by heating the assembly that contains the catalyst bed, which results in much of the power being wasted and/or lost to the surrounding environment. The catalyst bed is heated indirectly, thus requiring excessive power. With the electrically heated catalyst bed, virtually all of the power is used to heat the support, and only a small fraction is lost to the surroundings. Although the light-off temperature of most catalysts is only a few hundred degrees Celsius, the electrically heated foam is able to achieve temperatures of 1,200 C. Lower temperatures are achievable by supplying less electrical power to the foam. Furthermore, because of the foam s open-cell structure, the catalyst can be applied either directly to the foam ligaments or in the form of a catalyst- containing washcoat. This innovation would be very useful for heterogeneous catalysis where elevated temperatures are needed to drive the reaction.

Fortini, Arthur J.↗

Modeling Tools Predict Flow in Fluid Dynamics

"Because rocket engines operate under extreme temperature and pressure, they present a unique challenge to designers who must test and simulate the technology. To this end, CRAFT Tech Inc., of Pipersville, Pennsylvania, won Small Business Innovation Research (SBIR) contracts from Marshall Space Flight Center to develop software to simulate cryogenic fluid flows and related phenomena. CRAFT Tech enhanced its CRUNCH CFD (computational fluid dynamics) software to simulate phenomena in various liquid propulsion components and systems. Today, both government and industry clients in the aerospace, utilities, and petrochemical industries use the software for analyzing existing systems as well as designing new ones."

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