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At least 181 records · Page 10

Lithium thiostannate spinels: air-stable cubic semiconductors.

Lithium chalcogenide materials have been studied less than other alkali metal analogs and are of interest as ion conductors and semiconductors capable of thermal neutron detection. Herein, we describe the structural, thermal, magnetic, electronic, and ionic properties of a new family of cubic lithium thiospinels Li2MSn3S8 (M = Mg, Fe, Mn, Ni, Co) and Li1.66CuSn3.33S8. All compounds crystallize in the Fd (3) over barm space group and exhibit site occupancy disorder with Sn and M on the octahedral site for M = Mg, Fe, Mn, Ni, Co. The Li1.66CuSn3.33S8 compound also exhibits occupancy disorder on the tetrahedral sites between Li and Cu, as well as on the octahedral sites between Li and Sn. We demonstrate the ability to tune the physical properties of the compounds by changing their composition. By tuning the identity of the transition metal in the structure, the optical band gaps can vary between 0.91(2) and 2.19(2) eV, and electrical resistivities between 2.8 x 10(3) Omega-cm and 2.2 x 10(7)Omega-cm can be achieved. Density functional theory calculations for Li2MgSn3S8 and Li1.66CuSn3.33S8 suggest that both materials have indirect band gaps and significantly dispersive conduction bands. A bandwidth dispersion of 0.75 and 0.70 eV along the Gamma -> M direction in the conduction band are predicted for Li2MgSn3S8 and Li1.66CuSn3.33S8, respectively, with an electron effective mass of 0.49 and 0.55 m(e) at the Gamma point. The hole effective mass in the valence band is calculated to be 1.25 me at the M point and 0.75 me at the L point for Li2MgSn3S8 and Li1.66CuSn3.33S8, respectively. The ionic/electronic conductivity of each compound was determined using AC electrochemical impedance spectroscopy.

Quintero, Michael A.↗

Potential for neutron and proton transmutation doping of GaN and Ga 2 O 3

As the potential applications of GaN and Ga 2 O 3 are limited by the inadequacy of conventional doping techniques, specifically when uniform selective area p-type doping is required, the potential for transmutation doping of these materials is analyzed. All transmuted element concentrations are reported as a function of time for several common proton and neutron radiation sources, showing that previously published results considered a small subset of the dopants produced. A 40 MeV proton accelerator is identified as the most effective transmutation doping source considered, with a 2.25 × 10 17 protons per cm 2 fluence yielding net concentrations of uncompensated p-type dopants of 7.7 × 10 15 and 8.1 × 1015 cm -3 for GaN and Ga 2 O 3 , respectively. Furthermore, it is shown that high energy proton accelerator spectra are capable of producing dopants required for magnetic and neutron detection applications, although not of the concentrations required for current applications using available irradiation methods.

36 MATERIALS SCIENCE↗

Instrument design for an inertial confinement fusion ion temperature imager

A mix of contaminant mass is a known, performance-limiting factor for laser-driven inertial confinement fusion (ICF). It has also recently been shown that the contaminant mass is not necessarily in thermal equilibrium with the deuterium–tritium plasma. Contaminant mass temperature is one of the dominant uncertainties in contaminant mass estimates. The MixIT diagnostic is a new and potentially transformative diagnostic, capable of spatially resolving ion temperature. The approach combines principles of neutron time-of-flight and neutron imaging diagnostics. The information from the MixIT diagnostic can be used to optimize ICF target and laser drive designs as well as provide key constraints on ICF radiation-hydrodynamic simulations that are critical to contaminant mass estimates. This work details the design and optimization of the major components of the MixIT diagnostic: the neutron aperture, the neutron detector (scintillator), and the recording system.

47 OTHER INSTRUMENTATION↗

Structural characterization of highly alloyed (Al,Gd)N thin films

Highly alloyed (Al,Gd)N is of potential interest in a variety of applications, including neutron detection and in devices such as non-volatile memory. Gd has been shown to have very low equilibrium solubility in AlN at room temperature; however, non-equilibrium deposition techniques such as sputtering are able to deposit thin films, which incorporate large amounts of Gd. Here, we characterize a highly-alloyed (Al,Gd)N combinatorial thin film grown by RF sputtering on a GaN substrate, looking for any evidence of chemical or phase segregation or structural disorder in the films. Compositions with between 13% and 32% Gd (on a cation basis) were studied. No evidence was found for chemical or phase segregation in any studied composition. Higher degrees of Gd incorporation led to greater structural disorder in the film and a tendency toward amorphization; however, electron diffraction shows that the film does not become fully amorphous at any of the studied compositions, instead retaining textured local order even at 32% Gd. Electron energy loss spectra suggest that the material retains a locally wurtzite-like tetrahedral bonding environment at all studied compositions.

36 MATERIALS SCIENCE↗

Bayesian inference of anisotropic 2D small-angle scattering from sparse measurement

Here, we present a Bayesian inference framework for reconstructing anisotropic two-dimensional small-angle scattering (2D SAS) patterns from sparse, noisy, or partially missing data. The method combines a symmetry-aware angular basis with radial Gaussian process priors to enable accurate, training-free interpolation and denoising. Computational benchmarks demonstrate reliable recovery of both isotropic and high-order anisotropic features under severe data reduction. Experimental validations on stretched polymers, sheared wormlike micelles, and carbon fibers show improved fidelity and resolution compared to raw measurements, achieving comparable accuracy with up to 50-fold fewer detected neutrons. This approach enables quantitative structural analysis under low-flux, time-limited, or single-shot conditions, extending the applicability of 2D SAS techniques to compact neutron sources and mechanically driven soft matter systems undergoing transient structural changes.

Tung, Chi-Huan [Oak Ridge National Laboratory (ORN↗

Advancing Tritium Self-Sufficiency in Fusion Power Plants: Insights from the BABY Experiment

Abstract In the pursuit of fusion power, achieving tritium self-sufficiency stands as a pivotal challenge.
Tritium breeding within molten salts is a critical aspect of next-generation fusion reactors, yet experimental measurements of \gls{tbr} have remained elusive.
Here we present the results of the \gls{baby} experiment, which represents a pioneering effort in tritium research by utilizing high-energy (\SI{14}{\mega\electronvolt}) neutron irradiation of molten salts, a departure from conventional low-energy neutron approaches. 
Using a small-scale (\SI{100}{\milli\litre}) molten salt tritium breeding setup, we not only simulated, but also directly measured a \gls{tbr} \textcolor{red}{(\num{3.57e-4})}. 
This innovative approach provides crucial experimental validation, offering insights unattainable through simulation alone.
Moreover, our findings reveal a surprising outcome: tritium was predominantly collected as HT, contrary to the expected TF. 
This underscores the complexity of tritium behavior in molten salts, highlighting the need for further investigation.
This work lays the foundation for a more sophisticated experimental setup, including increasing the volume of the breeder, enhancing neutron detection, and refining tritium collection systems.
Such improvements are crucial for advancing our understanding of fusion reactor feasibility and paving the way for future experiments.

Delaporte-Mathurin, Rémi (ORCID:0000000310648882)↗

$β$-delayed neutron emission studies of 137,138 I and 144,145 Cs performed with trapped ions

A detailed study of the β-delayed neutron emission properties of 137,138 I and 144,145 Cs has been performed by confining ions in the Beta-decay Paul Trap. The daughter ions following β decay emerge from the trapped-ion cloud with negligible scattering allowing reconstruction of the recoil-ion energy from the time of flight. From this information, the neutron-emission branching ratios and neutron-energy spectra were deduced. The results for the 137 I and 144,145 Cs decays are in agreement with previous results performed using direct neutron-detection techniques. In the case of 138 I, a branching ratio of 6.18(50)% is obtained, yielding a value consistent with the more recent results, which are a factor of two larger than measurements made prior to 1978.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Modern version of the uncited 1938 experiment that first observed DT fusion

Experiments are described, and results are provided, for the duplication of the first-ever triton-deuterium (colloquially referred to as DT) fusion experiment accidentally performed by A.J. Ruhlig in 1938, but forgotten in the published scientific literature. Here, we find that Ruhlig overestimated the ratio of the triton-deuterium over deuteron-deuterium neutron yields in his secondary reaction (Reaction-in-Flight) experiment compared to modern theoretical calculations and our duplication of his experiment using modern neutron detection methods. Nevertheless, Ruhlig’s observation provided the motivation for the application of DT fusion after World War II and its more recent importance in peaceful energy production at DT fusion facilities around the world. Additionally, the experimental technique used in the present work provides a novel approach for checking on low-energy triton stopping powers in deuterium containing compounds.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Directed Flow and the Chiral Magnetic Effect in Ultrarelativistic Collisions at the LHC with CMS at the LHC (Final Technical Report)

This Technical Report focuses on two aspects of this project. First, the results from the calibration of the Spectator Reaction Plane Detector (SRPD) addition to the Zero Degree Calorimeter (ZDC) in the CMS experiment are presented, followed by the pre-liminary results from radiation studies of quartz being performed using the electron linac here at the University of Maryland. The data taken in the November 2018 run are being analyzed with the ultimate goal of producing a reaction plane measurement using spectator neutrons detected in the ZDC. Funds provided by this grant partially supported the graduate student who is performing these calibrations. They were also used to support radiation tests of quartz rod material being performed at the University of Maryland Radiation Facilities Electron Linear Accelerator.

43 PARTICLE ACCELERATORS↗

Sulfur Pellets Responses to a Bare and Steel Reflected Pulse of the Oak Ridge National Laboratory Health Physics Research Reactor

The experiments analyzed in this report were conducted at the Health Physics Research Reactor (HPRR), also known as the $\textit{Fast Burst Reactor}$. The reactor was designed and built at Oak Ridge National Laboratory (ORNL) in 1961. The HPRR was an unmoderated, unshielded fast reactor that used highly enriched uranium and molybdenum alloy as fuel. The reactor was initially sent to the Nevada Test Site in 1962, where it was used to evaluate radiation doses received as a result of the Hiroshima and Nagasaki bombings during World War II. A few years later, the reactor was sent back to ORNL to be part of the Dosimetry Application Research (DOSAR) facility shown in Figure 1, which included a reactor building shown on the left (west) of the picture and a control and laboratory building in the upper right corner (northeast). The critical assembly was used for numerous technical studies, including systems calibration, dosimetry, radiobiology of plants and animals, testing of radiation alarms, as well as teaching and training in radiation dosimetry and nuclear engineering. Between 1963 and 1987, the HPRR was operated for thousands of hours, achieving criticality close to 10,000 times and motivating many publications. The HPRR was decommissioned in 1987. The goal of this effort was to use historical data from operation of the HPRR to create a criticality accident alarm system (CAAS) benchmark to be included in the $\textit{International Handbook of Evaluated Criticality Safety Benchmark Experiments}$ (ICSBEP Handbook). A thorough inspection was performed of all available documentation and information available. The most promising experiments that were selected for evaluation were those described in the 1987 ORNL report entitled $\textit{Health Physics Research Reactor Reference Dosimetry}$, ORNL-6240. The report includes reference dosimetry results of the shielded and unshielded configurations of the HPRR after burst operations. Because of changes to the reactor positioning and storage systems that were made in 1985, the previous dosimetry reports became obsolete, and the newly designed experiments were needed to create the HPRR’s adjusted dosimetry data. The various results reported in ORNL-6240 include reference doses and dose equivalents from different conventions at different distances and elevations as determined using the detected neutron fluence and conversion factors. The HPRR neutron fluence was obtained through different methods, including sulfur pellet analysis and threshold detector unit data. Information about the HPRR spectrum was also obtained through Bonner sphere measurements. This benchmark is focused on a part of the measured sulfur fluences reported in Appendix H of ORNL-6240. Standard commercial sulfur pellets were placed at different distances from the HPRR centerline during burst operation and were activated due to the 32 S(n,p) 32 P reaction. The resulting 32 P activity was then measured and the information about the corresponding sulfur fluence and/or neutron dose could be extracted. Many of those measurements have 7 been performed with the HPRR in its bare configuration or with different shields (combinations of Lucite, concrete, steel). All the necessary, precise information about material and/or dimensions of the different shields was not found, so it was decided to focus only on the unshielded and steel-shielded configurations to minimize the benchmark uncertainty. A total of 31 cases (24 unshielded and 7 shielded cases at different positions) of sulfur fluence were selected before evaluation to develop the benchmark.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

REDC Process Instrumentation Modernization Project

Critical electronics used for isotopes production have become outdated and difficult to manufacture. In particular the alpha-particle and neutron detection electronics (commonly referred to as Q2809A-9 and -11) which are used to monitor effluent activity in ORNL Building 7920 were designed and deployed in 1966-67. These electronics are still used but some parts are no longer available for purchase. In addition, the printed circuit boards used in the Count Rate Monitor (CRM) module have no fabrication files or quality assurance documentation. In light of this, a project to modernize the modules for ability to manufacture with modern parts was undertaken. Both the preamplifier and CRM were modernized with new printed circuit boards and parts which are current catalog parts. In addition, QA documentation was generated which allows the manufacturer to assure proper operation prior to delivery.

42 ENGINEERING↗

Plutonium Basket Counter Measurement Control Q3-Q4 2023

The Plutonium Basket Counter (PBC) is a spent fuel nuclear safeguards instrument that was developed to measure spent-fuel elements from MAGNOX-type research reactors and determine their plutonium content. The instrument is designed to measure fuel elements in spent fuel cooling pools through underwater operation, but it is also able to measure radiation sources in air. The PBC determines fuel plutonium content by detecting neutrons with an array of Helium-3 detectors. The electronics make use of a JSR-15 shift register for data collection and IAEA Neutron Coincidence Counting (INCC) software for data analysis. The PBC is used to determine the 240 Pu content in spent MAGNOX fuel elements grouped into basket-like bundles, thus the instrument’s name. Reactor burnup calculations can be used in conjunction with the data from the PBC to estimate the total plutonium content in the fuel.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Demonstrating and Expanding DRiFT’s Helium-3 Detector Response Capabilities [Slides]

Helium-3 tubes are an efficient way to detect neutrons after they have thermalized by polyethylene. They are often arranged in rings to perform coincidence counting. Applications include nuclear safeguards, treaty verification, and emergency response. DRiFT has the ability to simulate pile-up, room return, and end effects. A new feature determines real and accidental correlated counts. The next steps include DRiFT 2.0 released as executable, continued demonstration of gas module capabilities, and semiconductor module under a development.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Using Neural Networks for Low Energy Reconstruction and Neutron Identification in the MicroBooNE LArTPC

Identifying and reconstructing final-state neutrons from neutrino interactions in Liquid Argon Time Projection Chambers (LArTPCs) will enhance future oscillation measurements by recovering missing energy and improving neutrino interaction channel identification. However, neutrons are challenging to reconstruct as the majority leave only small, isolated charge signatures known as blips. Here we present initial efforts to identify neutrons in the MicroBooNE LArTPC with low energy protons from neutron-argon inelastic interactions that present as blips below the traditional tracking threshold in the TPC. Unlike for tracks, there is no algorithmic method to determine direction for blips since they span only a few wires. Therefore, we developed and trained a Recurrent Neural Network (RNN) to reconstruct the directionality of proton-induced blips, allowing us to separate signal from background by selecting blips that point back to the neutrino vertex. The model achieves a preliminary average angular resolution of 17 degrees when tested on a simulated sample of protons over 6 MeV in kinetic energy. This novel tool will enhance neutron detection in LArTPCs and expand a broad range of other low-energy physics searches such as for solar and supernova neutrinos.

Silva, Liani Isabel [Unlisted, US]↗

Medium Energy Nuclear Physics Research at the University of Richmond

The first part is a technical paper on the fitting techniques used to extract the neutron detec tion efficiency from the CLAS12 detector at the Thomas Jefferson National Accelerator Facility in Newport News, VA. The second is the masters thesis of Mr. Jude Buckley who also studied the neutron detection efficiency. He was a student at the University of Surrey in the UK and supported by the grant.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Support for Advanced Fuel Fabrication MC&A Approaches

This report summarizes the key activities of the Material Protection, Accounting, and Control Technologies (MPACT) program’s safeguards training work package for FY25. The work focused on two main areas: domestic safeguards training and the development of new technologies for nuclear material accounting and control (NMAC). A key development during this FY was the delivery of NMAC statistics for US Nuclear Regulatory Commission requirements refresher course. The course objective was to assist industry in meeting the MC&A program requirements for fuel cycle facilities; this training focused on front-end bulk fuel cycle processes. At the same time, a report was prepared on the research output of an effort that focused on the benefits of commercial fuel debundling for NMAC and waste management. The MPACT team evaluated various technologies and proposed a fuel debundling detector that integrates gamma spectroscopy and neutron detection as the most practical solution. The scope of activities under this work package for FY26 focuses on developing a fundamental nuclear material control plan, also known as MC&A plan, for tristructural isotropic (TRISO) fuel fabrication facilities. This plan will address the various NMAC requirements for facilities that handle Category II.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

1FRAME - 1F Fuel Retrieval and Monitoring Experiments [Poster]

The 1FRAME (1F Fuel Retrieval and Monitoring Experiments) project includes collaborative research and development in the area of neutron detection, analysis, and simulations for fuel debris removal at Fukushima Daiichi nuclear power station. Technical advances are needed in all three focus areas to provide technical recommendations on a course of action for fuel debris removal. This work is part of collaborative research and development efforts between the US, Japan, and France.

Fuel Debris Removal↗