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At least 181 records · Page 10

Experiments of water-moderated plutonium metal arrays: part I — description

In the mid-1970s and early 1980s, almost one hundred critical and approach-to-critical experiments using water-moderated plutonium metal arrays were performed at the Rocky Flats Critical Mass Laboratory. The experiments were performed in two programs: 2x2xN arrays conducted in the 1970s and 3x3x3 arrays conducted in the 1980s. Both sets of experiments used the same double-canned plutonium parts and were water moderated. The major differences between the two programs were the support structure and tank and the administrative limits on criticality. This paper summarizes the critical data and results of both sets of experiments. In conclusion, these experiments are then analyzed in a companion paper.

42 ENGINEERING↗

Solvent Quality Effects on Scaling Behavior of Poly(methyl methacrylate) Brushes in the Moderate- and High-Density Regimes

Herein, we give a detailed experimental analysis for scaling law behavior in the “moderately dense” and “high-density” brush regimes for poly(methyl methacrylate) brushes swollen in a range of solvent conditions. This expansive experimental analysis aims to validate decades of mean field theory predictions on power law scaling behavior of grafted polymer chains. Brushes with grafting densities (σ) ranging from 0.1 to 0.8 nm –2 are prepared by atom-transfer radical polymerization. The swollen thickness (h) is characterized using liquid cell ellipsometry, and the solvent quality is varied using mixtures of acetone and methanol. In a good solvent, the exponential scaling behavior (h ∝ σ n ) has the typical n = 1/3 dependency for grafting densities of σ ≤ 0.4 nm –2 . For grafting densities of >0.4 nm –2 , n increases, indicating the transition from the moderately dense to the high-density brush regime. Furthermore, in a poor solvent, the scaling behavior is independent of σ and scales as h ∝ σ0.80, approaching the theoretical expectations of h ∝ σ 1 . An abrupt transition between these scaling law behaviors occurs at the Θ-solvent condition of ~45% (v/v) methanol in acetone. While our experimental results parallel trends predicted by mean field theory, differences are observed and appear to be attributed to self-solvation of the polymer, polydispersity in the molecular weight, and chain termination.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Relocation of Light and Moderate-Magnitude ( M 4-6) Seismicity Along the Central Mid-Atlantic

In this study, we estimate precise relative epicentroid locations of earthquakes along the Mid-Atlantic Ridge (MAR) between 12°N and 19°N using intermediate-period Rayleigh and Love wave cross-correlation measurements. We relocate 152 earthquakes with magnitudes ranging between 4.0 and 6.0 and when possible use P waveform modeling to estimate centroid depths. We compare surface-wave locations to locations in the U.S. Geological Survey, Global Centroid Moment Tensor, and Pacific Marine Environmental Laboratory hydroacoustic catalogs (Smith et al., 2002, https://doi.org/10.1029/2001GL013912) and demonstrate that surface-wave based relative location techniques provide significant improvement on precision. Our analyses shift locations to more tectonically consistent alignments that correlate strongly with bathymetric features. Relocations along the Fifteen-Twenty and Marathon Fracture Zones (FZs) move to within a few kilometers of the transform bathymetry. Events along ridge segments scatter over a distance of about 10–20 km perpendicular to the local plate boundary and most ridge-segment seismicity clusters spatially. North of the Fifteen-Twenty FZ, ridge events along several segments locate preferentially in the North American Plate, suggesting recent asymmetric seismic strain release and perhaps asymmetric spreading. Along the ridge between 13°N and 14°N, moderate-magnitude seismic strain release concentrates in an area with two active oceanic core complexes (OCC) along the western rift boundary, but the largest events along this segment appear to occur along the eastern boundary rift valley faults and represent deformation opposite the OCC detachment surface processes. Finally, precise moderate-magnitude earthquake epicentroid locations for events that occurred over the last few decades complement the results of temporary seismometer deployments that have imaged microseismic activity along the MAR.

58 GEOSCIENCES↗

Systems-wide analysis revealed shared and unique responses to moderate and acute high temperatures in the green alga Chlamydomonas reinhardtii

Different intensities of high temperatures affect the growth of photosynthetic cells in nature. To elucidate the underlying mechanisms, we cultivated the unicellular green alga Chlamydomonas reinhardtii under highly controlled photobioreactor conditions and revealed systems-wide shared and unique responses to 24-hour moderate (35°C) and acute (40°C) high temperatures and subsequent recovery at 25°C. We identified previously overlooked unique elements in response to moderate high temperature. Heat at 35°C transiently arrested the cell cycle followed by partial synchronization, up-regulated transcripts/proteins involved in gluconeogenesis/glyoxylate-cycle for carbon uptake and promoted growth. But 40°C disrupted cell division and growth. Both high temperatures induced photoprotection, while 40°C distorted thylakoid/pyrenoid ultrastructure, affected the carbon concentrating mechanism, and decreased photosynthetic efficiency. We demonstrated increased transcript/protein correlation during both heat treatments and hypothesize reduced post-transcriptional regulation during heat may help efficiently coordinate thermotolerance mechanisms. During recovery after both heat treatments, especially 40°C, transcripts/proteins related to DNA synthesis increased while those involved in photosynthetic light reactions decreased. We propose down-regulating photosynthetic light reactions during DNA replication benefits cell cycle resumption by reducing ROS production. Our results provide potential targets to increase thermotolerance in algae and crops.

59 BASIC BIOLOGICAL SCIENCES↗

Magnetic ordering and slow dynamics in a Ho-based bulk metallic glass with moderate random magnetic anisotropy

Results of magnetic measurements are presented for a Ho-based bulk metallic glass, which shows similarities and differences with conventional spin glasses (SGs), and significant differences with weak random magnetic anisotropy (RMA) systems. Both ac and dc magnetic measurements indicate a single transition from paramagnetic to speromagnetic or spin glasslike state around 5.6 K. The moderate RMA prevents the formation of long- (or quasilong)-range magnetic order and slows down the spin dynamics in the critical region. Further its isothermal remnant magnetization exhibits a small maximum, instead of a gradual increase with field in SGs. The roles of RMA in the magnetic structure and dynamics of disordered and frustrated systems are discussed by comparisons between the weak RMA system, the moderate or strong RMA system, and conventional SG.

36 MATERIALS SCIENCE↗

Surface hopping outperforms secular Redfield theory when reorganization energies range from small to moderate (and nuclei are classical)

We evaluate the accuracy of Tully’s surface hopping algorithm for the spin-boson model in the limit of small to moderate reorganization energy. We calculate transition rates between diabatic surfaces in the exciton basis and compare against exact results from the hierarchical equations of motion; we also compare against approximate rates from the secular Redfield equation and Ehrenfest dynamics. We show that decoherence-corrected surface hopping performs very well in this regime, agreeing with secular Redfield theory for very weak system-bath coupling and outperforming secular Redfield theory for moderate system-bath coupling. Surface hopping can also be extended beyond the Markovian limits of standard Redfield theory. Given previous work [B. R. Landry and J. E. Subotnik, J. Chem. Phys. 137, 22A513 (2012)] that establishes the accuracy of decoherence-corrected surface-hopping in the Marcus regime, this work suggests that surface hopping may well have a very wide range of applicability.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Basic factors for acquiring, correcting, and interpreting probe current-voltage characteristic in moderate-collisional plasma for determining electron energy distribution

Methods for inferring the electron distribution function (EDF) from a probe current–voltage trace are reviewed for moderate-collisional plasma. The explicit accounting of particle collisions, modeling sheath depletion, and electron refilling processes are rarely performed when analyzing probe measurements, yet they are critical for regime validity, EDF-profile accuracy, and space potential quantification precision. Furthermore, the advantages, limitations, and utilization of large-area wall probes in moderate-collisional plasma, capable of highly resolved indications of energetic electrons in plasma, are outlined.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Experimental verification of TNSA protons and deuterons in the multi-picosecond moderate intensity regime

Ion acceleration from high intensity short pulse laser interactions is of great interest due to a number of applications, and there has been significant work carried out with laser energies up to a few 100 J with 10's of femtosecond to 1 ps pulse durations. Here, we report results from an experiment at the OMEGA EP laser, where laser energy and pulse length were varied from 100 to 1250 J and 0.7–30 ps, respectively, in the moderate (2 × 10 17 –2 × 10 18 W/cm 2 ) laser intensity regime. Ions and electrons were simultaneously measured from disk targets made of CH and CD by a Thomson parabola and a magnetic spectrometer, respectively. Measurements showed that the electron temperature, T e (MeV), has a dependence on the laser energy, E L (J), and pulse duration, τ L (ps), and its empirical scaling was found to be 0.015 × E L 0.90 τ L –0.48. The maximum proton and deuteron energies are linearly dependent on the electron temperature, (5.60 ± 0.26) × T e and (3.17 ± 0.18) × T e , respectively. A significant increase in proton numbers with the laser energy was also observed. Furthermore, the increase in the maximum proton energy and proton count with higher energy longer duration pulses presented in this article shows that such laser conditions have a great advantage for applications, such as the proton radiograph, in the moderate laser intensity regime.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Accurate atmospheric parameters at moderate resolution using spectral indices: Preliminary application to the marvels survey

Studies of Galactic chemical, and dynamical evolution in the solar neighborhood depend on the availability of precise atmospheric parameters (effective temperature T {sub eff}, metallicity [Fe/H], and surface gravity log g) for solar-type stars. Many large-scale spectroscopic surveys operate at low to moderate spectral resolution for efficiency in observing large samples, which makes the stellar characterization difficult due to the high degree of blending of spectral features. Therefore, most surveys employ spectral synthesis, which is a powerful technique, but relies heavily on the completeness and accuracy of atomic line databases and can yield possibly correlated atmospheric parameters. In this work, we use an alternative method based on spectral indices to determine the atmospheric parameters of a sample of nearby FGK dwarfs and subgiants observed by the MARVELS survey at moderate resolving power (R ∼ 12,000). To avoid a time-consuming manual analysis, we have developed three codes to automatically normalize the observed spectra, measure the equivalent widths of the indices, and, through a comparison of those with values calculated with predetermined calibrations, estimate the atmospheric parameters of the stars. The calibrations were derived using a sample of 309 stars with precise stellar parameters obtained from the analysis of high-resolution FEROS spectra, permitting the low-resolution equivalent widths to be directly related to the stellar parameters. A validation test of the method was conducted with a sample of 30 MARVELS targets that also have reliable atmospheric parameters derived from the high-resolution spectra and spectroscopic analysis based on the excitation and ionization equilibria method. Our approach was able to recover the parameters within 80 K for T {sub eff}, 0.05 dex for [Fe/H], and 0.15 dex for log g, values that are lower than or equal to the typical external uncertainties found between different high-resolution analyses. An additional test was performed with a subsample of 138 stars from the ELODIE stellar library, and the literature atmospheric parameters were recovered within 125 K for T {sub eff}, 0.10 dex for [Fe/H], and 0.29 dex for log g. These precisions are consistent with or better than those provided by the pipelines of surveys operating with similar resolutions. These results show that the spectral indices are a competitive tool to characterize stars with intermediate resolution spectra.

79 ASTRONOMY AND ASTROPHYSICS↗

DISTINGUISHING CENTRAL PERTURBATIONS BY BINARY STELLAR AND PLANETARY SYSTEMS UNDER THE MODERATELY STRONG FINITE-SOURCE EFFECT

We investigate high-magnification events caused by wide binary stellar and planetary systems under the moderately strong finite-source effect where the diameter of the source star is comparable with the caustics induced by a binary companion and a planet. From this investigation, we find that a characteristic feature in the central perturbations induced by the binary systems commonly appears in a constant range where the size of the caustic induced by the binary companion is between 1.5 and 1.9 times of the diameter of the source, whereas in the central perturbations induced by the planetary systems the feature commonly appears in a range where the ratio of the size of the caustic induced by the planet to the source diameter changes with the planet/primary mass ratio. High-magnification events caused by the binary and planetary systems with the characteristic feature produce a distinctive short-duration bump in the residuals from the single-lensing light curve, where the bump occurs near the time of peak magnification of the events. Because of a well-known planet/binary degeneracy, we compare binary- and planetary-lensing events with the short-duration bump in the residuals. As a result, we find the features of the binary-lensing events that are discriminated from the planetary-lensing events despite the moderately strong finite-source effect and thus can be used to immediately distinguish between the binary and planetary companions. We also find the feature that appears only in binary-lensing events with a very low mass ratio or planetary-lensing events. This implies that the lens systems with the feature have a very low mass binary companion (such as a brown dwarf) or a planet.

79 ASTRONOMY AND ASTROPHYSICS↗

A COMPARATIVE ANALYSIS OF VIRIAL BLACK HOLE MASS ESTIMATES OF MODERATE-LUMINOSITY ACTIVE GALACTIC NUCLEI USING SUBARU/FMOS

We present an analysis of broad emission lines observed in moderate-luminosity active galactic nuclei (AGNs), typical of those found in X-ray surveys of deep fields, with the goal of testing the validity of single-epoch virial black hole mass estimates. We have acquired near-infrared spectra of AGNs up to z {approx} 1.8 in the COSMOS and Extended Chandra Deep Field-South Survey, with the Fiber Multi-Object Spectrograph mounted on the Subaru telescope. These near-infrared spectra provide a significant detection of the broad H{alpha} line, shown to be a reliable probe of black hole mass at low redshift. Our sample has existing optical spectroscopy that provides a detection of Mg II, typically used for black hole mass estimation at z {approx}> 1. We carry out a spectral-line fitting procedure using both H{alpha} and Mg II to determine the virial velocity of gas in the broad-line region, the continuum luminosity at 3000 A, and the total H{alpha} line luminosity. With a sample of 43 AGNs spanning a range of two decades in luminosity, we find a tight correlation between the ultraviolet and emission-line luminosity. There is also a close one-to-one relationship between the full width at half-maximum of H{alpha} and Mg II. Both of these then lead to there being very good agreement between H{alpha}- and Mg II-based masses over a wide range in black hole mass, i.e., M{sub BH} {approx} 10{sup 7-9} M{sub Sun }. In general, these results demonstrate that local scaling relations, using Mg II or H{alpha}, are applicable for AGNs at moderate luminosities and up to z {approx} 2.

79 ASTRONOMY AND ASTROPHYSICS↗

MOLYBDENUM, RUTHENIUM, AND THE HEAVY r-PROCESS ELEMENTS IN MODERATELY METAL-POOR MAIN-SEQUENCE TURNOFF STARS

The ratios of elemental abundances observed in metal-poor stars of the Galactic halo provide a unique present-day record of the nucleosynthesis products of its earliest stars. While the heaviest elements were synthesized by the r- and s-processes, dominant production mechanisms of light trans-ironic elements were obscure until recently. This work investigates further our 2011 conclusion that the low-entropy regime of a high-entropy wind (HEW) produced molybdenum and ruthenium in two moderately metal-poor turnoff stars that showed extreme overabundances of those elements with respect to iron. Only a few, rare nucleosynthesis events may have been involved. Here we determine abundances for Mo, Ru, and other trans-Fe elements for 28 similar stars by matching spectral calculations to well-exposed near-UV Keck HIRES spectra obtained for beryllium abundances. In each of the 26 turnoff stars with Mo or Ru line detections and no evidence for s-process production (therefore old), we find Mo and Ru to be three to six times overabundant. In contrast, the maximum overabundance is reduced to factors of three and two for the neighboring elements zirconium and palladium. Since the overproduction peaks sharply at Mo and Ru, a low-entropy HEW is confirmed as its origin. The overabundance level of the heavy r-process elements varies significantly, from none to a factor of four, but is uncorrelated with Mo and Ru overabundances. Despite their moderate metallicity, stars in this group trace the products of different nucleosynthetic events: possibly very few events, possibly events whose output depended on environment, metallicity, or time.

79 ASTRONOMY AND ASTROPHYSICS↗

Lifshitz-Transition-Driven Metal-Insulator Transition in Moderately Spin-Orbit-Coupled Sr 2-x La x RhO 4

Motivated by the novel insulating state of Sr 2 IrO 4 from strong spin-orbit coupling (SOC), we investigate, by means of angle resolved photoemission, the metal-insulator transition (MIT) mechanism in Sr 2-x La x RhO 4 whose mother compound is isovalent and isostructural but has smaller SOC strength compared to Sr 2 IrO 4 . Transport and angle resolved photoemission results from single crystalline Sr 2-x La x RhO 4 revealed that the MIT occurs coincidentally with a multi- to single-band transition (Lifshitz transition) at x=0.4. Starting from x=0.4, there is a gradual but anomalous enhancement in the band gap size with additional electron doping, suggesting that the insulating phase in Sr 2-x La x RhO 4 is a new type which has been rarely investigated. These results suggest that the insulating phase in Sr 2-x La x RhO 4 is likely induced by the moderate SOC strength and electron doping effect from the La. Our findings in this study not only elucidate the MIT mechanism in Sr 2-x La x RhO 4 , but may also open new avenues for novel MIT research in moderate SOC regimes.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Structural characteristics of alkaline phosphatase from the moderately halophilic bacterium Halomonas sp. 593

In order to clarify the structural basis of the halophilic characteristics of an alkaline phosphatase derived from the moderate halophile Halomonas sp. 593 (HaAP), the tertiary structure of HaAP was determined to 2.1 Å resolution by X-ray crystallography. The structural properties of surface negative charge and core hydrophobicity were shown to be intermediate between those characteristic of halophiles and non-halophiles, and may explain the unique functional adaptation to a wide range of salt concentrations. Alkaline phosphatase (AP) from the moderate halophilic bacterium Halomonas sp. 593 (HaAP) catalyzes the hydrolysis of phosphomonoesters over a wide salt-concentration range (1–4 M NaCl). In order to clarify the structural basis of its halophilic characteristics and its wide-range adaptation to salt concentration, the tertiary structure of HaAP was determined by X-ray crystallography to 2.1 Å resolution. The unit cell of HaAP contained one dimer unit corresponding to the biological unit. The monomer structure of HaAP contains a domain comprised of an 11-stranded β-sheet core with 19 surrounding α-helices similar to those of APs from other species, and a unique ‘crown’ domain containing an extended ‘arm’ structure that participates in formation of a hydrophobic cluster at the entrance to the substrate-binding site. The HaAP structure also displays a unique distribution of negatively charged residues and hydrophobic residues in comparison to other known AP structures. AP from Vibrio sp. G15-21 (VAP; a slight halophile) has the highest similarity in sequence (70.0% identity) and structure (C{sup α} r.m.s.d. of 0.82 Å for the monomer) to HaAP. The surface of the HaAP dimer is substantially more acidic than that of the VAP dimer (144 exposed Asp/Glu residues versus 114, respectively), and thus may enable the solubility of HaAP under high-salt conditions. Conversely, the monomer unit of HaAP formed a substantially larger hydrophobic interior comprising 329 C atoms from completely buried residues, whereas that of VAP comprised 264 C atoms, which may maintain the stability of HaAP under low-salt conditions. These characteristics of HaAP may be responsible for its unique functional adaptation permitting activity over a wide range of salt concentrations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

SU-F-T-644: Reproducibility of Target Position Using Moderate Voluntary Breath- Hold During Liver Stereotactic Ablative Radiotherapy

Purpose: To evaluate the reproducibility of target position using moderate voluntary breath-hold during liver stereotactic ablative radiotherapy (SABR). Methods: Two patients who underwent liver SABR on a Varian TrueBeam STx linac were used for this study. Fiducial markers were placed in and around the target in the liver as surrogates for the target position and motion. GTVs were contoured by assessing tumor extent on contrast enhanced CT. The PTV was created from the GTV by adding 2 mm margins to account for the residual motion during breath-holds. A portable biofeedback system was used to facilitate the breath-hold to a reproducible position. The Varian RPM system was used for gating the linac. Proceeding each treatment, orthogonal kV pairs were taken, and alignment to nearby bony anatomy was performed. Then the breath-hold CBCT was acquired to align the fiducial markers. On-line fluoroscopy was used to fine-tune the breath-hold gating thresholds to correlate with the positions of the fiducial markers. The inter-fraction reproducibility of the target was evaluated by the offsets of the daily breath-hold CBCTs from the paired kV matches as a direct measure of the target position relative to the bony anatomy. The intra-fraction reproducibility of the target position was assessed by the gated window of the RPM marker block for each fraction. Results: The absolute mean offsets between the CBCT and paired kV matches in the vertical, longitudinal, and lateral directions were 0.06 cm, 0.10 cm, and 0.06 cm for patient 1, and 0.37 cm, 0.62 cm, and 0.09 cm for patient 2. The gated window of the RPM marker block for the breath-hold for each fraction was within 0.63 ± 0.16 cm and 0.59 ± 0.12 cm for patients 1 and 2, respectively. Conclusion: Moderate voluntary breath-hold showed good inter- and intra-fraction reproducibility of target position during liver SABR.

60 APPLIED LIFE SCIENCES↗

Randomized control trial of moderate dose vitamin D alters microbiota stability and metabolite networks in healthy adults

ABSTRACT Evidence indicates that both vitamin D and the gut microbiome are involved in the process of colon carcinogenesis. However, it is unclear what effects supplemental vitamin D 3 has on the gut microbiome and its metabolites in healthy adults. We conducted a double-blind, randomized, placebo-controlled trial to identify the acute and long-term microbiota structural and metabolite changes that occur in response to a moderate dose (4,000 IU) of vitamin D 3 for 12 weeks in healthy adults. Our results demonstrated a significant increase in serum 25-hydroxy-vitamin D (25(OH)D) in the treatment group compared to placebo ( P < 0.0001). Vitamin D 3 significantly increased compositional similarity ( P < 0.0001) in the treatment group, and enriched members of the Bifidobacteriaceae family. We also identified a significant inverse relationship between the percent change in serum 25(OH)D and microbial stability in the treatment group ( R = −0.52, P < 0.019). Furthermore, vitamin D 3 supplementation resulted in notable metabolic shifts, in addition to resulting in a drastic rewiring of key gut microbial-metabolic associations. In conclusion, we show that a moderate dose of vitamin D 3 among healthy adults has unique acute and persistent effects on the fecal microbiota, and suggest novel mechanisms by which vitamin D may affect the host-microbiota relationship. IMPORTANCE Preventative measures to reduce the rise in early-onset colorectal cancer are of critical need. Both vitamin D, dietary and serum levels, and the gut microbiome are implicated in the etiology of colorectal cancer. By understanding the intimate relationship between vitamin D, the gut microbiome, and its metabolites, we may be able to identify key mechanisms that can be targeted for intervention, including inflammation and metabolic dysfunction. Furthermore, the similarity of vitamin D to cholesterol, which is metabolized by the gut microbiome, gives precedence to its ability to produce metabolites that can be further studied and leveraged for controlling colorectal cancer incidence and mortality.

Wyatt, Madhur↗

Effect of irradiation with MeV protons and electrons on the conductivity compensation and photoluminescence of moderately doped p-4H-SiC (CVD)

The compensation of moderately doped p-4H-SiC samples grown by the chemical vapor deposition (CVD) method under irradiation with 0.9-MeV electrons and 15-MeV protons is studied. The experimentally measured carrier removal rates are 1.2–1.6 cm{sup –1} for electrons and 240–260 cm{sup –1} for protons. The dependence of the concentration of uncompensated acceptors and donors, measured in the study, demonstrates a linear decrease with increasing irradiation dose to the point of complete compensation. This run of the dependence shows that compensation of the samples is due to the transition of carriers to deep centers formed by primary radiation-induced defects. It is demonstrated that, in contrast to n-SiC (CVD), primary defects in the carbon sublattice of moderately doped p-SiC (CVD) only cannot account for the compensation process. In p-SiC, either primary defects in the silicon sublattice, or defects in both sublattices are responsible for conductivity compensation. Also, photoluminescence spectra are examined in relation to the irradiation dose.

36 MATERIALS SCIENCE↗

Analytic Insights into the Neutronic Characteristics of Neutron Moderators from MCNP Calculations

In the course of re-processing the ENDF/B VIII.0 thermal scattering law data, formulas and data checking insights were developed from MCNP calculations into the neutronic characteristics of moderators. Infinite medium test calculations were carried out in MCNP as part of the verification effort for the ACE formatted thermal scattering files. Edit results from MCNP were combined with derived results to formulate several equations which give analytic insights into the neutronic behavior of moderators.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗