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At least 181 records · Page 10

The effect of Na vapor on the Na content of chondrules

Chondrules contain higher concentrations of volatiles (Na) than expected for melt droplets in the solar nebula. Recent studies have proposed that chondrules may have formed under non-canonical nebular conditions such as in particle/gas-rich clumps. Such chondrule formation areas may have contained significant Na vapor. To test the hypothesis of whether a Na-rich vapor would minimize Na volatilization reaction rates in a chondrule analog and maintain the Na value of the melt, experiments were designed where a Na-rich vapor could be maintained around the sample. A starting material with a melting point lower that typical chondrules was required to keep the logistics of working with Na volatilization from NaCl within the realm of feasibility. The Knippa basalt, a MgO-rich alkali olivine basalt with a melting temperature of 1325 +/- 5 C and a Na2O content of 3.05 wt%, was used as the chondrule analog. Experiments were conducted in a 1 atm, gas-mixing furnace with the fO2 controlled by a CO/CO2 gas mixture and fixed at the I-W buffer curve. To determine the extent of Na loss from the sample, initial experiments were conducted at high temperatures (1300 C - 1350 C) for duration of up to 72 h without a Na-rich vapor present. Almost all (up to 98%) Na was volatilized in runs of 72 h. Subsequent trials were conducted at 1330 C for 16 h in the presence of a Na-rich vapor, supplied by a NaCl-filled crucible placed in the bottom of the furnace. Succeeding Knudsen cell weight-loss mass-spectrometry analysis of NaCl determined the P(sub Na) for these experimental conditions to be in the 10(exp -6) atm range. This value is considered high for nebula conditions but is still plausible for non-canonical environments. In these trials the Na2O content of the glass was maintained or in some cases increased; Na2O values ranged from 2.62% wt to 4.37% wt. The Na content of chondrules may be controlled by the Na vapor pressure in the chondrule formation region. Most heating events capable of producing chondrules are sufficient to volatile Na. Sodium volatilization reaction rates will be reduced to varying degrees from melt droplets, depending on the magnitude of the P(sub Na) generated. A combination of Na vapor during, and Na diffusion back into chondrules after, formation could maintain and/or enrich Na concentrations in chondrules.

Lewis, R. Dean↗

From S-N to the Paris Law with a New Mixed-Mode Cohesive Fatigue Model

The relationship between fatigue life and fatigue crack propagation rate is explored with a new cohesive damage model. The parameters of the model are obtained from idealizations of S-N diagrams used in engineering design. The model is based on the hypothesis that both stable tearing damage and damage due to cyclic loading are representations of a density of microcracks and, therefore, a single damage variable can describe the state of damage. This assumption implies that the quasi-static cohesive law that describes tearing is also the envelope of the fatigue damage. Fatigue damage within the cohesive envelope is assumed to accumulate at a rate that depends on the displacement jumps. The fatigue model was implemented as a UMAT subroutine for Abaqus cohesive elements by adding fatigue damage accumulation to a cohesive model based on the Turon mixed-mode cohesive laws. The analyses were conducted using a simplified cyclic loading procedure in which the maximum applied load is kept constant and the computational expense of cycling the load is avoided. The predicted propagation rates in mode I and mixed mode were compared to experimental results for IM7/8552 graphite/epoxy tape. Several aspects of the results were investigated, including the effect of R-curves, the stress ratio R, and the difference between displacement control and force control.

Davila, Carlos G.↗

Effects of sudden mixing in the solar core on solar neutrinos and ice ages.

Some numerical experiments with a solar model have been conducted in connection with the hypothesis regarding the effects of mixing in the solar core. Questions concerning a plausible mechanism by which such a mixing could be produced are explored. The variation of solar luminosity throughout the numerical experiments is shown. In connection with a great change in luminosity after a second mixing, it is suggested that the earth is presently undergoing an ice age.

Ezer, D.↗

Electrically conducting ternary amorphous fully oxidized materials and their application

Electrically active devices are formed using a special conducting material of the form Tm--Ox mixed with SiO2 where the materials are immiscible. The immiscible materials are forced together by using high energy process to form an amorphous phase of the two materials. The amorphous combination of the two materials is electrically conducting but forms an effective barrier.

Giauque, Pierre↗

Initial development of a hypersonic free mixing layer

A preliminary experimental investigation to establish some of the characteristics and further the understanding of the initial development of a turbulent free mixing layer for hypersonic speeds has been conducted. Mean profile data at about 6 inches downstream of the exit of a hypersonic nozzle have been obtained in nitrogen for a nominal Mach number of 19.5, total temperature of about 1670 K and Reynolds number range from about 50,000 to 110,000 per foot and have been compared with profiles upstream of the nozzle exit. Static pressure varied across the shear layer for the present tests. The outer 80 percent of the high-velocity portion of the free shear layer can be calculated by a rotational method of characteristics. However, turbulent mixing is evidently important in the low-velocity region, and effects of eddy viscosity and eddy conductivity should be included in a theoretical analysis.

Harvey, W. D.↗

Determination of interlaminar fracture toughness and fracture mode dependence of composites using the edge delamination test

Edge delamination testing has been conducted in order to determine the mixed mode interlaminar fracture toughness of unnotched (+, -35/0/90)s and (0/+, -35/90)s laminates with graphite fibers and epoxy matrices, with or without elastomer additives. Although the two stacking sequences were chosen so that the total strain energy release rates were equal, the percentages of crack opening and shear mode energy release rates were found to vary widely between the layups. Plots of interlaminar fracture toughness as a function of crack opening energy release rate percentage have been drawn to generate delamination failure criteria which reflect the observed fracture mode dependence.

Obrien, T. K.↗

Kinetics of diffusional droplet growth in a liquid/liquid two-phase system

A new powerful experimental technique based on holographic observations, developed at the NASA Marshall Space Flight Center, now permits observation of small liquid droplets coarsening. This technique was developed and used for mixed-dimensional coarsening studies. Experiments were conducted on an isopycnic two-phase alloy of succinonitrile and water, annealed isothermally over a four-month period. The succinonitrile-rich droplets precipitate from a water-rich liquid matrix having a density very close to that of the droplets. The matrix and droplets, however, have different optical indices. The results of these experiments, along with the results of computer simulation based on the quasi-static diffusion approximation developed at Rensselaer are reported. These results were published recently. Copies of these papers are attached to this report.

Glickman, M. E.↗

Validity Using Pump-Probe Pulses to Determine the Optical Response of Niobate Crystals

A variety of niobate crystals have found their places in nonlinear optical applications as well as in laser devices. In recent years much attention has been paid to study the ultrafast optical response in a variety of photorefractive crystals such as KTa(1-x)Nb(x)O3 and KNbO3 crystals, glasses, semiconductors and polymers for applications in optical switching, information processing, optical computing, and all-optical device systems. Third-order optical nonlinearity is the most important property for realization of all-optical switching. Therefore experiments have been performed on the third order susceptibility using a variety of techniques such as the third-order harmonic generation, EFISH and degenerate four-wave mixing(DFWM). The latter has been conducted with a variety of pump wavelengths and with nanosecond, picosecond and femtosecond pulses. Niobate crystals, such as potassium niobate KNbO3, potassium tantalate niobate KTN family (KTa(1-x)Nb(x)O3), strontium barium niobate SBN (Sr(x)Ba(1-x)Nb2O6) and potassium-sodium niobate SBN (KNSBN) are attractive due to their photorefractive properties for application in optical storage and processing. The pulsed probe experiments performed on theses materials have suggested two types of time responses. These responses have been associated with an coherent response due to Chi(sup 3), and a long lived component due to excited state population. Recent study of DFWM on KNbO3 and KTN family reveals that the long lived component of those crystals depends on the crystal orientation. A slowly decaying signal is observable when the grating vector K(sub g) is not perpendicular to the C-axis of those photorefractive crystals', otherwise the optical response signal would be only a narrow coherent peak with FWHM equal to the cross-correlation width of the write beam pulses. Based on this understanding, we study the photodynamical process of a variety of niobate crystals using DFWM in a Kg perpindicular to C geometry with a ps-YAG: Nd laser operating at 532nm. However, the discrepancies in numerical estimations of Chi(sup 3) in these materials and other nonlinear optical media have resulted in a number of discussions. In order to better understand the photodynamical process of niobate crystals after an short pulse excitation we analyze the factors governing the coherent signal and present the DFWM spectra of niobate crystals.

Liu, Huimin↗

A Fuel-Efficient Conflict Resolution Maneuver for Separation Assurance

Automated separation assurance algorithms are envisioned to play an integral role in accommodating the forecasted increase in demand of the National Airspace System. Developing a robust, reliable, air traffic management system involves safely increasing efficiency and throughput while considering the potential impact on users. This experiment seeks to evaluate the benefit of augmenting a conflict detection and resolution algorithm to consider a fuel efficient, Zero-Delay Direct-To maneuver, when resolving a given conflict based on either minimum fuel burn or minimum delay. A total of twelve conditions were tested in a fast-time simulation conducted in three airspace regions with mixed aircraft types and light weather. Results show that inclusion of this maneuver has no appreciable effect on the ability of the algorithm to safely detect and resolve conflicts. The results further suggest that enabling the Zero-Delay Direct-To maneuver significantly increases the cumulative fuel burn savings when choosing resolution based on minimum fuel burn while marginally increasing the average delay per resolution.

Bowe, Aisha Ruth↗

Parametric Study of a Mixer/Ejector Nozzle with Mixing Enhancement Devices

A numerical study employing a simplified model of the High Speed Civil Transport mixer/ejector nozzle has been conducted to investigate the effect of tabs (vortex generators) on the mixing process. More complete mixing of the primary and secondary flows within the confined ejector lowers peak exit velocity resulting in reduced jet noise. Tabs were modeled as vortex pairs and inserted into the computational model. The location, size, and number of tabs were varied and its effect on the mixing process is presented here both quantitatively and qualitatively. A baseline case (no tabs) along with six other cases involving two different vortex strengths at three different orientations have been computed and analyzed. The case with the highest vorticity (six vortices representing large tabs) gives the best mixing. It is shown that the influence of the vorticity acts primarily in the forward or middle portions of the duct, significantly alters the flow structure, and promotes some mixing in the lateral direction. Unmixed pockets were found at the top and bottom of the lobe, and more clever placement of tabs improved mixing in the vertical direction. The technique of replacing tabs with vortices shows promise as an efficient tool for quickly optimizing tab placement in lobed mixers.

DalBello, T.↗

Some effects of ablation on transport properties in the Jovian atmosphere

In this paper the transport properties at the inner and outer boundary for mixing between ablation products and a Jovian-like atmosphere are calculated. The dominant species at these boundaries are C, H, O, He, H+, and e. Accurate potential energy curves are obtained for the fifteen possible two-body interactions among these species by fitting good semiempirical potentials for which transport collision cross sections have been tabulated to accurate experimental and theoretical information. Results are obtained for the viscosity and translational thermal conductivity of the pure species and the binary diffusion coefficients from 1000 K to 25,000 K. In addition, the mixture translational thermal conductivity and viscosity are calculated at the inner and outer mixing boundaries. This information is required for calculating flowfield properties and surface heating. The most important conclusion is that the translational thermal conductivity is substantially lower at the inner mixing boundary than it is at the outer mixing boundary.

Biolsi, L.↗

Feasibility study for the Cryogenic Orbital Nitrogen Experiment (CONE)

An improved understanding of low gravity subcritical cryogenic fluid behavior is critical for the continued development of space based systems. Although early experimental programs provided some fundamental understanding of zero gravity cryogenic fluid behavior, more extensive flight data are required to design space based cryogenic liquid storage and transfer systems with confidence. As NASA's mission concepts evolve, the demand for optimized in-space cryogenic systems is increasing. Cryogenic Orbital Nitrogen Experiment (CONE) is an attached shuttle payload experiment designed to address major technological issues associated with on-orbit storage and supply of cryogenic liquids. During its 7 day mission, CONE will conduct experiments and technology demonstrations in active and passive pressure control, stratification and mixing, liquid delivery and expulsion efficiency, and pressurant bottle recharge. These experiments, conducted with liquid nitrogen as the test fluid, will substantially extend the existing low gravity fluid data base and will provide future system designers with vital performance data from an orbital environment.

Bell, R. S.↗

Low Pressure Flame Blowoff from the Forward Stagnation Region of a Blunt-Nosed Cast PMMA Cylinder in Axial Mixed Convective Flow

Low-pressure blowoff experiments were conducted with a stagnation flame stabilized on the forward tip of cast PMMA rods in a vertical wind tunnel. Pressure, forced flow velocity, gravity, and ambient oxygen concentration were varied. Stagnation flame blowoff is determined from a time-stamped video recording of the test. The blowoff pressure is determined from test section pressure transducer data that is synchronized with the time stamp. The forced flow velocity is also determined from the choked flow orifice pressure. Most of the tests were performed in normal gravity, but a handful of microgravity tests were also conducted to determine the influence of buoyant flow velocity on the blowoff limits. The blowoff limits are found to have a linear dependence between the partial pressure of oxygen and the total pressure, regardless of forced flow velocity and gravity level. The flow velocity (forced and/or buoyant) affects the blowoff pressure through the critical Damkohler number residence time, which dictates the partial pressure of oxygen at blowoff. This is because the critical stretch rate increases linearly with increasing pressure at low pressure (sub-atmospheric pressures) since a second-order overall reaction rate with two-body reactions dominates in this pressure range.

flammability↗

Sensitivity of the structure of untripped mixing layers to small changes in initial conditions

An experimental study was conducted concerning the influence of small changes in initial conditions on the near- and far-field evolution of the three-dimensional structure of a plan mixing layer. A two-stream mixing layer with a velocity ratio of 0.6 was generated with the initial boundary layers on the splitter plate laminar and was nominally two-dimensional. The initial conditions were changed slightly by interchanging the high- and low-speed sides of the wind tunnel, while maintaining the same velocities, and hence velocity ratio. This resulted in small changes in the initial boundary layer properties, and the perturbations present in the boundary layers were interchanged between the high- and low-speed sides for the two cases. The results indicate that, even with this relatively minor change in initial conditions, the near-field regions of the two cases differ significantly. The peak Reynolds stress levels in the near-field differ by up to 100 percent, and this is attributed to a difference in the location of the initial spanwise vortex roll-up. In addition, the positions and shapes of the individual streamwise vortical structures differ for the two cases, although the overall structures differ for the two cases, although the overall qualitative description of these structures is comparable. The subsequent reorganization and decay of the streamwise vortical structures is very similar for the two cases. As a result, in the far field, both mixing layers achieve similar structure, yielding comparable growth rates, Reynolds stress, distribution, and spectral content.

Plesniak, M. W.↗

Influence of Geometry and Flow Variation on Jet Mixing and NO Formation in a Model Staged Combustor Mixer with Eight Orifices

A series of non-reacting parametric experiments was conducted to investigate the effect of geometric and flow variations on mixing of cold jets in an axis-symmetric, heated cross flow. The confined, cylindrical geometries tested represent the quick mix region of a Rich-Burn/Quick-Mix/Lean-Burn (RQL) combustor. The experiments show that orifice geometry and jet to mainstream momentum-flux ratio significantly impact the mixing characteristic of jets in a cylindrical cross stream. A computational code was used to extrapolate the results of the non-reacting experiments to reacting conditions in order to examine the nitric oxide (NO) formation potential of the configurations examined. The results show that the rate of NO formation is highest immediately downstream of the injection plane. For a given momentum-flux ratio, the orifice geometry that mixes effectively in both the immediate vicinity of the injection plane, and in the wall regions at downstream locations, has the potential to produce the lowest NO emissions. The results suggest that further study may not necessarily lead to a universal guideline for designing a low NO mixer. Instead, an assessment of each application may be required to determine the optimum combination of momentum-flux ratio and orifice geometry to minimize NO formation. Experiments at reacting conditions are needed to verify the present results.

Samuelsen, G. S.↗

Highly Conductive Multifunctional Graphene Polycarbonate Nanocomposites

Graphene nanosheet bisphenol A polycarbonate nanocomposites (0.027 2.2 vol %) prepared by both emulsion mixing and solution blending methods, followed by compression molding at 287 C, exhibited dc electrical percolation threshold of approx.0.14 and approx.0.38 vol %, respectively. The conductivities of 2.2 vol % graphene nanocomposites were 0.512 and 0.226 S/cm for emulsion and solution mixing. The 1.1 and 2.2 vol % graphene nanocomposites exhibited frequency-independent behavior. Inherent conductivity, extremely high aspect ratio, and nanostructure directed assembly of the graphene using PC nanospheres are the main factors for excellent electrical properties of the nanocomposites. Dynamic tensile moduli of nanocomposites increased with increasing graphene in the nanocomposite. The glass transition temperatures were decreased with increasing graphene for the emulsion series. High-resolution electron microscopy (HR-TEM) and small-angle neutron scattering (SANS) showed isolated graphene with no connectivity path for insulating nanocomposites and connected nanoparticles for the conductive nanocomposites. A stacked disk model was used to obtain the average particle radius, average number of graphene layers per stack, and stack spacing by simulation of the experimental SANS data. Morphology studies indicated the presence of well-dispersed graphene and small graphene stacking with infusion of polycarbonate within the stacks.

Yoonessi, Mitra↗

Final Report for Intravenous Fluid Generation (IVGEN) Spaceflight Experiment

NASA designed and operated the Intravenous Fluid Generation (IVGEN) experiment onboard the International Space Station (ISS), Increment 23/24, during May 2010. This hardware was a demonstration experiment to generate intravenous (IV) fluid from ISS Water Processing Assembly (WPA) potable water using a water purification technique and pharmaceutical mixing system. The IVGEN experiment utilizes a deionizing resin bed to remove contaminants from feedstock water to a purity level that meets the standards of the United States Pharmacopeia (USP), the governing body for pharmaceuticals in the United States. The water was then introduced into an IV bag where the fluid was mixed with USP-grade crystalline salt to produce USP normal saline (NS). Inline conductivity sensors quantified the feedstock water quality, output water purity, and NS mixing uniformity. Six 1.5-L bags of purified water were produced. Two of these bags were mixed with sodium chloride to make 0.9 percent NS solution. These two bags were returned to Earth to test for compliance with USP requirements. On-orbit results indicated that all of the experimental success criteria were met with the exception of the salt concentration. Problems with a large air bubble in the first bag of purified water resulted in a slightly concentrated saline solution of 117 percent of the target value of 0.9 g/L. The second bag had an inadequate amount of salt premeasured into the mixing bag resulting in a slightly deficient salt concentration of 93.8 percent of the target value. The USP permits a range from 95 to 105 percent of the target value. The testing plans for improvements for an operational system are also presented.

McQuillen, John B.↗

Experimental study of cross flow mixing in cylindrical and rectangular ducts

An experimental investigation of non-reacting cross flow jet injection and mixing in cylindrical and rectangular ducts has been conducted with application to a low emissions combustor. Quantitative measurement of injectant concentration distributions perpendicular to the duct axis were obtained by planar digital imaging of the Mie-scattered light from an aerosol seed mixed with the injectant. The flowfield unmixedness was evaluated using (1) a mixing parameter derived from the ratio of the jet concentration fluctuations to the fully mixed concentration, and (2) probability density functions of the concentration distributions. Mixing rate was measured for 45 degree slant slot and round orifice injectors.

Liscinsky, D. S.↗