High-Pressure, Low Temperature Composite Nozzles for Long-Term H2
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08 HYDROGEN↗
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Synthesis of Gold Hydride at High Pressure and High Temperature
Gold is an unreactive metal and its chemical interactions with hydrogen have only recently been explored. Here, in this study, we report the formation of gold hydride above 40 GPa and 2200 K in X-ray free electron laser heated diamond anvil cells using various hydrocarbons as hydrogen sources. Above 40 GPa, a hexagonal phase emerges close to the gold melting point, corresponding to a hydride with stoichiometry Au 2 H x , with x increasing from 0 to near 1 with pressure from 40 to 80 GPa. This is a high-temperature phase which reverts to face centered cubic gold on cooling to 295 K. Accompanying DFT-MD simulations are in excellent agreement with experiment and reveal the structure to consist of an hexagonal close packed gold lattice with atomic hydrogen disordered in the interstices. The hydrogen is superionic and exhibits high diffusivity through the crystalline gold lattice. Our results present the first solid-state binary compound of gold and hydrogen.
Ab initio calculations↗
The Evolution of the EH4 Chondrite Indarch at High Pressure and Temperature: The First Experimental Results
Chondrite groups are characterized by variations in bulk composition and oxidation state, illustrating in part heterogeneity in the early solar nebula. Planetary accretion could be explained by at least two different scenarios: the homogeneous [1] and heterogeneous accretion models [2, 3]. In particular, for the formation of the Earth, some studies (e.g. [2, 3]) assume that one component is highly reduced material comparable to enstatite chondrites, devoid of volatile elements but containing all other elements in C1 abundance ratios. To derive constraints on the understanding of early differentiation processes, studies of the silicate phase relations and their interactions with metal, at relevant P-T-fO2, are required. Melting relations and equilibrium partitioning behaviour have been studied on peridotitic and chondritic starting compositions at pressures and temperatures corresponding to the transition zone and lower mantle [4, 5, 6]. However, enstatite chondrites, which are highly reduced primitive meteorites, have not yet been studied experimentally under such conditions. Thus, multianvil experiments have been performed at 20-25 GPa and 2000-2400 C on the EH4 chondrite Indarch.
Berthet, S.↗
Calcined Polyethyleneimine-Coated Optical Fibers for Distributed pH Monitoring at High Pressures and Temperatures
In the oil and gas, CO2 sequestration, H2 subsurface storage, and geothermal energy sectors, subsurface pH measurements are critical for monitoring the geochemical conditions and estimating potential corrosion rates of wellbore systems. Real-time pH measurements in these conditions are vital for detecting and predicting corrosion deterioration of wellbore components that may jeopardize the safety and continued operation of wellbore systems. Previous tests using metal oxide-based coatings (TiO2) provided strong responses at elevated temperatures and moderate pressure stability but provided poor differentiation between acidic and alkaline solutions. Building off the pH responsiveness of the TiO2 surface and known pH sensitivity of amine-based polymers, a coating based on the secondary amine polymer polyethyleneimine (PEI) was developed. As the polymer itself is highly water soluble and easily removed by aqueous solutions, the sensor coating was treated with a high temperature (500 °C) calcination procedure in air to convert it into a more stable oxidized coating capable of withstanding hot aqueous solutions without dissolving while retaining linear pH sensitivity from pH values between 2 and 11. The sensor performance was measured using optical transmission measurements in solutions of various pHs and using optical backscatter reflectometry for distributed pH sensing demonstration in wellbore-relevant pressures (up to 1,000 psi) and temperatures (80 °C).
Shumski, Alexander↗
High Mg activation in implanted GaN by high temperature and ultrahigh pressure annealing
Not provided.We demonstrate high p-type conductivity and hole concentrations >10 18 cm -3 in Mg-implanted GaN. The implantation was performed at room temperature and by post-implantation annealing at 1 GPa of N 2 and in a temperature range of 1200–1400 °C. The high pressure thermodynamically stabilized the GaN surface without the need of a capping layer. We introduce a “diffusion budget,” related to the diffusion length, as a convenient engineering parameter for comparing samples annealed at different temperatures and for different times. Although damage recovery, as measured by XRD, was achieved at relatively low diffusion budgets, these samples did not show p-type conductivity. Further analyses showed heavy compensation by the implantation-induced defects. Higher diffusion budgets resulted in a low Mg ionization energy (~115 meV) and almost complete Mg activation. For even higher diffusion budgets, we observed significant loss of Mg to the surface and a commensurate reduction in the hole conductivity. High compensation at low diffusion budgets and loss of Mg at high diffusion budgets present a unique challenge for shallow implants. A direct control of the formation of compensating defects arising from the implantation damage may be necessary to achieve both hole conductivity and low Mg diffusion.
36 MATERIALS SCIENCE↗
High temperature and high pressure AlGaN/GaN electronics
Disclosed herein are devices, systems and methods useful for downhole sensors and electronics suitable for harsh thermal and mechanical environment associated with high-temperature geothermal drilling and high-temperature/high-pressure oil and gas drilling.
Ginley, David Samuel↗
Determination of the relative resistance to ignition of selected turbopump materials in high-pressure, high-temperature, oxygen environments, volume 1
Advances in the design of the liquid oxygen, liquid hydrogen engines for the Space Transportation System call for the use of warm, high-pressure oxygen as the driving gas in the liquid oxygen turbopump. The NASA Lewis Research Center requested the NASA White Sands Test Facility (WSTF) to design a test program to determine the relative resistance to ignition of nine selected turbopump materials: Hastelloy X, Inconel 600, Invar 36, Monel K-500, nickel 200, silicon carbide, stainless steel 316, and zirconium copper. The materials were subjected to particle impact and to frictional heating in high-pressure oxygen.
Stoltzfus, Joel M.↗
Long-Term High-Temperature High-Pressure Cable for Geothermal Logging Tools - Frequency Response
Frequency Response of the full length of the Prysmian Cable with 100 ft the cable placed in the oven. One set of S-parameter data was collected at room temperature (22 °C) and the second at 300 °C after 5 days of baking.
Wright, Andrew Alexander [Sandia National Laborato↗
High-temperature, high-pressure optical cells
For measuring the thermal diffusivity of HgCdTe melts by the laser-pulse method, an infrared transparent cell with flat windows of sufficient strength to withstand the high-vapor pressure of mercury had to be developed. Since mercury telluride expands on freezing, certain difficulties arose in returning the cell to room temperature without cracking it. T08 commercial fused silica is used in the construction of the cell, and the cells are transparent for wavelengths from about 3.5 microns in the infrared to 260 nm in the ultraviolet. The construction procedure for the required cells has been laborious. However, the obtained cell has routinely withstood internal pressures in excess of 60 atm at 900 C. Attention is given to the design of the windows, aspects of cell construction, and questions of loading.
Holland, L. R.↗
An experimental and modeling study on auto-ignition kinetics of ammonia/methanol mixtures at intermediate temperature and high pressure
A rapid compression machine (RCM) has been applied to measure the ignition delay times of NH 3 /CH 3 OH mixtures covering pressures of 20 and 40 bar, equivalence ratios of 0.5, 1.0 and 2.0, and temperatures between 845 and 1100 K. Here the measurements show that the NH 3 /CH 3 OH mixtures become more reactive with increasing methanol addition. Addition of merely 1% (molar basis) of CH 3 OH to NH 3 lowers the ignition temperature around 100 K at 40 bar in comparison to pure NH 3 . The ignition delay is a complex function of fuel mixture and stoichiometry. For the 1% CH 3 OH mixture, the leaner mixtures are more reactive, while the reverse trend is found for mixtures with 5%, 20% and pure CH 3 OH. Analysis of the pressure profiles shows three distinct ignition modes for NH 3/ CH 3 OH mixtures, facilitated by the pre-ignition heat release from NH 3 consumption. A detailed mechanism for ignition of NH 3 /CH 3 OH fuel blends has been developed, capable of reproducing the ignition behavior of mixtures with reasonable accuracy. A subset for amine / methanol interactions was established, with rate constants for the key reaction between NH 2 and CH 3 OH calculated from ab initio theory. A sensitivity analysis indicates that the critical reactions during the auto-ignition process vary with the CH 3 OH mole fraction in the fuel. The ammonia chemistry, namely NH 2 + NO, NH2 + NO 2 and NH 2 + HO 2 , is dominant for the mixture with 1% CH 3 OH, while the reactions related to CH 3 OH and H 2 O 2 are more important for the 20% CH 3 OH mixture. The interaction between ammonia and methanol shows a more prominent effect on auto-ignition for mixtures with 5% CH 3 OH in fuel as compared to those with 1% and 20% CH 3 OH. According to the modeling results, methanol addition is found to enrich the O/H radical pool, consuming ammonia and promoting auto-ignition through different reaction pathways.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
High-Temperature, High-Pressure Optical Cells
Optical cell constructed for measurement of thermal diffusivity of HgCdTe semiconductor by laser pulses. Container allows radiation from laser to enter one side of alloy sample, while allowing lower-energy infrared radiation to leave opposite side of sample so temperature rise read by sensor. Composed entirely of fused silica, cell includes two optical windows joined by tube. Cell withstands 1,000 degrees C cell-operating temperature and contains molten alloy at its 100-atmosphere vapor pressure. Finally, allows alloy to solidify without bursting even though alloy expands on cooling.
Harris, R. P.↗
A computer program for full-coverage film-cooled blading analysis including the effects of a thermal barrier coating
The program input, coolant flow and heat transfer model, and the program output are discussed. As an example, sections of the suction and pressure sides of a high temperature, high pressure turbine vane are analyzed to show the effects of a thermal barrier coating. Compared to the uncoated design, the coating halves the required coolant flow, while simultaneously reducing metal outer temperatures by over 111 K.
Source record↗
Calcined Polyethyleneimine Coated Optical Fibers for Distributed pH Monitoring at High Pressures and Temperatures
In the oil and gas, CO2 sequestration, H2 subsurface storage, and geothermal energy sectors, subsurface pH measurements are critical for monitoring the geochemical conditions and estimating potential corrosion rates of wellbore systems. Real-time pH measurements in these conditions are vital for detecting and predicting corrosion deterioration of wellbore components that may jeopardize the safety and continued operation of wellbore systems. Building off of earlier TiO2 based pH sensors and the known pH sensitivity of amine-based polymers, a coating based on the secondary amine polymer polyethyleneimine (PEI) was developed. The sensor coating was treated with a high temperature (500 °C) calcination procedure in air to convert it into a more stable oxidized coating capable of withstanding hot aqueous solutions without dissolving while retaining linear pH sensitivity from pH values between 2 and 11. The sensor performance was measured using optical transmission measurements in solutions of various pHs and using optical backscatter reflectometry for distributed pH sensing demonstration in wellbore-relevant pressures (up to 1000 psi) and temperatures (80 °C). A calibration curve with strong differentiation between acidic and alkaline pH was developed for both transmission-based and distributed pH measurements, using fixed wavelength transmission and integrated linear amplitude of backscattered light for distributed measurements.
Shumski, Alexander↗
High-temperature, high-pressure optical port for rocket engine applications
This paper discusses the design, fabrication, and test of a window assembly for instrumentation of liquid-fueled rocket engine hot gas systems. The window was designed to allow optical measurements of hot gas in the SSME fuel preburner and appears to be the first window designed for application in a rocket engine hot gas system. Such a window could allow the use of a number of remote optical measurement technologies including: Raman temperature and species concentration measurement, Raleigh temperature measurements, flame emission monitoring, flow mapping, laser-induced florescence, and hardware imaging during engine operation. The window assembly has been successfully tested to 8,000 psi at 1000 F and over 11,000 psi at room temperature. A computer stress analysis shows the window will withstand high temperature and cryogenic thermal shock.
Delcher, Ray↗
Physics-based Creep Simulations of Thick Section Welds in High Temperature and Pressure Applications
A physics-based model of creep in thick section welds has been developed. This presentation reviews the highlights for the last year of the project and issues related to the calibration of the model. Knowledge of the physics occurring in the transition to tertiary creep is lacking and preventing a full simulation of creep to failure from being performed.
36 MATERIALS SCIENCE↗
A high-pressure, high-temperature combustor and turbine-cooling test facility
NASA-Lewis Research Center is presently constructing a new test facility for developing turbine-cooling and combustor technology for future generation aircraft gas turbine engines. Prototype engine hardware will be investigated in this new facility at gas stream conditions up to 2480 K average turbine inlet temperature and 4,140,000 N per sq m turbine inlet pressure. The facility will have the unique feature of fully-automated control and data acquisition through the use of an integrated system of minicomputers and programmable controllers, which will result in more effective use of operating time, will limit the number of operators required, and will provide a built-in self-protection safety system. The paper describes the facility and the planning and design considerations involved.
Cochran, R. P.↗
Topological electride phase of sodium at high pressures and temperatures
Sodium, a textbook example of a nearly-free-electron metal, exhibits unforeseen pressure-induced behavior including the stabilization of numerous polymorphs—some possessing extremely complex unit cells—as well as a metal-to-insulator transition to the iconic hP4 phase. However, until recently, most of the experimental and theoretical studies on solid sodium have been restricted to the low-temperature regime. In this work, using ab initio evolutionary structure searches coupled with quasiharmonic calculations, we discover seven new phases of sodium that are more stable than the known hP4 phase at pressure-temperature conditions that were recently attained in ramp-compression experiments. From these, our calculations suggest that P6 3 /m Na is the ground state between ≈250 GPa at 710 K and ≈350 GPa at 1900 K. Electronic structure calculations show that this phase is a topological semimetal with a Dirac nodal surface that is protected by a nonsymmorphic symmetry S 2z and an electride owing to its non-nuclear charge localized within one-dimensional honeycomb channels and zero-dimensional cages. Our results highlight the complexity of dense sodium's free-energy landscape and intricate electronic structure that emerges at finite temperatures and conditions where ionic cores overlap.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Evidence for superionic H 2 O and diffusive He–H 2 O at high temperature and high pressure
In this work, we present the evidence of superionic phase formed in H 2 O and, for the first time, diffusive H 2 O–He phase, based on time-resolved x-ray diffraction experiments performed on ramp-laser-heated samples in diamond anvil cells. The diffraction results signify a similar bcc-like structure of superionic H 2 O and diffusive He–H 2 O, while following different transition dynamics. Based on time and temperature evolution of the lattice parameter, the superionic H 2 O phase forms gradually in pure H 2 O over the temperature range of 1350–1400 K at 23 GPa, but the diffusive He–H 2 O phase forms abruptly at 1300 K at 26 GPa. We suggest that the faster dynamics and lower transition temperature in He–H 2 O are due to a larger diffusion coefficient of interstitial-filled He than that of more strongly bound H atoms. This conjecture is then consistent with He disordered diffusive phase predicted at lower temperatures, rather than H-disordered superionic phase in He–H 2 O.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗