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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2013

MAGNETIC HELICITY IN THE DISSIPATION RANGE OF STRONG IMBALANCED TURBULENCE

Hybrid numerical simulations of freely decaying two-dimensional turbulence are presented. The background magnetic field is perpendicular to the simulation plane, which eliminates linear kinetic Alfven waves from the system. The net magnetic helicity of the initial fluctuations at large scales is zero. The turbulence is set to be imbalanced in the sense that the net cross-helicity is not zero. As the turbulence evolves, it develops nonzero magnetic helicity at smaller scales, in the proton kinetic range. In the quasi-steady state of evolution, the magnetic helicity spectrum has a peak consistent with the solar wind observations. The peak position depends on the plasma beta and correlates with a sharp decline of the cross-helicity spectrum.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

FIRST SYNOPTIC MAPS OF PHOTOSPHERIC VECTOR MAGNETIC FIELD FROM SOLIS/VSM: NON-RADIAL MAGNETIC FIELDS AND HEMISPHERIC PATTERN OF HELICITY

We use daily full-disk vector magnetograms from Vector Spectromagnetograph on Synoptic Optical Long-term Investigations of the Sun system to synthesize the first Carrington maps of the photospheric vector magnetic field. We describe these maps and make a comparison of the observed radial field with the radial field estimate from line-of-sight magnetograms. Furthermore, we employ these maps to study the hemispheric pattern of current helicity density, H{sub c} , during the rising phase of solar cycle 24. The longitudinal average over the 23 consecutive solar rotations shows a clear signature of the hemispheric helicity rule, i.e., H{sub c} is predominantly negative in the north and positive in the south. Although our data include the early phase of cycle 24, there appears to be no evidence for a possible (systematic) reversal of the hemispheric helicity rule at the beginning of the cycle as predicted by some dynamo models. Furthermore, we compute the hemispheric pattern in active region latitudes (-30 Degree-Sign {<=} {theta} {<=} 30 Degree-Sign ) separately for weak (100 G < |B{sub r} | < 500 G) and strong (|B{sub r} | > 1000 G) radial magnetic fields. We find that while the current helicity of strong fields follows the well-known hemispheric rule (i.e., {theta} {center_dot} H{sub c} < 0), H{sub c} of weak fields exhibits an inverse hemispheric behavior (i.e., {theta} {center_dot} H{sub c} > 0), albeit with large statistical scatter. We discuss two plausible scenarios to explain the opposite hemispheric trend of helicity in weak and strong field regions.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

EFFECTS OF THE NON-RADIAL MAGNETIC FIELD ON MEASURING MAGNETIC HELICITY TRANSPORT ACROSS THE SOLAR PHOTOSPHERE

It is generally believed that the evolution of magnetic helicity has a close relationship with solar activity. Before the launch of the Solar Dynamics Observatory (SDO), earlier studies had mostly used Michelson Doppler Imager/SOHO line of sight (LOS) magnetograms and assumed that magnetic fields are radial when calculating the magnetic helicity injection rate from photospheric magnetograms. However, this assumption is not necessarily true. Here we use the vector magnetograms and LOS magnetograms, both taken by the Helioseismic and Magnetic Imager on SDO, to estimate the effects of the non-radial magnetic field on measuring the magnetic helicity injection rate. We find that: (1) the effect of the non-radial magnetic field on estimating tangential velocity is relatively small; (2) when estimating the magnetic helicity injection rate, the effect of the non-radial magnetic field is strong when active regions are observed near the limb and is relatively weak when active regions are close to disk center; and (3) the effect of the non-radial magnetic field becomes minor if the amount of accumulated magnetic helicity is the only concern.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

Lepton asymmetries and primordial hypermagnetic helicity evolution

The hypermagnetic helicity density at the electroweak phase transition (EWPT) exceeds many orders of magnitude the galactic magnetic helicity density. Together with previous magnetic helicity evolution calculations after the EWPT and hypermagnetic helicity conversion to the magnetic one at the EWPT, the present calculation completes the description of the evolution of this important topological feature of cosmological magnetic fields. It suggests that if the magnetic field seeding the galactic dynamo has a primordial origin, it should be substantially helical. This should be taken into account in scenarios of galactic magnetic field evolution with a cosmological seed.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

CMB anisotropies generated by a stochastic background of primordial magnetic fields with non-zero helicity

We consider the impact of a stochastic background of primordial magnetic fields with non-vanishing helicity on CMB anisotropies in temperature and polarization. We compute the exact expressions for the scalar, vector and tensor part of the energy-momentum tensor including the helical contribution, by assuming a power-law dependence for the spectra and a comoving cutoff which mimics the damping due to viscosity. We also compute the parity-odd correlator between the helical and non-helical contribution which generate the TB and EB cross-correlation in the CMB pattern. We finally show the impact of including the helical term on the power spectra of CMB anisotropies up to multipoles with ℓ ∼ O(10{sup 3})

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Reduced bispectrum seeded by helical primordial magnetic fields

In this paper, we investigate the effects of helical primordial magnetic fields (PMFs) on the cosmic microwave background (CMB) reduced bispectrum. We derive the full three-point statistics of helical magnetic fields and numerically calculate the even contribution in the collinear configuration. We then numerically compute the CMB reduced bispectrum induced by passive and compensated PMF modes on large angular scales. There is a negative signal on the bispectrum due to the helical terms of the fields and we also observe that the biggest contribution to the bispectrum comes from the non-zero IR cut-off for causal fields, unlike the two-point correlation case. For negative spectral indices, the reduced bispectrum is enhanced by the passive modes. This gives a lower value of the upper limit for the mean amplitude of the magnetic field on a given characteristic scale. However, high values of IR cut-off in the bispectrum, and the helical terms of the magnetic field relaxes this bound. This demonstrates the importance of the IR cut-off and helicity in the study of the nature of PMFs from CMB observations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

Evaluation of CFD Methods for Simulation of Two-Phase Boiling Flow Phenomena in a Helical Coil Steam Generator

The U.S. Department of Energy, Office of Nuclear Energy charges participants in the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program with the development of advanced modeling and simulation capabilities that can be used to address design, performance and safety challenges in the development and deployment of advanced reactor technology. The NEAMS has established a high impact problem (HIP) team to demonstrate the applicability of these tools to identification and mitigation of sources of steam generator flow induced vibration (SGFIV). The SGFIV HIP team is working to evaluate vibration sources in an advanced helical coil steam generator using computational fluid dynamics (CFD) simulations of the turbulent primary coolant flow over the outside of the tubes and CFD simulations of the turbulent multiphase boiling secondary coolant flow inside the tubes integrated with high resolution finite element method assessments of the tubes and their associated structural supports. This report summarizes the demonstration of a methodology for the multiphase boiling flow analysis inside the helical coil steam generator tube. A helical coil steam generator configuration has been defined based on the experiments completed by Polytecnico di Milano in the SIET helical coil steam generator tube facility. Simulations of the defined problem have been completed using the Eulerian-Eulerian multi-fluid modeling capabilities of the commercial CFD code STAR-CCM+. Simulations suggest that the two phases will quickly stratify in the slightly inclined pipe of the helical coil steam generator. These results have been successfully benchmarked against both empirical correlations for pressure drop and simulations using an alternate CFD methodology, the dispersed phase mixture modeling capabilities of the open source CFD code Nek5000.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2016

RELATIONSHIPS BETWEEN FLUID VORTICITY, KINETIC HELICITY, AND MAGNETIC FIELD ON SMALL-SCALES (QUIET-NETWORK) ON THE SUN

We derive horizontal fluid motions on the solar surface over large areas covering the quiet-Sun magnetic network from local correlation tracking of convective granules imaged in continuum intensity and Doppler velocity by the Helioseismic and Magnetic Imager (HMI) on board the Solar Dynamics Observatory . From these we calculate the horizontal divergence, the vertical component of vorticity, and the kinetic helicity of fluid motions. We study the correlations between fluid divergence and vorticity, and between vorticity (kinetic helicity) and the magnetic field. We find that the vorticity (kinetic helicity) around small-scale fields exhibits a hemispherical pattern (in sign) similar to that followed by the magnetic helicity of large-scale active regions (containing sunspots). We identify this pattern to be a result of the Coriolis force acting on supergranular-scale flows (both the outflows and inflows), consistent with earlier studies using local helioseismology. Furthermore, we show that the magnetic fields cause transfer of vorticity from supergranular inflow regions to outflow regions, and that they tend to suppress the vortical motions around them when magnetic flux densities exceed about 300 G (from HMI). We also show that such an action of the magnetic fields leads to marked changes in the correlations between fluid divergence and vorticity. These results are speculated to be of importance to local dynamo action (if present) and to the dynamical evolution of magnetic helicity at the small-scale.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Two-scale Analysis of Solar Magnetic Helicity

We develop a two-scale formalism to determine global magnetic helicity spectra in systems where the local magnetic helicity has opposite signs on both sides of the equator, giving rise to cancellation with conventional methods. We verify this approach using first a synthetic one-dimensional magnetic field and then two-dimensional slices from a three-dimensional α effect-type dynamo-generated magnetic field, with forced turbulence of opposite helicity above and below the midplane of the domain. We then apply this formalism to global solar synoptic vector magnetograms. To improve the statistics, data from three consecutive Carrington rotations (2161–2163) are combined into a single map. We find that the spectral magnetic helicity representative of the northern hemisphere is negative at all wavenumbers and peaks at ≈0.06 Mm{sup −1} (scales around 100 Mm). There is no evidence of bihelical magnetic fields that are found in three-dimensional turbulence simulations of helicity-driven α effect-type dynamos.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Laminar Flow Heat Transfer In Helical Oval-Twisted Tube for Heat Exchanger Applications

The heat transfer performance of a novel tube configuration that combines the swirling velocity induced by oval-twisting and secondary flow generated by a helical geometrical flow path is presented. The Nusselt number (Nu) and friction factor (f) are compared for the laminar flow regime (Re = 250- 2000) under isothermal wall conditions. Under the same flow and boundary conditions, the oval-twisted helical tube increased the Nu and slightly increased the f over the circular helical tube. The best performance with the highest Nuand lowest f occurs at the coil curvature ratio (d h /D) of 0.17. The quantified enhancement performance factor (h) shows a 46 - 56% increase for the oval-twisted helical tube over the circular helical tube with d h /D = 0.17. Correlations for the Nu and f are developed and agreed with the numerical results: ± 6% and ± 5% for the Nu and f, respectively.

42 ENGINEERING↗
DOE OSTI2026

Data‐Driven Engineering of Thermostable Collagen‐Mimetic Peptoid Triple Helices

Collagen-mimetic peptides (CMPs) are engineered molecules designed to replicate the triple-helical structure of natural collagen. A repeating x–y-Gly sequence is the defining motif of CMPs and is critical to their triple-helical structure and stability. Substitutions to the residues occupying the x and y positions present a means to modulate the CMP structure and properties. Peptoid residues—N-substituted glycine derivatives—present an attractive potential substitution due to their thermal stability, proteolytic resistance, biocompatibility, and diverse palette of non-natural side chains, but also tend to introduce a high degree of backbone flexibility that can diminish the stability of the triple helix. In this work, we report a computational active learning cycle comprising molecular dynamics simulation, Gaussian process regression, and Bayesian optimization to computationally identify a number of promising peptoid substitutions predicted to stabilize the desired quaternary structure through side chain interactions and produce stable peptoid-based collagen-like triple helices. To experimentally test the computational predictions, a top candidate identified by the screen was synthesized and imaged using scanning electron microscopy to resolve fibril-like bundles consistent with collagen-like triple helices. This work predicts a number of CMP peptoid substitutions capable of forming stable triple-helical structures, presents a generalizable design strategy for engineering desired peptoid structures, and opens new avenues for the design of peptoid-based biomimetic materials.

active learning↗
DOE OSTI2014

Two new helical compounds based on Keggin clusters and N-donor multidentate ligand: Syntheses, structures and properties

Two isostructural polyoxometalate-based inorganic–organic hybrids with 1D helical chain, [CuH{sub 3}L{sub 2}(GeMo{sub 12}O{sub 40})]·2H{sub 2}O (1) and [CuH{sub 3}L{sub 2}(SiMo{sub 12}O{sub 40})]·2H{sub 2}O (2), where L=2,4,5-tri(4-pyridyl)-imidazole have been synthesized under hydrothermal conditions. It is the first time to use the L ligand to synthesis the Keggin-type polyoxometalate-based inorganic–organic hybrids. The two compounds possess the left- and right-handed helical chains and the POMs as pendants attach in the helical chains through Cu–O bonds. The two compounds have been characterized by elemental analyses, infrared (IR) spectroscopy, powder X-ray diffraction (PXRD), X-ray photoelectron spectra (XPS), thermogravimetric analysis (TGA) and photoluminescent spectroscopy. Moreover, nitrogen adsorption−desorption measurement, electrochemical and photocatalysis properties for degradation of methylene blue (MB) upon a UV irradiation of compound 1 have been examined. - Graphical abstract: Two new compounds, [CuH{sub 3}L{sub 2}(GeMo{sub 12}O{sub 40})]·2H{sub 2}O (1) and [CuH{sub 3}L{sub 2}(SiMo{sub 12}O{sub 40})]·2H{sub 2}O (2) have been synthesized under hydrothermal conditions. The two compounds possess the left- and right-handed helical chains. - Highlights: • The tridentate L ligand is first used to synthesis Keggin-type polyoxometalates. • The two compounds possess the left- and right-handed Cu–L helical chains. • Relationship between surface properties and photocatalytic activity was studied. • Two compounds exhibit photoluminescence of ligand-to-metal charge transfer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Rational assembly of Pb(II)/Cd(II)/Mn(II) coordination polymers based on flexible V-shaped dicarboxylate ligand: Syntheses, helical structures and properties

Six new coordination polymers, namely, [Pb(L)(H{sub 2}O)] (1), [Pb(L)(phen)] (2), [Pb{sub 2}(L){sub 2}(4,4′-bipy){sub 0.5}] (3), [Cd(L)(phen)] (4), [Cd(L)(4,4′-bipy)]·H{sub 2}O (5) and [Mn(L)(4,4′-bipy)]·H{sub 2}O (6) have been synthesized by the hydrothermal reaction of 2,2′-[hexafluoroisopropylidenebis(p-phenyleneoxy)]diacetic acid (H{sub 2}L) with Pb(II)/Cd(II)/Mn(II) in the presence of ancillary ligands 4,4′-bipyridine (4,4′-bipy) or 1,10-phenanthroline (phen). Complexes 1 and 4–6 exhibit 2-D structures, and complexes 2–3 display 3-D frameworks, of which L{sup 2−} ligands join metal ions to single-stranded helical chains of 1, 3–6 and double-stranded helical chains of 2. Complexes 2 and 3 also contain double-stranded Metal–O helices. Topology analysis reveals that complexes 1 and 4 both represent 4-connected sql net, 2 represents 6-connected pcu net, 3 exhibits a novel (3,12)-connected net, while 5 and 6 display (3,5)-connected gek1 net. The six complexes exhibit two kinds of inorganic–organic connectivities: I{sup 0}O{sup 2} for 1, 4–6, and I{sup 1}O{sup 2} for 2–3. The photoluminescent properties of 4–5 and the magnetic properties of 6 have been investigated. - Graphical abstract: Six new Pb(II)/Cd(II)/Mn(II) coordination polymers with helical structures based on flexible V-shaped dicarboxylate ligand have been synthesized and structurally characterized. Photoluminescent and magnetic properties have been investigated. - Highlights: • Six novel M(II) coordination polymers with 2,2′-[hexafluoroisopropylidenebis(p-phenyleneoxy)]diacetic acid and N-donor ligands. • Complexes 1–6 show diverse intriguing helical characters. • The luminescent properties of complexes 1–5 were investigated. • Complex 6 shows antiferromagnetic coupling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Crystal structures and thermodynamics/kinetics of Zn(II) coordination polymers with helical chains

Solvothermal reactions of Zn(II) acetates and four V-shaped carboxylates ligands in the presence of 1,4-Bis(2-methyl-imidazol-1-yl)butane afforded four interesting Zn(II) coordination polymers with helical chains, namely, {[Zn(bib)(atibdc)]·2H_2O}{sub n} (1), {[Zn(bib)(atbip)]·H_2O}{sub n} (2), {[Zn(bib)(2,2′-tda)]}{sub n} (3) and {[Zn(bib)(5-tbipa)]·EtOH}{sub n} (4), (H{sub 2}atibdc=5-amino-2,4,6-triiodoisophthalic acid, H{sub 2}atbip=5-amino-2,4,6-tribromoisophthalic acid, 2,2′-H{sub 2}tad=2,2′-thiodiacetic acid, 5-H{sub 2}tbipa=5-tert-butyl-isophthalic acid). 1 reveals a 3D chiral framework with three kinds of helical chains along a, b and c axis. 2 shows a 2D step-type chiral framework with right-handed helical chains. 3 displays a wavelike 2D layer network possessing alternate left- and right-handed helical chains. 4 presents a four-connected 3D framework with zigzag and meso-helical chains. The different spacers and substituent group of carboxylic acid ligands may lead to the diverse network structures of 1–4. The fluorescent properties of complexes 1−4 were studied. In addition, the thermal decompositions properties of 1–4 were investigated by simultaneous TG/DTG–DSC technique. The apparent activation energy E and the pre-exponential factor (A) of skeleton collapse for the complexes 1–4 are calculated by the integral Kissinger's method and Ozawa–Doyle's method. The activation energy E (E{sub 1}=209.658 kJ·mol{sup −1}, E{sub 2}=250.037 kJ mol{sup −1}, E{sub 3}=225.300 kJ mol{sup −1}, E{sub 4}=186.529 kJ·mol{sup −1}) demonstrates that the reaction rate of the melting decomposition is slow. The thermodynamic parameters (ΔH{sup ‡}, ΔG{sup ‡} and ΔS{sup ‡}) at the peak temperatures of the DTG curves were also calculated. ΔG{sup ‡}>0 indicates that the skeleton collapse is not spontaneous. ΔH{sub d}>0 suggests that the skeleton collapse is endothermic, corresponding to the intense endothermic peak of the DSC curve. The structural stability could be illustrated from the point of thermodynamics and kinetics. - Graphical abstract: Four new zinc coordination architectures constructed from the primary ligand bib, transition metal ions Zn(II) and four V-shaped carboxylate coligands. The different structural evolutions of complexes 1–4 have systematically illustrated that the carboxylate coligands play a critical role in the assemblies of the CPs. Their thermal decompositions properties of 1–4 were investigated by simultaneous TG/DTG–DSC technique. The apparent activation energy E and the pre-exponential factor (A) of skeleton collapse for the complexes 1−4 are calculated by the integral Kissinger’s method and Ozawa–Doyle’s method. The structural stability could be illustrated from the point of thermodynamics and kinetics. Display Omitted.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

A comparison of helical and spur external gear machines for fluid power applications: Design and optimization

In this paper we address the problem of determining the relative performance of spur and helical external gear pumps (EGPs) for fluid power applications. Helical EGPs are commonly considered as quieter units than spur ones; however, there is no specific study reported in literature that proves such claim. Similarly, it is hard to find data indicating which design is better in terms of compactness or energy performance. To tackle this problem, a procedure is developed for virtual design optimization of both helical and spur gear EGPs. This includes addressing the two fundamental challenges of the work, parameterizing a generic EGP design and quantifying its performance. By applying this procedure, a genetic algorithm can continue improving from generation to generation, until the pareto optimal set of designs is identified for both helical and spur units. In the comparison of these, the differences between the two configurations will be identified and the fundamental question of this work can be answered; are helical gears ‘better’ than spur gears?

42 ENGINEERING↗
DOE OSTI2018

Helically symmetric extended magnetohydrodynamics: Hamiltonian formulation and equilibrium variational principles

Hamiltonian extended magnetohydrodynamics (XMHD) is restricted to respect helical symmetry by reducing the Poisson bracket for the three-dimensional dynamics to a helically symmetric one, as an extension of the previous study for translationally symmetric XMHD (Kaltsas et al. , Phys. Plasmas , vol. 24, 2017, 092504). Four families of Casimir invariants are obtained directly from the symmetric Poisson bracket and they are used to construct Energy–Casimir variational principles for deriving generalized XMHD equilibrium equations with arbitrary macroscopic flows. The system is then cast into the form of Grad–Shafranov–Bernoulli equilibrium equations. The axisymmetric and the translationally symmetric formulations can be retrieved as geometric reductions of the helically symmetric one. As special cases, the derivation of the corresponding equilibrium equations for incompressible plasmas is discussed and the helically symmetric equilibrium equations for the Hall MHD system are obtained upon neglecting electron inertia. An example of an incompressible double-Beltrami equilibrium is presented in connection with a magnetic configuration having non-planar helical magnetic axis.

Physics↗
DOE OSTI2018

Impact of Helical Chain Shape in Sequence-Defined Polymers on Polypeptoid Block Copolymer Self-Assembly

Controlling the self-assembly of block copolymers with variable chain shape and stiffness is important for driving the self-assembly of functional materials containing nonideal chains as well as for developing materials with new mesostructures and unique thermodynamic interactions. The polymer helix is a particularly important functional motif. In the helical chain, the traditional scaling relationships between local chain stiffness and space-filling properties are not applicable; this in turn impacts the scaling relationships critical for governing self-assembly. Polypeptoids, a class of sequence-defined peptidomimetic polymers with controlled helical secondary structure, were used to systematically investigate the impact of helical chain shape on block copolymer self-assembly in a series of poly(n-butyl acrylate)-b-polypeptoid block copolymers. Small-angle X-ray scattering (SAXS) of the bulk materials shows that block copolymers form hexagonally packed cylinder domains. By leveraging sequence control, the polypeptoid block was controlled to form a helix only at the part either adjacent to or distant from the block junction. Differences in domain size from SAXS reveal that chain stretching of the helix near the block junction is disfavored, while helical segments at the center of cylindrical domains contribute to unfavorable packing interactions, increasing domain size. Finally, temperature-dependent SAXS shows that helix-containing diblock copolymers disorder at lower temperatures than the equivalent unstructured diblock copolymers; we attribute this to the smaller effective N of the helical structure resulting in a larger entropic gain upon disordering. These results emphasize how current descriptions of rod/coil interactions and conformational asymmetry for coil polymers do not adequately address the behavior of chain secondary structures, where the scalings of space-filling and stiff-elastic properties relative to chain stiffness deviate from those of typical coil, semiflexible, and rodlike polymers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Subtle Molecular Changes Largely Modulate Chiral Helical Assemblies of Achiral Conjugated Polymers by Tuning Solution-State Aggregation

Understanding the solution-state aggregate structure and the consequent hierarchical assembly of conjugated polymers is crucial for controlling multiscale morphologies during solid thin-film deposition and the resultant electronic properties. However, it remains challenging to comprehend detailed solution aggregate structures of conjugated polymers, let alone their chiral assembly due to the complex aggregation behavior. Herein, we present solution-state aggregate structures and their impact on hierarchical chiral helical assembly using an achiral diketopyrrolopyrrole-quaterthiophene (DPP-T4) copolymer and its two close structural analogues wherein the bithiophene is functionalized with methyl groups (DPP-T2M2) or fluorine atoms (DPP-T2F2). Combining in-depth small-angle X-ray scattering analysis with various microscopic solution imaging techniques, we find distinct aggregate in each DPP solution: (i) semicrystalline 1D fiber aggregates of DPP-T2F2 with a strongly bound internal structure, (ii) semicrystalline 1D fiber aggregates of DPP-T2M2 with a weakly bound internal structure, and (iii) highly crystalline 2D sheet aggregates of DPP-T4. These nanoscopic aggregates develop into lyotropic chiral helical liquid crystal (LC) mesophases at high solution concentrations. Intriguingly, the dimensionality of solution aggregates largely modulates hierarchical chiral helical pitches across nanoscopic to micrometer scales, with the more rigid 2D sheet aggregate of DPP-T4 creating much larger pitch length than the more flexible 1D fiber aggregates. Combining relatively small helical pitch with long-range order, the striped twist-bent mesophase of DPP-T2F2 composed of highly ordered, more rigid 1D fiber aggregate exhibits an anisotropic dissymmetry factor (g-factor) as high as 0.09. This study can be a prominent addition to our knowledge on a solution-state hierarchical assembly of conjugated polymers and, in particular, chiral helical assembly of achiral organic semiconductors that can catalyze an emerging field of chiral (opto)electronics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗