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At least 181 records · Page 10

Geochemical confirmation of the lunar magmasphere hypothesis

The lunar magmasphere (or magma ocean) hypothesis was originally conceived to account for the enrichment of cumulus plagioclase (Al and Ca) in the main (highlands) portion of the crust. The great age of the highlands, and the complementary pattern of Eu anomalies between the highlands and the younger mare basalts, helped convince most specialists that the magmasphere hypothesis is correct. Doubts persist, however, particularly among physicists concerned about heat sources. It was shown in 1976 that a plot of Na/Ca vs. Mg/Fe for pristine highlands cumulates manifests a profound bimodality: One group, the Mg-rich rocks, plots along a normal igneous trend of inverse correlation between Na/Ca and Mg/Fe; the other group, the ferroan anorthosites (FAN), features low Na/Ca and low Mg/Fe. Only the FAN group can be plausibly linked to plag. flotation over the magmasphere.

Warren, P. H.↗

Geochemical constraints on magma processes in a peralkaline system - The Paisano volcano, west Texas

Petrographic and trace element data from a continuous stratigraphic sequence of flows from the peralkaline Paisano Volcano in west Texas are used to delineate magnetic processes responsible for the chemical evolution of this volcano. It is shown that crystal fractionation of the phenocrystic assemblage explains the main compositional variation, but magma mixing of a less evolved melt composition also affected the chemical evolution of the volcano.

Mcdonough, W. F.↗

Geochemical characters and tectonic evolution of the Chitradurga schist belt: An Archaean suture (?) of the Dharwar Craton, India

The Chitradurga schist belt extending for about 450 km in a NS direction and 2-50 km across, is one of the most prominent Archean (2.6 b.y.) tectonic features of the Indian Precambrian terrain, comprising about 2 to 10 km thick sequence of volcano sedimentary rocks. The basal unit of this belt is composed of an orthoquartzite-carbonate facies, unlike many other contemporary greentone belts of the Gondwana land which begin with a basal mafic-ultramafic sequence. Eighty percent of the belt is made up of detrital and chemogenic sediments, their succession commencing with a poorly preserved quartz pebble basal conglomerate and current bedded quartzites which, in turn, rest on tonalitic gneisses, the latter having been further remobilized with along the schist belt. Deposition of current bedded matue arenites indicte the existence of platformal conditions near the shore line. Polymictic graywacke conglomerates, graywackes, shales, phyllites, carbonates, BIFs (oxide, carbonate and sulfide) BMF's (Banded Maganese Formations) and cherts thus constitute the main sedimentary rocks of the belt. The polymicitic conglomerates contain debris of rocks of older greenstone sequences, as well as an abundant measure of folded quartzites, BIF's and gneissic fragments which represent earlier orogenies.

Naqvi, S. M.↗

Use of satellite ocean color observations to refine understanding of global geochemical cycles

In October 1978, the first satellite-borne color sensor, the Coastal Zone Color Scanner (CZCS), was launched aboard Nimbus-7 with four visible and two infrared bands, permitting a sensitivity about 60 times that of the Landsat-1 multispectral scanner. The CZCS radiance data can be utilized to estimate ocean chlorophyll concentrations by detecting shifts in sea color, particularly in oceanic waters. The obtained data can be used in studies regarding problems of overfishing, and, in addition, in investigations concerning the consequences of man's accelerated extraction of nitrogen from the atmosphere and addition of carbon to the atmosphere. The satellite data base is considered along with a simulation analysis, and ships providing ground-truth chlorophyll measurements in the ocean.

Walsh, J. J.↗

Remote detection of soil geochemical anomalies from an aircraft platform - Examples from the Virginia Piedmont

The use of remote-sensing data on forest leaf flush to identify areas with anomalously high soil heavy-metal concentrations is demonstrated using airborne Thematic Mapper Simulator (TMS) leaf-area-index data obtained over two sites in Virginia in spring 1983 and 1984. Mean-reflectance differences, especially in the 760-900-nm and 630-690-nm bands, corresponding to delayed leaf flush are found to be good indicators of higher heavy-metal concentration. Airborne and ground-based canopy-temperature measurements are also shown to be significantly higher in high-heavy-metal areas than in control areas.

Bell, R.↗

Basalt depths in lunar basins using impact craters as stratigraphic probes: Evaluation of a method using orbital geochemical data

A rare look at the chemical composition of subsurface stratigraphy in lunar basins filled with mare basalt is possible at fresh impact craters. Mg/Al maps from orbital X-ray flourescence measurements of mare areas indicate chemical anomalies associated with materials ejected by large post-mare impacts. A method of constraining the wide-ranging estimates of mare basalt depths using the orbital MG/Al data is evaluated and the results are compared to those of investigators using different indirect methods. Chemical anomalies at impact craters within the maria indicate five locations where higher Mg/Al basalt compositions may have been excavated from beneath the surface layer. At eight other locations, low Mg/Al anomalies suggest that basin-floor material was ejected. In these two cases, the stratigraphic layers are interpreted to occur at depths less than the calculated maximum depth of excavation. In five other cases, there is no apparent chemical change between the crater and the surrounding mare surface. This suggests homogeneous basalt compositions that extend down to the depths sampled, i.e., no anorthositic material that might represent the basin floor was exposed.

Andre, C. G.↗

Disruption of the Mauna Loa magma system by the 1868 Hawaiian earthquake - Geochemical evidence

To test whether a catastrophic earthquake could affect an active magma system, mean abundances (adjusted for 'olivine control') of titanium, potassium, phosphorus, strontium, zirconium, and niobium of historic lavas erupted from Mauna Loa Volcano, Hawaii, after 1868 were analyzed and were found to decrease sharply relative to lavas erupted before 1868. This abrupt change in lava chemistry, accompanied by a halved lava-production rate for Mauna Loa after 1877, is interpreted to reflect the disruptive effects of a magnitude 7.5 earthquake in 1868. This interpretation represents a documentable case of changes in magmatic chemical variations initiated or accelerated by a major tectonic event.

Tilling, Robert I.↗

Changing styles of crustal growth in Southern Africa: Constraints from geochemical and Sr-Nd isotope studies in Archaean to Pan African terrains

Nd isotopic data was presented for southern Africa in support of episodic crustal growth. Over 50 percent of the continental crust there had formed before 2.5 Ga, and less than 10 percent was produced after about 1.0 Ga. The data imply a mean crustal age of about 2.4 Ga for southern Africa, and a higher rate of crustal growth than that derived from Australian shale data, particularly during the Proterozoic. Isotopic data from Damara metasediments imply that there is no need to invoke decoupling of the Rb-Sr and Sm-Nd systems in the continental crust.

Mcdermott, F.↗

Geochemical implications of the formation of the moon by a single giant impact

The origin of the moon by a single massive impact of a body slightly larger than Mars with the earth can explain the angular momentum, orbital characteristics and unique nature of the earth-moon system. The density and chemical differences between the earth and the moon are accounted for by deriving the moon from the mantle of the impactor. A cosmochemically plausible impactor can be formed in the region of the inner Solar System, lending support to the impact hypothesis.

Newsom, Horton E.↗

Geochemical evolution of Cenozoic-Cretaceous magmatism and its relation to tectonic setting, southwestern Idaho, U.S.A

The relationships between Cretaceous to Neogene magmatism and the tectonic setting of southwestern and central Idaho are evaluated. An overview of the tectonics and geology of the northwestern U.S. is presented. Major element, trace element, and Sr, Pb, and Nd isotopic data for the region are used to place constraints on magma source characteristics, the manner in which the magmatic sources evolved through time, and the nature of interactions among mantle and crustal domains in response to changing tectonic environment.

Norman, Marc D.↗

How life affects the geochemical cycle of carbon

Developing a quantitative understanding of the biogeochemical cycles of carbon as they have worked throughout Earth history on various time scales, how they have been affected by biological evolution, and how changes in the carbon content of ocean and atmosphere may have affected climate and the evolution of life are the goals of the research. Theoretical simulations were developed that can be tuned to reproduce such data as exist and, once tuned, can be used to predict properties that have not yet been observed. This is an ongoing process, in which models and results are refined as new data and interpretations become available and as understanding of the global system improves. Results of the research are described in several papers which were published or submitted for publication. These papers are summarized. Future research plans are presented.

Walker, James C. G.↗

Lunar meteorite Yamato-86032 - Mineralogical, petrological, and geochemical studies

Yamato-86032 is a shock-lithified anorthositic fragmental breccia. It consists mainly of highly feldspathic meta-breccias and meta-meltrocks and possibly contains a small contribution from mare lithologies, but there is no indication of a KREEP component. In many respects Y-86032 is similar to the previously described lunar meteorites Y-82192/3, but there are some notable differences. We have analyzed about 40 major and trace elements in bulk matrix, impact melt, and clast samples from two chips of Y-86032. The abundances of most lithophile and incompatible elements are lower in Y-86032 than in Y-82192 (which contains very low abundances compared to normal lunar highland rocks). The REE abundances are comparable to those of Y-82192. The elements Sc, Cr, Mn, Fe and Co have significantly lower abundances than in Y-82192, and the siderophile element pattern is also different. Since cosmic ray exposure data indicate pairing of Y-86032 with Y-82192/3, the source region for these meteorites on the moon must have been fairly heterogeneous.

Koeberl, Christian↗

Geochemical evidences for two chondritic-like cometary or asteroidal impacts before and at the K/T boundary

A number of geological and palaeontological evidences support multiple impacts of cometary showers within a short time (approximately 1-3 Ma) and their connection with mass extinctions. Observations include clustered crater ages, stratigraphic horizons of impact ejecta closely spaced in time, and evidence for stepwise mass extinctions spanning intervals of 1-3 Ma. For the K/T boundary, three candidates, Popigai, Manson, and Yucatan, have been proposed as impact craters. Two distinct strata at the K/T boundary in western North America have been interpreted as evidence for two sequential impacts. If multiple impacts occurred within a time span of about 1 Ma then multiple Ir enrichments should be observed. DSDP Hole 577B on the Shatsky Plateau in the northern Pacific at K/T time is the first site. Samples contain approximately greater than 97 percent CaCO3, which exhibit clear chemical signals associated with asteroidal/cometary impact. Ir, Fe, and Cr data are presented. From the Th-normalized data, two satellite peaks below the major peak at 78 cm and 81 cm of 577B-1-4 are clearly shown. The major Ir peak (K/T boundary) is at 72 cm. Fe and Cr, from C1-like impactor ejecta fallout, also show two peaks at the same positions. For hole 738C on the southern Kerguelen Plateau, Ir values reach a peak concentration of 18 ppb in the clay layer at 96.0-96.2 cm in section 20R-5, and gradually tail off. In the sample 115 cm above the boundary, Ir concentrations have still not reached background levels. From the Ir peak downward to the lowermost sample analyzed at 102 cm, the Ir concentration is still as high as 1.7 ppb. From the Th-normalized data, we observe a small Ir/Th peak at 100-101 cm. Though this peak is within the error margin, the trend is clear. Fe and Cr exhibit the same pattern. The third case is Hole 690C on the Queen Maud Ridge. Again, the Ir/Th plot indicates the strong possibility of satellite peaks at approximately 52 cm. The main peak is at 39-40 cm. For the Stevns Klint K/T boundary layers, the stratification of trace elements appears threefold with peak concentrations in sublayers A1, A3, and B2 for different element groups, including Ir. C1 ratios for many siderophile elements found in combined layers III and IV, corresponding to layers A, B, C, and D, strongly support the impact hypothesis. Also, multiple Ir anomalies in the K/T section at Lattengebirge, Bavarian Alps are reported. Recent works on Ni-rich spinels and Ir at the K/T boundaries clearly establish cometary/asteroidal impacts at the K/T boundary. Lastly, cometary showers can explain the enhanced Ir contents over approximately a 1 Ma interval in Gubbio shales.

Liu, Y.-G.↗

Consortium study of lunar meteorites Yamato-793169 and Asuka-881757: Geochemical evidence of mutual similarity, and dissimilarity versus other mare basalts

Compositions of bulk powders and separated minerals from two meteorites derived from the mare lava plains of the Earth's Moon, Yamato-793169 and Asuka-881757, indicate a remarkable degree of similarity to one another, and clearly favor lunar origin. However, these meteorites are unlike any previously studied lunar rock. In both cases, the bulk-rock TiO2 content is slightly greater than the level separating VLT from low-Ti mare basalt, yet the Sc content is much higher than previously observed except among high-Ti mare basalts. Conceivably, the Sc enrichment in A881757 reflects origin of this rock as a cumulate from a mare magma of 'normal' Sc content, but this seems unlikely. Mineral-separate data suggest that most of the Sc is in pyroxene, and a variety of evidence weighs against the cumulus hypothesis as a major cause for the high Sc. The remarkable similarity between Y793169 and A881757 suggests the possibility that they were derived from a single source crater on the Moon.

Warren, Paul H.↗

A Simulated Geochemical Rover Mission to the Taurus-Littrow Valley of the Moon

We test the effectiveness of using an alpha backscatter, alpha-proton, X ray spectrometer on a remotely operated rover to analyze soils and provide geologically useful information about the Moon during a simulated mission to a hypothetical site resembling the Apollo 17 landing site. On the mission, 100 soil samples are "analyzed" for major elements at moderate analytical precision (e.g., typical relative sample standard deviation from counting statistics: Si[11%], Al[18%], Fe[6%], Mg[20%], Ca[5%]). Simulated compositions of soils are generated by combining compositions of components representing the major lithologies occurring at the site in known proportions. Simulated analyses are generated by degrading the simulated compositions according to the expected analytical precision of the analyzer. Compositions obtained from the simulated analyses are modeled by least squares mass balance as mixtures of the components, and the relative proportions of those components as predicted by the model are compared with the actual proportions used to generate the simulated composition. Boundary conditions of the modeling exercise are that all important lithologic components of the regolith are known and are represented by model components, and that the compositions of these components are well known. The effect of having the capability of determining one incompatible element at moderate precision (25%) is compared with the effect of the lack of this capability. We discuss likely limitations and ambiguities that would be encountered, but conclude that much of our knowledge about the Apollo 17 site (based on the return samples) regarding the distribution and relative abundances of lithologies in the regolith could be obtained. This success requires, however, that at least one incompatible element be determined.

Korotev, Randy L.↗

Geochemical Comparison of Four Cores from the Manson Impact Structure

Concentrations of 33 elements were determined in relatively unaltered, matrix-rich samples of impact breccia at approximately 3-m-depth intervals in the M-1 core from the Manson impact structure, Iowa. In addition, 46 matrix-rich samples from visibly altered regions of the M-7, M-8, and M-10 cores were studied, along with 42 small clasts from all four cores. Major element compositions were determined for a subset of impact breccias from the M-1 core, including matrix-rich impact-melt breccia. Major- and trace-element compositions were also determined for a suite of likely target rocks. In the M-1 core, different breccia units identified from lithologic examination of cores are compositionally distinct. There is a sharp compositional discontinuity at the boundary between the Keweenawan-shale-clast breccia and the underlying unit of impact-melt breccia (IMB) for most elements, suggesting minimal physical mixing between the two units during emplacement. Samples from the 40-m-thick IMB (M-1) are all similar to each other in composition, although there are slight increases in concentration with depth for those elements that have high concentrations in the underlying fragmental-matrix suevite breccia (SB) (e.g., Na, Ca, Fe, Sc), presumably as a result of greater clast proportions at the bottom margin of the unit of impact-melt breccia. The high degree of compositional similarity we observe in the impact-melt breccias supports the interpretation that the matrix of this unit represents impact melt. That our analyses show such compositional similarity results in part from our technique for sampling these breccias: for each sample we analyzed a few small fragments (total mass: approximately 200 mg) selected to be relatively free of large clasts and visible signs of alteration instead of subsamples of powders prepared from a large mass of breccia. The mean composition of the matrix-rich part of impact-melt breccia from the M-1 core can be modeled as a mixture of approximately 35% shale and siltstone (Proterozoic "Red Clastics"), 23% granite, 40% hornblende-biotite gneiss, and a small component (less than 2%) of mafic-dike rocks.

Korotev, Randy L.↗

Investigation of Isotopic and Geochemical Evidence for an Active Planktonic Biota in the Precambrian

The funded research was motivated by the earlier study of Burdett et al. (1990), who collected carbon and oxygen isotopic data from Paleoproterozoic rocks of the Northwest Territories from deep-and shallow-water facies of the Rocknest Platform. Their results displayed a possible decrease in (delta)C-13 with depth when arranged by increasing distance from the paleoshore. The most C-13-depleted samples were seafloor cements and fans from the underlying siliciclastic Odjick Formation, and slope carbonates of the Rocknest platform.

Kump, Lee R.↗