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At least 181 records · Page 10

Evaporation kinetics in the hanging drop method of protein crystal growth

An engineering analysis of the rate of evaporation of solvent in the hanging drop method of protein crystal growth is presented; these results are applied to 18 different drop and well arrangements commonly encountered in the laboratory, taking into account the chemical nature of the salt, the drop size and shape, the drop concentration, the well size, the well concentration, and the temperature. It is found that the rate of evaporation increases with temperature, drop size, and with the salt concentration difference between the drop and the well. The evaporation possesses no unique half-life. Once the salt in the drop achieves about 80 percent of its final concentration, further evaporation suffers from the law of diminishing returns.

Baird, James K.↗

Conduction-driven chromospheric evaporation in a solar flare

Observations of gentle chromospheric evaporation during the cooling phase of a solar flare are presented. Line profiles of the low-temperature (T of about 6 x 10 to the 6th K) coronal Mg XI line, observed with the X-Ray Polychromator on the Solar Maximum Mission, show a blueshift that persisted for several minutes after the impulsive heating phase. This result represents the first detection of an evaporation signature in a soft X-ray line formed at this low temperature. By combining the Mg XI blueshift velocity data with simultaneous measurements of the flare temperature derived from Ca XIX observations, it is demonstrated that the upward flux of enthalpy transported by this gently evaporating plasma varies linearly with the downward flux of thermal energy conducted from the corona. This relationship is consistent with models of solar flares in which thermal conduction drives chromospheric evaporation during the early part of the cooling phase.

Zarro, Dominic M.↗

Turbulence And Evaporation In Clusters Of Drops

Report presents theoretical model of evaporation of cluster of drops of single-component liquid fuel in and of processes of exchange between cluster and gas surrounding it. Formulation of model has three components: description of conservation of mass, molecular species, and enthalpy in sphere of influence of each drop; description of conservation of mass, molecular species, and enthalpy in cluster volume; description of convective effects by use of differential equations expressing conservation of momentum for gases and drops. Results obtained from analysis show turbulence enhances evaporation and controlling factor in evaporation of very dense clusters. Practical implication of findings evaporation of fuel controlled more readily near fuel injector than farther along combustor.

Bellan, Josette↗

Isotope mass fractionation during evaporation of Mg2SiO4

Synthetic forsterite (Mg2SiO4) was partially evaporated in vacuum for various durations and at different temperatures. The residual charges obtained when molten Mg2SiO4 was evaporated to 12 percent of its initial mass were enriched in heavy isotopes by about 20, 30, and 15 per mil/amu for O, Mg, and Si, respectively, whereas solid forsterite evaporated to a similar residual mass fraction showed negligible fractionations. These results imply that calcium and aluminum-rich refractory inclusions in carbonaceous chondrites must have been at least partially molten in the primordial solar nebula if the observed large mass fractionation effects were caused by evaporation processes in the nebula.

Davis, Andrew M.↗

Relationship of multispectral satellite data to land surface evaporation from the Australian continent

Based on NOAA-9 AVHRR and Nimbus-7 SMMR satellite data, satellite indices of vegetation from the Australian continent are calculated for the period of May 1986 to April 1987. Visible (VIS) and near infrared (NIR) reflectances and the normalized difference (ND) vegetation index are calculated from the AVHRR sensor. The microwave polarization difference (PD) is also calculated as the difference between the vertically and horizontally polarized brightness temperatures at 37 GHz. ND, PD, VIS, and NIR indices were plotted against rainfall and water balance estimates of evaporation. It is concluded that direct satellite monitoring of annual evaporation across the Australian continent using PD or VIS satellite indices of vegetation biomass appears possible for areas with evaporation less than 600 mm/y and that use of the ND relationship at continental scale may underpredict monthly evaporation of forests relative to agriculture.

Smith, R. C. G.↗

Supernova remnant evolution in an interstellar medium with evaporating clouds

A new similarity solution that describes the evolution of an SNR expanding into a cloudy interstellar medium is expounded. The solution incorporates a reasonable model of the conductive evaporation of cold clouds embedded in the hot gas behind the shock. The model has two new parameters in addition to those describing the usual Sedov solution for a uniform interstellar medium. The X-ray, infrared, and optical luminosities of remnants with evaporating clouds are calculated, and some of the expected spectral characteristics in the various wavebands are discussed. The effects described may explain the class of remnants observed to have centrally peaked X-ray emission and shell-like radio emission. The total H-alpha luminosity from evaporating clouds predicted by this model is less than that observed for SNRs with centrally peaked thermal X-ray emission. A detailed calculation of the X-ray and optical line emission from evaporating clouds would be very useful in testing this model against the observations.

White, Richard L.↗

Studies on droplet evaporation and combustion in high pressures

High pressure droplet evaporation and combustion have been studied up to 15 MPa under normal and microgravity fields. From the evaporation studies, it has been found that in the supercritical environments, the droplet evaporation rate and lifetime take a maximum and a minimum at an ambient pressure over the critical pressure. Its maximum and minimum points move toward the lower ambient pressures if the ambient temperature is increased. It has been found from the combustion studies that the burning life time takes a minimum at an ambient pressure being equal to the critical pressure. It is attributable to both the pressure dependency of the diffusion rate and the droplet evaporation characteristics described above.

Sato, J.↗

A model of the evaporation of binary-fuel clusters of drops

A formulation has been developed to describe the evaporation of dense or dilute clusters of binary-fuel drops. The binary fuel is assumed to be made of a solute and a solvent whose volatility is much lower than that of the solute. Convective flow effects, inducing a circulatory motion inside the drops, are taken into account, as well as turbulence external to the cluster volume. Results obtained with this model show that, similar to the conclusions for single isolated drops, the evaporation of the volatile is controlled by liquid mass diffusion when the cluster is dilute. In contrast, when the cluster is dense, the evaporation of the volatile is controlled by surface layer stripping, that is, by the regression rate of the drop, which is in fact controlled by the evaporation rate of the solvent. These conclusions are in agreement with existing experimental observations. Parametric studies show that these conclusions remain valid with changes in ambient temperature, initial slip velocity between drops and gas, initial drop size, initial cluster size, initial liquid mass fraction of the solute, and various combinations of solvent and solute. The implications of these results for computationally intensive combustor calculations are discussed.

Harstad, K.↗

Theoretical and Experimental Investigations on Droplet Evaporation and Droplet Ignition at High Pressures

The evaporation of fuel droplets under high ambient pressure and temperature in normal gravity and microgravity has been investigated experimentally. For subcritical ambient conditions, droplet evaporation after a heat-up period follows the d(exp 2)-law. For all data the evaporation constant increases as the ambient temperature increases. At identical ambient conditions the evaporation constant under microgravity is smaller compared to normal gravity. This effect can first be observed at 1 bar and increases with ambient pressure. Preliminary experiments on ignition delay for self-igniting fuel droplets have been performed. Above a 1 s delay time, at identical ambient conditions, significant differences in the results of the normal and microgravity data are observed. Self-ignition occurs within different temperature ranges due to the influence of gravity. The time dependent behavior of the droplet is examined theoretically. In the calculations two different approaches for the gas phase are applied. In the first approach the conditions at the interface are given using a quasi steady theory approximation. The second approach uses a set of time dependent governing equations for the gas phase which are then evaluated. In comparison, the second model shows a better agreement with the drop tower experiments. In both cases a time dependent gasification rate is observed.

Ristau, R.↗

Chromospheric evaporation and decimetric radio emission in solar flares

We have discovered decimetric signatures of the chromospheric evaporation process. Evidence for the radio detection of chromospheric evaporation is based on the radio-inferred values of (1) the electron density, (2) the propagation speed, and (3) the timing, which are found to be in good agreement with statistical values inferred from the blueshifted Ca XIX soft X-ray line. The physical basis of our model is that free-free absorption of plasma emission is strongly modified by the steep density gradient and the large temperature increase in the upflowing flare plasma. The steplike density increase at the chromospheric evaporation front causes a local discontinuity in the plasma frequency, manifested as almost infinite drift rate in decimetric type III bursts. The large temperature increase of the upflowing plasma considerably reduces the local free-free opacity (due to the T(exp -3/2) dependence) and thus enhances the brightness of radio bursts emitted at the local plasma frequency near the chromospheric evaporation front, while a high-frequency cutoff is expected in the high-density regions behind the front, which can be used to infer the velocity of the upflowing plasma. From model calculations we find strong evidence that decimetric bursts with a slowly drifting high-frequency cutoff are produced by fundamental plasma emission, contrary to the widespread belief that decimetric bursts are preferentially emitted at the harmonic plasma level. We analyze 21 flare episodes from 1991-1993 for which broadband (100-3000 MHz) radio dynamic spectra from Pheonix, hard X-ray data from (BATSE/CGRO) and soft X-ray data from Burst and Transient Source Experiment/Compton Gamma Ray Observatory (GOES) were available.

Aschwanden, Markus J.↗

Marangoni-Benard Convection in a Evaporating Liquid Thin Layer

Marangoni-Benard convection in evaporating liquid thin layers has been investigated through flow visualization and temperature profile measurement. Twelve liquids, namely ethyl alcohol, methanol, chloroform, acetone, cyclohexane, benzine, methylene chloride, carbon tetrachloride, ethyl acetate, n-pentane, silicone oil (0.65 cSt.), and freon-113, were tested and convection patterns in thin layers of these samples were observed. Comparison among these tested samples shows that some liquids are sensitive to surface contamination from aluminum powder but some are not. The latter is excellent to be used for the investigation of surface-tension driven convection through visualization using the tracer. Two sample liquids, alcohol and freon-113 were particularly selected for systematic study. It was found that the wavelength of Benard cells would not change with thickness of the layer when it evaporates at room temperature. Special attention was focused on cases in which a liquid layer was cooled from below, and some interesting results were obtained. Convection patterns were recorded during the evaporation process and the patterns at certain time frame were compared. Benard cells were observed in thin layers with a nonlinear temperature profile and even with a zero or positive temperature gradient. Wavelength of the cells was found to increase as the evaporation progressed.

Chai, An-Ti↗

Chromospheric Evaporation and Decimetric Radio Emission in Solar Flares

We have discovered decimetric signatures of the chromospheric evaporation process. Evidence for the radio detection of chromospheric evaporation is based on the radio-inferred values of (1) the electron density, (2) the propagation speed, and (3) the timing, which are found to be in good agreement with statistical values inferred from the blueshifted Ca xix soft X-ray line. The physical basis of our model is that free-free absorption of plasma emission is strongly modified by the steep density gradient and the large temperature increase in the upflowing flare plasma. The steplike density increase at the chromospheric evaporation front causes a local discontinuity in the plasma frequency, manifested as almost infinite drift rate in decimetric type III bursts. The large temperature increase of the upflowing plasma considerably reduces the local free-free opacity (due to the T-(exp -3/2) dependence) and thus enhances the brightness of radio bursts emitted at the local plasma frequency near the chromospheric evaporation front, while a high-frequency cutoff is expected in the high-density regions behind the front, which can be used to infer the velocity of the upflowing plasma. From model calculations we find strong evidence that decimetric bursts with a slowly drifting high-frequency cutoff are produced by fundamental plasma emission, contrary to the widespread belief that decimetric bursts are preferentially emitted at the harmonic plasma level. We analyzed 21 flare episodes from 1991-1993 for which broadband (100-3000 MHz) radio dynamic spectra from Phoenix, hard X-ray data from BATSE/CGRO, and soft X-ray data from GOES were available. We detected slowly drifting high-frequency cutoffs between 1.1 and 3.0 GHz, with drift rates of -41 +/- 32 MHz/s, extending over time intervals of 24 +/- 23 s. Developing a density model for type III-emitting flare loops based on the statistically observed drift rate of type III bursts by Alvarez & Haddock, we infer velocities of up to 360 km/s for the upflowing plasma, with an average of v(sub CE) = 236 +/- 130 km /s for episodes with 5-15 s duration. The mean electron density of the upflowing plasma is n(sub e) = 5.2(+/-3.1) x 10(exp 10) /cu cm when it is first detected in radio, at coronal altitudes of h(sub 0) = 9.2 +/- 2.3 Mm.

Aschwanden, Markus J.↗

Further Evaluation of an Emperical Equation for Annual Total Evaporation

An empirical equation for annual total evaporation based on annual precipitation and net radiation was found to provide evaporation within 10% of the observed values at seven locations within temperate and tropical regions, but it overestimated evaporation by 90% at one location within the tundra region. A synthesis of observations at two other locations within the tundra region gives overestimates of about 65%. A general analysis of observed precipitation, net radiation, and runoff within the tundra region shows that the empirical equation is generally biased to overestimate annual evaporation within the tundra region. A theoretical analysis is being done to understand the reason behind this bias.

Choudhury, Bhaskar J.↗

Fluid Flow in An Evaporating Droplet

Droplet evaporation is a common phenomenon in everyday life. For example, when a droplet of coffee or salt solution is dropped onto a surface and the droplet dries out, a ring of coffee or salt particles is left on the surface. This phenomenon exists not only in everyday life, but also in many practical industrial processes and scientific research and could also be used to assist in DNA sequence analysis, if the flow field in the droplet produced by the evaporation could be understood and predicted in detail. In order to measure the fluid flow in a droplet, small particles can be suspended into the fluid as tracers. From the ratio of gravitational force to Brownian force a(exp 4)(delta rho)(g)/k(sub B)T, we find that particle's tendency to settle is proportional to a(exp 4) (a is particle radius). So, to keep the particles from settling, the droplet size should be chosen to be in a range 0.1 -1.0 microns in experiments. For such small particles, the Brownian force will affect the motion of the particle preventing accurate measurement of the flow field. This problem could be overcome by using larger particles as tracers to measure fluid flow under microgravity since the gravitational acceleration g is then very small. For larger particles, Brownian force would hardly affect the motion of the particles. Therefore, accurate flow field could be determined from experiments in microgravity. In this paper, we will investigate the fluid flow in an evaporating droplet under normal gravity, and compare experiments to theories. Then, we will present our ideas about the experimental measurement of fluid flow in an evaporating droplet under microgravity.

Hu, H.↗

Evaporation Loss of Light Elements as a Function of Cooling Rate: Logarithmic Law

Knowledge about the evaporation loss of light elements is important to our understanding of chondrule formation processes. The evaporative loss of light elements (such as B and Li) as a function of cooling rate is of special interest because recent investigations of the distribution of Li, Be and B in meteoritic chondrules have revealed that Li varies by 25 times, and B and Be varies by about 10 times. Therefore, if we can extrapolate and interpolate with confidence the evaporation loss of B and Li (and other light elements such as K, Na) at a wide range of cooling rates of interest based upon limited experimental data, we would be able to assess the full range of scenarios relating to chondrule formation processes. Here, we propose that evaporation loss of light elements as a function of cooling rate should obey the logarithmic law.

Xiong, Yong-Liang↗

Evaporation Rates for Liquid Water and Ice Under Current Martian Conditions

A number of studies have been concerned with the evaporation rates under martian conditions in order to place limits on the possible survival time of both liquid water and ice exposed on the surface of Mars. Such studies also aid in assessing the efficacy of an overlying layer of dust or loose regolith material in providing a barrier to free evaporation and thus prolong the lifetime of water in locations where its availability to putative living organisms would be significant. A better quantitative understanding of the effects of phase changes of water in the near surface environment would also aid the evaluation of the possible role of water in the formation of currently observed features, such as gullies in cliff walls and relatively short-term changes in the albedo of small surface areas ('dark stains'). Laboratory measurements aimed at refinement of our knowledge of these values are described here. The establishment of accurate values for evaporation rates and their dependence on the physical conditions of temperature, pressure and energy input, is an important benchmark for the further investigation of the efficacy of barriers to free evaporation in providing a prolonged period of survival of the water, particularly as a liquid.

Sears, D. W. G.↗

Gravity Effects in Condensing and Evaporating Films

A general overview of gravity effects in condensing and evaporating films is presented. The topics include: 1) Research Overview; 2) NASA Recognizes Critical Need for Condensation & Evaporation Research to Enable Human Exploration of Space; 3) Condensation and Evaporation Research in Reduced Gravity is Enabling for AHST Technology Needs; 4) Differing Role of Surface Tension on Condensing/Evaporating Film Stability; 5) Fluid Mechanisms in Condensing and Evaporating Films in Reduced Gravity; 6) Research Plan; 7) Experimental Configurations for Condensing Films; 8) Laboratory Condensation Test Cell; 9) Aircraft Experiment; 10) Condensation Study Current Test Conditions; 11) Diagnostics; 12) Shadowgraph Images of Condensing n- pentane Film in Unstable (-1g) Configuration; 13) Condensing n-Pentane Film in Normal Gravity (-1g) at Constant Pressure; 14) Condensing n-Pentane Film in Normal Gravity (-1g) with Cyclic Pressure; 15) Non-condensing Pumped Film in Normal Gravity (-1g); 16) Heat Transfer Coefficient in Developing, Unstable Condensing Film in Normal Gravity; 17) Heat Transfer for Unsteady Condensing Film (-1g); 18) Ultrasound Measurement of Film Thickness N-pentane Film, Stable (+1g) Configuration; and 19) Ultrasound Measurement of Film Thickness N-pentane Film, Unstable (-1g) Configuration.

Hermanson, J. C.↗

Analysis of a Free Surface Film from a Controlled Liquid Impinging Jet over a Rotating Disk Including Conjugate Effects, with and without Evaporation

A detailed analysis of the liquid film characteristics and the accompanying heat transfer of a free surface controlled liquid impinging jet onto a rotating disk are presented. The computations were run on a two-dimensional axi-symmetric Eulerian mesh while the free surface was calculated with the volume of fluid method. Flow rates between 3 and 15 1pm with rotational speeds between 50 and 200 rpm are analyzed. The effects of inlet temperature on the film thickness and heat transfer are characterized as well as evaporative effects. The conjugate heating effect is modeled, and was found to effect the heat transfer results the most at both the inner and outer edges of the heated surface. The heat transfer was enhanced with both increasing flow rate and increasing rotational speeds. When evaporative effects were modeled, the evaporation was found to increase the heat transfer at the lower flow rates the most because of a fully developed thermal field that was achieved. The evaporative effects did not significantly enhance the heat transfer at the higher flow rates.

Sankaran, Subramanian↗