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Los Alamos National Laboratory 2022 Annual Site Environmental Report (Rev. 2)

Los Alamos National Laboratory (Laboratory) annual site environmental reports are prepared each year by the Laboratory’s environmental organizations as required by U.S. Department of Energy Order 231.1B, Administrative Change 1, Environment, Safety, and Health Reporting, and Order 458.1, Administrative Change 4, Radiation Protection of the Public and the Environment. The chapters in this report discuss our compliance with environmental laws, regulations, and orders (Chapter 2, Compliance Summary); how we manage the Laboratory’s environmental performance and assure the quality of data from analysis of environmental samples (Chapter 3, Environmental Programs and Analytical Data Quality); how we monitor for air emissions of radioactive materials and for weather conditions (Chapter 4, Air Quality); how we monitor for effects of Laboratory operations on groundwater quality (Chapter 5, Groundwater Protection); how we monitor the levels of chemicals and radionuclides in storm water runoff and sediment (Chapter 6, Watershed Quality); how we monitor for the levels and effects of chemicals and radionuclides in plants, animals, soil, and vegetation (Chapter 7, Ecosystem Health); and finally, what radioactive dose or risk from chemical exposure that members of the public could experience as a result of Laboratory operations (Chapter 8, Public Dose and Risk Assessment).

54 ENVIRONMENTAL SCIENCES↗

Subsurface redox potential and water level at the Elkhorn Slough NERR

This resource contains various hydrological, and geochemical data from Elkhorn Slough National Estuarine Research Reserve from the years 2020 and 2021. These data have been used to assess how continuous measurements of environmental variables. The data can be used to understand processes at timescales over which biochemical transformations can happen. Especially, the data were used to explain the local subsurface hydrology, and its implication, in an experimental transect in a coasta estuary. Water level and water temperature were measured in-situ with Solinst pressure transducer loggers (Ontario, Canada). Redox potential was collected using in-situ, redox sensors (Paleoterra, The Netherlands) connected to CR1000X Campbell data loggers (Logan, Utah). Meteorological data was gathered from the Elkhorn Slough meteorological station.

54 ENVIRONMENTAL SCIENCES↗

Ontology-Enriched Specifications Enabling Findable, Accessible, Interoperable, and Reusable Marine Metagenomic Datasets in Cyberinfrastructure Systems

Marine microbial ecology requires the systematic comparison of biogeochemical and sequence data to analyze environmental influences on the distribution and variability of microbial communities. With ever-increasing quantities of metagenomic data, there is a growing need to make datasets Findable, Accessible, Interoperable, and Reusable (FAIR) across diverse ecosystems. FAIR data is essential to developing analytical frameworks that integrate microbiological, genomic, ecological, oceanographic, and computational methods. Although community standards defining the minimal metadata required to accompany sequence data exist, they haven’t been consistently used across projects, precluding interoperability. Moreover, these data are not machine-actionable or discoverable by cyberinfrastructure systems. By making ‘omic and physicochemical datasets FAIR to machine systems, we can enable sequence data discovery and reuse based on machine-readable descriptions of environments or physicochemical gradients. In this work, we developed a novel technical specification for dataset encapsulation for the FAIR reuse of marine metagenomic and physicochemical datasets within cyberinfrastructure systems. This includes using Frictionless Data Packages enriched with terminology from environmental and life-science ontologies to annotate measured variables, their units, and the measurement devices used. This approach was implemented in Planet Microbe, a cyberinfrastructure platform and marine metagenomic web-portal. Here, we discuss the data properties built into the specification to make global ocean datasets FAIR within the Planet Microbe portal. We additionally discuss the selection of, and contributions to marine-science ontologies used within the specification. Finally, we use the system to discover data by which to answer various biological questions about environments, physicochemical gradients, and microbial communities in meta-analyses. This work represents a future direction in marine metagenomic research by proposing a specification for FAIR dataset encapsulation that, if adopted within cyberinfrastructure systems, would automate the discovery, exchange, and re-use of data needed to answer broader reaching questions than originally intended.

59 BASIC BIOLOGICAL SCIENCES↗

Environmental Testing of SolarSCADA's SSI Data Acquisition System

In April of 2022, SolarSCADA, Inc., was awarded voucher funding to conduct research and analysis at the National Renewable Energy Laboratory (NREL) per the American-Made Solar Prize. SolarSCADA produces a fully integrated data acquisition system that is designed specifically for PV fields and includes a data monitoring platform. SolarSCADA is focused providing the SSI unit with all sensors/measurements per requirements in IEC-61724-1 [1] and with utility scale bankability. The objective of the SolarSCADA voucher funding was established as follows: Leverage NREL's existing calibration and environmental testing capabilities to evaluate the stability of the SSI channels and overall systeme in response to extreme environmental conditions associated with fielded PV.

14 SOLAR ENERGY↗

Data and scripts associated with “Riverine dissolved organic matter transformations increase with watershed area, water residence time, and Damköhler numbers in nested watersheds” (v2)

This data package is associated with the publication “Riverine dissolved organic matter transformations increase with watershed area, water residence time, and Damköhler numbers in nested watersheds” submitted to Biogeochemistry by Ryan et al., 2024 (DOI: https://doi.org/10.1007/s10533-024-01169-5). This study aims to investigate fundamental and transferable drivers of dissolved organic matter (DOM) diversity across five nested watersheds within the contiguous United States. DOM diversity was explored using ultrahigh-resolution Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS). The samples and the unprocessed FTICR-MS data used in this study are publicly available on the Environmental System Science Data Infrastructure for a Virtual Ecosystem (ESS-DIVE) data repository (see DOIs below). The data for the Willamette, Gunnison, Connecticut, and Deschutes basins were collected as part of a collaboration between the Watershed Rules of Life (WROL) project and Worldwide Hydrobiogeochemistry Observation Network for Dynamic River Systems (WHONDRS). The data for the Yakima River basin (YRB) was collected by the PNNL River Corridor SFA. The raw, unprocessed FTICR-MS data with additional (meta)data can be found at doi:10.15485/1895159 for WROL samples and doi:10.15485/1898912 for YRB samples. This data package contains the processed data used in the associated manuscript. This package also contains ancillary geospatial, hydrological, and geochemical information that supports the interpretation of the FTICR-MS data within Ryan et al., 2024. This data package is associated with the GitHub repository found at https://github.com/WHONDRS-Hub/rcsfa-RC4-WROL-YRB_DOM_Diversity. This data package was originally published August 2024. It was updated January 2025 (modified files). See the change history in the readme more details. At the directory level, the data package is comprised of three folders: (1) data, (2) output, and (3) src; and five additional files including the data dictionary (file ending in "_dd.csv”) and file-level metadata (file ending in “_flmd.csv”). The “src” folder contains the scripts used to process the FTICR data, conduct the analyses, and produce the manuscript figures. The inputs for these scripts are in the “data” folder and the returned outputs in the “output” folder. Inputs include temporal and spatial metadata associated with the sampling efforts, processed FTICR data, and total and normalized putative biochemical transformations per sample. Outputs include cleaned and combined data presented as tables, descriptive statistics, and plots. The file-level metadata file lists all files contained in this data package and descriptions for each. The data dictionary describes the units and definitions for each tabular data column or row header.

54 ENVIRONMENTAL SCIENCES↗

A Physics-Based Data-Driven Approach for Modeling of Environmental Degradation in Elastomers

Abstract Elastomers are now commonly used in a number of industries, including aerospace, structure, transportation, shipbuilding, and automotive, due to their excellent workability, formability, and flexibility. During their activity, elastomers are subjected to harsh environmental conditions, which decreases their resilience. False predictions made early in their lives can have major financial and environmental implications. Elastomers’ performance and properties, such as strength, durability, and density, are influenced by chemical changes in these materials, known as degradation, which occurs over time. This process can alter the morphology of a polymer matrix as well as cause chain scission and cross-linking, resulting in different behaviors than that of the unaged material. To demonstrate the effect of thermaloxidative aging on the mechanical behavior of elastomers, several experimental and theoretical models have been proposed. In view of the large volume of experimental data available on micro-structural evolution in the course of aging, we propose a physics-based data-driven approach to overcome the shortcomings of both phenomenological and micro-mechanical models. This work presents a novel thermodynamically consistent, multiagent machine-learned model for predicting the constitutive behavior of cross-linked elastomers during environmental aging, such as thermo-oxidative and hydrolytic aging for various states of deformation. Single mechanism degradation changes the polymer matrix over time where it is causing chain scission, reduction of cross-links, and morphology change. To capture the idealized Mullins effect and permanent set due to the effect of single aging mechanisms on nonlinear mechanical responses of elastomers, we propose a data-driven model for simulating inelastic elements in a polymer matrix. By using a sequential order reduction, we were able to reduce the 3D stress-strain tensor mapping problem to a small number of super-constrained 1D mapping problems. To systematically classify such mapping problems into a few categories, an assembly of multiple replicated conditional neural network learning agents (L-agents) is used based on our recent work. Each category is represented by a different type of agent. The effect of deformation history, aging time, and aging temperature is captured by this model. The model is validated using a broad collection of data, ranging from our experimental results to data from the literature. In addition, thermodynamic consistency and frame independence are investigated. The most significant achievements of this model are its precision, simplicity, and prediction of inelasticity under various states of deformation. The model’s accuracy and simplicity make it a good option for commercial and industrial applications. Conveniently, due to the model modular nature, it can be expanded in the future to include viscoelasticity and non-isotropic formation for better precision.

Ghaderi, Aref↗

Triton: Environmental Monitoring Technology Development, Collision Risk Data Collection (Final Report)

In this project, we assembled a sensor suite that combines a scientific echosounder (sonar) system with video and acoustic cameras (secondary sensors). The sensor suite generates data that is amenable to automated target detection algorithms and can provide inputs to animal encounter models. We developed software (archiving software) to collect data simultaneously from all sensors in the suite, analyze the sonar data automatically in near real-time to identify time periods when targets of interest were present, and automatically archive data from the secondary sensors for these time periods. The product of the archiving software is a data set for the secondary sensors, containing data only for the times when targets of interest were determined to be present by the sonar. We performed controlled field testing to verify the operation of the sensor suite and the archiving software.

47 OTHER INSTRUMENTATION↗

The value of human data annotation for machine learning based anomaly detection in environmental systems

Anomaly detection is the process of identifying unexpected data samples in datasets. Automated anomaly detection is either performed using supervised machine learning models, which require a labelled dataset for their calibration, or unsupervised models, which do not require labels. While academic research has produced a vast array of tools and machine learning models for automated anomaly detection, the research community focused on environmental systems still lacks a comparative analysis that is simultaneously comprehensive, objective, and systematic. This knowledge gap is addressed for the first time in this study, where 15 different supervised and unsupervised anomaly detection models are evaluated on 5 different environmental datasets from engineered and natural aquatic systems. To this end, anomaly detection performance, labelling efforts, as well as the impact of model and algorithm tuning are taken into account. As a result, our analysis reveals the relative strengths and weaknesses of the different approaches in an objective manner without bias for any particular paradigm in machine learning. Most importantly, our results show that expert-based data annotation is extremely valuable for anomaly detection based on machine learning.

54 ENVIRONMENTAL SCIENCES↗

California - Auxiliary Datasets for Buoy (120), Humboldt / Derived Data

This dataset compiles results from different model-based hindcasts and instruments that measure environmental variables at the location of the associated lidar buoys. This dataset complements the lidar buoy measurements by providing longer time histories of selected environmental parameters. The data were extracted from the closest grid point to the average lidar buoy position. The data were obtained from the public domain and references to the originators/owners are provided under each instrument.

17 WIND ENERGY↗

California - Auxiliary Datasets for Buoy (130), Morro Bay / Derived Data

This dataset compiles results from different model-based hindcasts and instruments that measure environmental variables at the location of the associated lidar buoys. This dataset complements the lidar buoy measurements by providing longer time histories of selected environmental parameters. The data were extracted from the closest grid point to the average lidar buoy position. The data were obtained from the public domain and references to the originators/owners are provided under each instrument.

17 WIND ENERGY↗

Mapping Support for Targeted Critical Minerals Exploration and Extraction

The United States’ dependency on imported minerals poses significant risks to economic stability and national security due to potential supply disruptions. Recognizing the strategic importance of critical minerals, the Department of Energy (DOE) emphasizes the need for a secure and resilient supply chain to support emissions reduction, technology development, and capitalization on clean energy opportunities. The DOE’s Office of Manufacturing and Energy Supply Chains (MESC), in collaboration with the Office of Policy (OP), addresses these vulnerabilities by focusing on upstream domestic critical minerals production, balancing extraction with social and environmental goals, including conservation, environmental justice, and respect for Tribal sovereignty. This report showcases a collaborative effort involving Idaho National Laboratory (INL), Argonne National Laboratory (Argonne), National Renewable Energy Laboratory (NREL), and the U.S. Geological Survey (USGS) to map mineral development potential along with key social and environmental datasets. A geographical information system (GIS)-based web map application was developed as a preliminary tool for environmental analysis, integrating 158 geospatial data layers such as critical habitat, land ownership, economic indicators, and environmental concerns. Data were sourced from agencies like the Bureau of Land Management (BLM) and USGS and processed using GIS technology to enhance visualization and analysis. The proposed analysis framework categorizes areas into high, mid, and low concern based on withdrawn lands, special status species, the Economic Development Capacity Index (EDCI) Mining Composite Index, and the Climate and Economic Justice Screening Tool (CEJST). While the application provides broad visualizations, it is not a substitute for detailed environmental reviews required under the National Environmental Policy Act (NEPA). Users must conduct further analyses and engage with tribal entities and other stakeholders for comprehensive planning. A case study of the Idaho Cobalt Belt (ICB) in Lemhi County, Idaho, has been provided in the report to illustrate the tool's practical use. This report introduces a GIS application and framework to support stakeholders in identifying and prioritizing areas for critical mineral exploration, promoting secure supply chains, and advancing the nation's energy independence through responsible resource stewardship.

54 ENVIRONMENTAL SCIENCES↗

Specifications and a Prototype Software to Demonstrate a Data Catalog for Hanford Datasets

Environmental management activities at the Hanford Site produce extensive data about site conditions, contaminants, and cleanup activities. Managing, archiving, and accessing that data requires a high degree of collaboration among site contractors and a high level of awareness by project managers and staff. The Hanford Site has a range of databases (e.g., Hanford Environmental Information System [HEIS]) and their associated user interfaces (e.g., Environmental Dashboard Application [EDA], Virtual Library [VL]), as well as other document management systems (e.g., Integrated Document Management System [IDMS]). However, Hanford lacks a single unified resource to find data (which itself comes in multiple formats) amongst the multiple disparate systems, not to mention ad hoc data not contained in an official repository/database.

54 ENVIRONMENTAL SCIENCES↗

Shedding light on U.S. small and midsize data centers: Exploring insights from the CBECS survey

As demand for digital services accelerates, the energy and environmental footprint of data centers faces increasing scrutiny. While hyperscale cloud facilities have driven efficiency gains, small and midsize U.S. data centers remain a critical yet underexamined segment with significant untapped potential for energy savings. This study leverages data from the Commercial Buildings Energy Consumption Survey (CBECS) to analyze trends in server stocks, computing customers, cooling system adoption and efficiency, and geospatial distribution from 2012 to 2018. Findings reveal a sharp decline in small and midsize data centers, from 1.764 million to 1.398 million, with server counts dropping from 5.177 million to 4.262 million—aligning with the broader shift toward cloud computing. More than 40 % of servers in small data centers and 55 % in midsize data centers are housed in office buildings, and over half of all servers are concentrated in climate zones 5A (cold), 3A (mixed-humid), and 4A (mixed-humid), with the highest densities in metropolitan hubs. While direct expansion units remain the dominant cooling system, a clear transition toward more energy-efficient solutions, particularly air economizers, is evident. By integrating server and cooling system distributions, we estimate Power Usage Effectiveness (PUE) and Water Usage Effectiveness (WUE) for U.S. data centers by size and year. Results show that midsize data centers are more energy-efficient but more water-intensive due to the widespread use of water-cooled chillers. These findings highlight the trade-offs in cooling system selection and provide a critical foundation for policies aimed at enhancing efficiency in an evolving data center landscape.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Detection of Anomalies in Environmental Gamma Radiation Background with Hopfield Artificial Neural Network - Consortium on Nuclear Security Technologies (CONNECT) Q3 Report

Environmental screening of gamma radiation consists of detecting weak nuisance and anomaly signal in the presence of strong and highly varying background. In a typical scenario, a mobile detector-spectrometer continuously measures gamma radiation spectra in short, e.g., one-second, signal acquisition intervals. The measurement data is a 2D matrix, where one dimension is gamma ray energy, and the other dimension is the number of measurements or total time. In principle, gamma radiation sources can be detected and identified from the measured data by their unique spectral lines. Detecting sources from data measured in a search scenario is difficult due to the highly varying background because of naturally occurring radioactive material (NORM), and low signal-to-noise ratio (S/N) of spectral signal measured during one-second acquisition intervals. The objective of this work is to investigate performance of a Hopfield Neural Network (HNN) in in detection and identification of weak nuisances and anomalies events in the presence of a highly fluctuating background. Performance of HNN algorithm is benchmarked using search data from an environmental screening campaign. One data set contained a 137 Cs source, and another dataset contained a 131 I source.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Characterizing Wet Season Precipitation in the Central Amazon Using a Mesoscale Convective System Tracking Algorithm

To comprehensively characterize convective precipitation in the central Amazon region, we utilize the Python FLEXible object TRacKeR (PyFLEXTRKR) to track mesoscale convective systems (MCSs) observed through satellite measurements and simulated by the Weather Research and Forecasting model at a convection-permitting resolution. This study spans a 2-month period during the wet seasons of 2014 and 2015. We observe a strong correlation between the MCS track density and accumulated precipitation in the Amazon basin. Key factors contributing to precipitation, such as MCS properties (number, size, rainfall intensity, and movement), are thoroughly examined. Our analysis reveals that while the overall model produces fewer MCSs with smaller mean sizes compared to observations, it tends to overpredict total precipitation due to excessive rainfall intensity for heavy rainfall events (≥10 mm hr –1 ). These biases in simulated MCS properties could vary with the constraints on the convective background environment. Moreover, while the wet bias from heavy (convective) rainfall outweighs the dry bias in light (stratiform) rainfall, the latter can be crucial, particularly when MCS cloud cover is significantly underestimated. A case study for 1 April 2014 highlights the influence of environmental conditions on the MCS lifecycle and identifies an unrealistic model representation in both stratiform and convective precipitation features.

54 ENVIRONMENTAL SCIENCES↗

Measuring impacts of California agri-environmental programs using field-scale satellite data

In the past decade, California has invested over $\$$200 million in direct grants to growers to support the adoption of agricultural practices that save water and/or improve soil health while also reducing greenhouse gas emissions. Ex-post evaluation of agri-environmental outcomes of these grant programs, however, is limited. We use satellite data to monitor changes in field-level consumptive water use and greenness (i.e. normalized difference vegetation index), a proxy for agricultural productivity, for the most frequently funded crop-types (almonds, grapes, and walnuts) in two California Department of Food and Agriculture programs. Nearly 600 fields receiving funding during the 2014–2022 period were analyzed using two causal inference methods. Fields that received grants to both upgrade irrigation systems and install irrigation water management sensors showed reduced consumptive water use and greenness by an average of 3.5% and 4.2%, respectively (significant at the 10% level). In contrast, we find that the adoption of only irrigation water management sensors, which are designed to inform irrigation scheduling and management, resulted in an average increase of 4.1% and 4.8% in consumptive water use and greenness respectively (significant at the 5% level). We find negligible effects for either consumptive water use or greenness when both pump efficiency upgrades and sensors were implemented. We further find that grants for compost addition and cover cropping led to small greenness increases of 1.7% and 2.8% respectively (significant at the 10% level) and had insignificant effects on consumptive water use. Our analysis of five agri-environmental program interventions reveals that several practice outcomes may be at odds with stated program goals of reducing water use while maintaining or improving agricultural productivity.

agriculture↗

Data for “Tree root nutrient uptake kinetics vary with nutrient availability, environmental conditions, and root traits: A global analysis”

This data package contains data and code used in the paper “Tree root nutrient uptake kinetics vary with nutrient availability, environmental conditions, and root traits: A global analysis”. The central product is a global dataset of root inorganic nutrient uptake rates and kinetics parameters covering temperate, boreal, and sub/tropical tree species, representing a collection of nutrient uptake data from published studies. This dataset enables tree investigation of root nutrient uptake rates across species, space, and experimental conditions. The data can also be combined with supplementary data on root and soil traits or with external datasets (e.g. R scripts contained within use data from FRED 3.0; (Iversen et al., 2021)). Contained within is the main nutrient data “uptake_data.csv” as well as 4 additional .csv files that link uptake data to supplementary measurements, source references, taxonomic information, and additional nutrient uptake measurements across nutrient gradients, and 1 .csv file that records meta-analysis results for plotting with the R scripts. There are seven R scripts that support data analysis and creation of the figures in the related publication.

54 ENVIRONMENTAL SCIENCES↗