Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “energy intermediate”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

The computer simulation of automobile use patterns for defining battery requirements for electric cars

A Monte Carlo simulation process was used to develop the U.S. daily range requirements for an electric vehicle from probability distributions of trip lengths and frequencies and average annual mileage data. The analysis shows that a car in the U.S. with a practical daily range of 82 miles (132 km) can meet the needs of the owner on 95% of the days of the year, or at all times other than his long vacation trips. Increasing the range of the vehicle beyond this point will not make it more useful to the owner because it will still not provide intercity transportation. A daily range of 82 miles can be provided by an intermediate battery technology level characterized by an energy density of 30 to 50 watt-hours per pound (66 to 110 W-hr/kg). Candidate batteries in this class are nickel-zinc, nickel-iron, and iron-air. The implication of these results for the research goals of far-term battery systems suggests a shift in emphasis toward lower cost and greater life and away from high energy density.

Schwartz, H. J.↗
NASA NTRS1976

The computer simulation of automobile use patterns for defining battery requirements for electric cars

The modeling process of a complex system, based on the calculation and optimization of the system parameters, is complicated in that some parameters can be expressed only as probability distributions. In the present paper, a Monte Carlo technique was used to determine the daily range requirements of an electric road vehicle in the United States from probability distributions of trip lengths, frequencies, and average annual mileage data. The analysis shows that a daily range of 82 miles meets to 95% of the car-owner requirements at all times with the exception of long vacation trips. Further, it is shown that the requirement of a daily range of 82 miles can be met by a (intermediate-level) battery technology characterized by an energy density of 30 to 50 Watt-hours per pound. Candidate batteries in this class are nickel-zinc, nickel-iron, and iron-air. These results imply that long-term research goals for battery systems should be focused on lower cost and longer service life, rather than on higher energy densities

Schwartz, H.-J.↗
NASA NTRS1979

Crack barriers improve the mechanical and thermal properties of non-metallic sinter materials

Means of improving the tensile strength of ceramic composites by introducing ductile intermediate layers capable of absorbing the elastic energy at the rupture front are studied. Tests with an Al203 laminate with niobium inclusions showed that crack propagation could be successfully precluded by dissipation of the energy by deformation and/or delamination at the inclusion/matrix interface.

Gruenthaler, K. H.↗
NASA NTRS1982

Temperature Controller for a Solar Furnace

Relatively-simple movable sheild has been suggested for controlling temperature of solar furnace. Temperature modulator can be set to have collected solar energy fully "on", fully "off" or any intermediate level. Parabolic mirror concentrates Sunlight into receiver. Shade plate that blocks insolation at back of receiver produces shade zone in center of collector. No radiation is returned to receiver from shade zone; only rays falling on other areas of reflecting surface are directed back toward receiver.

Hale, R. R.↗
NASA NTRS1981

On the fragmentation of rotating interstellar clouds

Simple physical arguments are used to estimate the time scale for fragmentation of a collapsing, rotating, isothermal, interstellar cloud. This time scale is compared with a similarly estimated time scale for the collapse upon itself of a transitory ring structure. It is shown to be plausible for a cloud with a given ratio of rotational to gravitational energy (beta) that as the ratio of thermal to gravitational energy (alpha) is varied, there is an intermediate range of alpha where a ring forms and collapses on itself, prior to fragmentation. For higher or lower alpha, however, the cloud fragments prior to ring self-collapse. The analysis is compared with the results of numerical multidimensional, gravitational, hydrodynamical collapse and shown to be in good agreement with them.

Boss, A. P.↗
NASA NTRS1983

Pulse radiolysis of epoxy-based matrix materials

Electron beam pulse radiolysis (600 KeV, 3 nsec) experiments have been carried out on epoxy-based matrix materials. Time and wavelength resolved emission and transient absorption techniques as well as ESR studies have been utilized to identify and monitor short lived reactive intermediates resulting from energetic electron impact. An energy deactivation model based on the results of this work has been developed. Recombination of primary charged species is found to be fast, resulting in the formation of longer lived excited electronic states and radicals which control the subsequent energy deactivation.

Coulter, D. R.↗
NASA NTRS1989

Active rendezvous between a low-earth orbit user spacecraft and the Space Transportation System (STS) shuttle

Active rendezvous of an unmanned spacecraft with the Space Transportation System (STS) Shuttle is considered. The various operational constraints facing both the maneuvering spacecraft and the Shuttle during such a rendezvous sequence are discussed. Specifically, the actively rendezvousing user spacecraft must arrive in the generic Shuttle control box at a specified time after Shuttle launch. In so doing it must at no point violate Shuttle separation requirements. In addition, the spacecraft must be able to initiate the transfer sequence from any point in its orbit. The four-burn rendezvous sequence incorporating two Hohmann transfers and an intermediate phasing orbit as a low-energy solution satisfying the above requirements are discussed. The general characteristics of the four-burn sequence are discussed, with emphasis placed on phase orbit altitude and delta-velocity requirements. The planning and execution of such a sequence in the operational environment are then considered. Factor crucial in maintaining the safety of both spacecraft, such as spacecraft separation and contingency analysis, are considered in detail.

Hooper, H. L.↗
NASA NTRS1992

The coupling of interfacial instabilities and the stabilization of two-layer annular flows

In this paper the stability of annular pressure-driven parallel flows of two liquids sandwiching a free cylindrical interface is considered. For small to moderate Reynolds numbers, the interface is susceptible to capillary and interfacial wave instabilities, the latter instability caused by a jump in viscosity at the interface. It is shown that favorable velocity profiles in both liquids may stabilize capillary breakup of the interface and suppress the axisymmetric interfacial wave instability. A long-wave analysis leads to the physical mechanism responsible for stabilization of capillary breakup. This physical mechanism is a generalization of that by which capillary breakup is stabilized by interfacial shear in an annular film of a single liquid. Stabilization of intermediate wavelengths is studied with a mechanical energy analysis, which leads to a description of the energetic processes at work.

Dijkstra, Henk A.↗
NASA NTRS1981

On the Fragmentation of Rotating Interstellar Clouds

Simple physical arguments are used to estimate the time scale for fragmentation of a collapsing, rotating, isothermal, interstellar cloud. This time scale is compared with a similarly estimated time scale for the collapse upon itself of a transitory ring structure. It is shown to be plausible for a cloud with a given ratio of rotational to gravitational energy (beta) that as the ratio of thermal to gravitational energy (alpha) is varied, there is an intermediate range of alpha where a ring forms and collapses on itself, prior to fragmentation. For higher or lower alpha however, the cloud fragments prior to ring self-collapse. The analysis is compared with the results of numerical multidimensional, gravitational, hydrodynamical collapse and shown to be in good agreement with them.

Boss, Alan Paul↗
NASA NTRS1999

Mechanosensitive channels in bacteria as membrane tension reporters

The purpose of this short review is to discuss recent data on the molecular structure and mechanism of gating of MscL, a mechanosensitive channel of large conductance from Escherichia coli. MscL is the first isolated molecule shown to convert mechanical stress of the membrane into a simple response, the opening of a large aqueous pore. The functional complex appears to be a stable homo-pentamer of 15-kDa subunits, the gating transitions in which are driven by stretch forces conveyed through the lipid bilayer. We have measured the open probability of MscL and the kinetics of transitions as a function of membrane tension. The parameters extracted from the single-channel current recordings and dose-response curves such as the energy difference between the closed, open, and intermediate conducting states, and the transition-related changes in protein dimensions suggest a large conformational rearrangement of the channel complex. The estimations show that in native conditions MscL openings could be driven primarily by forces of osmotic nature. The thermodynamic and spatial parameters reasonably correlate with the available data on the structure of a single MscL subunit and multimeric organization of the complex. Combined with the functional analysis of mutations, these data give grounds to hypotheses on the nature of the channel mechanosensitivity.

Review↗
NASA NTRS2006

Quantum Entanglement Molecular Absorption Spectrum Simulator

Quantum Entanglement Molecular Absorption Spectrum Simulator (QE-MASS) is a computer program for simulating two photon molecular-absorption spectroscopy using quantum-entangled photons. More specifically, QE-MASS simulates the molecular absorption of two quantum-entangled photons generated by the spontaneous parametric down-conversion (SPDC) of a fixed-frequency photon from a laser. The two-photon absorption process is modeled via a combination of rovibrational and electronic single-photon transitions, using a wave-function formalism. A two-photon absorption cross section as a function of the entanglement delay time between the two photons is computed, then subjected to a fast Fourier transform to produce an energy spectrum. The program then detects peaks in the Fourier spectrum and displays the energy levels of very short-lived intermediate quantum states (or virtual states) of the molecule. Such virtual states were only previously accessible using ultra-fast (femtosecond) laser systems. However, with the use of a single-frequency continuous wave laser to produce SPDC photons, and QEMASS program, these short-lived molecular states can now be studied using much simpler laser systems. QE-MASS can also show the dependence of the Fourier spectrum on the tuning range of the entanglement time of any externally introduced optical-path delay time. QE-MASS can be extended to any molecule for which an appropriate spectroscopic database is available. It is a means of performing an a priori parametric analysis of entangled photon spectroscopy for development and implementation of emerging quantum-spectroscopic sensing techniques. QE-MASS is currently implemented using the Mathcad software package.

Nguyen, Quang-Viet↗
NASA NTRS1988

Fluoride salts as phase change materials for thermal energy storage in the temperature range 1000-1400 K

Eutectic compositions and congruently melting intermediate compounds in binary and ternary fluoride salt systems were characterized for potential use as latent heat of fusion phase change materials to store thermal energy in the temperature range 1000-1400 K. The melting points and eutectic compositions for many systems with published phase diagrams were experimentally verified and new eutectic compositions having melting points between 1000 and 1400 K were identified. Heats of fusion of several binary and ternary eutectics and congruently melting compounds were experimentally measured by differential scanning calorimetry. For a few systems in which heats of mixing in the melts have been measured, heats of fusion of the eutectics were calculated from thermodynamic considerations and good agreement was obtained between the measured and calculated values. Several combinations of salts with high heats of fusion per unit mass (greater than 0.7 kJ/g) have been identified for possible use as phase change materials in advanced solar dynamic space power applications.

Misra, Ajay K.↗
NASA NTRS2019

EMIC Wave-Driven Bounce Resonance Scattering of Energetic Electrons in the Inner Magnetosphere

While electromagnetic ion cyclotron (EMIC) waves have been long studied as a scattering mechanism for ultrarelativistic (megaelectron volt) electrons via cyclotron‐resonant interactions, these waves are also of the right frequency to resonate with the bounce motion of lower‐energy (approximately tens to hundreds of kiloelectron volts) electrons. Here we investigate the effectiveness of this bounce resonance interaction to better determine the effects of EMIC waves on subrelativistic electron populations in Earth's inner magnetosphere. Using wave and plasma parameters directly measured by the Van Allen Probes, we estimate bounce resonance diffusion coefficients for four different events, illustrative of wave and plasma parameters to be encountered in the inner magnetosphere. The range of electron energies and pitch angles affected is examined to better assess the realistic effects of EMIC‐driven bounce resonance on energetic electron populations based on actual, locally observed event‐based parameters. Significant local diffusion coefficients (~ > 10(exp −6) s(exp −1)) for 50‐ to 100‐keV electrons are achieved for both H+ band wave events as well as He+ band, with diffusion coefficients peaking for near‐90° pitch angles but remaining elevated for intermediate ones as well. Diffusion coefficients for higher‐energy 200‐keV electrons are typically multiple orders of magnitude lower (ranging from 10(exp −11) to 10(exp −6) s(exp −1)) and often peak at lower pitch angles (~20–30°). These results suggest that both H+ and He+ band EMIC waves can play a role in shaping lower‐energy electron dynamics via bounce‐resonant interactions, in addition to their role in relativistic electron loss via cyclotron resonance.

Blum, L. W.↗
NASA NTRS1974

Solar-energy absorber: Active infrared (IR) trap

Efficiency of solar-energy absorbers may be improved to 95% by actively cooling their intermediate glass plates. This approach may be of interest to manufacturers of solar absorbers and to engineers and scientists developing new sources of energy.

Brantley, L. W., Jr.↗
NASA NTRS1984

Quantum chemical studies of a model for peptide bond formation. 3. Role of magnesium cation in formation of amide and water from ammonia and glycine

The SN2 reaction between glycine and ammonia molecules with magnesium cation Mg2+ as a catalyst has been studied as a model reaction for Mg(2+)-catalyzed peptide bond formation using the ab initio Hartree-Fock molecular orbital method. As in previous studies of the uncatalyzed and amine-catalyzed reactions between glycine and ammonia, two reaction mechanisms have been examined, i.e., a two-step and a concerted reaction. The stationary points of each reaction including intermediate and transition states have been identified and free energies calculated for all geometry-optimized reaction species to determine the thermodynamics and kinetics of each reaction. Substantial decreases in free energies of activation were found for both reaction mechanisms in the Mg(2+)-catalyzed amide bond formation compared with those in the uncatalyzed and amine-catalyzed amide bond formation. The catalytic effect of the Mg2+ cation is to stabilize both the transition states and intermediate, and it is attributed to the neutralization of the developing negative charge on the electrophile and formation of a conformationally flexible nonplanar five-membered chelate ring structure.

Magnesium/chemistry↗
NASA NTRS2007

Atomic Data and Spectral Line Intensities for CA XVII

Electron impact collision strengths, energy levels, oscillator strengths and spontaneous radiative decay rates are calculated for Ca XVII. The configurations used are 2s(sup 2), 2s2p, 2p(sup 2), 2l3l', 214l' and 2s5l', with l = s,p and l' = s,p, d giving rise to 92 fine-structure levels in intermediate coupling. Collision strengths are calculated at seven incident energies (15, 30, 75, 112.5, 150, 187.5 and 225 Ry) for the transitions within the three lowest configurations corresponding to the 10 lowest energy levels, and five incident energies (75, 112.5, 150, 187.5 and 225 Ry) for transitions between the lowest five levels and the n = 3,4,5 configurations. Calculations have been carried out using the distorted wave approximation. Excitation rate coefficients are calculated as a function of electron temperature by assuming a Maxwellian electron velocity distribution. Using the excitation rate coefficients and the radiative transition rates of the present work, and R-Matrix results for the 2s2, 2s2p, 2p2 configurations available in the literature, statistical equilibrium equations for level populations are solved at electron densities covering the range of 10(exp 8)-10(exp 14)/cu cm at an electron temperature of log Te(K)=6.7, corresponding to the maximum abundance of Ca XVII. Spectral line intensities are calculated, and their diagnostic relevance L; discussed. This dataset will be made available in the next version of the CHIANTI database.

Bhatia, A.K.↗
NASA NTRS1999

Noise and Bandwidth Measurements of Diffusion-Cooled Nb Hot-Electron Bolometer Mixers at Frequencies Above the Superconductive Energy Gap

Diffusion-cooled Nb hot-electron bolometer (HEB) mixers have the potential to simultaneously achieve high intermediate frequency (IF) bandwidths and low mixer noise temperatures for operation at THz frequencies (above the superconductive gap energy). We have measured the IF signal bandwidth at 630 GHz of Nb devices with lengths L = 0.3, 0.2, and 0.1 micrometer in a quasioptical mixer configuration employing twin-slot antennas. The 3-dB EF bandwidth increased from 1.2 GHz for the 0.3 gm long device to 9.2 GHz for the 0.1 gm long device. These results demonstrate the expected 1/L squared dependence of the IF bandwidth at submillimeter wave frequencies for the first time, as well as the largest EF bandwidth obtained to date. For the 0.1 gm device, which had the largest bandwidth, the double sideband (DSB) noise temperature of the receiver was 320-470 K at 630 GHz with an absorbed LO power of 35 nW, estimated using the isothermal method. A version of this mixer with the antenna length scaled for operation at 2.5 THz has also been tested. A DSB receiver noise temperature of 1800 plus or minus 100 K was achieved, which is about 1,000 K lower than our previously reported results. These results demonstrate that large EF bandwidth and low-noise operation of a diffusion-cooled HEB mixer is possible at THz frequencies with the same device geometry.

Wyss, R. A.↗