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At least 181 records · Page 10

Ammonia in northeast Colorado is increasing, rising most quickly in regions close to confined animal feeding operations

The Colorado Front Range urban corridor and nearby agricultural operations are important source regions of atmospheric ammonia (NH 3 ). Upslope flows periodically transport these emissions into Rocky Mountain National Park (RMNP), located 50 km west of the urban corridor, where wet and dry deposition of excess reactive nitrogen (N) impacts ecosystems. Here, we use a combination of in situ passive NH 3 measurements and NH 3 vertical column density retrievals from the Infrared Atmospheric Sounding Interferometer (IASI) to assess variability and changes in NH 3 across three land use categories in the northeast Colorado source region (agricultural, urban, and remote) during the period 2013-2023. A strong seasonal cycle is present across the region with increased NH 3 during summer months. Elevated NH 3 is spatially correlated with the number of permitted animal units in confined animal feeding operations (CAFOs) within 12 km. Ground-level NH 3 concentrations are strongly positively correlated with monthly gridded IASI satellite column densities. Satellite retrievals reveal an increasing trend in NH 3 column amounts of ∼3% per year in agricultural and ∼2% per year in urban sub-regions. The magnitude of the trend observed in NH 3 columns averaged over the agricultural sub-region is > 3 times larger than observed near and over Denver. The largest increases in NH 3 are closely aligned with the distribution of CAFOs. Reductions in particle sulfate associated with declining sulfur dioxide (SO 2 ) emissions could account for only ∼0.1% per year increase in gaseous NH 3 . Wildfire smoke across the region has increased but appears unlikely to explain the majority of the observed NH 3 increase.

54 ENVIRONMENTAL SCIENCES↗

Quantifying Subsurface Biogeochemical Variability in a High Altitude Watershed During Winter Isolation

Shallow subsurface microbial and geochemical processes in watersheds are dynamic and responsive to seasonal and long-term environmental change. At high elevation or latitude, such changes may occur during winter months when normal sampling is impossible, impractical, unsafe, or may actually alter the processes being studied. Yet accurate modeling of biogeochemical parameters in these environments requires sampling that can capture events and persistent cold climate trends. Gaps in current models exist where data have not been collected during extended snow- or ice-covered periods. The goals of our exploratory study were to examine the biogeochemical processes occurring in a well-studied high altitude watershed during winter when the system is largely inaccessible. We tested the hypothesis that during snow cover in the East River (ER) watershed, episodic excursions of microbial community structure and biogeochemical processes and concentrations fluctuated from values extrapolated from pre- and post-snow time periods. Through our research we identified previously unresolved subsurface-surface transport phenomena and a heretofore under-appreciated methane cycle occurring during wintertime months, thus providing valuable insight into watershed processes. Our research showed that autonomous sampling techniques, first used in marine systems, is extremely versatile and can be adapted for use in harsh continental settings to examine temporal changes in freshwater chemistry and microbial community assemblage. Further, we found that by sampling during periods when systems are hard to access, will lend insight and better accountability for global budgets for methane, an important greenhouse gas. By strengthening our knowledge of wintertime biogeochemical relationships in high altitude watersheds our research leads to more complete descriptions of cryptic processes and ultimately will inform and improve the reactive transport models that simulate processes in these systems.

54 ENVIRONMENTAL SCIENCES↗

Dynamic soil columns simulate Arctic redox biogeochemistry and carbon release during changes in water saturation

Thawing Arctic permafrost can induce hydrologic change and alter redox conditions, shifting the balance of soil organic matter (SOM) decomposition. There remains uncertainty about how soil saturation and redox transitions impact dissolved and gas phase carbon fluxes, and efforts to link hydrobiogeochemical processes to ecosystem-scale models are limited. This study evaluates SOM decomposition of Arctic tundra soils using column experiments, water chemistry measurements, microbial community analysis, and a PFLOTRAN reactive transport model. Soil columns from a thermokarst channel (TC) and an upland tundra (UC) were exposed to cycles of saturation and drainage, which controlled carbon emissions. During saturation, an outflow of dissolved organic carbon from the UC soil correlated with elevated reduced iron and decreased pH; during drainage, UC carbon dioxide fluxes were 70% higher than TC fluxes. Intermittent methane release was observed for TC, consistent with higher methanogen abundance. Slower drainage in the TC soil correlated with more subtle biogeochemical changes. PFLOTRAN simulations captured experimental trends in soil carbon fluxes, oxygen concentrations, and water contents. The model was then used to evaluate additional soil water drainage rates. This study emphasizes the importance of considering hydrologic change when evaluating and simulating SOM decomposition in dynamic Arctic tundra environments.

54 ENVIRONMENTAL SCIENCES↗

Warm-season net CO 2 uptake outweighs cold-season emissions over Alaskan North Slope tundra under current and RCP8.5 climate

Abstract Arctic warming has increased vegetation growth and soil respiration during recent decades. The rate of Arctic warming will likely amplify over the 21st century. Previous studies have revealed that the most severe Arctic warming occurred during the cold season (September to May). The cold-season warming has posited significant CO 2 emissions to the atmosphere via respiration, possibly offsetting warm-season (June to August) net CO 2 uptake. However, prevailing Earth system land models poorly represent cold-season CO 2 emissions, making estimates of Arctic tundra annual CO 2 budgets highly uncertain. Here, we demonstrate that an improved version of the energy exascale Earth system model (E3SM) land model (ELMv1-ECA) captures the large amount of cold-season CO 2 emissions over Alaskan Arctic tundra as reported by two independent, observationally-constrained datasets. We found that the recent seven-decades warming trend of cold-season soil temperature is three times that of the warm-season. The climate sensitivity of warm-season net CO 2 uptake, however, is threefold higher than for the cold-season net CO 2 loss, mainly due to stronger plant resilience than microbial resilience to hydroclimatic extremes. Consequently, the modeled warm-season net CO 2 uptake has a larger positive trend (0.74 ± 0.14 gC m −2 yr −1 ) than that of cold-season CO 2 emissions (0.64 ± 0.11 gC m −2 yr −1 ) from 1950 to 2017, supported by enhanced plant nutrient uptake and increased light- and water-use efficiency. With continued warming and elevated CO 2 concentrations under the representative concentration pathway (RCP) 8.5 scenario, the increasing rate of warm-season net CO 2 uptake is more than twice the rate of cold-season emissions (1.33 ± 0.32 gC m −2 yr −1 vs 0.50 ± 0.12 gC m −2 yr −1 ), making the modeled Alaskan Arctic tundra ecosystem a net CO 2 sink by 2100. However, other geomorphological and ecological disturbances (e.g. abrupt permafrost thaw, thermokarst development, landscape-scale hydrological changes, wildfire, and insects) that are not considered here might alter our conclusion.

54 ENVIRONMENTAL SCIENCES↗

ATLAS Beam Steering Mechanism Lessons Learned

This paper describes the design, testing, and lessons learned during the development of the Advanced Topographic Laser Altimeter System (ATLAS) Beam Steering Mechanism (BSM). The BSM is a 2 degree-of-freedom tip-tilt mechanism for the purpose of pointing a flat mirror to tightly control the co-alignment of the transmitted laser and the receiver telescope of the ATLAS instrument. The high resolution needs of the mission resulted in sub-arcsecond pointing and knowledge requirements, which have been met. Development of the methodology to verify performance required significant effort. The BSM will fly as part of the Ice, Cloud, and Elevation Satellite II Mission (ICESat II), which is scheduled to be launched in 2017. The ICESat II primary mission is to map the earth's surface topography for the determination of seasonal changes of ice sheet thickness and vegetation canopy thickness to establish long-term trends.

controls↗

ATLAS Beam Steering Mechanism (BSM) Lessons Learned

This paper describes the design, testing, and lessons learned during the development of the Advanced Topographic Laser Altimeter System (ATLAS) Beam Steering Mechanism (BSM). The BSM is a 2 degree-of-freedom tip-tilt mechanism for the purpose of pointing a flat mirror to tightly control the co-alignment of the transmitted laser and the receiver telescope of the ATLAS instrument. The high resolution needs of the mission resulted in sub-arcsecond pointing and knowledge requirements, which have been met. Development of the methodology to verify performance required significant effort. The BSM will fly as part of the Ice, Cloud, and Elevation Satellite II Mission (ICESat II), which is scheduled to be launched in 2017. The ICESat II primary mission is to map the Earth's surface topography for the determination of seasonal changes of ice sheet thickness and vegetation canopy thickness to establish long-term trends.

Blumenstock, Kenneth A.↗

Experimental Comparison of Piezoelectric and Magnetostrictive Shunt Dampers

A novel mechanism called the vibration ring is being developed to enable energy conversion elements to be incorporated into the driveline of a helicopter or other rotating machines. Unwanted vibration is transduced into electrical energy, which provides a damping effect on the driveline. The generated electrical energy may also be used to power other devices (e.g., health monitoring sensors). PZT (piezoceramic) and PMN-30PT (single crystal) stacks, as well as a Tb_0.3 Dy_0.7 Fe_1.92 (Terfenol-D) rod with a bias magnet array and a pickup coil, were tested as alternative energy conversion elements to use within the vibration ring. They were tuned for broadband damping using shunt resistors, and dynamic compression testing was conducted in a high-speed load frame. Energy conversion was experimentally optimized at 750Hz by tuning the applied bias stress and resistance values. Dynamic testing was conducted up to 1000Hz to determine the effective compressive modulus, shunt loss factor, internal loss factor, and total loss factor. Some of the trends of modulus and internal loss factor versus frequency were unexplained. The single crystal device exhibited the greatest shunt loss factor whereas the Terfenol-D device had the highest internal and total loss factors. Simulations revealed that internal losses in the Terfenol-D device were elevated by eddy current effects, and an improved magnetic circuit could enhance its shunt damping capabilities. Alternatively, the Terfenol-D device may be simplified to utilize only the eddy current dissipation mechanism (no pickup coil or shunt) to create broadband damping.

energy conversion↗

Experimental Comparison of Piezoelectric and Magnetostrictive Shunt Dampers

A novel mechanism called the vibration ring is being developed to enable energy conversion elements to be incorporated into the driveline of a helicopter or other rotating machines. Unwanted vibration is transduced into electrical energy, which provides a damping effect on the driveline. The generated electrical energy may also be used to power other devices (e.g., health monitoring sensors). PZT (piezoceramic) and PMN-30%PT (single crystal) stacks, as well as a Tb_0.3 Dy_0.7 Fe_1.92 (Terfenol-D) rod with a bias magnet array and a pickup coil, were tested as alternative energy conversion elements to use within the vibration ring. They were tuned for broadband damping using shunt resistors, and dynamic compression testing was conducted in a high-speed load frame. Energy conversion was experimentally optimized at 750Hz by tuning the applied bias stress and resistance values. Dynamic testing was conducted up to 1000Hz to determine the effective compressive modulus, shunt loss factor, internal loss factor, and total loss factor. Some of the trends of modulus and internal loss factor versus frequency were unexplained. The single crystal device exhibited the greatest shunt loss factor whereas the Terfenol-D device had the highest internal and total loss factors. Simulations revealed that internal losses in the Terfenol-D device were elevated by eddy current effects, and an improved magnetic circuit could enhance its shunt damping capabilities. Alternatively, the Terfenol-D device may be simplified to utilize only the eddy current dissipation mechanism (no pickup coil or shunt) to create broadband damping.

piezoelectric↗

Unlocking Dysprosium Constraints for China’s 1.5 °C Climate Target

Some key low-carbon technologies, ranging from wind turbines to electric vehicles, are underpinned by the strong rare-earth-based permanent magnets of the Nd, Pr (Dy)–Fe–Nb type (NdFeB). These NdFeB magnets, which are sensitive to demagnetization with temperature elevation (the Curie point), require the addition of variable amounts of dysprosium (Dy), where an elevation of the Curie point is needed to meet operational conditions. Given that China is the world’s largest REE supplier with abundant REE reserves, the impact of an ambitious 1.5 °C climate target on China’s Dy supply chain has sparked widespread concern. Here, we explore future trends and innovation strategies associated with the linkage between Dy and NdFeBs under various climate scenarios in China. We find China alone is expected to exhaust the global present Dy reserve within the next 2–3 decades to facilitate the 1.5 °C climate target. By implementing global available innovation strategies, such as material substitution, reduction, and recycling, it is possible to avoid 48%–68% of China’s cumulative demand for Dy. Nevertheless, ongoing efforts in REE exploration and production are still required to meet China’s growing Dy demand, which will face competition from the United States, European Union, and other countries with ambitious climate targets. Here our analysis urges China and those nations to form wider cooperation in REE supply chains as well as in NdFeB innovation for the realization of a global climate-safe future.

54 ENVIRONMENTAL SCIENCES↗

High-temperature ohmic contact to n-type 6H-SiC using nickel

Specific contact resistances measured at elevated temperatures for Ni ohmic contacts to 6H-SiC were reported. The specific contact resistances were measured with the linear transmission line method at both room temperature and at 500 C and yielded values less than 5 x 10(exp -6) ohm sq cm at both temperatures. The trend shows a decreasing contact resistance at higher temperature. The annealed metal film is a nickel silicide with substantial mixing of C throughout the silicide layer.

Crofton, J.↗

Effect of Elevated Carbon Dioxide on Nutritional Quality of Tomato

Tomato (Lycopersicon esculentum Mill.) cvs. Red Robin (RR) and Reimann Philipp (RP) were grown hydroponically for 105 d with a 12 h photoperiod, 26 C/22 C thermoperiod, and 500 micromol/ sq m/s PPF at either 400, 1200, 5000, or 10,000 micromol/mol (0.04, 0.12, 0.50, 1.00 kPa) CO2. Harvested fruits were analyzed for proximate composition, total dietary fiber, nitrate, and elemental composition. No trends were apparent with regard to CO2 effects on proximate composition, with fruit from all treatments and both cultivars averiging 18.9 % protein, 3.6 % fat, 10.2 % ash, and 67.2 % carbohydrate. In comparison, average values for field-grown fruit are 16.6 % protein, 3.8 % fat, 8.1 % ash, and 71.5 % carbohydrate (Duke and Atchely, 1986). Total dietary fiber was highest at 10,000 micromol/mol (28.4 % and 22.6 % for RR and RP) and lowest at 1000 micromol/mol (18.2 % and 15.9 % for RR and RP), but showed no overall trend in response to CO2. Nitrate values ranged from 0.19 % to 0.35 % and showed no trend with regard to CO2. K, Mg, and P concentrations showed no trend in response to CO2, but Ca levels increased from 198 and 956 ppm in RR and RP at 400 micromol/mol, to 2537 and 2825 ppm at 10,000 micromol/mol. This increase in Ca caused an increase in fruit Ca/P ratios from 0.07 and 0.37 for RR and RP at 400 micromol/molto 0.99 and 1.23 for RR and RP at 10,000 micromol/mol suggesting that more dietary Ca should be available from high CO2-grown fruit.

Wheeler, R. M.↗

Constitutive modelling of single crystal and directionally solidified superalloys

The trend towards improved engine efficiency and durability places increasing demands on materials that operate in the hot section of the gas turbine engine. These demands are being met by new coatings and materials such as single crystal and directionally solidified nickel-base superalloys which have greater creep/fatigue resistance at elevated temperatures and reduced susceptibility to grain boundary creep, corrosion and oxidation than conventionally cast alloys. Work carried out as part of a research program aimed at the development of constitutive equations to describe the elevated temperature stress-strain-time behavior of single crystal and directionally solidified turbine blade superalloys is discussed. The program involves both development of suitable constitutive models and their verification through elevated temperature tension-torsion testing of single crystals of PWA 1480.

Jordan, E. H.↗

Results from a study of scintillation behavior at 12, 20, and 30 GHz using the results from the Virginia Tech Olympus receivers

Tropospheric scintillations are rapid fluctuations of signal caused by multiple scattering from the small scale turbulent refractive index inhomogeneities in the troposphere. They can strongly impair satellite communications links operating at frequency above 10 GHz. The VA Tech OLYMPUS propagation experiment which includes 12, 20, and 30 GHz beacon receivers at an elevation angle of 14 degrees provides us with valuable multifrequency scintillation data. A long term analysis of tropospheric scintillation results from the VA Tech OLYMPUS experiment is presented. It includes statistics of both the scintillation intensity and the attenuation relative to clear air as well as seasonal, diurnal and meteorological trends. A comparison with the Consultative Committee for International Radio (CCIR) predictive model for scintillation fading is presented.

Pratt, Timothy↗

Airborne detection of oceanic turbidity cell structure using depth-resolved laser-induced water Raman backscatter

Airborne laser-induced, depth-resolved water Raman backscatter is useful in the detection and mapping of water optical transmission variations. This test, together with other field experiments, has identified the need for additional field experiments to resolve the degree of the contribution to the depth-resolved, Raman-backscattered signal waveform that is due to (1) sea surface height or elevation probability density; (2) off-nadir laser beam angle relative to the mean sea surface; and (3) the Gelbstoff fluorescence background, and the analytical techniques required to remove it. When converted to along-track profiles, the waveforms obtained reveal cells of a decreased Raman backscatter superimposed on an overall trend of monotonically decreasing water column optical transmission.

Hoge, F. E.↗

Using Relative Position and Temporal Judgments to Assess the Effects of Texture and Field of View on Spatial Awareness for Synthetic Vision Systems Displays

Synthetic Vision Systems (SVS) depict computer generated views of terrain surrounding an aircraft. In the assessment of textures and field of view (FOV) for SVS, no studies have directly measured the 3 levels of spatial awareness: identification of terrain, its relative spatial location, and its relative temporal location. This work introduced spatial awareness measures and used them to evaluate texture and FOV in SVS displays. Eighteen pilots made 4 judgments (relative angle, distance, height, and abeam time) regarding the location of terrain points displayed in 112 5-second, non-interactive simulations of a SVS heads down display. Texture produced significant main effects and trends for the magnitude of error in the relative distance, angle, and abeam time judgments. FOV was significant for the directional magnitude of error in the relative distance, angle, and height judgments. Pilots also provided subjective terrain awareness ratings that were compared with the judgment based measures. The study found that elevation fishnet, photo fishnet, and photo elevation fishnet textures best supported spatial awareness for both the judgments and the subjective awareness measures.

Bolton, Matthew L.↗

Zero-Boil-Off Tank (ZBOT) Experiment: Ground-Based Validation of Self-Pressurization and Pressure Control Two-Phase CFD Model

Integral to all phases of NASA's projected space and planetary expeditions is affordable and reliable cryogenic fluid storage for use in propellant or life support systems. Cryogen vaporization due to heat leaks into the tank from its surroundings and support structure can cause self-pressurization relieved through venting. This has led to a desire to develop innovative pressure control designs based on mixing of the bulk tank fluid together with some form of active or passive cooling to allow storage of the cryogenic fluid with zero or reduced boil-off. The Zero-Boil-Off Tank (ZBOT) Experiments are a series of small scale tank pressurization and pressure control experiments aboard the International Space Station (ISS) that use a transparent volatile simulant fluid in a transparent sealed tank to delineate various fundamental fluid flow, heat and mass transport, and phase change phenomena that control storage tank pressurization and pressure control in microgravity. The hardware for ZBOT-1 flew to ISS on the OA-7 flight in April 2017 and operations are planned to begin in September 2017, encompassing more than 90 tests. This paper presents preliminary results from ZBOT's ground-based research delineating both pressurization and pressure reduction trends in the sealed test tank. Tank self-pressurization tests are conducted under three modes: VJ heating, strip heating and simultaneous VJ and strip heating in attempt to simulate heat leaks from the environment, the support structure and both. The jet mixing pressure control studies are performed either from an elevated uniform temperature condition or from thermally stratified conditions following a self-pressurization run. Jet flow rates are varied from 2-25 cm/s spanning a range of jet Re number in laminar, transitional, and turbulent regimes and a range of Weber numbers covering no ullage penetration, partial penetration and complete ullage penetration and break-up (only in microgravity). Numerical prediction of a two-phase CFD model are compared to experimental 1g results to both validate the model and also indicate the effect of the residual non-condensable gas on evolution of pressure and temperature distributions in the tank during pressurization and pressure control.

microgravity evaporation condensatio↗

The sources and diurnal variations of submicron aerosols in a coastal–rural environment near Houston, US

Aerosol properties were characterized at a rural site southwest of Houston from May to September 2022 during the intensive operation periods (IOPs) of the Tracking Aerosol Convection Interactions ExpeRiment (TRACER). Backward trajectory analysis reveals three major air mass types: marine air mass from the Gulf, urban air mass influenced by urban emissions, and regional air mass. Marine aerosols typically show a bimodal size distribution and have the lowest particle number and mass concentrations of PM 1 (particulate matter with an aerodynamic diameter of less than 1 µm), while aerosols from air masses strongly influenced by urban emissions exhibit the highest concentrations. Organic aerosol (OA) accounts for more than 50 % of PM 1 for urban and regional air masses, whereas sulfate is comparable to OA in marine air masses. Positive matrix factorization (PMF) analysis of aerosol mass spectra identifies 6 OA factors: hydrocarbon-like OA (HOA), OA from the oxidation of monoterpenes (MT-SOA), OA from the reactive uptake of isoprene epoxydiols by acidic sulfate particles (isoprene-SOA), oxygenated OA arising from shipping emissions (shipping-OOA), and two oxygenated OA factors with high O : C ratios (OOA1 and OOA2). OOA2 has the highest O : C ratio and exhibits elevated mass concentration in the afternoon. Similar diurnal variation of highly oxidized OA factors was commonly observed in the Houston area during previous studies and attributed to the SOA formation by photochemistry and mixing from aloft. Here, using air mass backward trajectories and a 1-D box model, we show the diurnal trend of OOA2 mass concentration is instead driven by changes in air mass arriving at the rural site. The air mass changes are likely caused by the shift between land breezes and sea/bay breezes. Within the same air mass type (e.g., either urban or marine air mass), OOA2 mass concentration is largely independent of wind direction and shows essentially no diurnal variation, suggesting OOA2 is related to aged OA with minimal influence by local emissions. This study helps identify the major sources of OA in the Houston region and highlights the impacts of both atmospheric chemistry and meteorology on aerosol properties in the coastal–rural environment.

54 ENVIRONMENTAL SCIENCES↗

Regional Rates of Young US Forest Growth Estimated From Annual Landsat Disturbance History and IKONOS Stereo Imagery

Forests of the Contiguous United States (CONUS) have been found to be a large contributor to the global atmospheric carbon sink. The magnitude and nature of this sink is still uncertain and recent studies have sought to define the dynamics that control its strength and longevity. The Landsat series of satellites has been a vital resource to understand the long-term changes in land cover that can impact ecosystem function and terrestrial carbonstock. We combine annual Landsat forest disturbance history from 1985 to 2011 with single date IKONOS stereoimagery to estimate the change in young forest canopy height and above ground live dry biomass accumulation for selected sites in the CONUS. Our approach follows an approximately linear growth rate following clearing over short intervals and does not estimate the distinct non-linear growth rate over longer intervals.We produced canopy height models by differencing digital surface models estimated from IKONOS stereo pairs with national elevation data (NED). Correlations between height and biomass were established independently using airborne LiDAR, and then applied to the IKONOS-estimated canopy height models. Graphing current biomass against time since disturbance provided biomass accumulation rates. For 20 study sites distributed across five regions of the CONUS, 19 showed statistically significant recovery trends (p is less than 0.001) with canopy growth from 0.26 m yr-1to 0.73 m yr-1. Above ground live dry biomass (AGB) density accumulation ranged from 1.31 t/ha yr-1 to 12.47 t/ha yr-1. Mean forest AGB accumulationwas 6.31 t/ha yr-1 among all sites with significant growth trends. We evaluated the accuracy of our estimates by comparing to field estimated site index curves of growth, airborne LiDAR data, and independent model predictions of C accumulation. Growth estimates found with this approach are consistent with site index curves and total biomass estimates fall within the range of field estimates. This is aviable approach to estimate forest biomass accumulation in regions with clear-cut harvest disturbances.

Neigh, Christopher S. R.↗