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At least 181 records · Page 10

Cyclic Injection Leads to Larger and More Frequent Induced Earthquakes under Volume-Controlled Conditions

As carbon storage technologies advance globally, methods to understand and mitigate induced earthquakes become increasingly important. Although the physical processes that relate increased subsurface pore pressure changes to induced earthquakes have long been known, reliable methods to forecast and control induced seismic sequences remain elusive. Suggested reservoir engineering scenarios for mitigating induced earthquakes typically involve modulation of the injection rate. Some operators have implemented periodic shutdowns (i.e., effective cycling of injection rates) to allow reservoir pressures to equilibrate (e.g., Paradox Valley) or shut-in wells after the occurrence of an event of concern (e.g., Basel, Switzerland). Other proposed scenarios include altering injection rates, actively managing pressures through coproduction of fluids, and preinjection brine extraction. Here, in this work, we use 3D physics-based earthquake simulations to understand the effects of different injection scenarios on induced earthquake rates, maximum event magnitudes, and postinjection seismicity. For comparability, the modeled injection considers the same cumulative volume over the project’s operational life but varies the schedule and rates of fluid injected. Simulation results show that cyclic injection leads to more frequent and larger events than constant injection. Furthermore, with intermittent injection scenario, a significant number of events are shown to occur during pauses in injection, and the seismicity rate remains elevated for longer into the postinjection phase compared to the constant injection scenario.

58 GEOSCIENCES↗

NGNP Program 2013 Status and Path Forward

High temperature gas-cooled reactor (HTGR) technology can play an important role in the energy future of the United States by extending the use of nuclear energy for non-electricity energy production missions, as well as continuing to provide a considerable base load electric power generation capability. Extending nuclear energy into the industrial and transportation sectors through the coproduction of process heat and electricity provides safe, reliable energy for these sectors in an environmentally responsible manner. The modular HTGR provides a substantial improvement in nuclear plant safety for the protection of the public and the environment, and supports collocation of the HTGRhigh temperature gas-cooled reactor with major industrial facilities. Under U.S. Department of Energy direction since 2006, the Next Generation Nuclear Plant Project at Idaho National Laboratory has been working toward commercializing the HTGR technology. However, a recent decision by the Secretary of Energy to reduce the scope of the Next Generation Nuclear Plant Project to a research and development program, considerable realignment has taken place. This report: (1) summarizes the accomplishments of the Next Generation Nuclear Plant Program from FY2011 through FY2013; (2) lays out the path forward necessary to achieve the ultimate objective of commercializing HTGR technology; and (3) discusses ongoing technical, licensing, and evaluation activities under the realigned Next Generation Nuclear Plant program considered important to preserve the significant investment made by the government to-date and to maintain some progress in meeting the objectives of the Energy Policy Act of 2005 (EPAct2005).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Process Design and Economics for the Conversion of Algal Biomass to Biofuels: Algal Biomass Fractionation to Lipid- and Carbohydrate-Derived Fuel Products

Beginning in 2013, NREL began transitioning from the singular focus on ethanol to a broad slate of products and conversion pathways, ultimately to establish similar benchmarking and targeting efforts. One of these pathways is the conversion of algal biomass to fuels via extraction of lipids (and potentially other components), termed the 'algal lipid upgrading' or ALU pathway. This report describes in detail one potential ALU approach based on a biochemical processing strategy to selectively recover and convert select algal biomass components to fuels, namely carbohydrates to ethanol and lipids to a renewable diesel blendstock (RDB) product. The overarching process design converts algal biomass delivered from upstream cultivation and dewatering (outside the present scope) to ethanol, RDB, and minor coproducts, using dilute-acid pretreatment, fermentation, lipid extraction, and hydrotreating.

09 BIOMASS FUELS↗

National Alliance for Advanced Biofuels and Bio-Products Final Technical Report

The main objective of NAABB was to combine science, technology, and engineering expertise from across the nation to break down critical technical barriers to commercialization of algae-based biofuels. The approach was to address technology development across the entire value chain of algal biofuels production, from selection of strains to cultivation, harvesting, extraction, fuel conversion, and agricultural coproduct production. Sustainable practices and financial feasibility assessments ununderscored the approach and drove the technology development.

09 BIOMASS FUELS↗

Recovery Act: Alpena Biorefinery and Alpena Biorefinery Lignin Separation Final Technical Report

The Alpena Biorefinery (AB) was constructed in Alpena, Michigan, at the Decorative Panels International hardboard manufacturing facility. The goal of the AB was to demonstrate a modular, technically successful, and financially viable process of making cellulosic ethanol from woody biomass extract at wood processing facilities. At full capacity, the AB can produce 894,200 gallons per year of cellulosic ethanol and 696,000 gallons per year of aqueous potassium acetate, using extract from northern hardwood and aspen woodchips feedstock. The project objectives and the value proposition of AB promote the national goals of energy independence, greenhouse gas reduction, and green job creation and retention. A successful outcome of the Alpena Biorefinery project has been commercial sales of the first ever cellulosic ethanol RINS generated from woody biomass in the US, under the EPA’s Renewable Fuels Standard Program. We believe that American Process is also likely the first company in the world to produce commercial quantities of cellulosic ethanol from mixed forest residue. Life Cycle Analysis performed by Michigan Institute of Technology found that the entire life cycle greenhouse gas emissions from the plant’s cellulosic ethanol were only 25 percent that of petroleum-based gasoline. They found the potassium acetate runway de-icer coproduct generates up to 45 percent less greenhouse gases than the production of conventional potassium acetate. The Alpena Biorefinery project created 31 permanent jobs for direct employees and helped retain 200 jobs associated with the existing Decorative Panels International facility, by increasing its economic viability through significant savings in waste water treatment costs. The AB project has been declared a Michigan Center of Energy Excellence and was awarded a $4 million State of Michigan grant. The project also received New Market Tax Credit financing for locating in an economically distressed community. All other equity funds were contributed by American Process Inc. The facility will remain operational after the demonstration period. It will also be available as a pilot-plant “for hire,” where third parties can perform trials on emerging biorefinery technologies. Additional capital projects are underway outside of the scope of DOE project.

09 BIOMASS FUELS↗

MidSouth/Southeast BioEnergy Consortium DE-FG3608GO88036 Final Report

GO88036 project was conducted at three universities: Arkansas State University, University of Arkansas and University of Georgia from 2009 to 2012, and University of Arkansas from 2012 to 2014. The funds were used at all three universities to build capacity: 1) infrastructure, such as purchase of laboratory equipment and laboratory set-up; and, 2) agronomic capabilities, including the establishment of field trials and acquisition of harvesting equipment. This infrastructure was critical to ramping bioenergy activities at all three universities. Thermochemical and biochemical conversion were investigated; algal, woody, annual and perennial herbaceous energy crops were established and monitored; educational and outreach events were organized; co-product production and extraction were investigated; and, the nutritional qualities of biorefinery coproducts were evaluated. Funding from this project enabled 15 graduate students to submit PhD or MSc level theses; publication of one book and six book chapters; generation of 19 published abstracts; production of three lay press articles; and, dissemination of 31 peer-reviewed articles in good quality scientific journals.

09 BIOMASS FUELS↗

2017 Algae Harmonization Study: Evaluating the Potential for Future Algal Biofuel Costs, Sustainability, and Resource Assessment from Harmonized Modeling

To present a more unified picture of the long-term future potential for algal biofuels and the goals that must be met to reach that potential, four algae modeling groups collaborated to harmonize respective models for resource assessment (Pacific Northwest National Laboratory), techno-economic analysis (National Renewable Energy Laboratory and Pacific Northwest National Laboratory), and life-cycle analysis (Argonne National Laboratory) of algal biomass production and conversion processes. In contrast to prior harmonization studies that this group has previously conducted, which focused on establishing benchmarks attributed to current performance at the time, the primary intent of the present harmonization study was to project these models to forward-looking targets that must be achieved to reduce fuel costs and greenhouse gas emission profiles to Bioenergy Technologies Office target levels, subject to specific location constraints imposed by resource assessment modeling and thus national-scale fuel output potential (i.e., billion gallons gasoline equivalent per year, or BGGE/yr). In all, while based on a number of aspirational goals not yet demonstrated but plausible to achieve over coming years, the harmonized outputs indicate promising potential for algal biofuels to make a significant contribution to the U.S. fuels market, based on substantial quantities of biomass (104-235 MM tons/yr) projected to be available at costs below 700/ton (generally below 500/ton for freshwater cultivation). While these costs are still significantly higher than terrestrial biomass cost targets, the propensity for capturing high fuel yields and/or high-value tailored coproducts from algal biomass is shown here to provide plausible paths to achieve future targets for cost and sustainability metrics at meaningful volumes.

09 BIOMASS FUELS↗

γ-Valerolactone-Extracted Lignin to Porous Carbon Materials

Synthesis of multiphase materials from lignin, a biorefinery coproduct, offers limited success due to the inherent difficulty in controlling dispersion of these renewable hyperbranched macromolecules in the product or its intermediates. Effective use of the chemically reactive functionalities in lignin, however, enables tuning morphologies of the materials. Here, we bind a lignin oligomer with a rubbery macromolecule followed by thermal crosslinking to form a carbon precursor with phase contrasted morphology at submicron scale. The solvent-free mixing is conducted in a high-shear melt-mixer. With this, the carbon precursor is further modified with potassium hydroxide for a single-step carbonization to yield activated carbon with tunable pore structure. A typical precursor with 90% lignin yields porous carbon with 2120 m 2 /g surface area and a supercapacitor with 215 F/g capacitance. The results show a simple route towards manufacturing carbon-based energy-storage materials, eliminating the need for conventional template-synthesis.

36 MATERIALS SCIENCE↗

Development of a Sustainable Green Chemistry Platform for Production of Acetone and Downstream Drop-in Fuel and Commodity Products Directly From Biomass Syngas Via a Novel Energy Conserving Route in Engineered Acetogenic Bacteria

LanzaTech and Oak Ridge National Laboratory have developed and scaled up a process for sustainable production of acetone and downstream drop-in fuel and commodity products directly from biomass syngas via a novel energy conserving route in engineered acetogenic bacteria. This process offers a safer and more environmentally-friendly production method for acetone production than the current phenol-dependent method, and the product has significantly lower GHG emissions. The developed process offers a cost competitive route to Acetone and enables biofuels at or below DOE’s $3 gge target. In addition, it also provides an attractive biological alternative to traditional sugar-based ABE fermentation, by enabling utilization of non-food biomass resources as fermentation feedstocks. Challenges overcome: • By-products formation: Byproduct 2,3-butandiol and 3-hydroxybutyrate reduce yield and stability. Addressed by elimination of both pathways in our chassis acetone production strain. • Cost competitiveness: Addressed by developing an integrated acetone strain and eliminating by-products to increase yield and stability. Optimized co-selectivity and coproductivity of acetone and ethanol instead of titer, based on technoeconomic analysis. • Limited enzyme variety: Addressed by genome mining of over 300 industrial strains in LanzaTech collection, identifying unique enzyme sequences, and refactoring these unique enzyme variants through LanzaTech’s engineering platform. Resulted in over 10x improvement in acetone production from gas. • Continuous process (stability): Identified bottleneck through detailed omics studies, addressed by integration of the acetone pathway on the chromosome. • Novel process to scale up: Addressed by demonstrating stable acetone production in a 80- L pilot reactor, with acetone productivity and selectivity comparable to those observed under the same conditions in 2-L reactors. We have demonstrated stable acetone production for over 7 days at commercial target rate and selectivity in 2-L reactors and have piloted the process.

09 BIOMASS FUELS↗

Energy and Water Sustainability in the U.S. Biofuel Industry

In 2018, Argonne National Laboratory, with support from the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Bioenergy Technologies Office, conducted a survey of biofuel producers in the United States. The survey covered a full range of plant operation parameters, including plant capacity, feedstock, product, production volume, coproducts, water resources, water treatment, water usage, wastewater management, and process fuel and electricity consumption, as reflected in 2017 plant operation data. This report presents the most up-to-date analysis of commercial-scale plants in the U.S., including facilities producing fuels from both starch and cellulosic materials. This is the first survey that includes the comprehensive recording of water resources, water use, and water and wastewater management for the U.S. biofuel industry at the facility level. Data presented in this study reflect primarily information on full-scale ethanol production from dry mills that was available at the time of survey. Results highlight the complexity of energy and water resource use in process steps and the role of water conservation, recycling, and reuse in advancing the production of biofuel and its contribution to the bioeconomy and the FEW nexus.

09 BIOMASS FUELS↗

Algal Biomass Conversion to Fuels via Combined Algae Processing (CAP): 2019 State of Technology and Future Research

NREL’s algae state of technology benchmarking efforts focus both on front-end algal biomass production and separately on back-end conversion to fuels through NREL’s “combined algae processing” (CAP) pathway. The production model is based on outdoor long-term cultivation data, enabled by comprehensive algal biomass production trials conducted under the Development of Integrated Screening, Cultivar Optimization, and Verification Research consortium (DISCOVR) efforts, driven by data furnished by Arizona State University (ASU) at the Arizona Center for Algae Technology and Innovation (AzCATI) testbed site. The CAP model is based on experimental efforts conducted under NREL research and development projects. This report focuses on back-end conversion of algal biomass through the CAP pathway, highlighting the 2019 updates to minimum fuel selling price (MFSP). This milestone reports on key process sustainability indicators for the CAP conversion stage including mass and carbon yields to fuels and coproducts, freshwater consumption, and facility power balances/natural gas demands.

09 BIOMASS FUELS↗

Development of Algal Biomass Yield Improvements in an Integrated Process (Final Report)

This project built on the success of Global Algae Innovations Algae Biomass Yield Phase 1 project to accelerate the commercialization of algal biofuels through development of an integrated, economical, photosynthetic, open raceway system to produce algal oil. Two parallel pathways to a biofuel were investigated. In the algal crude oil pathway, highlighted in blue, the dewatered algal biomass slurry is used as a feed to hydrothermal liquefaction to produce an algae crude oil and recycle aqueous stream. In the algal lipid oil pathway, highlighted in green, the algal biomass slurry is dried, and the oil is extracted to produce an algal lipid oil biofuel intermediate and a high protein algae meal co-product. Upgrading to drop-in fuels has been demonstrated for the biofuel intermediates in both pathways. Since the algal lipid oil pathway requires lipid accumulation, the productivity is generally lower than the algal crude oil pathway, but the required productivity for economical algal biofuel production is also lower because the coproduct value is greater. The outdoor cultivation was performed at the Kauai Algae Farm. The project team has expertise across the full breadth strain development, advanced algal cultivation, open raceway contamination control, CO 2 supply, harvesting, dewatering, extraction, hydrothermal liquefaction, technoeconomic analysis and life cycle analysis: Hildebrand laboratory at Scripps Institution of Oceanography – diatom strain development. Mayfield laboratory at UCSD - green algae strain development. TSD Management Associates- CO 2 supply, algal harvesting and dewatering, and algal drying and extraction. Qualitas - large-scale test site for algal harvesting technology. Texas A&M University - algal drying and extraction technology. Pacific Northwest National Laboratory - hydrothermal liquefaction technology. GE Water and Power - membrane technology. National Renewable Energy Laboratory - algal techno-economic analysis. Phase 1 of the project resulted in tremendous productivity and pre-processing improvements in an integrated, large-scale, low-cost cultivation and pre-processing process that moved algal technology closer to economic viability for biofuels than ever before. Phase 2 accomplishments further facilitate development of a commercial algal biofuel industry by adding: several top performing strains and strain development tools including breeding; open-pond cultivation innovations that achieved a 30% improvement in overall productivity, an 83% reduction in cost, and a 95% reduction in energy use relative to conventional technology; further improvements in harvesting that led to the Zobi harvester ® as a universal, economical, low energy, commercially available microalgae harvesting solution; breakthroughs in drying and extraction including a new low energy drying process and several new low energy extraction unit operations that together with the Zobi harvester ® achieve a 90% reduction in cost and 97% reduction in energy use relative to conventional technology. These improvements are sufficient to enable economical production of algae biofuel and protein meal co-product if the process were scaled up to a commercial-scale 5,000-acre algae farm.

09 BIOMASS FUELS↗

Algal Biomass Conversion to Fuels via Combined Algae Processing (CAP): 2020 State of Technology and Future Research

The annual State of Technology (SOT) assessment is an essential activity for platform research conducted under the Bioenergy Technologies Office. It allows for the impact of research progress to be quantified in terms of economic improvements in the overall biofuel production process for a particular biomass processing pathway, whether based on terrestrial or algal biomass feedstocks. As such, initial benchmarks can be established for currently demonstrated performance, and progress can be tracked towards out-year goals to ultimately demonstrate economically viable biofuel technologies. NREL's algae state of technology benchmarking efforts focus both on front-end algal biomass production and separately on back-end conversion to fuels through NREL's "combined algae processing" (CAP) pathway. The production model is based on outdoor long-term cultivation data, enabled by comprehensive algal biomass production trials conducted under the Development of Integrated Screening, Cultivar Optimization, and Verification Research consortium (DISCOVR) efforts, driven by data furnished by Arizona State University (ASU) at the Arizona Center for Algae Technology and Innovation (AzCATI) testbed site. The CAP model is based on experimental efforts conducted under NREL research and development projects. This report focuses on back-end conversion of algal biomass through the CAP pathway, highlighting the 2020 updates to minimum fuel selling price (MFSP). Notably, this analysis marks the first time that polyurethane (PU) is included as a value-added coproduct in the SOT case. Relative to prior 2019 benchmarks, the 2020 CAP SOT achieved further MFSP reductions of over $4/gallon gasoline equivalent, reflective of (a) the inclusion of PU co-production, (b) reduced SOT biomass production costs, and (c) higher pretreatment sugar yield data.

09 BIOMASS FUELS↗

Algal Biomass Conversion to Fuels via Combined Algae Processing (CAP) (2021 State of Technology and Future Research)

The annual State of Technology (SOT) assessment is an essential activity for platform research conducted under the Bioenergy Technologies Office. It allows for the impact of research progress to be quantified in terms of economic improvements in the overall biofuel production process for a particular biomass processing pathway, whether based on terrestrial or algal biomass feedstocks. As such, initial benchmarks can be established for currently demonstrated performance, and progress can be tracked towards out-year goals to ultimately demonstrate economically viable biofuel technologies. NREL's algae state of technology benchmarking efforts focus both on front-end algal biomass production and separately on back-end conversion to fuels through NREL's "combined algae processing" (CAP) pathway. The production model is based on outdoor long-term cultivation data, enabled by comprehensive algal biomass production trials conducted under the Development of Integrated Screening, Cultivar Optimization, and Verification Research consortium (DISCOVR) efforts, driven by data furnished by Arizona State University (ASU) at the Arizona Center for Algae Technology and Innovation (AzCATI) testbed site. The CAP model is based on experimental efforts conducted under NREL research and development projects. This report focuses on back-end conversion of algal biomass through the CAP pathway, highlighting the 2021 updates to minimum fuel selling price (MFSP). This update maintains an important recent inclusion of polyurethane (PU) previously incorporated in the 2020 SOT as a value-added coproduct. Relative to the 2020 SOT case, this indicates a minimal increase of $0.10-$0.14/GGE (roughly 2%) for both the acids and BDO pathways, attributed to minimal increases in upstream algal biomass costs from slightly lower demonstrated cultivation productivities in the 2021 SOT.

09 BIOMASS FUELS↗

2023 Billion-Ton Report: An Assessment of U.S. Renewable Carbon Resources - Microalgae

Microalgae is a unique biomass resource that does not need to compete for land and water with other biomass feedstocks because it can be cultivated on low-quality unencumbered land using noncompetitive water types including saline and wastewater. It is included as a complementary resource alongside other biomass feedstocks reported in this study, albeit at higher biomass production costs reflective of more capital-intensive farming operations than typical for terrestrial biomass. Higher biomass costs can be offset by the potential to produce value-added coproducts unique to compositional constituents of microalgae. Relative to the 2016 Billion-Ton Report, this chapter reflects the latest analysis from the 2022 Algae Harmonization Update, which uses the latest parameterized and high-performing saline algal strain, second-generation carbon capture of point-source waste CO 2 , and high-pressure pipeline transport resolved to specific point-source types, saline water sourcing up to 40,000 mg/L total dissolved solids for source and makeup water salinity, blowdown water treatment and recycle, and brine disposal handling. National-scale algal biomass availability potential was calculated at 152 million tons/yr ash-free dry weight (AFDW) (191 million tons/yr dry weight) at an average biomass

09 BIOMASS FUELS↗

Chapter 7.1: Microalgae

Microalgae is a unique biomass resource that does not need to compete for land and water with other biomass feedstocks because it can be cultivated on low-quality unencumbered land using noncompetitive water types including saline and wastewater. It is included as a complementary resource alongside other biomass feedstocks reported in this study, albeit at higher biomass production costs reflective of more capital-intensive farming operations than typical for terrestrial biomass. Higher biomass costs can be offset by the potential to produce value-added coproducts unique to compositional constituents of microalgae. Relative to BT16, this chapter reflects the latest analysis from the 2022 Algae Harmonization Update, which uses the latest parameterized and high-performing saline algal strain, second-generation carbon capture of point-source waste CO2 and high-pressure pipeline transport resolved to specific point-source types, saline water sourcing up to 40,000 mg/L total dissolved solids for source and makeup water salinity, blowdown water treatment and recycle, and brine disposal handling. National-scale algal biomass availability potential was calculated at 152 million tons/yr ash-free dry weight (AFDW) (191 million tons/yr dry weight) at an average biomass productivity of 26.2 g/m2 -day AFDW (about 50 tons/acre/yr dry weight).1 The algal biomass was cultivated on 3.9 million acres of multi-criteria screened and potentially available land for CONUS and fixed 268 million tons of waste CO2 based on biomass uptake. The algae biomass can be produced at an average MBSP of $674/ton AFDW ($536/ton dry weight) in 2020 dollars,2 corresponding to a total energy potential of 3.3 quads/yr at an average MBSP of $31.2/MMBtu (higher-heating-value [HHV] basis).

algae↗

Diverse Profile of Fermentation Byproducts From Thin Stillage

The economy of biorefineries is influenced not only by biofuel production from carbohydrates but also by the production of valuable compounds from largely underutilized industrial residues. Currently, the demand for many chemicals that could be made in a biorefinery, such as succinic acid (SA), medium-chain fatty acids (MCFAs), and lactic acid (LA), is fulfilled using petroleum, palm oil, or pure carbohydrates as raw materials, respectively. Thin stillage (TS), the residual liquid material following distillation of ethanol, is an underutilized coproduct from the starch biofuel industry. This carbon-rich material has the potential for chemical upgrading by microorganisms. Here, we explored the formation of different fermentation products by microbial communities grown on TS using different bioreactor conditions. At the baseline operational condition (6-day retention time, pH 5.5, 35°C), we observed a mixture of MCFAs as the principal fermentation products. Operation of a bioreactor with a 1-day retention time induced an increase in SA production, and a temperature increase to 55°C resulted in the accumulation of lactic and propionic acids. In addition, a reactor operated with a 1-day retention time at 55°C conditions resulted in LA accumulation as the main fermentation product. The prominent members of the microbial community in each reactor were assessed by 16S rRNA gene amplicon sequencing and phylogenetic analysis. Under all operating conditions, members of the Lactobacillaceae family within Firmicutes and the Acetobacteraceae family within Proteobacteria were ubiquitous. Members of the Prevotellaceae family within Bacteroidetes and Lachnospiraceae family within the Clostridiales order of Firmicutes were mostly abundant at 35°C and not abundant in the microbial communities of the TS reactors incubated at 55°C. The ability to adjust bioreactor operating conditions to select for microbial communities with different fermentation product profiles offers new strategies to explore and compare potentially valuable fermentation products from TS and allows industries the flexibility to adapt and switch chemical production based on market prices and demands.

59 BASIC BIOLOGICAL SCIENCES↗

Hot Water Extraction Improves the Characteristics of Willow and Sugar Maple Biomass With Different Amount of Bark

Shrub willows are being developed as a short rotation woody crop (SRWC) that can grow on marginal agricultural land. Willow has a high net energy ratio (energy produced/ fossil fuel energy consumed), low greenhouse gas footprint and high carbohydrate production potential. Willow biomass can be combined with forest biomass, but willow often has a higher proportion of bark that creates challenges because it increases the ash content and decreases the melting point. Hot water extraction is a pretreatment that has been shown to improve the quality of chipped material while producing a marketable stream of byproducts. This study evaluated how the amount of bark (0%, 33%, 66% and 100%) on three willow cultivars and sugar maple impact the output of hot water extraction in terms of mass removal and extract composition, as well as its influence on the heating value, ash and elemental content. The hot water extraction process resulted in ash content up to 50% for sugar maple and willow, but there was variation among the willow varieties. The heating value after hot water extraction was about 5% higher because of the removal of mostly hemicelluloses, which have relatively low heating value. HWE led to significant reductions of calcium, potassium, magnesium and sulfur contents. The hot water extraction provides a fermentable sugar stream and other coproducts after multiple separation and treatment steps, and improves the characteristics of willow and sugar maple biomass for combined heat and power. This paper demonstrates how biomass with higher bark content can generate a useable sugar stream while improving the quality of the biomass for combined heat and power by managing its ash content while simultaneously producing other valuable products.

09 BIOMASS FUELS↗