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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Mesopore differences between pillared lamellar MFI and MWW zeolites probed by atomic layer deposition of titania and consequences on photocatalysis

The pillared MWW (PMWW or MCM-36) and pillared MFI (PMFI) are two prominent representatives of meso-/microporous lamellar zeolites, which are made by pillaring of layered MCM-22(P) and multilamellar MFI precursors, respectively. They both consist of a 10-membered ring sinusoidal micropore channel within each zeolitic layer and mesopore voids created by pillars between two adjacent zeolitic layers. Although catalytic activities of PMWW and PMFI have been compared, identification of mesopore differences between these two pillared lamellar zeolites has not been attempted. In this work, we report the differences in mesopore characteristics between PMWW and PMFI zeolites probed by atomic layer deposition (ALD) of titania (ALD-TiO2) species and a combination of structural, textural, composition and catalytic property analyses of the samples before and after ALD treatment, respectively. The results suggest PMFI has cylindrical mesopores with uniform sizes from pore entrance to main body, while PMWW has ink-bottle mesopores with the neck size much smaller than pore body. The communication between micropore and mesopore in PMFI is direct, but no communication exists in PMWW zeolites. Here, the ALD-TiO 2 process considerably modified external surface composition of PMFI and PMWW zeolites, which consequently led to a new application of the pillared lamellar zeolite materials, i.e., photo-catalytically active meso-/microporous zeolites for environmental remedy reactions.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Consequences of neglecting the interannual variability of the solar resource: A case study of photovoltaic power among the Hawaiian Islands

The interannual variability of the solar irradiance and meteorological conditions are often ignored in favor of single-year data sets for modeling power generation and evaluating the economic value of photovoltaic (PV) power systems. Yet interannual variability significantly impacts the generation from one year to another of renewable power systems such as wind and PV. Consequently, the interannual variability of power generation corresponds to the interannual variability of capital returns on investment. The penetration of PV systems within the Hawaiian Electric Companies' portfolio has rapidly accelerated in recent years and is expected to continue to increase given the state's energy objectives laid out by the Hawaii Clean Energy Initiative. We use the National Solar Radiation Database (1998-2015) to characterize the interannual variability of the solar irradiance and meteorological conditions across the State of Hawaii. These data sets are passed to the National Renewable Energy Laboratory's System Advisory Model (SAM) to calculate an 18-year PV power generation data set to characterize the variability of PV power generation. We calculate the interannual coefficient of variability (COV) for annual average global horizontal irradiance (GHI) on the order of 2% and COV for annual capacity factor on the order of 3% across the Hawaiian archipelago. Regarding the interannual variability of seasonal trends, we calculate the COV for monthly average GHI values on the order of 5% and COV for monthly capacity factor on the order of 10%. We model residential-scale and utility-scale PV systems and calculate the economic returns of each system via the payback period and the net present value. We demonstrate that studies based on single-year data sets for economic evaluations reach conclusions that deviate from the true values realized by accounting for interannual variability.

14 SOLAR ENERGY↗
DOE OSTI2013

Diphenylarsinic acid, a chemical warfare-related neurotoxicant, promotes liver carcinogenesis via activation of aryl hydrocarbon receptor signaling and consequent induction of oxidative DAN damage in rats

Diphenylarsinic acid (DPAA), a chemical warfare-related neurotoxic organic arsenical, is present in the groundwater and soil in some regions of Japan due to illegal dumping after World War II. Inorganic arsenic is carcinogenic in humans and its organic arsenic metabolites are carcinogenic in animal studies, raising serious concerns about the carcinogenicity of DPAA. However, the carcinogenic potential of DPAA has not yet been evaluated. In the present study we found that DPAA significantly enhanced the development of diethylnitrosamine-induced preneoplastic lesions in the liver in a medium-term rat liver carcinogenesis assay. Evaluation of the expression of cytochrome P450 (CYP) enzymes in the liver revealed that DPAA induced the expression of CYP1B1, but not any other CYP1, CYP2, or CYP3 enzymes, suggesting that CYP1B1 might be the enzyme responsible for the metabolic activation of DPAA. We also found increased oxidative DNA damage, possibly due to elevated CYP1B1 expression. Induction of CYP1B1 has generally been linked with the activation of AhR, and we found that DPAA activates the aryl hydrocarbon receptor (AhR). Importantly, the promotion effect of DPAA was observed only at a dose that activated the AhR, suggesting that activation of AhR and consequent induction of AhR target genes and oxidative DNA damage plays a vital role in the promotion effects of DPAA. The present study provides, for the first time, evidence regarding the carcinogenicity of DPAA and indicates the necessity of comprehensive evaluation of its carcinogenic potential using long-term carcinogenicity studies. - Highlights: • DPAA, an environmental neurotoxicant, promotes liver carcinogenesis in rats. • DPAA is an activator of AhR signaling pathway. • DPAA promoted oxidative DNA damage in rat livers. • AhR target gene CYP 1B1 might be involved in the metabolism of DPAA.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2015

Redox cycling of endogenous copper by ferulic acid leads to cellular DNA breakage and consequent cell death: A putative cancer chemotherapy mechanism

Ferulic acid (FA) is a plant polyphenol showing diverse therapeutic effects against cancer, diabetes, cardiovascular and neurodegenerative diseases. FA is a known antioxidant at lower concentrations, however at higher concentrations or in the presence of metal ions such as copper, it may act as a pro-oxidant. It has been reported that copper levels are significantly raised in different malignancies. Cancer cells are under increased oxidative stress as compared to normal cells. Certain therapeutic substances like polyphenols can further increase this oxidative stress and kill cancer cells without affecting the proliferation of normal cells. Through various in vitro experiments we have shown that the pro-oxidant properties of FA are enhanced in the presence of copper. Comet assay demonstrated the ability of FA to cause oxidative DNA breakage in human peripheral lymphocytes which was ameliorated by specific copper-chelating agent such as neocuproine and scavengers of ROS. This suggested the mobilization of endogenous copper in ROS generation and consequent DNA damage. These results were further validated through cytotoxicity experiments involving different cell lines. Thus, we conclude that such a pro-oxidant mechanism involving endogenous copper better explains the anticancer activities of FA. This would be an alternate non-enzymatic, and copper-mediated pathway for the cytotoxic activities of FA where it can selectively target cancer cells with elevated levels of copper and ROS. - Highlights: • Pro-oxidant properties of ferulic acid are enhanced in presence of copper. • Ferulic acid causes oxidative DNA damage in lymphocytes as observed by comet assay. • DNA damage was ameliorated by copper chelating agent neocuproine and ROS scavengers. • Endogenous copper is involved in ROS generation causing DNA damage. • Ferulic acid exerts cancer cell specific cytotoxicity as observed by MTT assay.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2016

Structural and Functional Consequences of Three Cancer-Associated Mutations of the Oncogenic Phosphatase SHP2

The proto-oncogene PTPN11 encodes a cytoplasmic protein tyrosine phosphatase, SHP2, which is required for normal development and sustained activation of the Ras-MAPK signaling pathway. Germline mutations in SHP2 cause developmental disorders, and somatic mutations have been identified in childhood and adult cancers and drive leukemia in mice. Despite our knowledge of the PTPN11 variations associated with pathology, the structural and functional consequences of many disease-associated mutants remain poorly understood. Here, in this paper, we combine X-ray crystallography, small-angle X-ray scattering, and biochemistry to elucidate structural and mechanistic features of three cancer-associated SHP2 variants harboring single point mutations within the N-SH2:PTP interdomain autoinhibitory interface. Our findings directly compare the impact of each mutation on autoinhibition of the phosphatase and advance the development of structure-guided and mutation-specific SHP2 therapies.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2018

Costs and consequences of wind turbine wake effects arising from uncoordinated wind energy development

Optimal wind farm locations require a strong and reliable wind resource and access to transmission lines. As onshore and offshore wind energy grows, preferred locations become saturated with numerous wind farms. An upwind wind farm generates 'wake effects' (decreases in downwind wind speeds) that undermine a downwind wind farm's power generation and revenues. Here we use a diverse set of analysis tools from the atmospheric science, economic and legal communities to assess costs and consequences of these wake effects, focusing on a West Texas case study. We show that although wake effects vary with atmospheric conditions, they are discernible in monthly power production. In stably stratified atmospheric conditions, wakes can extend 50+ km downwind, resulting in economic losses of several million dollars over six years for our case study. However, our investigation of the legal literature shows no legal guidance for protecting existing wind farms from such significant impacts.

17 WIND ENERGY↗
DOE OSTI2015

Metal-only Lewis pairs between group 10 metals and Tl( I ) or Ag( I ): insights into the electronic consequences of Z-type ligand binding

Complexes bearing electron rich transition metal centers, especially those displaying coordinative unsaturation, are well-suited to form reverse-dative σ-interactions with Lewis acids. Herein we demonstrate the generality of zerovalent, group 10 m -terphenyl isocyanide complexes to form reverse-dative σ-interactions to Tl( I ) and Ag( I ) centers. Structural and spectroscopic investigations of these metal-only Lewis pairs (MOLPs) has allowed insight into the electronic consequences of Lewis-acid ligation within the primary coordination sphere of a transition metal center. Treatment of the bis-isocyanide complex, Pt(CNAr Dipp2 ) 2 (Ar Dipp2 = 2,6-(2,6-(i-Pr) 2 C 6 H 3 ) 2 C 6 H 3 ) with TlOTf (OTf = [O 3 SCF 3 ] – ) yields the Pt/Tl MOLP [TlPt(CNAr Dipp2 ) 2 ]OTf ( 1 ). 1 H NMR and IR spectroscopic studies on 1 , and its Pd congener [TlPd(CNAr Dipp2 ) 2 ]OTf ( 2 ), demonstrate that the M → Tl interaction is labile in solution. However, treatment of complexes 1 and 2 with Na[BAr F 4 ] (Ar F = 3,5-(CF 3 ) 2 C 6 H 3 ) produces [TlPt(CNAr Dipp2 ) 2 ]BAr F 4 ( 3 ) and [TlPd(CNAr Dipp2 ) 2 ]BAr F 4 ( 4 ), in which Tl( I ) binding is shown to be static by IR spectroscopy and, in the case of 3 , 195 Pt NMR spectroscopy as well. This result provides strong evidence that the M → Tl linkages can be attributed primarily to σ-donation from the group 10 metal to Tl, as loss of ionic stabilization of Tl by the triflate anion is compensated for by increasing the degree of M → Tl σ-donation. In addition, X-ray Absorption Near-Edge Spectroscopy (XANES) on the Pd/Tl and Ni/Tl MOLPs, [TlPd(CNAr Dipp2 ) 2 ]OTf ( 2 ) and [TlNi(CNAr Mes2 ) 3 ]OTf, respectively, is used to illustrate that the formation of a reverse-dative σ-interaction with Tl( I ) does not alter the spectroscopic oxidation state of the group 10 metal. Also reported is the ability of M(CNAr Dipp2 ) 2 (M = Pt, Pd) to form MOLPs with Ag( I ), yielding the complexes [AgM(CNAr Dipp2 ) 2 ]OTf ( 5 , M = Pt; 6 , M = Pd). As was determined for the Tl-containing MOLPs 1–4 , it is shown that the spectroscopic oxidation states of the group 10 metal in 5 and 6 are essentially unchanged compared to the zerovalent precursors M(CNAr Dipp2 ) 2 . However, in the case of 5 and 6 , the formation of a dative M → Ag σ-bonding interaction facilitates the binding of Lewis bases to the group 10 metal trans to Ag, illustrating the potential of acceptor fragments to open up new coordination sites on transition metal complexes without formal, two-electron oxidation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Influence of system size on the properties of a fluid adsorbed in a nanopore: Physical manifestations and methodological consequences

Hysteresis and discontinuities in the isotherms of a fluid adsorbed in a nanopore in general hamper the determination of equilibrium thermodynamic properties, even in computer simulations. A way around this has been to consider both a reservoir of small size and a pore of small extent in order to restrict the fluctuations of density and approach a classical van der Waals loop. We assess this suggestion by thoroughly studying through Monte Carlo simulations and density functional theory the influence of system size on the equilibrium configurations of the adsorbed fluid and on the resulting isotherms. We stress the importance of pore-symmetry-breaking states that even for modest pore sizes lead to discontinuous isotherms and we discuss the physical relevance of these states and the methodological consequences for computing thermodynamic quantities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Covalency in Fe 2 O 3 and FeO: Consequences for XPS satellite intensity

The covalent character of the interaction between the metal cation and the oxygen ligands has been examined for two Fe oxides with different nominal oxidation states, Fe(II)O, and Fe(III) 2 O 3 . The covalent character is examined for the initial, ground state configuration and for the ionic states involving the removal of a shallow core, Fe 3p, and a deep core, Fe 2p, electron. The covalency is assessed based on novel theoretical analyses of wave functions for the various cases. It is found that the covalency is considerably different for different oxidation states and for different ionized and non-ionized configurations. The changes in covalency for the ions are shown to be responsible for important changes in relaxation energies for X-Ray Photoelectron Spectroscopy (XPS) spectra and in the intensity lost from main XPS peaks to shake satellites. While these consequences are not observables themselves, they are important for the interpretation of the XPS spectra, in particular, for efforts to extract stoichiometries of these iron oxides from XPS data. This is a finding likely applicable across various 3d transition metal oxide materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Electrical, optical, and magnetic properties of amorphous yttrium iron oxide thin films and consequences for non-local resistance measurements

We present magnetic characterization, charge resistivity, and optical photoluminescence measurements on amorphous yttrium iron oxide thin films ( ⁠a-Y–Fe–O), with supporting comparisons to amorphous germanium (⁠ a-Ge) films. We measured magnetic properties with both SQUID magnetometry and polarized neutron reflectometry. These results not only confirm that a-Y–Fe–O is a disordered magnetic material with strong predominantly antiferromagnetic exchange interactions and a high degree of frustration, but also that it is best understood electrically as a disordered semiconductor. As with amorphous germanium, a-Y–Fe–O obeys expectations for variable-range hopping through localized electron states over a wide range of temperature. We also clarify the consequences of charge transport through such a semiconducting medium for non-local voltage measurements intended to probe spin transport in nominally insulating magnetic materials. We further compare non-local resistance measurements made with “quasi-dc” automated current reversal to ac measurements made with a lock-in amplifier. These show that the “quasi-dc” measurement has an effective ac current excitation with frequency up to approximately 22 Hz, and that this effective ac excitation can cause artifacts in these measurements including incorrect sign of the non-local resistance. Here, this comprehensive investigation of non-local resistance measurements in a-Y–Fe–O shows no evidence of spin transport on micrometer length scales, which is contrary to our original work, and in line with more recent investigations by other groups.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Debris-induced consequences on turbulence and vorticity in solar photovoltaic module-generated array wakes

Particle-laden flows in solar photovoltaic (PV) systems are inevitable, where wind-swept debris in open environments are carried by high winds and turbulence, coating panel surfaces or damaging structures. Particle deposition, or soiling, is a well-known issue for large-scale plants which rely on uninhibited solar rays for optimal production. But understanding the mechanisms leading to soiling requires a physical and fluid dynamics-centered focus, since turbulence dominates PV panel wakes and is also known to alter particle concentration and trajectories. This study presents an experimental campaign toward consequences of particle-laden flow between two model PV panels using time-resolved particle image velocimetry. The model array was subjected to varied particle volume fractions, including a tracer particle case and a water droplet case. Characterization of mean velocity, turbulence statistics, and mean kinetic energy within the single phase and, separately, particle phase flows showed modified features due to particle inertia. Images captured at a frequency of 1 kHz in the near wake of the upstream panel allow for a first experimental look at vorticity and convective velocity of vortex structures for single-phase and particle-phase flows which are crucial to debris transport and soiling in PV environments.

Energy & Fuels↗
DOE OSTI2025

Ecosystem consequences of a nitrogen-fixing proto-organelle

Microscale symbioses can be critical to ecosystem functions, but the mechanisms of these interactions in nature are often cryptic. Here, we use a combination of stable isotope imaging and tracing to reveal carbon (C) and nitrogen (N) exchanges among three symbiotic primary producers that fuel a salmon-bearing river food web. Bulk isotope analysis, nanoSIMS (secondary ion mass spectrometry) isotope imaging, and density centrifugation for quantitative stable isotope probing enabled quantification of organism-specific C- and N-fixation rates from the subcellular scale to the ecosystem. After winters with riverbed-scouring floods, the macroalga Cladophora glomerata uses nutrients in spring runoff to grow streamers up to 10 m long. During summer flow recession, riverine N concentrations wane and Cladophora becomes densely epiphytized by three species of Epithemia, diatoms with N-fixing endosymbionts (proto-organelles) descended from a free-living Crocosphaera cyanobacterium. Over summertime epiphyte succession on Cladophora, N-fixation rates increased as Epithemia spp. became dominant, Cladophora C-fixation declined to near zero, and Epithemia C-fixation increased. Carbon transfer to caddisflies grazing on Cladophora with high densities of Epithemia was 10-fold higher than C transfer to caddisflies grazing Cladophora with low Epithemia loads. In response to demand for N, Epithemia allocates high levels of newly fixed C to its endosymbiont. Consequently, these endosymbionts have the highest rates of C and N accumulation of any taxon in this tripartite symbiosis during the biologically productive season and can produce one of the highest areal rates of N-fixation reported in any river ecosystem.

Marks, Jane C. [Northern Arizona Univ., Flagstaff,↗
DOE OSTI2014

North-south asymmetric solar cycle evolution: Signatures in the photosphere and consequences in the corona

The heliospheric current sheet is the continuum of the coronal magnetic equator that divides the heliospheric magnetic field into two sectors (polarities). Several recent studies have shown that the heliospheric current sheet is southward shifted during approximately 3 years in the solar declining phase (the so-called bashful ballerina phenomenon). In this article we study the hemispherical asymmetry in the photospheric and coronal magnetic fields using Wilcox Solar Observatory measurements of the photospheric magnetic field since 1976 as well as the potential field source surface model. Multipole analysis of the photospheric magnetic field shows that during the late declining phase of solar cycles since the 1970s, the 'bashful ballerina phenomenon' is a consequence of the g{sub 2}{sup 0} quadrupole term, signed oppositely to the dipole moment. Surges of new flux transport magnetic field from low latitudes to the poles, thus leading to a systematically varying contribution to the g{sub 2}{sup 0}-term from different latitudes. In the case of a north-south asymmetric flux production, this is seen as a quadrupole contribution traveling toward higher latitudes. When the quadrupole term is largest, the main contribution comes from the polar latitudes. At least during the four recent solar cycles, the g{sub 2}{sup 0}-term arises because the magnitude of the southern polar field is larger than the magnitude found in the north in the declining phase of the cycle. In the heliosphere this hemispheric asymmetry of the coronal fields is seen as a southward shift of the heliospheric current sheet by about 2°.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2023

Quantifying electron cyclotron power deposition broadening in DIII-D and the potential consequences for the ITER EC system

Abstract The injection of electron cyclotron (EC) waves fulfills a number of important tasks in nuclear fusion devices for which detailed knowledge of the spatial power deposition profile is critical. This deposition profile is commonly determined using forward models such as beam or ray tracing. Recent numerical and experimental studies have shown that small-angle scattering of the EC beam as it passes through the turbulent plasma edge can cause significant broadening of the effective deposition profile, leading to considerable underestimation of the deposition width by forward methods. However, traditional inverse methods to determine the deposition profile from measurements overestimate the deposition profile width due to transport broadening. In this work, we implement three novel methods to resolve the EC power deposition profile from measurements that counteract transport broadening by simultaneously resolving transport and power deposition. We validate their assumptions and compare the results from these methods to the traditional break-in-slope method as well as to the TORAY ray-tracing code in a set of DIII-D discharges spanning five different confinement modes. We show that the four different inverse methods, novel and established, paint a consistent picture of deposition broadening. Specifically, we show that the measured power deposition profile is between 1.6 and 3.6 times wider than the TORAY profiles. Moreover, we show the considerable consequences that this level of broadening can have for ITER.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Global economic consequences of deploying bioenergy with carbon capture and storage (BECCS)

Bioenergy with carbon capture and storage (BECCS) is considered a potential source of net negative carbon emissions and, if deployed at sufficient scale, could potentially help reduce carbon dioxide emissions and concentrations. However, the viability and economic consequences of large-scale BECCS deployment are not fully understood. We use the GCAM integrated assessment model to explore the potential global and regional economic impacts of BECCS. BECCS always needs a net subsidy to be deployed; it never produces net tax revenue. We show that by mid-century, in a world committed to limiting climate change to 2°C, carbon tax revenues have peaked and are rapidly approaching the point where climate mitigation is a net burden on general tax revenues. Assuming that the required policy instruments are available to support BECCS deployment, we consider its effects on regional fossil fuels and biomass trade patterns. We find that in a world committed to limiting climate change to 2°C, the absence of CCS harms fossil-fuel exporting regions, while the presence of CCS and BECCS allows greater continued use and export of fossil fuels. We also explore the relationship between carbon prices, food crop prices and BECCS. We show that the carbon price and food-crop prices are directly related. We also show that BECCS reduces the upward pressure on food crop prices exerted by carbon prices due to its effect on lowering carbon prices and lowering the total biomass demand in climate change mitigation scenarios. All of this notwithstanding, many challenges, both technical and institutional, remain to be addressed before BECCS could be deployed at scale.

09 BIOMASS FUELS↗
DOE OSTI2020

Uncertainty Analysis of Consequence Management Data Products

An interlaboratory effort has developed a probabilistic framework to characterize uncertainty in data products that are developed by the US Department of Energy Consequence Management Program in support of the Federal Radiological Monitoring and Assessment Center. The purpose of this paper is to provide an overview of the probability distributions of input variables and the statistical methods used to propagate and quantify the overall uncertainty of the derived response levels that are used as contours on data products due to the uncertainty in input parameters. Uncertainty analysis results are also presented for several study scenarios. This paper includes an example data product to illustrate the potential real-world implications of incorporating uncertainty analysis results into data products that inform protective action decisions. Data product contours that indicate areas where public protection actions may be warranted can be customized to an acceptable level of uncertainty. Finally, the investigators seek feedback from decision makers and the radiological emergency response community to determine how uncertainty information can be used to support the protective action decision-making process and how it can be presented on data products.

61 RADIATION PROTECTION AND DOSIMETRY↗
DOE OSTI2017

Phenomenological consequences of enhanced bulk viscosity near the QCD critical point

In the proximity of the QCD critical point the bulk viscosity of quark-gluon matter is expected to be proportional to nearly the third power of the critical correlation length, and become significantly enhanced. Here, this work is the first attempt to study the phenomenological consequences of enhanced bulk viscosity near the QCD critical point. For this purpose, we implement the expected critical behavior of the bulk viscosity within a non-boost-invariant, longitudinally expanding 1 + 1 dimensional causal relativistic hydrodynamical evolution at nonzero baryon density. We demonstrate that the critically enhanced bulk viscosity induces a substantial nonequilibrium pressure, effectively softening the equation of state, and leads to sizable effects in the flow velocity and single-particle distributions at the freeze-out. In conclusion, the observable effects that may arise due to the enhanced bulk viscosity in the vicinity of the QCD critical point can be used as complementary information to facilitate searches for the QCD critical point.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Cosmological consequences of first-order general-relativistic viscous fluid dynamics

In this work, we investigate the out-of-equilibrium dynamics of viscous fluids in a spatially flat Friedmann-LemaîtreRobertson-Walker cosmology using the most general causal and stable viscous energy-momentum tensor defined at first order in spacetime derivatives. In this new framework a pressureless viscous fluid having equilibrium energy density ρ can evolve to an asymptotic future solution in which the Hubble parameter approaches a constant while ρ → 0, even in the absence of a cosmological constant (i.e., Λ = 0). Thus, while viscous effects in this model drive an accelerated expansion of the universe, the equilibrium energy density itself vanishes, leaving behind only the acceleration. This behavior emerges as a consequence of causality in first-order theories of relativistic fluid dynamics and it is fully consistent with Einstein’s equations.

79 ASTRONOMY AND ASTROPHYSICS↗