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At least 181 records · Page 10

Satellite-Derived Management Zones

The term "satellite-derived management zones" (SAMZ) denotes agricultural management zones that are subdivisions of large fields and that are derived from images of the fields acquired by instruments aboard Earth-orbiting satellites during approximately the past 15 years. "SAMZ" also denotes the methodology and the software that implements the methodology for creating such zones. The SAMZ approach is one of several products of continuing efforts to realize a concept of precision agriculture, which involves optimal variations in seeding, in application of chemicals, and in irrigation, plus decisions to farm or not to farm certain portions of fields, all in an effort to maximize profitability in view of spatial and temporal variations in the growth and health of crops, and in the chemical and physical conditions of soils. As used here, "management zone" signifies, more precisely, a subdivision of a field within which the crop-production behavior is regarded as homogeneous. From the perspective of precision agriculture, management zones are the smallest subdivisions between which the seeding, application of chemicals, and other management parameters are to be varied. In the SAMZ approach, the main sources of data are the archives of satellite imagery that have been collected over the years for diverse purposes. One of the main advantages afforded by the SAMZ approach is that the data in these archives can be reused for purposes of precision agriculture at low cost. De facto, these archives contain information on all sources of variability within a field, including weather, crop types, crop management, soil types, and water drainage patterns. The SAMZ methodology involves the establishment of a Web-based interface based on an algorithm that generates management zones automatically and quickly from archival satellite image data in response to requests from farmers. A farmer can make a request by either uploading data describing a field boundary to the Web site or else drawing the boundary on a reference image. Hence, a farmer can start to engage in precision farming shortly after gaining access to the Web site, without the need for incurring the high costs of conventional precision-agriculture data-collection practices that include collecting soil samples, mapping electrical conductivity of soil, and compiling multiyear crop-yield data. Given the boundary of a field, a SAMZ server computes the zones within the field in a three-stage process. In the first stage, a vector-valued image of the field is constructed by assembling, from the archives, the equivalent of a stack of the available images of the field (see figure). In the second stage, the vector-valued image is analyzed by use of a wavelet transform that detects spatial variations considered significant for precision farming while suppressing small-scale heterogeneities that are regarded as insignificant. In the third stage, a segmentation algorithm assembles the zones from smaller regions that have been identified in the wavelet analysis.

Lepoutre, Damien↗

Organic carbon thermodynamics elucidate spatiotemporal mechanisms governing hyporheic zone biogeochemical cycling

This element of the PNNL SFA has contributed to a predictive understanding of river corridor hydrobiogeochemical function by revealing processes governing the oxidation of organic carbon (OC) in the hyporheic zone. Groundwater-surface water mixing zones (i.e., hyporheic zones) exhibit enhanced biogeochemical cycling, and strongly influence river corridor function. Processes governing biogeochemical cycling in these zones remain a crucial uncertainty in watershed-scale process models. To reveal governing processes we combined ultra-high resolution OC characterization, geophysical monitoring, microbial ecology, and biogeochemical assays to determine novel processes associated with the concept of ‘priming’ and how those processes are influenced by (i) riparian vegetation and (ii) hydrologic mixing in the Columbia River hyporheic zone. Here, priming occurs when microbial oxidation of thermodynamically unfavorable OC is fueled by the addition of more bioavailable OC. Field surveys of sediment-associated OC (and related biogeochemical data) conflicted with priming expectations. We found that inputs of thermodynamically favorable OC protected thermodynamically unfavorable mineral-bound OC. We also found that the presence of riparian vegetation shifted biochemical pathways that drive the oxidation of OC. Further, despite the respective oxidation of water-soluble vs. mineral-bound OC pools in dense and sparsely vegetated areas, thermodynamically favorable OC was preferentially depleted in both areas. This suggests universal thermodynamic principles underlie biogeochemical cycling in the hyporheic zone. In contrast, field surveys of pore water were consistent with priming. These data revealed that groundwater contains thermodynamically favorable OC at low concentrations while surface water contains thermodynamically unfavorable OC at higher concentrations. As such, OC oxidation is concentration-limited in groundwater and thermodynamically-limited in surface water. When groundwater mixes with surface water thermodynamically favorable OC in groundwater primes microbial communities to oxidize less favorable OC compounds in surface water. We also show concomitant deterministic shifts in hyporheic zone microbial communities and shifts in OC biochemical transformations. These results provide a mechanistic foundation for modeling hyporheic zone biogeochemistry under temporally dynamic mixing conditions.

Graham, Emily B.↗

Field Test Bed for Vadose-Zone Monitoring Approaches - 20404

In the Central Plateau at the U.S. Department of Energy Hanford Site, a large inventory of contaminants resides in unsaturated sediments within the approximately 100-meter-thick vadose zone, posing a potential continuing risk to groundwater. Vadose zone remedies used to address these contaminants will require performance monitoring to provide feedback during implementation and for long-term verification that remedial action objectives have been met. Passive approaches may also need long-term monitoring to demonstrate that the flux of contaminants from the vadose zone to the groundwater are below thresholds established to meet groundwater protection goals. Collection of physical (e.g., groundwater or sediment) samples is a common method for identifying contaminant concentration distributions, but this approach is limited by the number of locations and the frequency with which data can be collected. In situ vadose zone measurements have evolved over the past few years to include key measurements of water content, soil water pressure, temperature, and chemical concentration. However, the current generation of sensors is designed for relatively short-term use in near-surface soils or sediments. Geophysical methods have been evolving but are also limited in that they have not been designed for the specific long-term vadose zone monitoring needs at the Hanford Site. Overall, monitoring under unsaturated conditions can be difficult due to the need to install and maintain instrumentation over a large area and depth and the need to identify preferential flow pathways due to geologic and chemical heterogeneities over long periods. Thus, a vadose zone monitoring test bed was initiated to address these challenges and identify cost-effective approaches for implementation and postclosure monitoring of the deep vadose zone. The monitoring test bed is expected to provide valuable field-scale information for the design of vadose zone monitoring systems. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The impact of immobile zones on the transport and retention of nanoparticles in porous media

Nanoparticle transport and retention within porous media is treated by conceptualizing the porous media as a series of independent collectors (e.g., Colloid Filtration Theory). This conceptualization assumes that flow phenomena near grain–grain contacts, such as immobile zones (areas of low flow), exert a negligible influence on nanoparticle transport and assumes that retention and release of particles depends only on surface chemistry. This study investigated the impact of immobile zones on nanoparticle transport and retention by employing synchrotron X–ray computed microtomography (SXCMT) to examine pore–scale silver nanoparticle distributions during transport through three sand columns: uniform iron oxide, uniform quartz, and well–graded quartz. Extended tailing was observed during the elution phase of all experiments suggesting that hydraulic retention in immobile zones, not detachment from grains, was the source of tailing. A numerical simulation of fluid flow through an SXCMT data set predicted the presence of immobile zones near grain–grain contacts. SXCMT–determined silver nanoparticle concentrations observed that significantly lower nanoparticle concentrations existed near grain–grain contacts throughout the duration of all experiments. In addition, the SXCMT–determined pore–scale concentration gradients were found to be independent of surface chemistry and grain size distribution, suggesting that immobile zones limit the diffusive transport of nanoparticles toward the collectors. Furthermore, these results suggest that the well–known overprediction of nanoparticle retention by traditional CFT may be due to ignoring the influences of grain–grain contacts and immobile zones. As such, accurate prediction of nanoparticle transport requires consideration of immobile zones and their influence on both hydraulic and surface retention.

42 ENGINEERING↗

Degradation of natural habitats by roads: Comparing land-take and noise effect zone

Roads may act as barriers, negatively influencing the movement of animals, thereby causing disruption in landscapes. Roads cause habitat loss and fragmentation not only through their physical occupation, but also through traffic noise. The aim of this study is to provide a method to quantify the habitat degradation including habitat loss and fragmentation due to road traffic noise and to compare it with those of road land-take. Two types of fragmentation effects are determined: structural fragmentation (based on road land-take only), and functional fragmentation (noise effect zone fragmentation, buffer using a threshold of 40 dB). Noise propagation for roads with a traffic volume of more than 1000 vehicles per day was simulated by Calculation of Road Traffic Noise (CRTN) model. Habitat loss and fragmentation through land-take and noise effect zone were calculated and compared in Zagros Mountains in western Iran. The study area is characterized by three main habitat types (oak forest, scattered woodland and temperate grassland) which host endangered and protected wildlife species. Due to topographic conditions, land cover type, and the traffic volume in the region, the noise effect zone ranged from 50 to 2000 m which covers 18.3% (i.e. 516,929.95 ha) of the total study area. The results showed that the habitat loss due to noise effect zone is dramatically higher than that due to road land-take only (35% versus 1.04% of the total area). Temperate grasslands lost the highest proportion of the original area by both land-take and noise effect zone, but most area was lost in scattered woodland as compared to the other two habitat types. The results showed that considering the noise effect zone for habitat fragmentation resulted in an increase of 25.8% of the area affected (316,810 ha) as compared to using the land-take only (555,874 ha vs. 239,064 ha, respectively). The results revealed that the degree of habitat fragmentation is increasing by considering the noise effect zone. We conclude that, although the roads are breaking apart the patches by land-take, road noise not only dissects habitat patches but takes much larger proportions of or even functionally eliminates entire patches.

54 ENVIRONMENTAL SCIENCES↗

MAGNETIZED ACCRETION AND DEAD ZONES IN PROTOSTELLAR DISKS

The edges of magnetically dead zones in protostellar disks have been proposed as locations where density bumps may arise, trapping planetesimals and helping form planets. Magneto-rotational turbulence in magnetically active zones provides both accretion of gas on the star and transport of mass to the dead zone. We investigate the location of the magnetically active regions in a protostellar disk around a solar-type star, varying the disk temperature, surface density profile, and dust-to-gas ratio. We also consider stellar masses between 0.4 and 2 M{sub Sun }, with corresponding adjustments in the disk mass and temperature. The dead zone's size and shape are found using the Elsasser number criterion with conductivities including the contributions from ions, electrons, and charged fractal dust aggregates. The charged species' abundances are found using the approach proposed by Okuzumi. The dead zone is in most cases defined by the ambipolar diffusion. In our maps, the dead zone takes a variety of shapes, including a fish tail pointing away from the star and islands located on and off the midplane. The corresponding accretion rates vary with radius, indicating locations where the surface density will increase over time, and others where it will decrease. We show that density bumps do not readily grow near the dead zone's outer edge, independently of the disk parameters and the dust properties. Instead, the accretion rate peaks at the radius where the gas-phase metals freeze out. This could lead to clearing a valley in the surface density, and to a trap for pebbles located just outside the metal freezeout line.

79 ASTRONOMY AND ASTROPHYSICS↗

Evaluation of a coastal acoustic buoy for cetacean detections, bearing accuracy and exclusion zone monitoring

Abstract There is strong socio‐political support for offshore wind development in US territorial waters and construction is planned off several east coast states. Some of the planned development sites coincide with important habitat for critically endangered North Atlantic right whales. Both exclusion zones and passive acoustic monitoring are important tools for managing interactions between marine mammals and human activities. Understanding where animals are with respect to exclusion zones is important to avoid costly construction delays while minimizing the potential for negative impacts. Impact piling from construction of hundreds of offshore wind turbines likely require exclusion zones as large as 10 km. We have developed a three‐hydrophone passive acoustic monitoring system that provides bearing information along with marine mammal detections to allow for informed management decisions in real‐time. Multiple units form a monitoring system designed to determine whether marine mammal calls originate from inside or outside of an exclusion zone. In October 2021, we undertook a full system validation, with a focus on evaluating the detection range and bearing accuracy of the system with respect to right whale upcalls. Five units were deployed in Mid‐Atlantic waters and we played more than 3500 simulated right whale upcalls at known locations to characterize the detection function and bearing accuracy of each unit. The modelled results of the detection function error were then used to compare the effectiveness of a bearing‐based system to a single sensor that can only detect a signal but not ascertain directivity. Field trials indicated maximum detection ranges from 4–7.3 km depending on source and ambient noise levels. Simulations showed that incorporating bearing detections provide a substantial improvement in false alarm rates (6 to 12 times depending on number of units, placement and signal to noise conditions) for a small increase in the risk of missed detections inside of an exclusion zone (1%–3%). We show that the system can be used for monitoring exclusion zones and clearly highlight the value of including bearing estimation into exclusion zone monitoring plans while noting that placement and configuration of units should reflect anticipated ambient noise conditions.

17 WIND ENERGY↗

Characterization of Persistent Volatile Contaminant Sources in the Vadose Zone

Remediation activities over time will alter the subsurface distribution of contaminants and likely create significant changes in the source-zone architecture. A field method was demonstrated for use of data collected from multiple individual soil vapor extraction (SVE) system well tests to locate and characterize the distribution of persistent VOC sources in the vadose zone. Operational data collected at the Department of Energy’s Hanford site were used to examine source zone alteration over time due to SVE operation and to illustrate the source-zone characterization approach. Individual well test results confirmed a heterogeneous distribution of permeability and contaminant mass discharge throughout the vadose zone. The trends in mass discharge and concentration were analyzed to determine the location and extent of the primary source zone within a lower-permeability unit at the site. This information is useful to evaluate the performance of SVE operations, and support decisions concerning system alteration or closure based on risk assessments of the impact of vadose-zone sources on groundwater contamination or vapor intrusion.

carbon tetrachloride↗

The Application of Radon for Mapping Open Fracture Networks in a Thin Vadose Zone

The use of naturally occurring tracers to elucidate subsurface flow and transport of water and gasses through fractured vadose zones represents a powerful and inexpensive methodology for understanding geologic systems. Our study was conducted at Sheply’s Hill, a highly fractured granite highland at the old Fort Devens military base. This study evaluates the applicability of using cheap, readily available passive radon detectors to identify conductive structures (e.g., fractures and fracture networks) in fracture-dominated vadose zones. Radon data from this study provides strong evidence that, even within an intensively fractured system, a relatively smaller subset of the fractures is responsible for the majority of the vertical migration of gas and water that recharges contaminated groundwater sites. Our study found that zones of high recharge potential associated with open fracture networks could be identified based on the 222 Rn flux within the highly fractured Shepley’s Hill. Based on the results of this study, 222 Rn is an environmental tracer capable of efficiently detecting major bedrock fracture sets in the vadose zone responsible for water infiltration into contaminated aquifers. Results from the Shepley’s Hill study show a clear spatial correlation of elevated 222 Rn concentrations emanating from fracture zones previously identified by independent geologic studies. At Shepley’s Hill, the 222 Rn concentrations measured from detector locations directly above the major bedrock fractures, located within the Disc Golf Fracture Zone (DGFZ) and the Nona-Shep Fracture Zone (NSFZ), were almost exclusively the highest values measured in the study. Conversely, probes located above areas of less-fractured bedrock, although highly fractured, showed relatively low 222 Rn concentrations. Furthermore, these two observations provide strong supporting evidence that not all fractures are equal when it comes to their ability to transmit gas or water into and out of the subsurface.

58 GEOSCIENCES↗

Development of Diamond Membrane-Based X-Ray Optics: Fresnel Zone Plates, Beam Stops, and Grids

This project was proposed to develop the design and fabrication of zone plates for hard X-ray focusing up to 25 keV photon energies with 20 nm resolution (with zone doubling), based on diamond membranes. The benefits of using diamond are: improved mechanical robustness which among other advantages prevents collapse of high-aspect-ratio ring structures, a known high-aspect-ratio etch method, and excellent compatibility with other processes, excellent radiation hardness, extremely low X-ray absorption, and significantly improved thermal/dimensional stability as compared to alternative materials. The Phase I findings enable Phase II goals as well as significant progress in other diamond-membrane devices, such as diamond-supported X-ray optics (beam stops, apertures, phase shift disks for phase contrast X-ray microscopy, grids, resolution targets, coded apertures for coherence measurements, etc), X-ray windows and membrane–based detectors. Zone plates with outermost zones of 60 nm were written in 500 nm electron resist and transferred to a depth of up to 1.8 mm (exceeding the expectations) into a stack of engineered multilayer ultra-nano-crystalline diamond alternating non-conductive and conductive layers. The active material for focusing was added on top (Au and Ir). Several processes were investigated and validated to enable in Phase II the enhancement of the thickness of the structures, including polishing the over-plated zone plates and growing diamond on top of Ir-coated zone plates without the destruction of the nanostructures underneath. The zone plates were geometrically characterized.

07 ISOTOPE AND RADIATION SOURCES↗

Synthesis of Post-fire Monitoring Activities in the Great Basin Desert, Mojave Desert, and Transition Zones

In the deserts of the American Southwest, fire return intervals of centuries to millennia are being replaced by fire return intervals of decades. This increased burn frequency has implications for post-closure management and long-term stewardship for Soils Corrective Action Units (CAUs) and Corrective Action Sites (CASs) on the Nevada National Security Site (NNSS), Tonopah Test Range, and Nevada Test and Training Range for which the U.S. Department of Energy (DOE), Environmental Management-Nevada (EM-NV) is responsible. For many CAUs and CASs, where closure-in-place alternatives were implemented or are being considered, there is a chance that these sites could burn over while they still pose a risk to the environment or human health given the long half-lives of some of the radionuclide contaminants of concern (COCs) (Shafer et al., 2007; Shafer and Gomes, 2009). Although it would have been ideal to conduct a fire-related study at a radionuclide contaminated site on the NNSS to determine how contaminated soils are transported post-fire, it was more practical to examine fires in environments analogous to where Soils Activity CAUs and CASs exist. Therefore, a series of studies were initiated at three radiologically uncontaminated analog sites to better understand the possible effects of wildfire on erosion and sediment transport by wind and water should vegetation at contaminated sites burn at the NNSS. The studies took place at the sites of the Gleason Fire, a prescribed burn that occurred near Ely, Nevada, which is in the Great Basin ecoregion; the White Rock Fire that occurred near Mesquite, Nevada, which is in the Mojave Desert ecoregion; and the Jacob Fire that occurred near Hiko, Nevada, in the transitional zone between the Great Basin Desert and the Mojave Desert. Each site was representative of one of the three ecoregions found on the NNSS. Erosion and vegetation characteristics were measured multiple times post-fire on both burned and unburned test plots at these study sites to compare and monitor the effects of fire over time. However, at the Mojave Desert site, there was an additional burn from nearly 25 years ago that was also compared with the more recent burned areas from 2013. Also, the time elapsed after the fire and the time when sampling began differed among the ecoregions. For example, at the Great Basin site, samples were collected prior to the fire and less than one month after the fire, whereas data collected at the Mojave Desert site did not occur until 22 months after the fire. The differences between the sample measurements and the time that elapsed after the fire may contribute to the variability in the data and the interpretations of the data. Runoff and water erosion were quantified through a series of rainfall and runoff simulation tests in which controlled amounts of water were delivered to the soil surface. Runoff data were collected from different microhabitats (e.g., undercanopies, interspace soils, ridges, and drainage areas). The data showed soil hydrophobicity (i.e., water repellency) on the Great Basin site for up to 12 months after the fire. The soil structure remained changed and weaker on the burned areas compared with the unburned areas for the three-year study period. Although runoff data at both the Great Basin site and transition zone site were highly variable, the post-fire runoff potential did not generally increase at either location after three years of monitoring. Mojave runoff did not differ much between fire ages or between burned and unburned areas, possibly because of the amount of vegetation growing on all three surfaces and because the fire intensity was likely lower relative to other ecoregions due to the amount of space between plants. Additionally, the measurements conducted on the Mojave fire occurred several years after the fire had burned and not within several months of the burn, which may also account for the lack of differences in runoff between burned and unburned locations. Wind erosion was assessed and quantified with a Portable In-Situ Wind ERosion Lab (PI-SWERL) on both the burned and unburned soils of different microhabitats (e.g., ridges, drainages, interspaces between plants, and plant undercanopies). Estimates of emissions (e.g., particulate matter with aerodynamic diameters less than or equal to 10 micrometers, or PM10) at different wind speeds were collected and filter samples were analyzed for chemical composition. The measurements among the fires were similar and the results of the wind erosion measurements indicate that there were seasonal influences on many parameters, but the potential for PM10 windblown dust emissions was higher on burned areas compared with unburned areas. Among the burned areas, drainages produced the most dust emissions, whereas burned ridges were the least emissive. Emissions at the Mojave site and transition zone site were similar between burned and unburned areas approximately three years after the respective fires. Emissions remained much greater on burned soils at the Great Basin site. However, site selection may have also contributed to the differences of emissions among the three study locations. Post-fire vegetation responses were documented for three years following each fire in different microhabitats (e.g., ridge, drainage, undercanopy, and interspace) at the Great Basin and transition zone sites. In 2013, at the Mojave fire site, random permanent plots were established in newly burned areas, areas that burned approximately 25 years ago, and an unburned control area. At each fire site, the regeneration of native plant species dominated the burned areas, but invasive annual grasses were present at each fire site. During the course of each three-year study, the invasive annual grasses increased in density or percentage at both the Great Basin and transition fire sites but not at the Mojave site, where annual invasive grasses remained high throughout the study period. However, the chronosequence data from the Mojave site indicate a transition to different invasive grass species with time. The post-burn vegetation at all three ecoregions is still in the early stages of succession, and shrub size should increase over time and shrub density should decrease over time. However, the recovery of the plant communities to pre-burn compositions may not occur for decades or centuries, or may not occur because of changes in climate and the presence of invasive annual grasses. Results from the three study locations suggested that contaminated soils on the NNSS that experienced wildfire had the potential for soil erosion and transport of contaminated soils. Both wind and soil runoff studies indicated that locations in the Great Basin and transition zone ecoregions were more susceptible to erosion than the Mojave Desert ecoregion, but the highest levels of erosion occurred during the early portions of the study (the first 24 months) and the Mojave Desert was not measured until 22 months after the burn. Additionally, data from the Great Basin indicated deeper soils may increase susceptibility to wind erosion. Historically, the Great Basin and transition zone ecoregions burned more frequently than the Mojave Desert because of fuel abundance and connectivity—and they continue to burn more frequently, particularly after the introduction of invasive grasses (Davies and Nafus, 2013). However, both ecoregions and the transition zone have burned with extensive, high-severity fires when certain weather and fuel conditions are met. For example, the high abundance and productivity of annual grasses and forbs—which are usually produced by above average winter precipitation—combined with early spring and summer warm, dry conditions. Future climate scenarios predict increased temperatures, variable to reduced precipitation, and larger, more extreme wildfires throughout western North America. These predictions suggest that future fires on the NNSS could increase in frequency, intensity, and severity similar to their analog ecosystems throughout the Great Basin and Mojave Desert (Dennison et al., 2014; Abatzoglou andWilliams, 2016; Westerling, 2016).

54 ENVIRONMENTAL SCIENCES↗

Effect of Heterogeneities on the Reaction-zone of a Propagating Detonation Wave

Reactive burn models for propagating detonation waves in an explosive are based on the ZND (Zel'dovich-Von Neumann-Doring) theory. A key property of the ZND theory, which leads to self-sustaining detonation waves, is a sonic point relative to the front in the reaction zone. Moreover, burn models assume the explosive is a homogeneous material. This assumption is used for plastic-bonded explosives, even though they are heterogeneous materials. The heterogeneities are accounted for only with an empirical burn rate. Furthermore, the reaction-zone width can be less than the length scale of heterogeneities. This raises the question of the effect of heterogeneities on the reaction zone. In particular, whether the reaction zone can be steady and have a well defined sonic point. To examine this question we focus on PBX 9501 since there is data on the grain-binder heterogeneities and on the reaction-zone velocity time history of a steady planar detonation wave. Using pseudo-mesoscale 1-D simulations, we examine the effect of a detonation wave transversing explosive and binder segments of random length. The simulations show that the reaction zone is quasi-steady with only short wavelength small amplitude variations in the detonation wave pressure and speed. The main effect of the heterogeneities is to introduce noise in the pressure and velocity fields that propagates into the Taylor wave behind the detonation. This is consistent with the scatter in the reaction-zone measurements for PBX 9501.

42 ENGINEERING↗

The hidden dynamics of relativistic electrons (0.7-1.5 MeV) in the inner zone and slot region

We present measurements of relativistic electrons (0.7–1.5 MeV) in the inner zone and slot region obtained by the Magnetic Electron and Ion Spectrometer (MagEIS) instrument on Van Allen Probes. The data presented are corrected for background contamination, which is primarily due to inner-belt protons in these low-L regions. We find that ~1 MeV electrons were transported into the inner zone following the two largest geomagnetic storms of the Van Allen Probes era to date, the March and June 2015 events. As ~1 MeV electrons were not observed in Van Allen Probes data in the inner zone prior to these two events, the injections created a new inner belt that persisted for at least 1.5 years. In contrast, we find that electrons injected into the slot region decay on much faster timescales, approximately tens of days. Furthermore, we find no evidence of >1.5 MeV electrons in the inner zone during the entire time interval considered (April 2013 through September 2016). The energies we examine thus span a transition range in the steeply falling inner zone electron spectrum, where modest intensities are observed at 0.7 MeV, and no electrons are observed at 1.5 MeV. To validate the results obtained from the background corrected flux measurements, we also present detailed pulse-height spectra from individual MagEIS detectors. These measurements confirm our results and also reveal low-intensity inner zone and slot region electrons that are not captured in the standard background corrected data product. Lastly, we briefly discuss efforts to refine the upper limit of inner zone MeV electron flux obtained in earlier work.

58 GEOSCIENCES↗

Dynamic Model of Basic Oxygen Steelmaking Process Based on Multi-zone Reaction Kinetics: Model Derivation and Validation

A multi-zone kinetic model coupled with a dynamic slag generation model was developed for the simulation of hot metal and slag composition during the basic oxygen furnace (BOF) operation. The three reaction zones (i) jet impact zone, (ii) slag–bulk metal zone, (iii) slag–metal–gas emulsion zone were considered for the calculation of overall refining kinetics. In the rate equations, the transient rate parameters were mathematically described as a function of process variables. A micro and macroscopic rate calculation methodology (micro-kinetics and macro-kinetics) were developed to estimate the total refining contributed by the recirculating metal droplets through the slag–metal emulsion zone. The micro-kinetics involves developing the rate equation for individual droplets in the emulsion. The mathematical models for the size distribution of initial droplets, kinetics of simultaneous refining of elements, the residence time in the emulsion, and dynamic interfacial area change were established in the micro-kinetic model. In the macro-kinetics calculation, a droplet generation model was employed and the total amount of refining by emulsion was calculated by summing the refining from the entire population of returning droplets. A dynamic Fe{sub t}O generation model based on oxygen mass balance was developed and coupled with the multi-zone kinetic model. The effect of post-combustion on the evolution of slag and metal composition was investigated. The model was applied to a 200-ton top blowing converter and the simulated value of metal and slag was found to be in good agreement with the measured data. The post-combustion ratio was found to be an important factor in controlling Fe{sub t}O content in the slag and the kinetics of Mn and P in a BOF process.

36 MATERIALS SCIENCE↗

Study of seismic diffractions caused by a fracture zone at In Salah carbon dioxide storage project

The In Salah CO 2 storage project in Algeria has injected over 3 million tonnes of carbon dioxide into a water filled tight sand formation. Interferometric Synthetic Aperture Radar (InSAR) range change data revealed a double lobbed pattern of deformation that has been modeled as the opening of a sub-vertical fracture, or damage, zone. The location and geometry of the linear feature were subsequently verified using a seismic reflection survey. The elastic properties of the fracture zone, including anisotropic Poisson ratio ( ν ), Young's ( E ) and shear ( G ) moduli, were estimated from coupled geomechanical and hydrological modeling of surface deformation and pressure variations in the injection well. The elastic moduli reflect the fracture properties after CO 2 flow through the fracture zone. Thus, the seismic signature of the fracture zone could be used for monitoring the CO 2 plume. Using the estimated fracture model, we built two and three dimensional models consisting of an anisotropic fracture zone embedded within an isotropic background. Finite-difference modeling of seismic shot gathers allows us to estimate the effects of scattering from the fracture zone, potentially further constraining the geomechanical model. From the seismic modeling results, we find diffracted waves, induced by the fracture zone, which behave similar to point source diffractions. This modeling is intended to guide a search for diffraction events in the 3D surface seismic field data. The modeling results indicate that using the moduli estimated from geomechanical modeling, fracture scattered events would be 100 times lower amplitude than the interface reflections, and thus would be hard to detect. While diffracted waves are observed in the field data, which may imply the need for revision of the fracture model, including shape and elastic moduli, we are not able to match the field observation with our modeled events. This article presents a frontier study on the integration of geomechanical and geophysical methods at the In Salah site as a means to test the estimate of the subsurface CO 2 flooded fracture properties.

58 GEOSCIENCES↗

Zoned near-zero refractive index fishnet lens antenna: Steering millimeter waves

A zoned fishnet metamaterial lens is designed, fabricated, and experimentally demonstrated at millimeter wavelengths to work as a negative near-zero refractive index lens suitable for compact lens antenna configurations. At the design frequency f = 56.7 GHz (λ{sub 0} = 5.29 mm), the zoned fishnet metamaterial lens, designed to have a focal length FL = 9λ{sub 0}, exhibits a refractive index n = −0.25. The focusing performance of the diffractive optical element is briefly compared with that of a non-zoned fishnet metamaterial lens and an isotropic homogeneous zoned lens made of a material with the same refractive index. Experimental and numerically-computed radiation diagrams of the fabricated zoned lens are presented and compared in detail with that of a simulated non-zoned lens. Simulation and experimental results are in good agreement, demonstrating an enhancement generated by the zoned lens of 10.7 dB, corresponding to a gain of 12.26 dB. Moreover, beam steering capability of the structure by shifting the feeder on the xz-plane is demonstrated.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Vadose Zone Model for B-3A/B Pond for Composite Analysis

The objectives of the vadose modeling for the updated Hanford Site composite analysis (CA) are to simulate the flow and transport of water and radionuclide releases from the surface to the water table and to provide radionuclide transfer rates for the plateau to river (P2R) model, version 8.3 (CP-57037, Model Package Report: Plateau to River Groundwater Model, Version 8.3). Water additions include natural recharge and water discharged to the ground as a result of industrial processes associated with Hanford Site operations. Contaminant sources include radionuclides in water discharged to the ground during operations and radionuclides disposed “dry” in solid waste burial grounds or other means. The following 16 radionuclides were selected for this modeling effort; carbon-14 (C-14), chlorine-36 (Cl-36), tritium (H-3), iodine-129 (I-129), neptunium-237 (Np-237), rhenium-187 (Re-187), strontium-90 (Sr-90), technetium-99 (Tc-99), uranium-232 (U-232), uranium-233 (U-233), uranium-234 (U-234), uranium-235 (U-235), uranium-236 (U-236), uranium-238 (U-238), radium-226 (Ra-226), and thorium-230 (Th-230). The simulation time starts in 1943 and ends at 12070, which is 10,000 years after assumed Hanford Site closure in 2070. The parallel version of the Subsurface Transport Over Multiple Phases (STOMP) simulator officially named the exascale Subsurface Transport Over Multiple Phases (eSTOMP), is used to simulate flow and transport for the vadose models. The documentation for the STOMP code is comprehensive. The theoretical and numerical approaches applied in the STOMP code are documented in a published theory guide (PNNL-12030, STOMP Subsurface Transport Over Multiple Phases Version 2.0 Theory Guide). The code has undergone a rigorous verification procedure against analytical solutions, laboratory-scale experiments, and field-scale demonstrations. The application guide (PNNL-11216, STOMP Subsurface Transport Over Multiple Phases Application Guide) provides instructive examples in the application of the code to classical groundwater problems. The user’s guide (PNNL-15782, STOMP: Subsurface Transport Over Multiple Phases Version 4.0: User’s Guide) describes the general use, input file formatting, compilation, and execution of the code. The primary output of the vadose zone modeling is radionuclide transfer rates to the groundwater for input into the P2R model. The rates will be summed over the 100 by 100 m P2R grid cells that fall within the vadose zone model source domain. The Hanford Site Central Plateau was subdivided into 26 individual vadose zone models, with 13 in the 200 East Area and 13 in the 200 West Area. Waste sites that have a completed performance assessment (PA) or past-leak analysis were not included as sources of radionuclides. Instead the vadose zone to groundwater transfer rates of the Environmental Restoration Disposal Facility, Integrated Disposal Facility, US Ecology, and Waste Management Area C (WMA C) PAs and the past-leak analysis for WMA C were used as direct input to the P2R model. Each of the vadose zone models is documented in separate environmental calculation files (ECFs). This ECF describes the B-3A/B Ponds model. The scope of this ECF is to document the development and results of the B-3 A/B Ponds vadose zone model. CP-63515, Model Package Report: Central Plateau Vadose Zone Models, describes the approach, assumptions, process of determining the number of models required and domain of each model, input data, and processing common to all the models.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Vadose Zone Model for SALDS for Composite Analysis

The objectives of the vadose modeling for the updated Hanford Site composite analysis (CA) are to simulate the flow and transport of water and radionuclide releases from the surface to the water table and to provide radionuclide transfer rates for the plateau to river (P2R) model, version 8.3 (CP-57037, Model Package Report: Plateau to River Groundwater Model, Version 8.3). Water additions include natural recharge and water discharged to the ground as a result of industrial processes associated with Hanford Site operations. Contaminant sources include radionuclides in water discharged to the ground during operations and radionuclides disposed “dry” in solid waste burial grounds or other means. The following 16 radionuclides were selected for this modeling effort: carbon-14 (C-14), chlorine-36 (Cl-36), tritium (H-3), iodine-129 (I-129), neptunium-237 (Np-237), rhenium-187 (Re-187), strontium-90 (Sr-90), technetium-99 (Tc-99), uranium-232 (U-232), uranium-233 (U-233), uranium-234 (U-234), uranium-235 (U-235), uranium-236 (U-236), uranium-238 (U-238), radium-226 (Ra-226), and thorium-230 (Th-230). The simulation time starts in 1943 and ends at 12070, which is 10,000 years after assumed Hanford Site closure in 2070. The parallel version of the Subsurface Transport Over Multiple Phases (STOMP1) simulator, officially named the exascale Subsurface Transport Over Multiple Phases (eSTOMP) is used to simulate flow and transport for the vadose models. The documentation for the STOMP code is comprehensive. The theoretical and numerical approaches applied in the STOMP code are documented in a published theory guide (PNNL-12030, STOMP Subsurface Transport Over Multiple Phases Version 2.0 Theory Guide). The code has undergone a rigorous verification procedure against analytical solutions, laboratory-scale experiments, and field-scale demonstrations. The application guide (PNNL-11216, STOMP Subsurface Transport Over Multiple Phases Application Guide) provides instructive examples in the application of the code to classical groundwater problems. The user’s guide (PNNL-15782, STOMP: Subsurface Transport Over Multiple Phases Version 4.0: User’s Guide) describes the general use, input file formatting, compilation, and execution of the code. The primary output of the vadose zone modeling is radionuclide transfer rates to the groundwater for input into the P2R model. The rates will be summed over the 100 by 100 m P2R grid cells that fall within the vadose zone model source domain. The Hanford Site Central Plateau was subdivided into 26 individual vadose zone models, with 13 in the 200 East Area and 13 in the 200 West Area. Waste sites that have a completed performance assessment (PA) or past-leak analysis were not included as sources of radionuclides. Instead the vadose zone to groundwater transfer rates of the Environmental Restoration Disposal Facility, Integrated Disposal Facility, US Ecology, and Waste Management Area C (WMA C) PAs and the past-leak analysis for WMA C were used as direct input to the P2R model. Each of the vadose zone models is documented in separate environmental calculation files (ECFs). This ECF describes the State-Approved Land Disposal Site (SALDS) model. The scope of this ECF is to document the development and results of the SALDS vadose zone model. CP-63515, Model Package Report: Central Plateau Vadose Zone Models, describes the approach, assumptions, process of determining the number of models required and domain of each model, input data, and processing common to all the models.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗