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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Si 1-X Ge X /Si Heterojunction Internal Photoemission Long Wavelength Infrared Detector

Long wavelength Si 1-X Ge X /Si heterojunction internal photoemission (HIP) infrared detectors have been successfully demonstrated utilizing the growth of degenerately boron doped Si 1-X Ge X layers on Si. Recently, Si 0.7 GE 0.3 /SI HIP detectors with either a Si 1-X Ge X single layer or a Si 1-X Ge X /Si multilayer have been demonstrated with cutoff wavelengths out to 23 µm. Near-ideal thermionic emission dark current characteristics were measured and the electrical potential barriers were determined by the Richardson plot. A photoresponse model, similar to the modified Fowler Equation has been developed for the Si 1-X Ge X /Si heterojunction internal photoemission infrared detector at wavelengths corresponding to photon energies less than the Fermi energy. The optical potential barriers, the corresponding cutoff wavelengths, and the emission coefficients, C 1 , for the HIP detectors have been determined from the measured spectral responses using the photoresponse model. Similar optical and thermal potential barriers were obtained.

infrared↗

The Peak Absorbance Wavelength of Photosynthetic Pigments Around Other Stars From Spectral Optimization

In the search for life on other planets, the presence of photosynthetic surface vegetation may be detectable from the colors of light it reflects, which on the modern Earth is a steep increase in reflectance between the red and near-infrared wavelengths, a “red edge.” This edge-like signature occurs at wavelengths of peak photon absorbance, which are the result of adaptations of the phototroph to their spectral environment. On planets orbiting different stellar types, red edge analogs may occur at other colors than red. Thus, knowing the wavelengths at which photosynthetic organisms preferentially absorb and reflect photons is necessary to detect red edge analogs on other planets. Using a numerical model that predicts the absorbance spectrum of extant photosynthetic pigments on Earth from Marosvolgyi & van Gorkom (2010), we calculate the absorbance spectrum for pigments on an Earth-like planet around F through late M type stars that are adapted for maximal energy production. In this model, cellular energy production is maximized when pigments are tuned to absorb at the wavelength that maximizes energy input from incident photons while minimizing energy losses due to thermal emission and building cellular photosynthetic apparatus. We find that peak photon absorption for photosynthetic organisms around F type stars tends to be in the blue while for G, K, and early M type stars, red or just beyond is preferred. Around the coolest M type stars, these organisms may preferentially absorb in the near-infrared, possibly past 1 micron. These predictions are consistent with previous, qualitative estimates of pigment absorptance. Our predicted absorbance spectra for photosynthetic surface organisms depend on both the stellar type and planetary atmospheric composition, especially atmospheric water vapor concentrations, which alter the availability of surface photons and thus the predicted pigment absorption. By constraining the absorbance spectra of alien, photosynthetic organisms, future observations may be better equipped to detect the weak spectral signal of red edge analogs.

astrobiology↗

Analysis of Aeronet Extended Wavelength Retrievals of Aerosol Absorption Parameters Including 380 NM and 500 NM for Detection of Brown Carbon in Biomass Burning and Iron Oxides in Desert Dust

To investigate near UV aerosol absorbers, such as iron in mineral dust and brown carbon from biomass burning, AERONET spectral imaginary refractive index and size distributions retrievals were performed with the input of additional wavelength data. This includes adding both measured spectral AOD and sky radiances at 380 nm and 500 nm to the four channels (440, 675, 870 and 1020 nm) that are used in the standard retrieval data product. The vector radiative transfer code in the AERONET Version 3 retrievals enabled more accurate computations in the ultraviolet region (380 nm). Calibration of the 380 nm channel radiances was done by the vicarious method since the integrating sphere radiance source that is used for all other wavelengths does not produce sufficient energy at 380 nm. Spectral single scattering albedo, imaginary refractive indices and aerosol size distributions from these six wavelength retrievals are compared to the standard four wavelength retrieval values.

Aerosol↗

Adaptive Wavelength Scanning Lidar (AWSL) for 3D Mapping from Space

We present the design and performance of an adaptive wavelength scanning lidar (AWSL) for highly efficient mapping from low Earth orbit (LEO). Mapping is accomplished by steering a laser beam across 1,200 resolvable spots using wavelength tuning and grating dispersion. Any subset of these 1,200 spots can be selected by wavelength switching. The design is validated with an 1550-nm prototype using a fast wavelength-tuned (500-kHz) pulsed (2-ns) fiber laser with the beam dispersed by gratings for beam steering. Reflected pulses are detected with an eight-pixel detector array with single-photon sensitivity. Eight lidar returns are time-multiplexed to one output that is digitized with a single 1-GSPS-digitizer, to save power. A grating spectrometer rejects solar background noise spatially and spectrally, and images laser footprints on to the detector array. The gratings retain the fiber laser beam quality. We are developing a 1030-nm AWSL intended for a LEO SmallSat platform.

Guangning Yang↗

Dual wavelength negative imaging DLP-SLA system

The present disclosure relates to a digital light projector (DLP) system which has first and second light sources. The first optical source may generate a first beam at a first wavelength which causes polymerization of a photopolymerizable resist. The second optical source may generate a second beam at a second wavelength different from the first wavelength, and where the second beam inhibits polymerization of the photopolymerizable resist. A digital micromirror device (DMD) is included which has a plurality of micromirrors and is configured to be illuminated by the first and second beams and to generate a pattern on the micromirrors which has light from the first and second light wavelengths controlled by the micromirror position. The first light image causes polymerization of a first portion of the photopolymerizable resist, while the second image inhibits polymerization of a second portion of the photopolymerizable resist.

Moran, Bryan D.↗

Estimating snow cover from high-resolution satellite imagery by thresholding blue wavelengths

We report the extent and duration of snow cover, a critical component of the hydrologic cycle and the global climate system, is expected to shift dramatically under climate change. Therefore, developing high-resolution assessments of snow cover change is crucial for estimating the impact of changing snow cover on watershed and ecosystems processes in cold regions. Remote sensing tools provide a powerful method for mapping snow-covered area (SCA) across a landscape. The most common method for estimating SCA utilizes the normalized difference snow index (NDSI), which relies on spectral measurements in the shortwave-infrared wavelengths (SWIR). NDSI can effectively estimate catchment- to regional-scale SCA, but it cannot be used to assess fine-scale SCA because of current limitations on the spatial resolution of satellite-derived SWIR measurements. Here, we map SCA using a threshold of blue wavelengths and high-resolution satellite imagery. The thresholding method, which we call the Blue Snow Threshold algorithm (BST), has previously been used with digital camera imagery. We refine and automate the algorithm for use with cloud-free high-resolution satellite imagery and find that the BST can be used to assess fine-scale SCA. For validation, we compared BST-derived estimates of SCA to a) airborne lidar surveys, b) Landsat fractional SCA, and c) snow disappearance dates from Snow Telemetry (SNOTEL) stations. When compared to airborne lidar surveys of SCA, the BST predicted SCA had a range of F-scores between 0.81 and 0.94 in four study areas in California and Colorado. We also found general agreement between SCA and snow disappearance at multiple SNOTEL sites across the western United States. Given the relatively recent availability of high-resolution satellite imagery with spectral measurements in the visible wavelengths but lacking in SWIR, the BST offers a reliable and easy-to-apply tool for examining fine-scale snow-related processes.

54 ENVIRONMENTAL SCIENCES↗

Ice processes in Antarctica: identification via multi-wavelength active and passive measurements and model evaluation (Final Report)

This project is based on new multi-frequency radar observations collected during the AWARE field campaign in 2016 at McMurdo Station by the ARM Mobile facility. Three scientific goals have been achieved. We have developed ice and mixed-phase cloud microphysics retrievals from multi-wavelength radar observations and ancillary observations, generally applicable at ARM sites. These technique generally better characterize the size of the ice crystals, their equivalent water content and the degree of riming better than using single wavelength techniques. We have characterized ice microphysical properties and ice processes via multi-frequency signatures. We have identified a unique mode in the McMurdo dataset appearing at quite cold temperature that we have attributed to riming processes. Triple frequency radar measurements unfortunately were available only for a short period but our work lays the foundation for building climatological and testing their replicability in models. Simultaneously case studies from the AWARE campaign have been exploited to evaluate and improve the NASA GISS ModelE3 climate model, including selection of case studies for combined goals of (i) running side-by-side using large-eddy simulation (LES) and ModelE3 in single-column model (SCM) mode and (ii) fingerprinting cloud processes in multi-wavelength radar observations. The different components of this work have contributed to 15 published papers with two currently under review.

54 ENVIRONMENTAL SCIENCES↗

Large-aperture Wide-bandwidth Antireflection-coated Silicon Lenses for Millimeter Wavelengths

The increasing scale of cryogenic detector arrays for submillimeter and millimeter wavelength astrophysics has led to the need for large aperture, high index of refraction, low loss, cryogenic refracting optics. Silicon with n 3.4, low loss, and high thermal conductivity is a nearly optimal material for these purposes but requires an antireflection (AR) coating with broad bandwidth, low loss, low reflectance, and a matched coefficient of thermal expansion. We present an AR coating for curved silicon optics comprised of subwavelength features cut into the lens surface with a custom three-axis silicon dicing saw. These features constitute a metamaterial that behaves as a simple dielectric coating.We have fabricated silicon lenses as large as 33.4 cm in diameter with micromachined layers optimized for use between 125 and 165 GHz. Our design reduces average reflections to a few tenths of a percent for angles of incidence up to 30deg with low cross polarization.We describe the design, tolerance, manufacture, and measurements of these coatings and present measurements of the optical properties of silicon at millimeter wavelengths at cryogenic and room temperatures. This coating and lens fabrication approach is applicable from centimeter to submillimeter wavelengths and can be used to fabricate coatings with greater than octave bandwidth.

thermal expansion↗

Large-Aperture Wide-Bandwidth Anti-Reflection-Coated Silicon Lenses for Millimeter Wavelengths

The increasing scale of cryogenic detector arrays for sub-millimeter and millimeter wavelength astrophysics has led to the need for large aperture, high index of refraction, low loss, cryogenic refracting optics. Silicon with n = 3.4, low loss, and relatively high thermal conductivity is a nearly optimal material for these purposes, but requires an antireflection (AR) coating with broad bandwidth, low loss, low reflectance, and a matched coffecient of thermal expansion. We present an AR coating for curved silicon optics comprised of subwavelength features cut into the lens surface with a custom three axis silicon dicing saw. These features constitute a metamaterial that behaves as a simple dielectric coating. We have fabricated and coated silicon lenses as large as 33.4 cm in diameter with coatings optimized for use between 125-165 GHz. Our design reduces average reflections to a few tenths of a percent for angles of incidence up to 30 deg. with low cross-polarization. We describe the design, tolerance, manufacture, and measurements of these coatings and present measurements of the optical properties of silicon at millimeter wavelengths at cryogenic and room temperatures. This coating and lens fabrication approach is applicable from centimeter to sub-millimeter wavelengths and can be used to fabricate coatings with greater than octave bandwidth.

millimeter wavelength astrophysics↗

Extended Cut-Off Wavelength nBn Detector Utilizing InAsSb/InSb Digital Alloy Absorber

We investigated a novel approach to extend a cut -off wavelength of Sb-based nBn detectors. We incorporated a series of single InSb monolayer into InAsSb bulk that allowed to realize a digital alloy absorber with an extended cut-off wavelength of λ = 4.6 μm at T = 200 K. The cut-off wavelength extension to 4.6μm is technologically important for realization of detectors covering CO2 absorption line at 4.26μm

InAsSb/InSb photodiodes↗

InP-Based Ridge Waveguide Lasers for Wavelength Division Multiplexing Applications

Wavelength division multiplexed (WDM) systems place stringent requirements on the absolute wavelength and wavelength spacing of the elements in laser arrays. Ridge waveguides (RW) show excellent potential for practical implementation due to their simple fabrication with relaxed fabrication tolerances, high reliability and good performancce. An analysis of the fabrication tolerances for RW and buried heterostructure (BH) devices is performed, showing the advantages offered by the ridge design.

wavelength↗

Hybrid Additive and Subtractive Manufacturing of Dual‐Wavelength Photopolymer Thermosets

Additive manufacturing (AM) techniques such as digital light processing (DLP) AM and stereolithography enable the production of highly complex structures with speed and ease as not previously possible. However, many traditional thermosetting photopolymers used in these processes result in a permanently crosslinked structure incapable of being broken down or modified without the use of energy-intensive processes such as mechanical machining or ablation. To overcome this limitation, this production is described of thiol-ene photopolymer thermosets with dual-wavelength photopolymerization and photodegradation reaction pathways. The dual wavelength selectivity of the polymerization (405 nm) and degradation (365 nm) processes, combined with dual-wavelength DLP AM technology, enables hybrid manufacturing with the ability to add and sequentially subtract material with excellent spatiotemporal control. 2D lithographs and complex 3D architectures with soft elastomeric properties are produced with resolutions as small as 50 µm. Furthermore, the ability to selectively subtract supports from 3D printed structures with deliberate and accurate control is demonstrated. In conclusion, the ability to correct or modify existing structures enables a new paradigm of adaptable materials for corrective manufacturing techniques and temporary structures.

3D Printing↗

Wavelength-Dependent Spin Excitation with Circularly Polarized Light in CdSe Nanoplatelets

Zinc-blende (ZB) cadmium selenide (CdSe) nanoplatelets (NPLs) have drawn increasing attention as an ideal condensed-phase material for facilitating photon-to-spin transduction in quantum networks. Yet, a systematic investigation of their fidelity in converting circularly polarized light (CPL) to exciton spin polarization as a function of excitation wavelength is lacking. Here, this work demonstrates using time-resolved transient absorption (TA) spectroscopy combined with density functional theory calculations that ZB CdSe NPLs exhibit wavelength-dependent CPL-induced spin polarization. The capacity of CPL to inject spin polarization is maximized for resonant excitation of band-edge valence-to-conduction band (VB/CB) transitions, and the degree to which CPL induces spin polarization can be modified for non-resonant excitation wavelengths as excitation occurs at k-points away from the Γ point from VB states with varying degrees of mixed heavy-hole (HH) and light-hole (LH) characters. Furthermore, it is highlighted that spin polarization within the LH exciton (LX) population created from resonant LH/CB excitation is retained upon LX → HH exciton (HX) relaxation due to the slow electron spin-flip rate (~1.1 ps) compared to the LH → HH inter-band relaxation rate (~200 fs).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Wavelength conversion through plasmon-coupled surface states

Surface states generally degrade semiconductor device performance by raising the charge injection barrier height, introducing localized trap states, inducing surface leakage current, and altering the electric potential. We show that the giant built-in electric field created by the surface states can be harnessed to enable passive wavelength conversion without utilizing any nonlinear optical phenomena. Photo-excited surface plasmons are coupled to the surface states to generate an electron gas, which is routed to a nanoantenna array through the giant electric field created by the surface states. The induced current on the nanoantennas, which contains mixing product of different optical frequency components, generates radiation at the beat frequencies of the incident photons. We utilize the functionalities of plasmon-coupled surface states to demonstrate passive wavelength conversion of nanojoule optical pulses at a 1550 nm center wavelength to terahertz regime with efficiencies that exceed nonlinear optical methods by 4-orders of magnitude.

42 ENGINEERING↗

Wavelength-dependent photodissociation of iodomethylbutane

Ultrashort XUV pulses of the Free-Electron-LASer in Hamburg (FLASH) were used to investigate laser-induced fragmentation patterns of the prototypical chiral molecule 1-iodo-2-methyl-butane (C 5 H 11 I) in a pump-probe scheme. Ion velocity-map images and mass spectra of optical-laser-induced fragmentation were obtained for subsequent FEL exposure with photon energies of 63 eV and 75 eV. These energies specifically address the iodine 4d edge of neutral and singly charged iodine, respectively. The presented ion spectra for two optical pump-laser wavelengths, i.e., 800 nm and 267 nm, reveal substantially different cationic fragment yields in dependence on the wavelength and intensity. For the case of 800-nm-initiated fragmentation, the molecule dissociates notably slower than for the 267 nm pump. The results underscore the importance of considering optical-laser wavelength and intensity in the dissociation dynamics of this prototypical chiral molecule that is a promising candidate for future studies of its asymmetric nature.

74 ATOMIC AND MOLECULAR PHYSICS↗

Neutron radiation hardness of aluminum gallium nitride UV LEDs at various wavelengths

Radiation hard diagnostics are critical to the success of nuclear fusion at National Ignition Facility, Z, ITER, and prolonged space explorations. We have first demonstrated the exceptional proton radiation hardness of initial GaN devices and qualified their space flight and deployment for missions such as the Laser Interferometer Space Antenna and International Space Station. We have further conducted neutron radiation hardness experiments at Los Alamos Neutron Science Center by opening a new high fluence beam station. During 2014–2016, we irradiated multiple Aluminum Gallium Nitride (AlGaN) LEDs with a maximum fluence of 2.4 × 1013 neutrons/cm2 in 3 years and generated 54 161 current–voltage (I–V) scan traces. Our data processing program analyzes each and all I–V traces. In addition, we retrieved local temperature records to analyze and remove temperature effects in the outdoor environment. The I–V curve families of AlGaN UV LEDs with emitting wavelengths of 265, 275, and 310 nm were compared. The I–V curves of 265 nm AlGaN UV LEDs have the smallest deviations from the average value, while the I–V curves for 310 nm AlGaN LEDs showed the largest deviations from the average value. We have reached another important recommendation for the optimal use of multiple AlGaN optoelectronic devices or imaging arrays for inertially confined fusion diagnostics: Shorter wavelength devices at 265 nm exhibit more consistent radiation hardness performance than the 310 nm devices. Higher aluminum content LEDs or AlxGa1–xN devices with higher mole fraction x for generating shorter wavelengths have better radiation hardness for fusion diagnostics.

Sun, K. -X. (ORCID:0000000224659235)↗

Wide wavelength-tunable narrow-band thermal radiation from moiré patterns

Wavelength-tunable narrow-band thermal emitters are highly desired for various applications including multigas sensing. However, current thermal emitters suffer from either too broad bandwidth or too narrow tuning range. Here, based on the moiré effect, we provide a scheme of wavelength-tunable narrow-band thermal emitters with tunability over a wide wavelength range and operation at an arbitrary temperature. Thanks to the unique sensitivity of moiré patterns, our emitter achieves a tuning range to bandwidth ratio of 313, which is 68 times larger than the previous largest value ever reported.

42 ENGINEERING↗

Telecommunication-wavelength two-dimensional photonic crystal cavities in a thin single-crystal diamond membrane

We demonstrate two-dimensional photonic crystal cavities operating at telecommunication wavelengths in a single-crystal diamond membrane. We use a high-optical-quality and thin (~300 nm) diamond membrane, supported by a polycrystalline diamond frame, to realize fully suspended two-dimensional photonic crystal cavities with a high theoretical quality factor of ~8 × 10 6 and a relatively small mode volume of ~2(λ/n) 3 . The cavities are fabricated in the membrane using electron-beam lithography and vertical dry etching. We observe cavity resonances over a wide wavelength range spanning the telecommunication O- and S-bands (1360–1470 nm) with Q factors of up to ~1800. Our method paves the way for on-chip diamond nanophotonic applications in the telecommunication-wavelength range.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗