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At least 181 records · Page 10

High Pressure Cosmochemistry of Major Planetary Interiors: Laboratory Studies of the Water-rich Region of the System Ammonia-water

The behavior of gas-ice mixtures in major planets at very high pressures was studied. Some relevant pressure-temperature-composition (P-T-X) regions of the hydrogen (H2)-helium (He)-water (H2O-ammonia (NH3)-methane (CH4) phase diagram were determined. The studies, and theoretical model, of the relevant phases, are needed to interpret the compositions of ice-gas systems at conditions of planetary interest. The compositions and structures of a multiphase, multicomponent system at very high pressures care characterized, and the goal is to characterize this system over a wide range of low and high temperatures. The NH3-H2O compositions that are relevant to planetary problems yet are easy to prepare were applied. The P-T surface of water was examined and the corresponding surface for NH3 was determined. The T-X diagram of ammonia-water at atmospheric pressure was studied and two water-rich phases were found, NH3-2H2O (ammonia dihydrate), which melts incongruently, and NH3.H2O (ammonia monohydrate), which is nonstoichiometric and melts at a higher temperature than the dihydrate. It is suggested that a P-T surface at approximately the monohydrate composition and the P-X surface at room temperature is determined.

Nicol, M.↗

Nimbus 7 SMMR derived seasonal variations in the water vapor, liquid water, and surface winds over the global oceans

A study based on monthly mean maps of atmospheric water vapor, liquid water, and surface wind derived from Nimbus-7 SMMR over the oceans for 13 months, is examined. A discussion of the retrieval technique used to derive the parameters is presented. The seasonal changes in the strength and position of several of the parameter features are revealed by the December 1978 and June 1979 maps. Zonal averages of the water vapor, liquid water, and surface wind for December and June are compared with information derived from conventional measurements and the results are presented in graphs.

Prabhakara, C.↗

Performance characterization of water recovery and water quality from chemical/organic waste products

The water reclamation subsystems currently being evaluated for the Space Shuttle Freedom are briefly reviewed with emphasis on a waste water management system capable of processing wastes containing high concentrations of organic/inorganic materials. The process combines low temperature/pressure to vaporize water with high temperature catalytic oxidation to decompose volatile organics. The reclaimed water is of potable quality and has high potential for maintenance under sterile conditions. Results from preliminary experiments and modifications in process and equipment required to control reliability and repeatability of system operation are presented.

Moses, W. M.↗

Wet inside and out? Constraints on water in the Martian mantle and on outgassed water, based on melt inclusions in SNC meteorites

Constraints on the volatile inventory and outgassing history of Mars are critical to understanding the origin of ancient valley systems and paleoclimates. Planetary accretion models for Mars allow either a volatile-rich or volatile-poor mantle, depending on whether the accreted materials were fully oxidized or whether accretion was homogeneous so that water was lost through reaction with metallic iron. The amount of water that has been outgassed from the interior is likewise a contentious subject, and estimates of globally distributed water based on various geochemical and geological measurements vary from a few meters to more than a thousand meters. New data on SNC meteorites, which are thought to be Martian igneous rocks, provide constraints on both mantle and outgassed water.

Mcsween, H. Y., Jr.↗

Production of long-term global water vapor and liquid water data set using ultra-fast methods to assimilate multi-satellite and radiosonde observations

In recent years climate research scientists have recognized the need for increased time and space resolution precipitable and liquid water data sets. This project is designed to meet those needs. Specifically, NASA is funding STC-METSAT to develop a total integrated column and layered precipitable water data set. This is complemented by a total column liquid water data set. These data are global in extent, 1 deg x 1 deg in resolution, with daily grids produced. Precipitable water is measured by a combination of in situ radiosonde observations and satellite derived infrared and microwave retrievals from four satellites. This project combines these data into a coherent merged product for use in global climate research. This report is the Year 2 Annual Report from this NASA-sponsored project and includes progress-to-date on the assigned tasks.

Vonderhaar, Thomas H.↗

A New Neural Network Approach Including First-Guess for Retrieval of Atmospheric Water Vapor, Cloud Liquid Water Path, Surface Temperature and Emissivities Over Land From Satellite Microwave Observations

The analysis of microwave observations over land to determine atmospheric and surface parameters is still limited due to the complexity of the inverse problem. Neural network techniques have already proved successful as the basis of efficient retrieval methods for non-linear cases, however, first-guess estimates, which are used in variational methods to avoid problems of solution non-uniqueness or other forms of solution irregularity, have up to now not been used with neural network methods. In this study, a neural network approach is developed that uses a first-guess. Conceptual bridges are established between the neural network and variational methods. The new neural method retrieves the surface skin temperature, the integrated water vapor content, the cloud liquid water path and the microwave surface emissivities between 19 and 85 GHz over land from SSM/I observations. The retrieval, in parallel, of all these quantities improves the results for consistency reasons. A data base to train the neural network is calculated with a radiative transfer model and a a global collection of coincident surface and atmospheric parameters extracted from the National Center for Environmental Prediction reanalysis, from the International Satellite Cloud Climatology Project data and from microwave emissivity atlases previously calculated. The results of the neural network inversion are very encouraging. The r.m.s. error of the surface temperature retrieval over the globe is 1.3 K in clear sky conditions and 1.6 K in cloudy scenes. Water vapor is retrieved with a r.m.s. error of 3.8 kg/sq m in clear conditions and 4.9 kg/sq m in cloudy situations. The r.m.s. error in cloud liquid water path is 0.08 kg/sq m . The surface emissivities are retrieved with an accuracy of better than 0.008 in clear conditions and 0.010 in cloudy conditions. Microwave land surface temperature retrieval presents a very attractive complement to the infrared estimates in cloudy areas: time record of land surface temperature will be produced.

Aires, F.↗

The ISS Water Processor Catalytic Reactor as a Post Processor for Advanced Water Reclamation Systems

Advanced water processors being developed for NASA s Exploration Initiative rely on phase change technologies and/or biological processes as the primary means of water reclamation. As a result of the phase change, volatile compounds will also be transported into the distillate product stream. The catalytic reactor assembly used in the International Space Station (ISS) water processor assembly, referred to as Volatile Removal Assembly (VRA), has demonstrated high efficiency oxidation of many of these volatile contaminants, such as low molecular weight alcohols and acetic acid, and is considered a viable post treatment system for all advanced water processors. To support this investigation, two ersatz solutions were defined to be used for further evaluation of the VRA. The first solution was developed as part of an internal research and development project at Hamilton Sundstrand (HS) and is based primarily on ISS experience related to the development of the VRA. The second ersatz solution was defined by NASA in support of a study contract to Hamilton Sundstrand to evaluate the VRA as a potential post processor for the Cascade Distillation system being developed by Honeywell. This second ersatz solution contains several low molecular weight alcohols, organic acids, and several inorganic species. A range of residence times, oxygen concentrations and operating temperatures have been studied with both ersatz solutions to provide addition performance capability of the VRA catalyst.

Nalette, Tim↗

Integration of In-Flight and Post-Flight Water Monitoring Resources in Addressing the U.S. Water Processor Assembly Total Organic Carbon (TOC) Anomaly

Beginning in June of 2010, the total organic carbon (TOC) concentration in the U.S. Water Processor Assembly (WPA) product water started to increase. A surprisingly consistent upward TOC trend was observed through weekly ISS total organic carbon analyzer (TOCA) monitoring. As TOC is a general organic compound indicator, return of water archive samples was needed to make better-informed crew health decisions on the specific compounds of concern and to aid in WPA troubleshooting. TOCA-measured TOC was more than halfway to the health-based screening limit of 3,000 g/L before archive samples were returned. Archive samples were returned on 22 Soyuz in September 2010 and on ULF5 in November of 2010. The samples were subjected to extensive analysis. Although TOC was confirmed to be elevated, somewhat surprisingly, none of the typical target compounds were detected at high levels. After some solid detective work, it was confirmed that the TOC was associated with a compound known as dimethylsilanediol (DMSD). DMSD is believed to be a breakdown product of siloxanes which are thought to be ubiquitous in the ISS atmosphere. A toxicological limit was set for DMSD and a forward plan was developed for conducting operations in the context of understanding the composition of the TOC measured in flight. This required careful consideration of existing ISS flight rules, coordination with ISS stakeholders, and development of a novel approach for the blending of inflight TOCA data with archive results to protect crew health. Among other challenges, team members had to determine how to utilize TOCA readings when making decisions about crew consumption of WPA water. This involved balancing very real concerns associated with the assumption that TOC would continue to be comprised of only DMSD. Demonstrated teamwork, multidisciplinary awareness, and innovative problem-solving were required to respond effectively to this anomaly.

Straub, John E., II↗

Midwest Water Resources II: Evaluating Evapotranspiration with NASA Earth Observations and In Situ Observations to Understand Water Balance in Midwest Agriculture

Seasonal water variability in the midwestern United States extensively affects the agricultural community, as it impacts irrigation schedules, growing seasons, and overall ecosystem function. Evapotranspiration (ET) is a critical climatic variable in the water cycle and is used to evaluate spatiotemporal trends in drought and flood conditions. The NASA DEVELOP team partnered with the United States Department of Agriculture (USDA) Midwest Climate Hub, the Minnesota Department of Agriculture, the Illinois State Water Survey, and Michigan State University to compare remotely sensed ET products with in situ observations from January 2001 through December 2020. Remotely sensed actual ET (aET) data were sourced from NASA’s Terra Moderate Resolution Imaging Spectroradiometer (MODIS), and reference ET (refET) data were derived from the Gridded Surface Meteorological (gridMET) dataset. For in situ comparison, aET data were downloaded from the AmeriFlux database while refET data were collected from the Illinois Climate Network and Michigan State University’s Enviro-weather database. For a holistic assessment of ET, this project generated comparisons between remotely sensed and in situ observations, calculated descriptive statistics for validation between refET datasets, and spatially produced statistical validation maps regarding in situ sites. The temporal and spatial gaps of AmeriFlux data limited aET analysis. This comparative assessment of ET products across the Midwest can be used by project partners to assess regional water trends and guide future land management decisions.

Addison Pletcher↗

Risks and Benefits of Pressurized Water Reactor Coupling to Energy Storage and Water Desalination

This research explored potential options to improve nuclear pressurized water reactors’ (PWRs) operational flexibility through integration with thermal energy storage (TES) and water desalination technologies. Benefits and challenges of TES technologies were reviewed, which includes sensible heat storage systems, latent heat storage systems, and thermochemical storage systems. Water desalination technologies were reviewed and compared, which includes multi-stage flash, reverse osmosis, and multi-effect distillation. The multi-effect distillation technology was selected to be coupled with a generic PWR. Risk of this cogeneration was quantified using the probabilistic risk assessment (PRA) methodology. Results suggest that nuclear-desalination cogeneration can be done safely because the additional risk to the PWR is trivial, and even in certain cases the PWR risk is decreased. This cogeneration operation is expected to improve efficiency of thermal utilization and the nuclear plant’s revenues. In summary, this study supports the potential of nuclear-desalination cogeneration systems to address water scarcity while optimizing nuclear energy use and managing safety.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

Water-Fed, Photovoltaic-Driven Anion-Exchange Membrane Water Electrolysis for Solar Hydrogen Production

Direct coupled photovoltaic (PV)-electrolysis is a promising approach for low-cost hydrogen production, avoiding the need for separate electricity generation. Without solar concentration, the operating current densities of a PV-electrolyzer are small, and low capital costs are needed to reach hydrogen production cost targets (<$2/kg). Anion-exchange membrane (AEM) electrolyzers could be well-suited for this application due to their ability to use platinum group metal (PGM)-free catalysts and operate without supporting electrolytes, but a water-fed PV-AEM system has not yet been demonstrated. In this work, the performance of two AEM electrolyzer designs under pure-water, low-temperature, and diurnal-cycling conditions was evaluated. A simple PV-electrolyzer system design with direct electric coupling to a commercial 84 cm2 Si mini module and passive heating and water flow to the electrolyzer was used for on-sun testing in October 2025. The best-performing PV-AEM system achieved an average solar-to-hydrogen (STH) efficiency of 6.6% and a production rate of 15 mg/kWh/m2 of solar irradiance over 11 days. Minimal electrolyzer corrosion was observed, with no loss in efficiency over the diurnal cycles. While highlighting areas for improved electrolyzer and system design, this work is a proof of concept for distributed hydrogen production using inexpensive and abundant materials.

08 HYDROGEN↗

Reducing stomatal density by expression of a synthetic epidermal patterning factor increases leaf intrinsic water use efficiency and reduces plant water use in a C4 crop

Abstract Enhancing crop water use efficiency (WUE) is a key target trait for climatic resilience and expanding cultivation on marginal lands. Engineering lower stomatal density to reduce stomatal conductance (gs) has improved WUE in multiple C3 crop species. However, reducing gs in C3 species often reduces photosynthetic carbon gain. A different response is expected in C4 plants because they possess specialized anatomy and biochemistry which concentrates CO2 at the site of fixation. This modifies the relationship of photosynthesis (AN) with intracellular CO2 concentration (ci), such that photosynthesis is CO2 saturated and reductions in gs are unlikely to limit AN. To test this hypothesis, genetic strategies were investigated to reduce stomatal density in the C4 crop sorghum. Constitutive expression of a synthetic epidermal patterning factor (EPF) transgenic allele in sorghum led to reduced stomatal densities, reduced gs, reduced plant water use, and avoidance of stress during a period of water deprivation. In addition, moderate reduction in stomatal density did not increase stomatal limitation to AN. However, these positive outcomes were associated with negative pleiotropic effects on reproductive development and photosynthetic capacity. Avoiding pleiotropy by targeting expression of the transgene to specific tissues could provide a pathway to improved agronomic outcomes.

59 BASIC BIOLOGICAL SCIENCES↗

Hydrometeor Transport and the Stratiform Water Budget in Amazonian Mesoscale Convective Systems

A significant portion of precipitation falls within the stratiform regions of mesoscale convective systems (MCSs). These regions are formed from convective clouds that have either weakened and formed a horizontally stratified structure or have advected hydrometeors to form a trailing-stratiform region, with further precipitation growth promoted by in situ dynamical and microphysical processes. Green Ocean Amazon 2014/5 (GoAmazon2014/5) field campaign observations are used to quantify the stratiform water budget of six MCSs (three each from the wet and dry seasons) utilizing the framework from Leary and Houze, with an emphasis on the transfer of hydrometeors (C A ) from the convective to the stratiform regions. The storms were predominantly leading-line/trailing-stratiform MCSs, but two had embedded convection in the stratiform region, which can complicate water budget calculations. A pulse-like pattern with a mean interval of 21 min occurs in C A during each storm resulting from a lag between the initial convective updrafts and the subsequent hydrometeor transport and sedimentation in the stratiform region. Here, the peaks in C A were followed by peaks in hydrometeor growth associated with the mesoscale updraft (C mu ) in the stratiform region. Averaged over the six storms, the positive contributions of C A and C mu to the stratiform water budget were roughly equal, although storm-to-storm variations existed. Negative contributions from evaporation below cloud base in the mesoscale downdraft and detrainment from the stratiform region into the nonprecipitating anvil cloud and environment accounted for 53% and 21% of the sum of C A and C mu , respectively, resulting in a mean stratiform region precipitation efficiency of 26%.

54 ENVIRONMENTAL SCIENCES↗

Big Cypress Water Resources: Using Earth Observations to Assess Water Quality in Big Cypress Reservation, FL

Upstream agricultural development and runoff are driving harmful algal blooms in the Big Cypress Reservation. The Seminole Tribe of Florida Environmental Resource Management Department monitors water quality in the Big Cypress Reservation, located on the north end of Big Cypress National Preserve. The Environmental Resource Management Department aims to incorporate Earth observations into its investigative approach, which consists of Geographic Information Systems and in situ water sampling. We assessed the feasibility of using Earth observations to measure harmful algal blooms over time and identify vulnerable areas. We analyzed data from multiple remote sensing platforms and sensors, including Landsat 8 Thermal Infrared Spectrometer(TIRS), Landsat 9 TIRS-2, Landsat 9 Operational Land Imager 2, Sentinel-2 MultiSpectral Instrument, and Sentinel-3 Ocean and Land Color Instrument. We determined that it was challenging to use Sentinel-3, Landsat 8, and Landsat 9 imagery for monitoring the canals within the Reservation, and that Sentinel-2 was the most capable platform for the study area. Using Sentinel-2, we created spectral indices for the detection of algal blooms. We used these indices to measure algal blooms at 8 stations across the Big Cypress Reservation. We then created time series and seasonal decompositions of in situ water sample data and indices to visualize relationships between datasets, along with correlation matrices. Our correlations were not conclusive. However, we found that the spectral indices have the potential to detect algal blooms. Lastly, we evaluated Maxar WorldView-3 imagery and found that using data from sensors with higher spatial resolutions would improve results.

Remote sensing↗

Deformation band corrosion as a result of applied stress and cold-work in 304 stainless steel in simulated pressurized water reactor primary water conditions

Stainless steels like 304SS are commonly used in pressurized water reactor primary water environments due to their excellent resistance to stress corrosion cracking (SCC). However, SCC susceptibility has been observed in cold-worked 304SS. Cold-rolling introduces a high density of defects, such as deformation bands or dislocations, into the microstructure; applied stress, even if macroscopically below the yield stress, can result in regions with high localized stresses. Cold-worked and non-cold-worked samples were exposed to 360 °C simulated PWR primary water for 1500 h with and without active loading. Corrosion susceptibility of dislocations and deformation bands induced by cold-rolling and/or applied stress was studied using high-resolution (analytical) transmission electron microscopy. Deformation bands were generated in all specimens examined in the study. Penetrative oxidation was observed in some deformation bands in each specimen. The depth of penetrative deformation band oxidation frequently exceeded the depth of grain boundary oxidation in all specimens. However, deformation band oxides generally were narrowly confined to the deformation band plane. Highly Ni-rich regions were observed beyond all oxidation fronts. Surface oxides were thicker in the specimens exposed under active loading. In conclusion, the implications of these findings at surfaces for deformation bands intersecting stress corrosion crack paths are discussed.

EFTEM↗

Resolving the Solvation Structure and Transport Properties of Aqueous Zinc Electrolytes from Salt-in-Water to Water-in-Salt Using Neural Network Potential

Zn Cl 2 solutions are promising electrolytes for aqueous zinc-ion batteries. Here, we report a joint computational and experimental study of the structural and dynamic properties of aqueous Zn Cl 2 electrolytes with concentrations ranging from salt-in-water to water-in-salt (WIS). By developing a neural network potential (NNP) model, we perform molecular dynamics (MD) simulations with accuracy but at much larger lengths and longer timescales. The NNP predicted structures are validated by the structure factors measured by X-ray total scattering experiments. The MD trajectories provide a comprehensive and quantitative picture of the Zn 2 + solvation shell structures. Additionally, we find that the O − H covalent bonds in water are strengthened with increasing salt concentration, thus expanding the electrochemical stability window of aqueous electrolytes. In terms of dynamic properties, the calculated and experimentally measured conductivities are in good agreement. Through the analysis of the calculated cation transference number, we propose a three-stage charge carrier transport mechanism with increasing concentration: independent ion transport, strongly correlated ion transport, and small positive charge carrier diffusion through negatively charged polymeric clusters. Our study provides fundamental atomic scale insights into the structure and transport properties of the Zn Cl 2 electrolyte that can aid the optimization and development of WIS electrolytes. Published by the American Physical Society 2025

25 ENERGY STORAGE↗

A practical method of determining water current velocities and diffusion coefficients in coastal waters by remote sensing techniques

A simplified procedure is presented for determining water current velocities and diffusion coefficients. Dye drops which form dye patches in the receiving water are made from an aircraft. The changes in position and size of the patches are recorded from two flights over the area. The simplified data processing procedure requires only that the ground coordinates about the dye patches be determined at the time of each flight. With an automatic recording coordinatograph for measuring coordinates and a computer for processing the data, this technique provides a practical method of determining circulation patterns and mixing characteristics of large aquatic systems. This information is useful in assessing the environmental impact of waste water discharges and for industrial plant siting.

James, W. P.↗

Photometric and polarimetric mapping of water turbidity and water depth

A Digital Photometric Mapper (DPM) was used in the Fall of 1971 in an airborne survey of New York and Boston area waters to acquire photometric, spectral and polarimetric data. The object of this study is to analyze these data with quantitative computer processing techniques to assess the potential of the DPM in the measurement and regional mapping of water turbidity and depth. These techniques have been developed and an operational potential has been demonstrated. More emphasis is placed at this time on the methodology of data acquisition, analysis and display than on the quantity of data. The results illustrate the type, quantity and format of information that could be generated operationally with the DPM-type sensor characterized by high photometric stability and fast, accurate digital output. The prototype, single-channel DPM is suggested as a unique research tool for a number of new applications. For the operational mapping of water turbidity and depth, the merits of a multichannel DPM coupled with a laser system are stressed.

Halajian, J.↗