Inelastic molecular scattering
Molecular beam study of vibrational state population ratio changes for CsF colliding with CO2, and inelastic scattering theory
Fenstermaker, R. W.↗
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Results for “Vibrational states”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Nonadiabatic translations in polyatomic molecules
Matrix elements of nonadiabatic perturbation emphasized in semiempirical theory for evaluating polyatomic molecules radiationless rate constants in terms of electronic-vibrational state
Young, J. H.↗
Vibrational population distributions in nonequilibrium nozzle expansion flows
Experimental measurements and theoretical calculations of the vibrational population distribution in nonequilibrium nozzle expansion flows of gas mixtures are reported. These studies were directed toward determining whether vibrational energy exchange pumping could lead to laser action on the vibrational bands of a diatomic molecule. Three different types of experiments were conducted. These showed (1) that vibrational energy was preferentially transferred from N2 to CO in supersonic nozzle flows containing these gases; (2) that under some conditions this vibrational energy exchange pumping mechanism created population inversions in the vibrational levels of CO; and (3) that at large expansion ratios the magnitude of these population inversions was sufficient to sustain lasing in the nozzle. A theoretical model was developed to calculate vibrational state population distributions in gas dynamic expansions of a mixture of diatomic gases. Although only isothermal calculations have been completed, these data indicate that population inversions are predicted for conditions similar to those obtained in the nozzle expansion flows.
Watt, W. S.↗
Precise laboratory determination of rotational transition frequencies in cyanoacetylene.
The results are discussed of a high-precision laboratory determination of the rotational constants and transition frequencies in the ground vibrational state of the linear molecule cyanoacetylene, discovered in the direction of the galactic center by Turner (1971). The values obtained make it possible to determine more precisely the interstellar cyanoacetylene velocities and to simplify the identification of additional interstellar rotational transitions.
De Zafra, R. L.↗
Broadening of the infrared absorption lines at reduced temperatures. II - Carbon monoxide in an atmosphere of carbon dioxide.
The strengths of the rotational lines in the R branch of the CO fundamental have been determined at temperatures of 298, 202, and 132 K by means of a high-resolution spectrograph. The results can be used to determine line strengths at other temperatures by means of the Herman-Wallis relation or by considerations of the populations of the rotational levels in the ground vibrational state. Parameters describing the self-broadening and carbon dioxide broadening of CO lines have been determined at 298 and 202 K. The results are compared with other recent experimental and theoretical studies.
Tubbs, L. D.↗
A high-pressure carbon dioxide gasdynamic laser
A carbon dioxide gasdynamic laser was operated over a range of reservoir pressure and temperature, test-gas mixture, and nozzle geometry. A significant result is the dominant influence of nozzle geometry on laser power at high pressure. High reservoir pressure can be effectively utilized to increase laser power if nozzle geometry is chosen to efficiently freeze the test gas. Maximum power density increased from 3.3 W/cu cm of optical cavity volume for an inefficient nozzle to 83.4 W/cu cm at 115 atm for a more efficient nozzle. Variation in the composition of the test gas also caused large changes in laser power output. Most notable is the influence of the catalyst (helium or water vapor) that was used to depopulate the lower vibrational state of the carbon dioxide. Water caused an extreme deterioration of laser power at high pressure (100 atm), whereas, at low pressure the laser for the two catalysts approached similar values. It appears that at high pressure the depopulation of the upper laser level of the carbon dioxide by the water predominates over the lower state depopulation, thus destroying the inversion.
Kuehn, D. M.↗
Infrared pumping processes for SiO masers
The J = 2 to 1 transition of the first excited vibrational state (v = 1) Si(28)O(16) has recently been shown to produce maser amplification near 86,245 MHz in Orion A and in several stars. Two possible pumping mechanisms are proposed for such masers. One involves the near coincidence between the frequencies of the 1-0 (RO) and 3-2 (R18) transitions in Si(28)O(16). The other requires emission by SiO and reabsorption without the necessity for an accidental frequency coincidence. Each of these types of mechanisms may occur for other transitions of molecules in a medium illuminated by intense infrared radiation, or with strong temperature gradients.
Geballe, T. R.↗
Dynamic substructure analysis of the International Ultraviolet Explorer (IUE) spacecraft
The results are presented of a steady state vibration analysis of the IUE spacecraft simulating its sinusoidal vibration test. The model of the spacecraft, including solar arrays and the scientific instrument, consisted of three separate substructure models one of which was used to represent the two identical solar arrays. Substructuring techniques were used since the large overall size of the problem precluded solving it utilizing a single model. The models used for each substructure are discussed, including reduction to an acceptable size for the combined dynamic analysis. The DMAP alters needed for performing the modal analysis and the subsequent modal frequency response and substructure data recovery are included. Comparison of the results with data obtained during vibration tests of the spacecraft are also included.
Case, W. R.↗
Vibrationally excited SiO - A new type of maser source in the millimeter wavelength region
The recently discovered strong emission lines at 86.24 GHz from the J = 2-1 rotational transition of SiO in its first excited vibrational state have been found to be a maser source associated with infrared stars. Twelve maser sources have been detected, and almost all are late M-type Mira or semiregular variables. Many of the known OH/H2O/IR sources are also SiO maser sources, and good velocity correlations between SiO and H2O emission profiles were found. Characteristics of these new SiO maser sources are discussed.
Kaifu, N.↗
Recombination of NO/+/ in the ionosphere
Simultaneous nighttime measurements of ion and neutral concentrations and temperatures made by the Atmosphere Explorer-C satellite were used to determine the recombination rate coefficient of NO(+) as a function of electron temperature. The results agree in shape and absolute magnitude to within one standard deviation with those of Walls and Dunn (1974), indicating that NO(+) ions in the ionosphere may be in the ground vibrational state.
Torr, D. G.↗
Recombination of O2/+/ in the ionosphere
In spite of the excellent agreement between various laboratory measurements of the recombination rate of O2(+) with electrons, it is still questionable whether the laboratory results apply in the ionosphere, because although the radiative lifetime of vibrating O2(+) is not well known, indications are that it may be very long. Whether the laboratory results apply in the atmosphere depends on whether the recombination rate is dependent on the vibrational state of the O2(+) ion and on whether the ions are deactivated (or not) in both the laboratory experiments and the atmosphere prior to recombination. To obtain reliable answers to these questions, the present study was carried out to determine the recombination of O2(+) in the ionosphere from in situ measurements of the relevant temperatures and densities made by the open source mass spectrometer carried by the AE-C satellite. The photochemistry involved is discussed. The results show that the ionospheric determination of the recombination rate of O2(+) with electrons agrees with the laboratory measurements of Walls and Dunn (1974) for electron temperatures between 1200 and 2000 K.
Torr, D. G.↗
Infrared vibration-rotation spectra of the ClO radical using tunable diode laser spectroscopy
Tunable diode laser spectroscopy is used to measure the infrared vibration-rotation spectra of the ClO radical. The radical is generated in a flow system where a Cl2-He mixture passes through a microwave discharge to dissociate the Cl2. An O3-O2 mixture from an ozone generator is injected into the system downstream of the microwave discharge where O3 combines with Cl to form ClO. By adjusting the gas flow rates to yield an excess of Cl atoms, all the ozone is combined. ClO concentration is measured with UV absorption at 2577 and 2772 A and a deuterium lamp as a continuous source. Total cell pressure is 5.5 torr. The diode laser spectrometer is calibrated with ammonia lines as a reference where possible. The frequency of vibration-rotation lines is expressed as a function of rotational quantum number, fundamental vibrational frequency, and the rotational constants of the upper and lower vibrational states.
Rogowski, R. S.↗
Observation of nuclear quadrupole hyperfine structure in the infrared spectrum of hydrogen iodide using a tunable-diode laser
Nuclear quadrupole hyperfine structure has been observed in the 1-0 vibration-rotation band of hydrogen iodide with a tunable-diode laser. The measured splittings agree well with microwave measurements of the HI molecule. Evidence for a slight change in the iodine nuclear quadrupole coupling constant from the ground to first excited vibrational state in hydrogen iodide was found.
Strow, L. L.↗
Photoexcitation of lasers and chemical reactions for NASA missions: A theoretical study
The possibility of obtaining CW laser oscillation by optical pumping in the infrared at an elevated gas pressure is reviewed. A specific example utilizing a mixture of CO and NO gases is included. The gas pressures considered are in excess of several atmospheres. Laser frequency tuning over a broad region becomes possible at such elevated gas pressures due to collisional broadening of the amplifying transitions. The prior-rate and surprisal analysis are applied to obtain detailed VV and VT rates for CO and NO molecules and the transfer rates in a CO-NO gas mixture. The analysis is capable of giving temperature dependence of the rate constants. Computer estimates of the rates are presented for vibrational levels up to v = 50. The results show that in the high-lying vibrational states the VV transfer rates with Delta nu = 2 become appreciable.
Javan, A.↗
Molecule formation and infrared emission in fast interstellar shocks. II - Dissociation speeds for interstellar shock waves
The postshock destruction of molecules is examined, including the processes of (1) collisions with neutral hydrogen atoms and molecules, (2) electronic collisions, and (3) neutral chemical reactions with atoms, particularly atomic hydrogen. By using conservative estimates of collisional dissociation rates from individual vibrational states, it is found that process (1) leads to the destruction of molecular hydrogen behind shocks with speeds equal to or greater than 25 km/s if the preshock molecular gas has hydrogen nucleus densities of equal to or greater than 10 to the 4th/cu cm. At lower densities (100 per cu cm), destruction occurs for shock speeds equal to or greater than 50 km/s and process (2) dominates. Dissociation of molecules such as CO, H2O, and O2 follows the destruction of H2, as the resultant hydrogen atoms chemically dissociate the metal atoms from their bonds (process 3) in the hot postshock gas. These results demonstrate that many of the observed high-speed interstellar molecules, if shock accelerated, must have dissociated and reformed in the postshock gas.
Hollenbach, D.↗
Experimental and Theoretical Studies of Interstellar Grains
Steady state vibrational populations of SiO and CO in dilute black body radiation fields were calculated as a function of total pressure, kinetic temperature and chemical composition of the gas. Approximate calculations for polyatomic molecules are presented. Vibrational disequilibrium becomes increasingly significant as total pressure and radiation density decrease. Many regions of postulated grain formation are found to be far from thermal equilibrium before the onset of nucleation. Calculations based upon classical nucleation theory or equilibrium thermodynamics are expected to be of dubious value in such regions. Laboratory measurements of the extinction of small iron and magnetite grains were made from 195 nm to 830 nm and found to be consistent with predictions based upon published optical constants. This implies that small iron particles are not responsible for the 220 nm interstellar extinction features. Additional measurements are discussed.
Nuth, J. A., III↗
Modelling of the 10-micrometer natural laser emission from the mesospheres of Mars and Venus
The NLTE radiative transfer problem is solved to obtain the 00 deg 1 vibrational state population. This model successfully reproduces the existing center-to-limb observations, although higher spatial resolution observations are needed for a definitive test. The model also predicts total fluxes which are close to the observed values. The strength of the emission is predicted to be closely related to the instantaneous near-IR solar heating rate.
Deming, D.↗
Identification of forbidden transitions in the nu-4 band of (N-14)H3 by intracavity laser-Stark spectroscopy
These transitions are forbidden in the sense that they follow the selection rule delta K = + or - 2, which violates the usual rule that delta K = + or - 1 for a perpendicular band of a symmetric top, where K is the projection of the total angular momentum onto the molecular symmetry axis. The assignments are based for the most part on laser-Stark measurements made with a CO laser and an intracavity Stark cell. The procedure followed in making the assignments is described. Attention is called to the significance of these new lines in the analysis of the nu-4 vibrational state and in an improved determination of the ground-state rotational and centrifugal distortion constants.
Weber, W. H.↗