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At least 181 records · Page 10

Experimental mineral/liquid partition coefficients of the rare earth elements /REE/, Sc and Sr for perovskite, spinel and melilite

Experimental determinations of the mineral/liquid partition coefficients of REE (La, Sm, Eu, Gd, Tb, Yb and Lu), Sc and Sr are reported for the minerals perovskite, spinel and melilite in synthetic systems. Perovskite concentrates light REE with respect to the residual liquid but shows no preference for heavy REE. Spinel greatly discriminates against the incorporation of REE, especially light REE, into its crystal structure. The partition of REE into melilite from a silicate liquid is quite dependent upon both the bulk melt and melilite solid-solution (gehlenite and akermanite components) compositions. As such, melilite can be enriched in REE or will reject REE with corresponding strong negative or strong positive Eu anomalies, respectively.

Nagasawa, H.↗

The ultraviolet spectrum of the peculiar A star HD 51418

High-dispersion observations of the peculiar A star HD 51418 have been carried out in the ultraviolet by the IUE satellite. Atomic resonance lines observed in the regions 1800-2000 and 2500-3000 A include those of Mg II, Ti II, Cr I, Cr II, Mn II, Fe II and Zn II, and possibly Si II, S I, V II, Fe I, Co II, Y II, Ce II, Ce III, Eu II, Eu III and Tb III. The Mg II 2796 and 2803 A resonance lines exhibit definite variations in equivalent width with orbital phase, which can be attributed to changes in the local atmospheric structure due to the patchy distribution of other elements. In addition, the observations confirm the well known trend for a light-heavy asymmetry in iron peak spectra similar to that observed in the rare earths.

Adelman, S. J.↗

Method for shaping and aiming narrow beams

A sonar method and apparatus is discribed which utilizes a linear frequency chirp in a transmitter/receiver having a correlator to synthesize a narrow beamwidth pattern from otherwise broadbeam transducers when there is relative velocity between the transmitter/receiver and the target. The chirp is so produced in a generator in bandwidth, B, and time, T, as to produce a time bandwidth product, TB, that is increased for a narrower angle. A replica of the chirp produced in a generator is time delayed and Doppler shifted for use as a reference in the receiver for correlation of received chirps from targets. This reference is Doppler shifted to select targets preferentially, thereby to not only synthesize a narrow beam but also aim the beam in azimuth and elevation.

Heyser, R. C.↗

Surface morphology of erbium silicide

The surface of rare-earth silicides (Er, Tb, etc.), formed by the reaction of thin-film metal layers with a silicon substrate, is typically dominated by deep penetrating, regularly shaped pits. These pits may have a detrimental effect on the electronic performance of low Schottky barrier height diodes utilizing such silicides on n-type Si. This study suggests that contamination at the metal-Si or silicide-Si interface is the primary cause of surface pitting. Surface pits may be reduced in density or eliminated entirely through either the use of Si substrate surfaces prepared under ultrahigh vacuum conditions prior to metal deposition and silicide formation or by means of ion irradiation techniques. Silicide layers formed by these techniques possess an almost planar morphology.

Lau, S. S.↗

The chemistry of rare earth elements in the solar nebula

The high concentration of rare earth elements (REE) in primitive CaS suggests that the REE along with the other normally lithophile elements form stable sulfides under the unusual conditions which existed during the formation of enstatite chrondites. In order to acquire a more quantitative framework in which to interpret these data, the behavior of the REE in systems with solar, or slightly fractionated solar, composition is being studied. These new data introduce modest changes in the behavior of some of the REE when compared to previous studies. For example, the largest differences are in the stabilities of the gaseous monoxides of Ce, Eu, Tb, Ho, and Tm, all of which now appear to be less stable than previously thought, and YbO(g) which is somewhat more stable. Much more significant are the changes in REE distribution in the gas phase in fractionated systems, especially those made more reducing by changing the C/O ratio from the solar value of 0.6 to about 1.0. In almost all cases, the exceptions being Eu, Tm and Yb whose elemental gaseous species dominate, the monosulfides become more abundant. Moreover, the solid oxides of Eu, Tm and Yb become less stable under more reducing conditions which, in effect, should reduce the condensation temperature of all REE in more reduced systems.

Larimer, J. W.↗

On the solution of integral equations with a generalized cauchy kernel

In this paper a certain class of singular integral equations that may arise from the mixed boundary value problems in nonhomogeneous materials is considered. The distinguishing feature of these equations is that in addition to the Cauchy singularity, the kernels contain terms that are singular only at the end points. In the form of the singular integral equations adopted, the density function is a potential or a displacement and consequently the kernel has strong singularities of the form (t-x) sup-2, x sup n-2 (t+x) sup n, (n or = 2, 0x,tb). The complex function theory is used to determine the fundamental function of the problem for the general case and a simple numerical technique is described to solve the integral equation. Two examples from the theory of elasticity are then considered to show the application of the technique.

Kaya, A. C.↗

A continued program of planetary study at the University of Texas McDonald Observatory

The beginning of eclipses of the Pluto-Charon system was detected. The onset of coma formation of P/Halley at 5.4 au was detected and evidence of sublimation at 4.8 au when CN emission was detected. Extensive spatial maps of the gas in the comae of comets Halley and Giacobini-Zinner were obtained in fall 1985. Halley was time variable, and Giacobini-Zinner was depleted in C2 and C3 relative to CN. Comet Kopff was shown to have a pre-perihelion brightness maximum of its gas, consistent with mantle development if the comet is a high obliquity object. New Haser model scale lengths for CN, C3, and C2 were determined using results from the Faint Comet Survey. Spectra of 12 asteroids in unusual orbits showed no evidence of any comet-like emission features. In particular, 3200 Phaethon (1983 TB) has no gas or dust coma, in spite of the similarity of its orbit with the Geminid meteor stream. Data were analyzed on Saturn's H2 and CH4 bands for the recent southern summer using a Tomasko-Doose type of haze distribution. This haze model fits the data moderately well, giving a CH4 mixing ratio of (4.2 + or 0.4)x003. Simple functions were found to approximate the collision-induced rotation-translation thermal opacity of H2.

Smith, H. J.↗

Astrometric observations of comets and asteroids and subsequent orbital investigations

During the past year some 500 observations were made on 66 nights and published on the MPCs (Minor Planet Circulars/Minor Planets and Comets). In addition, a handful of measurements of earlier plates were completed and published. 121 of the observations published referred to comets. Of special importance were observations of comets (P/Giacobini-Zinner and P/Halley) in connection with the NASA ICE and ESA Giotto missions, but a special effort was made to get good coverage of almost all of the observable comets. Observations were also made of (2060) Chiron and of the earth-approaching objects (1627) Ivar, (1866) Sisyphys, (1943) Anteros, (3362) 1984 QA, 1985 JA, PA, TB and WA, and 1986 DA and EB. 46 minor planets were given permanent numbers entirely as a result of the observations.

Mccrosky, R. E.↗

Astrometric observations of comets and asteroids and subsequent orbital investigations

The 155-cm reflector was used for observations of comets and minor planets on 32 nights during April-October. The distribution was fairly uniform, ranging from 45 in June and September to 28 in July: on September 1 a total of 17 observations was made. A table is included which lists the 230 measurements published during the semester. These include six additional measurements going back to 1984 and the republication of a previously misidentified 1976 observation as a new discovery. Thirty-two of the observations refer to comets, 83 to numbered minor planets, and the remainder to unnumbered minor planets. Among the older-numbered minor planets observed were the Earth-approaching objects (3103) 1982 BB, (3199) 1982 RA (Nefertiti), (3361) 1982 HR and (3362) 1984 QA (Khufu), some of which were of interest for radar experiments. Unnumbered Earth-approaching objects observed were 1963 RH, 1983 RD, 1985 TB and 1986 DA, as well as the new discoveries 1986 JK, 1986 LA and 1986 PA.

Mccrosky, R. E.↗

Growth-induced anisotropy in bismuth - Rare-earth iron garnets

The bismuth-doped rare-earth iron garnets, (R3-x-yBixPby)Fe5O12 (Bi:RIG, R = Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y), were prepared under constant growth conditions to investigate the influence of ionic species on the bismuth-based growth-induced uniaxial anisotropy K(u) exp g. The effect of ionic species on growth-induced anisotropy in Bi:RIG was not consistent with the ionic size model of site ordering. In particular, Bi:SmIG, Bi:EuIG, and Bi:TbIG displayed high growth-induced anisotropies, up to 331,000 erg/cu cm at room temperature for x of about 0.5. The temperature dependence of these K(u) exp gs was somewhat higher than that of the well studied Bi:YIG. The site ordering of Bi can be modeled by assuming that small, low-oxygen-coordination BiOw exp +3-2 w melt complexes have a strong site selectivity for small, high-oxygen coordination sites at the growth interface.

Fratello, V. J.↗

Automated detection of severe thunderstorms using geosynchronous infrared data

A procedure to identify thunderstorms from short-interval (5 min) GOES infrared (IR) data and to estimate their intensity (updraft strength) in an automated fashion is described. Thunderstorms are identified in the IR field by a simple pattern-recognition approach. For mature thunderstorms, two key parameters are used to estimate intensity: the amount of penetration above the neutral point and the occurrence (or not) of a cold-warm couplet in the IR TB field. Based on cloud model results, the amount of penetration is related to the maximum updraft speed, which is converted to an index. Application of the algorithm to a case study is presented.

Adler, Robert F.↗

Spaceborne optical disk controller development

The current status and potential applications of an optical-disk buffer (ODB) memory system being developed by an interagency consortium including NASA and the USAF are reviewed. The design goals for the ODB include usable capacity 1 Tb, maximum data rate 1.6 Gb/s, read error rate less than 10 to the -12th, time to initial access less than 100 ms, and unlimited read/write cycles. Present efforts focus on a brassboard ODB which employs 12 14-inch magnetooptic disks and 24 nine-diode read/write heads. A typical space application of an optical disk mass memory system (ODMMS) is discussed: as communications buffer, temporary storage, and/or multiuser I/O buffer for data management on the Space Station Earth Observing System. Environmental, operational, system-architecture, and functional-separation factors; critical design issues; and standardization questions for spaceborne ODMMSs are examined in detail.

Shull, Thomas A.↗

Mapping freeze/thaw boundaries with SMMR data

Nimbus 7 Scanning Multichannel Microwave Radiometer (SMMR) data are used to map daily freeze/thaw patterns in the upper Midwest for the Fall of 1984. The combination of a low 37 GHz radiobrightness and a negative 10.7, 18, and 37 GHz spectral gradient, Partial Derivative of Tb with Respect to f, appears to be an effective discriminant for classifying soil as frozen or thawed. The 37 GHz emissivity is less sensitive to soil moisture than are the lower frequency emissivities so that the 37 GHz radiobrightness appears to track soil surface temperature relatively well. The negative gradient for frozen ground is a consequence of volume scatter darkening at shorter microwave wavelengths. This shorter wavelength darkening is not seen in thawed moist soils.

Zuerndorfer, B. W.↗

Transport critical current and magnetization measurements of melt-processed YBa2Cu3O(7-x)

This paper reports on the magnetic field dependence of the transport critical current and dc magnetic susceptibility measurements on YBa2Cu3O(7-x) superconductors formed by melt-solid reactions at 950 C between Ba-Cu-O (or Tb-Ba-cu-O) and solid nonstoichiometric Y-Ba-Cu oxide. Four-probe dc critical current measurements at 77, 64, and 4.2 K show strong depression of the critical current density with increasing magnetic field, in agreement with a model of weakly linked superconducting regions. Diamagnetic shielding and Meissner flux expulsion measurements in the temperature range 10-300 K show about one-third volume fraction of perfect superconductivity. Both shielding and flux expulsion were observed to be approximately temperature independent below 60 K, indicating strong coupling between the grains throughout the entire volume below this temperature.

Hermann, A. H.↗

Effects of grain size and grain boundary on critical current density of high T(sub c) superconducting oxides

By means of adding impurity elements in high T sub c oxides, the effects were studied of grain size and grain boundary on the critical current density of the following systems: YBa2Cu3O(7-y) and Bi-Pr-Sr-Ca-Cu-O. In order to only change the microstructure instead of the superconductivity of the grains in the samples, the impurity elements were added into the systems in terms of the methods like this: (1) substituting Y with the lanthanide except Pr, Ce, and Tb in YBa2Cu3O(7-y) system to finning down grains in the samples, therefore, the effect can be investigated of the grain size on the critical current density of 1:2:3 compounds; (2) mixing the high T sub c oxides with the metal elements, such as Ag, according to the composition of (high T sub c oxide)1-xAgx to metallize the grain boundaries in the samples, studying the effect of the electric conductivity of the grain boundaries on the critical current density; (3) adding SiO2, PbO2, and SnO2 into the high T sub c oxide to form impurity phases in the grain boundaries, trying to find out the effects of the impurity phases or metalloid grain boundaries on the critical current density of the high T sub c superconductors. The experimental results indicate that in the case of of the presence of the metalloid grain boundaries finning down grains fails to enhance the j sub c, but restrains it strongly, the granular high T sub c superconductors with the small size grains coupled weakly is always the low j sub c system.

Zhao, Y.↗

Evolution of comets into asteroids

This paper presents observational evidence, together with recent theoretical developments, supporting the hypothesis that at least some asteroids might be extinct or dormant cometary nuclei. The observations include the discovery of a number of apparent asteroids in chaotic Jupiter-crossing orbits; the IRAS discovery of 1983 TB, an asteroid in the same orbit as the Geminid meteor shower; the apparent low activity levels determined for several short-period comet nuclei including Comet Halley; and observations of possible cometary activity in some earth-crossing asteroids. Theoretical developments include explorations of dynamical mechanisms capable of delivering main-belt asteroids into earth-crossing orbits, and an understanding of possible processes which may affect comets during their long residence in the Oort cloud and lead to the formation of nonvolatile crusts before and after they enter the planetary system.

Weissman, Paul R.↗

Network accessible multi-terabyte archive

Features of the Rotary Storage System (RSS), developed by Metrum Information Storage, are presented in vugraph format. The RSS makes use of the T-120 Super-VHS media with 10.4 GB per cartridge. Other features of the RSS are as follows: (1) Very Large Data Store (VLDS) tape drives; (2) robots with on-line capacity to 6.2 TB; (3) bar code reader; (4) data management computer; and (5) network accessible.

Rybczynski, Fred↗

Microwave radiative transfer studies of precipitation

Since the deployment of the DMSP SSM/I microwave imagers in 1987, increased utilization of passive microwave radiometry throughout the 10 - 100 GHz spectrum has occurred for measurement of atmospheric constituents and terrestrial surfaces. Our efforts have focused on observations and analysis of the microwave radiative transfer behavior of precipitating clouds. We have focused particular attention on combining both aircraft and SSM/I radiometer imagery with ground-based multiparameter radar observations. As part of this and the past NASA contract, we have developed a multi-stream, polarized radiative transfer model which incorporates scattering. The model has the capability to be initialized with cloud model output or multiparameter radar products. This model provides the necessary 'link' between the passive microwave radiometer and active microwave radar observations. This unique arrangement has allowed the brightness temperatures (TB) to be compared against quantities such as rainfall, liquid/ice water paths, and the vertical structure of the cloud. Quantification of the amounts of ice and water in precipitating clouds is required for understanding of the global energy balance.

Bringi, V. N.↗